• Journal of environmental and Sanitary engineering
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• v.15 no.4
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• pp.123-133
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• 2000

The kinetic analysis was carried out for commercial rubbers such as NR, IR, BR, SBR 1500, and SBR 1700. Kinetic analysis for the commercial rubbers was performed using the thermogravimetric method, with which the activation energies of NR obtained by Kissinger, Friedman, and Ozawa's method were 195.0, 198.3 and 186.3kJ/mol, whereas that of SBR 1500 were 246.4, 247.5 and 254.8kJ/mol, respectively. It was shown that the yield of pyrolytic oil was generally increased with final temperature increasing, yet slightly decreased or increased over $700^{\circ}C$. Considering the effect of heating rate, it was found that the yield of pyrolytic oil was not consistent for each sample. The number average molecular weight of SBR 1500 was in the range of 740~2486. The calorific value of SBR 1500 was 39~40kJ/g, which were made comparative study of the conventional fuel such as kerosene, diesel, light fuel, and heavy fuel. Therefore it was essential that the selection of the suitable kinetic model and the mathematical solution because of the difference in parameters obtained from each method. It was proposed that the range of $600~700^{\circ}C$ in final temperature and high heating rate due to short run time. It was suggested that the pyrolytic oil be available to use to the fuel.

• Journal of Environmental Science International
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• v.19 no.1
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• pp.97-103
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• 2010

The biodegradable oil absorption resin was prepared by the suspension polymerization of the modified starch and 2-ethylhexyl acrylate (2-EHA). The highest oil-absorption capacity of B-PEHA prepared showed at the condition of the modified starch content of 10 g and ethyleneglycol dimethacrylate (EGDMA) of 0.133 wt%. Its maximum oil absorption capacity per g of oil absorber was chloroform 30.88 g, toluene 19.75 g, xylene 18.78 g, tetrahydofuran (THF) 15.96 g, octane 11.43 g, hexane 9.5 g diesel oil 12.80 g, and kerosene 13.79 g, respectively. The biodegradation of poly-2-ethylhexylacrylate (B-PEHA) determined by enzymatic hydrolysis showed approximately 17~20%. The results showed that the preparation of the biodegradable oil absorption resin is available using the modified starch.

• Resources Recycling
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• v.2 no.2
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• pp.39-44
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• 1993

This study was carried out to remove the water from low grade anthracite slurry produced at Eoryong coal mine by the oil agglomeration process. 80% of Anthracite as a coal oil mixture (COM) was separated from water by the difference of specific gravity. Then, the amount of kerosene, diesel oil, and heavy oil forming COM was 10% of the amount of sample, respectively. The recovery rate of combustibles and ash content of agglomerated anthracite were affected largely by the amount of added oil, pulp density, particle size, mixing time, and impeller speed. The recovery rate of combustibles was increased to 95% and ash content was decrea-sed from 30% to 13.5% under the optimum conditions.

• KSBB Journal
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• v.13 no.2
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• pp.209-213
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• 1998

The characteristics of de-emulsification of pertroleum emulsion by Nocardia amarae were investigated. Insoluble medium containing n-hexadecane was more effective than soluble medium in de-emulsification of emulsion containing diesel and bunker C as the organic phase. Emulsion made by the addition of xanthan or bioemulsifier was de-emulsified by N. amarae, and longer culture age was effective. In low viscosity range, organic phase with longer carbon chain was more effective. The contact, angle between bacterial film and water droplet in air increased from 16 degree for 4 day culture age to 26 degree for 15 day. The contact angle between bacterial film and water droplet in kerosene, n-heyxane or n-hexadecane also increased to greater than 100 degree after 3 day culture age. The hydrophobicity of bactgerial film increased according to the culture age.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.523-526
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• 2006

The target of this work was the process development of demonstration plant to produce the high quailty alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70t/y and the pi lot plant of 360 t/v had been developed. Main research contents in this step were the process performance test of pilot plant ot 360ton/year and the development of demonstration plant of 3 000 t/y which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/v showed components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1116-1123
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• 2021

Oil spilled in seawater undergoes physical and chemical changes as well as biological degradation through various weathering processes, such as evaporation, diffusion, dispersion, emulsification, dissolution, oxidation, and sedimentation. Evaporation is one of the most immediate and prompt weathering processes, and it has the greatest influence on majority of pollutants. In this study, the evaporation characteristics of different oil samples were studied; the volatilization characteristics of gasoline, kerosene, and diesel were compared at average seawater (25 ℃) and near-equator (35 ℃) temperatures. The oil samples were pre-treated and then collected at regular intervals. Gas chromatography-mass spectrometry analysis was performed, and the changes in the amount of the hydrocarbons were calculated.

• Fire Science and Engineering
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• v.28 no.3
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• pp.43-48
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• 2014

The purpose of this study is to analyze the flame propagation speed, radiation range, diffusion pattern and combustion completion time of a fire by filling a divided space with single combustible substance. It was found that the flame propagation speed was the fastest (0.2 s) for kerosene and the lowest (82.1 s) for alcohol. In the case of paint thinner, it took 19.0 s for the flame to reach its peak at the fastest speed after ignition while in the case of alcohol, it took 138.6 s for the flame to reach its peak at the lowest speed. In the case of the combustion of 200 ml of flammable liquids, the combustion completion time was 79.9 s for paint thinner, which is the shortest, 135 s for gasoline, 170 s for kerosene, 231.4 s for diesel and 337.0 s for alcohol. In addition, when flammable liquids are combusted, the lower part of the flame is governed by laminar flow pattern and the upper part of the flame showed turbulence pattern. In the case of a test performed for bean oil, it could be seen that if the fire source was removed, the flame was automatically extinguished without further combustion and that white smoke was generated due to incomplete combustion.

• Journal of Soil and Groundwater Environment
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• v.17 no.4
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• pp.63-72
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• 2012

The main objective of this study is to assess the compatibility between Korean ministry of environment (KME) standard and ISO (KS I ISO) standard for the determination of BTEX and TPH content in soil. We carried out comparison analysis for both methods using CRM and matrix spiked samples. In case of GC-MS analysis for BTEX, we got statistically (significance level: 0.05) the same results from KME standard (ES 07600.1) and ISO standard (KS I ISO 15009). However, it showed statistically (significance level: 0.05) different results when TPH was analyzed by KME standard (ES 07552.1) and ISO standard (KS I ISO 16703). To clarify the reason why both methods produced different results for TPH content, we also did some additional experiments in terms of differences in extraction, clean-up and target hydrocarbon range. Extraction with polar and non-polar compounds mixed solvent (acetone+n-heptane) of KS I ISO 16703 showed higher extraction efficiency than with only non polar solvent (dichloromethane) extraction of ES 07552.1 by about 9%. While column type clean-up of KS I ISO 16703 showed the reduction in TPH content between before and after clean-up, batch type of clean-up of ES 07552.1 did not show any changes in TPH content through clean-up process. The target hydrocarbon range of ES 07552.1 and KS I ISO 16703 is $C_8{\sim}C_{40}$ and $C_{10}{\sim}C_{40}$, respectively. From this point of view, kerosene and JP-8 contaminated soil showed higher RPD (relative producibility deviation) values between results by both method than that of lubricant or diesel contaminated soil. The higher content of hydrocarbon ($C_8{\sim}C_{10}$) in kerosene and JP-8 played an important role in increasing RPD values in addition to the effects caused by different solvents and clean-up method. Consequently, it was concluded that both methods (ES 07552.1 and KS I ISO 16703) were not compatible.

• Journal of Biosystems Engineering
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• v.5 no.2
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• pp.58-66
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• 1980

A survey was conducted to investigate the power tiller accidents. Eight provinces were covered for this study, and 278 power tiller owners were selected randomly by computer random generator. The results are summarized as follows : A. Frequency of accident. (1) Each power tiller had an accident 0.98 times a year and once every 361 hours of use. Higher frequency of accident was found during the miscellaneous operations including the preparation for farming operation, and there was one accident for every 92 hours of use. (2) The power tiller, which are more than six years old, met an accident 1.19 times a year , or one every 311 hours of use. This value was the highest one compared with any other group. (3) Kerosene engine power tillers met an accident 0.97 times a year, or one every 389 hours of use. It was one tie a year, or once every 329 hours of use for diesel engine power tillers. (4) Among diesel-engine power tillers, 10 horse-power group showed a higher frequency tillers. B. Cause of accident (1) The accidents of power tiller were mainly of sefety , which occurred due to the lack of attention during the operation and 47.4% of the total accidents. The next was of accidental, which represented 26.3% of the total accidents. (2) High percentage of safety accidents occurred during the preparation for farming operation including adjustment. Most of the accidental accidents occurred during the transportation. (3) Lower frequency of accident was found in the power tiller group which were operated by the 21-40 years old operator in comparison with that of the power tiller which was operated by other age group. Power tillers which were operated by high school graduates experienced less accidents compared to other education levels. C. Damage by accident (1) Eighty seven pescents of the total accidents caused damage to the power tiller operator , and 13 % of the total accidents caused property damage only. (2) With regard to the damage to the power tiller operator, 73.8% of the total accidents caused light injury but 26.3% caused heavy injury. (3) Accidents which occurred during machine preparation , and farming operations caused minor injury to the operator, but the accidents during transportation caused heavy injury which cost more than 15 days for recovery. (4) Among the 39 accidents , which caused property damage 18 accidents were from the transportation . Among the total property damage accidents 53.8% were light one which cost only less than 1,000 won. (5) The property damage from each accident cost 1,017 won, on the average, with regard to the kinds of operation, the highest property damage occurred during transportation work, with the value of 2, 965won.

• Journal of Environmental Science International
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• v.16 no.7
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• pp.799-804
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• 2007

Oil spill caused severe effects on the marine fauna and flora due to direct contact of organisms with the oil and even in regions not directly affected by the spill. This study was conducted to understand the effects of the oil spill accidents and the use of dispersant on the red tide of Cochlodinium polykrikoides. Crude oil produced in Kuwait, bunker-C, kerosene and diesel oil, and a chemical dispersant produced in Korea, were added with a series of 10 ppb to 100 ppm in the f/2-Si medium at $20^{\circ}C$ under a photon flux from cool white fluorescent tubes of $100\;mol\;m^{-2}\;s^{-1}$ in a 14: 10 h L:D cycle for the culture of C. polykrikoides. In low concentrations of ${\leq}$ 1 ppm of examined oils no impact on the growth of C. polykrikoides was recorded, while in high concentration of ${\geq}$ 10 ppm, cell density was significantly decreased with the range of 10 to 80% in comparison with the control. The growth of C. polykrikoides after the addition of the dispersant and the mixtures combined with oils and a dispersant of ${\geq}$ 10 ppm appeared to decrease, whereas the growth of C. polykrikoides exposed to ${\leq}$ 100 ppb showed little serious impact. However, almost all the C. polykrikoides cells were died regardless of a dispersant and combined mixtures within a few days after the addition of high concentrations.