• 대한기계학회논문집
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• 제16권6호
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• pp.1021-1029
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• 1992

본 연구에서는 거대한 평판형 격자구조물에 대한 등가 연속체모델을 유도하기 위한 보다 간편하고 합리적인 방법을 개발하고, 예제해석을 통해 새로이 개발된 방법 의 타당성을 보이는데 있다.

• Wind and Structures
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• 제26권1호
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• pp.1-9
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• 2018

This research studies the dynamic analysis of a concrete column reinforced with titanium dioxide ($TiO_2$) nanoparticles under earthquake load. The effect of nanoparticles accumulation in a region of concrete column is examined using Mori-Tanaka model. The structure is simulated mathematically based on the theory of sinusoidal shear deformation theory (SSDT). By calculating strain-displacement and stress-strain relations, the system energies include potential energy, kinetic energy, and external works are derived. Then, using the Hamilton's principle, the governing equations for the structure are extracted. Using these equations, the response of the concrete column under earthquake load is investigated using the numerical methods of differential quadrature (DQ) and Newark. The purpose of this study is to study the effects of percentage of nanoparticles, nanoparticles agglomeration, geometric parameters and boundary conditions on the dynamic response of the structure. The results indicate that by increasing the volume percent of $TiO_2$ nanoparticles, the maximum dynamic deflection of the structure decreases.

• 대한방사선기술학회지:방사선기술과학
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• 제21권2호
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• pp.53-56
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• 1998

Highly sensitive $CaSO_4:Tm$ TLD is fabricated and their trap parameters are determined. The glow curve of $CaSO_4:Tm$ consists of three glow peaks and these peaks are isolated by the thermal bleaching method. The isolated glow peaks are fitted by a least squares method. The activation energies are 0.68, 0.82 and 1.03 eV. The frequency factors are $8.09{\times}10^8,\;9.14{\times}10^8$ and $1.03{\times}10^9/s$, and the kinetic orders are 1.37, 1.54 and 1.68, respectively. The optimum temperature range of the main peak for radiation dosimetry is between 220 and $290^{\circ}C$.

• 대한화학회지
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• 제9권1호
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• pp.23-28
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• 1965

90% ethanol solution에서 benzyl chloride와 radioactive chloride($^{36}Cl^-$)와의 exchange를 反應速度論的으로 硏究하였으며 그 結果로 交換反應은 typical bimolecular reaction임을 알았고 그 activation parameter들은 각기 다음과 같았다. ${\Delta}H^{\neq}$= 18.50 Kcal ${\Delta}S^{\neq}$= -22.09 e.u. 특히 本實驗 缺課와 다른 實驗結果를 綜合討論함으로써 反應速度는 attacking anion의 nuclephilic ability에 크게 관계 됨을 입증할 수 있었으며 또한 exchange reaction에 있어서 halide들의 reactivity의 순서는 bond dissociation energy의 差로써 보다는 오히려 Swain의 nucleophilic parameter(n)로써 설명함이 더욱 타당함을 알았다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2008년도 춘계학술대회논문집
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• pp.96-100
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• 2008

In this paper, a experimental and theoretical study is carried out on the hydroelastic vibration for a rectangular bottom and side plate of tank. It is assumed that the tank wall is clamped along the plate edges. The fluid velocity potential is used for the simulation of fluid domain and to obtain the added mass due to plate vibration. It is assumed that the fluid is imcompressible and inviscid. Assumed mode method is utilized to the plate model and hydrodynamic force is obtained by the proposed approach. The coupled natural frequencies are obtained from the relationship between kinetic energies of a wall including fluid and the potential energy of the wall. The theoretical result is compared with the three-dimensional finite element method. In order to verify the result, modal test was carried out for bottom/side plate of tank model by using impact hammer. It was found the fundamental natural frequency of bottom plate is lower than that of side plate of tank and theoretical result was in good agreement with that of commercial three-dimensional finite element program.

• 전기화학회지
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• 제15권1호
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• pp.54-66
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• 2012

The phase-shift method and correlation constants, which are unique electrochemical impedance spectroscopy techniques for studying the linear relationship between the phase shift ($90^{\circ}{\geq}-{\varphi}{\geq}0^{\circ}$) vs. potential (E) behavior for the optimum intermediate frequency ($f_o$) and the fractional surface coverage ($0{\leq}{\theta}{\leq}1$) vs. E behavior, are proposed and verified to determine the Frumkin, Langmuir, and Temkin adsorption isotherms and the related electrode kinetic and thermodynamic parameters. At Ni/0.5 M $H_2SO_4$ and 0.1M LiOH aqueous solution interfaces, the Frumkin and Temkin adsorption isotherms (${\theta}$ vs. E) of H for the cathodic hydrogen ($H_2$) evolution, interaction parameters (g), equilibrium constants (K), standard Gibbs energies (${\Delta}G^0_{\theta}$) of H adsorption, and rates of change (r) of ${\Delta}G^0_{\theta}$ with ${\theta}$ have been determined using the phase-shift method and correlation constants. A lateral repulsive interaction (g>0) between the adsorbed H species appears. The value of K in the alkaline aqueous solution is much greater than that in the acidic aqueous solution.

• Computers and Concrete
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• 제2권2호
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• pp.125-146
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• 2005

The objective of this paper is setting out, for a cable-stayed bridge with a curtain suspension, a method to determine the modes of vibration of the structure. The system of differential equations governing the vibrations of the bridge, derived by means of a variational formulation in a nonlinear field, is reported in Appendix C. The whole analysis results from the application of Hamilton's principle, using the expressions of potential and kinetic energies and of the virtual work made by viscous damping forces of the various parts of the bridge (Monaco and Fiore 2003). This paper focuses on the equation concerning the transversal motion of the girder of the cable-stayed bridge and in particular on its final form obtained, restrictedly to the linear case, neglecting some quantities affecting the solution in a non-remarkable way. In the hypotheses of normal mode of vibration and of steady-state, we propose the resolution of this equation by a particular method based on a numerical approach. Respecting the boundary conditions, we derive, for each mode of vibration, the corresponding frequency, both natural and damped, the shape-function of the girder axis and the exponential function governing the variability of motion amplitude in time. Finally the results so obtained are compared with those deriving from the dynamic analysis performed by a finite elements calculation program.

• Bulletin of the Korean Chemical Society
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• 제23권11호
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• pp.1513-1518
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• 2002

Kinetic studies on the water-gas shift reaction catalyzed by magnetite/chromium oxide and copper/zinc oxide were carried out by using an in situ photoacoustic spectroscopic technique. The reactions were performed in a closed-circulation reactor system using a differential photoacoustic cell at total pressure of 40 Torr in the temperature range of 100 to $350^{\circ}C.$ The CO2 photoacoustic signal varying with the concentration of CO2 during the catalytic reaction was recorded as a function of time. The time-resolved photoacoustic spectra obtained for the initial reaction stage provided precise data of CO2 formation rate. The apparent activation energies determined from the initial rates were 74.7 kJ/mol for the magnetite/chromium oxide catalyst and 50.9 kJ/mol for the copper/zinc oxide catalyst. To determine the reaction orders, partial pressures of CO(g) and H2O(g) in the reaction mixture were varied at a constant total pressure of 40 Torr with N2 buffer gas. For the magnetite/chromium oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.93 and 0.18, respectively. For the copper/zinc oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.79 and 0, respectively.

• 한국소음진동공학회논문집
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• 제15권4호
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• pp.457-464
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• 2005

A three-dimensional (3-D) method of analysis is presented for determining the free vibration frequencies and mode shapes of thick, complete (not truncated) conical shells of revolution, Unlike conventional shell theories, which are mathematically two-dimensional (2-D). the present method is based upon the 3-D dynamic equations of elasticity. Displacement components $u_{r},\;u_{z},\;and\;u_{\theta}$ in the radial, axial, and circumferential directions, respectively, are taken to be sinusoidal in time, periodic in , and algebraic polynomials in the r and z directions. Potential (strain) and kinetic energies of the conical shells are formulated, the Ritz method is used to solve the eigenvalue problem, thus yielding upper bound values of the frequencies by minimizing the frequencies. As the degree of the polynomials is increased, frequencies converge to the exact values. Convergence to four-digit exactitude is demonstrated for the first five frequencies of theconical shells. Novel numerical results are presented for thick, complete conical shells of revolution based upon the 3-D theory. Comparisons are also made between the frequencies from the present 3-D Ritz method and a 2-D thin shell theory.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.396-401
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• 2008

The disc-pad brake system is an important part of automobile safety system. During braking, the kinetic energy and potential energies of a moving vehicle are converted into the thermal energy through frictional heat between the brake disc and the pads. Most of the thermal energy dissipated through the brake disc. The temperature could be exceed the critical value for a given material, which leads to undesirable effects, such as the brake fade, premature wear, brake fluid vaporization, bearing failure, thermal cracks, and thermallyexcited vibration. The object of the present study is to investigate temperature field and temperature variation of brake disc and pad during single brake. The brake disc is decelerated at the initial speed with constant acceleration, until the disc comes to stop. The pad-disc brake assembly is built by 3D model with the appropriate boundary condition. In the simulation process, the mechanical loads are applied to the thermomechanical coupling analysis in order to simulate the process of heat produced by friction.