• Title/Summary/Keyword: large grains

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Abnormal Grain Growth in Ferrites (페라이트 이상 입성장)

  • Shigeru Ito
    • Resources Recycling
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    • v.9 no.5
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    • pp.16-21
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    • 2000
  • Generation of abnormally large grains in the microstructure of small grains has been investigated on some ferrites. Some fractions of large grains were observed in the microstructue of sintered ZnFe$_2$O$_4$, Mn-ZnFe$_2$O$_4$, Fe$_3$O$_4$(in $N_2$) and MnFe$_2$O$_4$(in air). On the other hand, the large grains were not observed in $NiFe_2$$O_4$ and $CoFe_2$$O_4$, independent of calcining and sintering conditions. The large grains seem to be generated in such ferrites that are easy to very their compositions or valencies at high temperatures. as the sintering proceeded, the number of large grains was increasing to from a continuous structure consisting of large grains, while the size of large grains did not increase remarkably. In addition, the growth of small grains was also very slow during the generation of the large grains. The large grains appeared be suddenly generated after some induction periods. Avrami equation could be applied to the relation between net volume of large grains and sintering time. Thus, the grain boundaries may be strongly stabilized when the large grains are generated. The large grain is generated y the local activation of the stabilized rain boundaries, which is caused by the variation of composition or valencies during sintering. It is concluded that the essence of the abnormal gain growth is not the generation of abnormally large grains, but the abnormal stabilization and the local activation of he grain boundaries.

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Abnormal Grain Growth in Ferrites

  • Ito, Shigeru
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 1999.09a
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    • pp.1-63
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    • 1999
  • Generation of abnormally large grains in the microstructure of small grains has been investigated on some ferrites. Some fractions of large grains were observed in the microstructure of sintered ZnFe$_2$O$_4$, Mn-ZnFe$_2$O$_4$, Fe$_3$O$_4$(in N$_2$) and MnFe$_2$O$_4$(in air). On the other hand, the large grains were not observed in NiFe$_2$O$_4$ and CoFe$_2$O$_4$, independent of calcining and sintering conditions. The large grains seem to be generated in such ferrites that are easy to vary their compositions or valencies at high temperatures. As the sintering proceeded, the number of large grains was increasing to form a continuous structure consisting of large grains, while the size of large grains did not increase remarkably. In addition, the growth of small grains was also very slow during the generation of the large grains. The large grains appeared to be suddenly generated after some induction periods. Avrami equation could be applied to the relation between net volume of large grains and sintering time. Thus, the grain boundaries may be strongly stabilized when the large grains are generated. The large grain in generated by the local activation of the stabilized grain boundaries, which is caused by the variation of compositions or valencies during sintering. It is concluded that the essence of the abnormal grain growth is not the generation of abnormally large grains, but the abnormal stabilization and the local activation of the grain boundaries.

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Microstructure Features of Large Grains in WC-Co Alloys

  • Delanoe, A.;Lay, S.;Missiaen, J.M.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.650-651
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    • 2006
  • This paper presents a study of large grains by transmission electron microscopy in two WC-Co alloys, one W rich and one C rich. In the W rich alloy, some large grains are found in contact with the $\eta$ phase. The C content influences the morphology of large grains: they are flatter in the C rich alloy with smoother interfaces. Whatever the C content, they contain few dislocations compared to matrix grains except often in a small area. Small WC grains are often found inside the large grains. They have likely been engulfed during the growth of the large grains owing to the low boundary energy.

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여천지역 준설.매립토의 침강압밀 특성

  • Song, Jeong-Rak;Baek, Seung-Hun;Yeo, Yu-Hyeon
    • Proceedings of the Korean Geotechical Society Conference
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    • 1992.10a
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    • pp.55-60
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    • 1992
  • Hydraulically filled ground is formed by the settling of soil grains from the mixture of soil grains and water. It was generally known that the settling speed of the soil grains in governed by Stokes low. In the case of clayed dredged material, the shape of soil grains is not round, the surface of the soil grains is relatively large compared to the weight of soil grains and inter-grain ionic force is relatively large compared to the wight of soil grains. By this reason the settling and consolidation behavior of hydraulically filled quite different from that of Stokes law. This study investigated the settling and consolidation behavior of hydraulically filled materials of Yeochon industrial complex by large scale laboratory settling & consolidation container. The test results showed tat actual settling speed of soil grains in quite large compared to that of Stokes law. It was turned out that this phenomenon was due to the aggregation of soil grains. Also, it was truned out that the void ration and water content after the completion of settling process was 8.7 and 322% respectively. The consolidtion settlement of clayey hydraulic fill material was predicated better by "incremental small strain" consolidation concept than classical Terzaghj's consolidation concept (infinitesimal strain).

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Grain Growth Revealed by Multi-wavelength Analysis of Non-axisymmetric Substructures in the Protostellar Disk WL 17

  • Han, Ilseung;Kwon, Woojin;Aso, Yusuke
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.59.2-59.2
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    • 2020
  • Disks around protostars are the birthplace of planets. The first step toward planet formation is grain growth from ㎛-sized grains to mm/cm-sized grains in a disk, particularly in dense regions. In order to study whether grains grow and segregate at the protostellar stage, we investigate the ALMA Band 3 (3.1 mm) and 7 (0.87 mm) dust continuum observations of the protostellar disk WL 17 in ρ Ophiuchus L1688 cloud. As reported in a previous study, the Band 3 image shows substructures: a narrow ring and a large central hole. On the other hand, the Band 7 image shows different substructures: a non-axisymmetric ring and an off-center hole. The two-band observations provide a mean spectral index of 2.3, which suggests the presence of mm/cm-sized large grains. Its non-axisymmetric distribution may imply dust segregation between small and large grains. We perform radiative transfer modeling to examine the size and spatial distributions of dust grains in the WL 17 disk. The best-fit model suggests that large grains (>1 cm) exist in the disk, settling down toward the midplane, whereas small grains (~10 ㎛) well mixed with gas are distributed off-center and non-axisymmetrically in a thick layer. The low spectral index and the modeling results suggest that grains rapidly grow at the protostellar stage and that grains differently distribute depending on sizes, resulting in substructures varying with observed wavelengths. To understand the differential grain distributions and substructures, we discuss the effects of the protoplanet(s) expected inside the large hole and the possibility of gravitational instability.

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The Effects of Seed Size on the Early Seedling Growth and Yield of Three Soybean(Glycine max. L.) Cultivars (대두종자(大豆種子)의 대소(大小)가 초기생육(初期生育) 및 수량(收量)에 미치는 영향(影響))

  • Park, Ki Sun;Choi, Chang Yeol;Kang, Jea Chul
    • Korean Journal of Agricultural Science
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    • v.16 no.2
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    • pp.138-151
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    • 1989
  • In order to find the effects of seed size on the early seedling growth and yield of soybean, three soybean cultivars in Korea were investigated. Seed size was classified into large and small according to the weight and planted in pots(1/5000a) and in the field. Three soybean cultivars respresenting large, medium and small grains were Hwangkeum-kong, Kwangkyo and Bangsa-kong respectively. These cultivars were planted on June 20, 1987. 1. The plant height, stem diameter, root length and leaf area index(LAI) of the seed with large size seemed larger than the seed with small size regardless of cultivars. 2. The fresh and dry weight were different depending upon the grain sizes. The large grain had heavier fresh and dry weight than the small grains. 3. The protein consumption rate of the cotyledon of Bangsa-kong with small grain size was faster than the Hwangkeum-kong with large grain size. 4. The stem length, stem diameter and number of main stem node of the seed with large size seemed larger than the seed with small size. Large grains of Hwangkeum-kong were the highest in the number of branch node and number of node. 5. The number of pods and grains per plant of Bangsa-kong with small grain size was larger than the Kwangkyo with large grain size. 6. The yield per 10a for Hwangkeum-kong, Hwangkyo and Bangsa-kong were 226.3kg, 193.0kg and 192.8kg, respectively and they were all statistically different. The yield increases of large grains over small grains in the Hwangkeum-kong, Kwangkyo, and Bangsa-kong were 7.4%, 8.0% and 9.2%, respectively.

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Discovery of a New Mechanism of Dust Destruction in Strong Radiation Fields and Implications

  • Hoang, Thiem;Tram, Le Ngoc;Lee, Hyseung;Ahn, Sang-hyeon
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.44.3-44.3
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    • 2019
  • Massive stars, supernovae, and kilonovae are among the most luminous radiation sources in the universe. Observations usually show near- to mid-infrared (NIR-MIR, 1-5~micron) emission excess from H II regions around young massive star clusters (YMSCs) and anomalous dust extinction and polarization towards Type Ia supernova (SNe Ia). The popular explanation for such NIR-MIR excess and unusual dust properties is the predominance of small grains (size a<0.05micron) relative to large grains (a>0.1micron) in the local environment of these strong radiation sources. The question of why small grains are predominant in these environments remains a mystery. Here we report a new mechanism of dust destruction based on centrifugal stress within extremely fast rotating grains spun-up by radiative torques, namely the RAdiative Torque Disruption (RATD) mechanism, which can resolve this question. We find that RATD can destroy large grains located within a distance of ~ 1 pc from a massive star of luminosity L~ 10^4L_sun and a supernova. This increases the abundance of small grains relative to large grains and successfully reproduces the observed NIR-MIR excess and anomalous dust extinction/polarization. We show that small grains produced by RATD can also explain the steep far-UV rise in extinction curves toward starburst and high redshift galaxies, as well as the decrease of the escape fraction of Ly-alpha photons observed from HII regions surrounding YMSCs.

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Preparation of Silicon Carbide Ceramics with Self-reinforced Microstructure by the Control of Starting Phases (출발상 제어에 의한 자기복합화 미세구조의 탄화규소 세라믹스 제조)

  • Lee, Jong-Kook;Kang, Hyun-Hee;Lee, Eun-Gu;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.34 no.12
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    • pp.1240-1246
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    • 1997
  • Silicon carbides with self-reinforced microstructure which hore a small grain matrix and dispersed large grains with rod-like type were prepared by the liquid-phase sintering and the control of starting phases of raw materials. The specimens with self-reinforced microstructure could be obtained from the compacts with mixed compositions of $\alpha$-SiC and 10-50 % $\beta$-SiC powders and by the pressureless sintering at 185$0^{\circ}C$ for 5h. Large grains with rod or plate-like types were 4H-SiC and small grains with equi-axed type were 6H-SiC. Fracture grains with rod or plate-like types were 4h-SiC and small grains with equi-axed type were 6H-SiC. Fracture toughness of specimens with self-reinforced microstructure was increased by the crack deflection and formation of microcracking due to the existence of rod-like large grains during crack propagation.

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Suppression of the Abnormal Grain Growth in the Sintering of Yttrium Iron Garnet (Yttrium Iron Garnet의 소결시 나타나는 비정상 입성장 현상과 그의 억제)

  • 김동영;이홍열;전동석;이상석
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12
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    • pp.1131-1135
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    • 2003
  • In the sintering of YIG, abnormal grain growth phenomena were observed. This abnormal grain growth is related to the sintering temperature in this experiment. In the sintering below 1450$^{\circ}C$, the sintered body showed narrow size distribution. However, in the sintering at 1450$^{\circ}C$, a few grains grew rapidly with respect to other grains, and bimodal size distribution was appeared. From the observation of the microstructure, liquid phase was not observed far from the abnormally grown large grains, but only near the large grains. This means that the abnormal grain growth was caused by the nonuniform distribution of liquid phase which promote the grains growth. Because the growth rate of grains near the liquid phase is much higher than that of the other grains, a few grains grow rapidly. This nonuniform distribution of liquid phase was thought to be due to the nonuniform mixing of the calcined powders. This abnormal grain growth was suppressed by enhancement of the compositional uniformity by multiple calcination.

Effect of Large $\alpha$-Silicon Carbide Seed Grains on Microstructure and Fracture Toughness of Pressureless-Sintered $\alpha$-Silicon Carbide

  • Young-Wook Kim;Kyeong Sik Cho;June-Gunn Lee
    • The Korean Journal of Ceramics
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    • v.2 no.1
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    • pp.39-42
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    • 1996
  • ${\alpha}-SiC$ powder with or without the addition of 0.1 wt% of large ${\alpha}-SiC$ partices(seeds) was pressureless-sintered at $1950^{\circ}C$ for 0.5, 2, and 4 h using $Y_3Al_5 O_{12}$ (yttrium aluminum garnet, YAG) as a sintering aid. The materials without seeds had an equiaxed grain struture. In contrast, the materials with seeds sintered for 2 and 4 h had a duplex microstructure with large elongated grains and amall equiaxed grains. Addition of large ${\alpha}-SiC$ seeds into ${\alpha}-SiC$ accelerated the grain growth of some ${\alpha}-SiC$ grains during sintering and resulted in the increased fracture toughness of the sintered materials. The fracture toughnesses of materials with or without seeds sintered for 4 h were 6.6 and $5.2 MPa \;m^{12}$, respectively.

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