• Title/Summary/Keyword: large grains

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Effects of artificial holes in very large single-grain Y1.5Ba2Cu3O7-y bulk superconductors

  • Park, S.D.;Park, H.W.;Jun, B.H.;Kim, CJ.
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.3
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    • pp.27-32
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    • 2017
  • The effects of artificial holes on the trapped magnetic fields and magnetic levitation forces of very large single-grain $Y_{1.5}Ba_2Cu_3O_{7-y}$ (Y1.5) bulk superconductors were studied. Artificial holes were made for Y1.5 powder compacts by die pressing using cylindrical dies with a diameter of 30 mm or 40 m, or rectangular dies with a side length of 50 mm. The single grain Y1.5 bulk superconductors (25 mm, 33 mm in diameter and 42 mm in side length) with artificial holes were fabricated using a top-seeded melt growth (TSMG) process for the die-pressed Y1.5 powder compacts. The magnetic levitation forces at 77 K of the 25 mm single grain Y1.5 samples with one (diameters of 4.2 mm) or six artificial holes (diameters of 2.5 mm) were 10-17% higher than that of the Y1.5 sample without artificial holes. The trapped magnetic fields at 77 K of the Y1.5 samples with artificial holes were also 9.6-18% higher than that of the Y1.5 sample without artificial holes. The 33 mm and 42 mm single grain Y1.5 samples with artificial holes (2.5 mm and 4.2 mm in diameter) also showed trapped magnetic fields 10-13% higher than that of the Y1.5 samples without artificial holes in spite of the reduced superconducting volume fraction due to the presence of artificial holes. The property enhancement in the large single grain Y1.5 bulk superconductors appears to be attributed to the formation of the pore-free regions near the artificial holes and the homogeneous oxygen distribution in the large Y123 grains.

Preparation and Characterization of Tungsten Carbide Using Products of Hard Metal Sludge Recycling Process (초경합금 슬러지 재활용 공정 산물을 활용한 텅스텐 탄화물 제조 및 특성 평가)

  • Kwon, Hanjung;Shin, Jung-Min
    • Resources Recycling
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    • v.31 no.4
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    • pp.19-25
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    • 2022
  • In this study, tungsten carbide (WC) powder was prepared using a novel recycling process for hard metal sludge that does not use ammonium paratungstate. Instead of ammonia, acid was used to remove the sodium and crystallized tungstate, resulting in the formation of tungstic acid (H2WO4). The WC powder was successfully synthesized by the carbothermal reduction of tungstic acid through H2O decomposition, reduction of WO3 to W, and formation of WC. The carbon content and holding time at the carbothermal reduction temperature were optimized to remove free carbon from the WC powder. As a result, most of the free carbon in the WC powder prepared from sludge was removed, and the content of free carbon in the synthesized WC powder was lower than that in commercial WC powder. Moreover, the crystallite size of WC prepared from H2WO4 was much smaller than that of commercial micron-sized WC powder produced from APT. The small crystallite size of WC induces grain growth during the sintering of the WC-Co composite; thus, a WC-Co composite with large WC grains was fabricated using the WC powder prepared from H2WO4. The large WC grains affected the mechanical properties of the WC-Co composite. Further, due to the large grain size, the WC-Co composite fabricated from H2WO4 exhibited a higher toughness than that of the WC-Co composite prepared from commercial WC powder.

High-rate growth $YBa_2$$Cu_3$$O_{7-x}$ thick films and thickness dependence of critical current density (Y$Ba_2$$Cu_3$$O_{7-x}$ 후막의 고속 증착과 임계 전류 밀도의 두께 의존성)

  • Jo W.
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.13-18
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    • 2004
  • High-.ate in-situ$ YBa_2$Cu$Cu_3$$O_{7-x}$ (YBCO) film growth was demonstrated by means of the electron beam co-evaporation. Even though our oxygen pressure is low, ∼$5 ${\times}$10^{-5}$ Torr, we can synthesize as-grown superconducting YBCO films at a deposition rate of around 10 nm/s. Relatively high temperatures of around 90$0^{\circ}C$ was necessary in this process so far, and it suggests that this temperature at a given oxygen activity allows a Ba-Cu-O liquid formation along with an YBCO epitaxy. Local critical current density shows a clear correlation with local resistivity. Homogeneous transport properties with a large critical current density ($4 ∼ 5 MA/\textrm{cm}^2$ at 77K, 0T) are observed in top faulted region while it is found that the bottom part carries little supercurrent with a large local resistivity. Therefore, it is possible that thickness dependence of critical current density is closely related with a topological variation of good superconducting paths and/or grains in the film bodies. The information derived from it may be useful in the characterization and optimization of superconducting films for electrical power and other applications.

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Development of World's Largest 21.3' LTPS LCD Using Sequential Lateral Solidification (SLS) Technology

  • Kang, Myung-Koo;Kim, H.J.;Chung, J.K.;Kim, D.B.;Lee, S.K.;Kim, C.H.;Chung, W.S.;Hwang, J.W.;Joo, S.Y.;Maeng, H.S.;Song, S.C.;Kim, C.W.;Chung, Kyu-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.241-244
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    • 2003
  • The world largest 21.3" LTPS LCD has been successfully developed using SLS crystallization technology. Successful integration of gate circuit, transmission gate and level shifter was performed in a large area uniformly. Uniformity and high performance from high quality grains of SLS technology make it possible to come true a uniform large size LTPS TFT-LCD with half number of data driver IC's used in typical a-Si LCD. High aperture ratio of 65% was obtained using an organic inter insulating method, which lead a high brightness of 500cd/cm2.

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Characteristics of Spikelets and Vascular Bundles in Panicle of Japonica Rice Cultivar, 'Iksan 435'

  • Park, Hong-Kyu;Kang, Si-Yong;Choi, Weon-Young;Kim, Sang-Su;Cho, Soo-Yeon;Choi, Won-Yul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.2
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    • pp.117-121
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    • 1999
  • Spikelet and vascular bundle development in rice panicles is considered to be the important elements in determining the genotype's yield capacity and translocation ability of assimilates into grains, respectively. This study was conducted to clarify the varietal differences of the spikelet and vascular bundle formations among three rice cultivars; Iksan 435 (japonica), Dongjinbyeo (japonica) and Namcheonbyeo (Tongl-type). Iksan 435 had more primary rachis branches (PRBs), secondary rachis branches (SRBs) and spikelets per panicle than Dongjinbyeo, but less than Namcheonbyeo. Among three cultivars, Namcheonbyeo showed the highest spikelet number per panicle which were differentiated SRBs mainly on PRBs of lower rachis nodes. And Namchenbyeo showed the highest number of large vascular bundle (LVB) as well as small vascular bundle (SVB) and it displayed the largest diameter of LVB. Between the two japonica cultivars, the numbers of LVBs end SVBs were significantly higher in Iksan 435 than those in Dongjinbyeo. The PRBs to LVBs ratio of Namcheonbyeo was twice as large as those of Dongjinbyeo and Iksan 435. These results indicate that the newly bred cultivar, Iksan 435, has improved yield capacity by increasing the number of especially rachis branches and spikelets formation as well as 1,000 grain weight, compared to other former japonicas.

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Electrochemical Properties of 3D Cu-Sn Foam as Anode for Rechargeable Lithium-Ion Battery (3D-foam 구조의 구리-주석 합금 도금층을 음극재로 사용한 리튬이온배터리의 전기화학적 특성 평가)

  • Jung, Minkyeong;Lee, Gibaek;Choi, Jinsub
    • Journal of Surface Science and Engineering
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    • v.51 no.1
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    • pp.47-53
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    • 2018
  • Sn-based lithium-ion batteries have low cost and high theoretical specific capacity. However, one of major problem is the capacity fading caused by volume expansion during lithiation/delithiation. In this study, 3-dimensional foam structure of Cu-Sn alloy is prepared by co-electrodeposition including large free space to accommodate the volume expansion of Sn. The Cu-Sn foam structure exhibits highly porous and numerous small grains. The result of EDX mapping and XPS spectrum analysis confirm that Cu-Sn foam consists of $SnO_2$ with a small quantity of CuO. The Cu-Sn foam structure electrode shows high reversible redox peaks in cyclic voltammograms. The galvanostatic cell cycling performances show that Cu-Sn foam electrode has high specific capacity of 687 mAh/g at a current rate of 50 mA/g. Through SEM observation after the charge/discharge processes, the morphology of Cu-Sn foam structure is mostly maintained despite large volume expansion during the repeated lithiation/delithiation reactions.

Development of High Strength Mg-Zn-Gd Alloys by Rapid Solidification Processing

  • Kim, Min-Chul;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1048-1049
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    • 2006
  • Rapidly solidified ribbon-consolidation processing was applied for preparation of high strength bulk Mg-Zn-Gd alloys. Mg alloys have been used in automotive and aerospace industries. Rapid solidification (RS) process is suitable for the development of high strength Mg alloys, because the process realizes grain-refinement, increase in homogeneity, and so on. Recently, several nanocrystalline Mg-Zn-Y alloys with high specific tensile strength and large elongation have been developed by rapidly solidified powder metallurgy (RS P/M) process. Mg-Zn-Y RS P/M alloys are characterized by long period ordered (LPO) structure and sub-micron fine grains. The both additions of rare earth elements and zinc remarkably improved the mechanical properties of RS Mg alloys. Mg-Zn-Gd alloy also forms LPO structure in -Mg matrix coherently, therefore, it is expected that the RS Mg-Zn-Gd alloys have excellent mechanical properties. In this study, we have developed high strength RS Mg-Zn-Gd alloys with LPO structure and nanometer-scale precipitates by RS ribbon-consolidation processing. $Mg_{97}Zn_1Gd_2$ and $Mg_{95.5}Zn_{1.5}Gd_3$ and $Mg_{94}Zn_2Gd_4$ bulk alloys exhibited high tensile yield strength (470 MPa and 525 MPa and 566 MPa) and large elongation (5.5% and 2.8% and 2.4%).

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Far-infrared Study of Supernova Remnants in the Large Megellanic Cloud

  • Kim, Yesol;Koo, Bon-Chul;Seok, Ji Yeon
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.1
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    • pp.53-53
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    • 2013
  • We present preliminary results of far-infrared(FIR) study of the supernova remnant(SNR)s in the Large Magellanic Cloud using the Herschel HERITAGE (HERschel Inventory of The Agents of Galaxy Evolution) data set. HERITAGE provides FIR data covering the entire LMC at 100,160, 250, 350, and 500 um. In order to confirm FIR emission associated with SNRs, we refer to Magellanic Cloud Emission-Line Survey (MCELS) H-alpha & SII data, Spitzer surveying the Agents of a Galaxy's Evolution (SAGE) Multiband Imaging Photometer (MIPS) 24um & 70um data, Chandra Supernova Remnants Catalog, and ATCA 4.8GHz continuum images of Dickel et al. (2005). Among 47 SNRs in the LMC, 7 SNRs show associated FIR emission. We present multi-wavelength view of 5 SNRs; DEM L249, N49, N63A, N132D, and the SNR in N4. N49 and N132D show morphological correlation in FIR and X-ray, suggesting that the FIR emission is from dust grains collisionally heated by X-ray emitting plasma. The FIR emission of N63A resembles H-alpha emission, which implies that the FIR line radiation could be dominant. The FIR images of the rest two objects, DEM L249 and SNR in N4, show no correlation to the other-waveband images.

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On the Possibility of Bulk Large Diamond Single Crystal Synthesis with Hydrothermal Process

  • Andrzej M. Szymanski
    • Journal of the Mineralogical Society of Korea
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    • v.10 no.1
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    • pp.18-32
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    • 1997
  • Analysis of geological data, relating to occurrence and formation of diamonds as well as host rocks, inclined author to have different outlook on the diamond genesis and to establish a proposition on their formation at pneumatolytic-hydrothermal conditions near superficial Earth zones. Based on that theoretical foundations and experimental works, the first low-pressure and low-temperature hydrothermal diamond synthesis from water solution in pressure autoclave was executed. As a result, the natural diamond seed crystal grew bigger ad coupling of the synthetic diamond single-crystalline grains were obtained. SEM documentation proofs that parallely paragenetic crystallization of quartz and diamond, and nucleation of new octahedral diamond crystals brush take place on the seed crystal surface. Forecast of none times growth of diamond industrial application at 2000 and seventeen times at 2010 with reference to 1995, needs technology of large and pure single-crystals diamond synthesis. Growth of the stable and destressed diamond single-crystals in the pseudo-metastable diamond plot, may be realized with processes going through the long time and with participation of free radicals catalysts admixtures only. Sol-gel colloidal processes are an example of environment which form stable crystals in thermodynamically unstable conditions through a long time. Paper critically discusses a whole way of studies on the diamond synthesis, from high-pressure and high-temperature processes through chemical vapour deposition up to hydrothermal experiments.

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The decreased molar ratio of phytate:zinc improved zinc nutriture in South Koreans for the past 30 years (1969-1998)

  • Do, Mi-Sook;Lomeda, Ria-Ann R.;Cho, Young-Eun;Kwun, In-Sook
    • Nutrition Research and Practice
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    • v.1 no.4
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    • pp.356-362
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    • 2007
  • For the assessment of representative and longitudinal Zn nutriture in South Koreans, Zn, phytate and Ca intakes were determined using four consecutive years of food consumption data taken from Korean National Nutrition Survey Report (KNNSR) every 10 years during 1969-1998. The nutrient intake data are presented for large city and rural areas. Zn intake of South Koreans in both large city and rural areas was low during 1969-1988 having values between 4.5-5.6 mg/d, after then increased to 7.4 (91% Estimated Average Requirements for Koreans, EAR = 8.1 mg/d) and 6.7 mg/d (74% EAR) in 1998 in large city and rural areas, respectively. In 1968, Zn intake was unexpectedly higher in rural areas due to higher grain consumption, but since then until 1988 Zn intake was decreased and increased back in 1998. Food sources for Zn have shifted from plants to a variety of animal products. Phytate intake of South Koreans during 1969-1978 was high mainly due to the consumption of grains and soy products which are major phytate sources, but decreased in 1998. The molar ratios of phytate:Zn and millimmolar ratio of phytate${\times}$Ca:Zn were decreased due to the decreased phytate intake in South Koreans, which implies higher zinc bioavailability. The study results suggest that Zn nutriture has improved by increased dietary Zn intakes and the decreased molar ratio of phytate:Zn in South Koreans in both large city and rural areas.