• Title/Summary/Keyword: k-DOP

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Effect of temperature gradient and residence time on droplet formation of gaseous Di-Octyl Phthalate (DOP가스의 액적형성에 미치는 온도경사 및 체류시간의 영향)

  • Lee, Myong-Hwa;Park, Byung Hyun
    • Particle and aerosol research
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    • v.6 no.1
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    • pp.1-7
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    • 2010
  • Generally, large amounts of DOP(Di-Octyl Phthalate) chemicals are used as plasticizers in PVC compound manufacturing processes. However, it is very important to collect DOP species immediately from a workplace in order to protect worker's heath and recover them. To accomplish these objectives, we need to understand the droplet formation and growth mechanisms of DOP species. In this study, two important parameters such as temperature gradient and residence time were considered to clarify these mechanisms. We found that residence time is very critical to determine the droplet size distribution of DOP, whereas temperature gradient in general operating conditions(less than $-6.8^{\circ}C/cm$) is negligible.

Effect of Neutral Solvent on the Phase Behavior of Polystyrene-block-Poly(n-butyl methacrylate) Copolymers

  • Li, Chaoxu;Li, Guang-Hua;Moon, Hong-Chul;Lee, Dong-Hyun;Kim, Jin-Kon;Cho, Jun-Han
    • Macromolecular Research
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    • v.15 no.7
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    • pp.656-661
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    • 2007
  • The effects of a neutral solvent of dioctyl phthalate (DOP) on the phase behavior of symmetric polystyrene-block-poly(n-butyl methacrylate) copolymers (PS-b-PnBMA) were assessed herein. Closed-loop phase behavior with a lower disorder-to-order transition (LDOT) and an upper order-to-disorder transition (UODT) was observed for PS-b-PnBMA/DOP solution when the quantity of DOP was carefully controlled. When the molecular weight of PS-b-PnBMA became larger, the LDOT did not appreciably change at smaller quantities of DOP. With larger quantities of DOP, the reduction in the UODT is greater than the increase in the LDOT. This behavior is discussed in accordance with a molecular theory predicated on a compressible random-phase approximation.

Analysis of DOP using Radio-navigation Transmitter (전파항법 신호원의 배치에 따른 측위 정확도 분석)

  • Lim, Joong-Soo;Chae, Gyoo-Soo;Kim, Min-Nyun;Kim, Young-Ho
    • Journal of the Korea Convergence Society
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    • v.2 no.2
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    • pp.7-12
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    • 2011
  • In this study, we investigate on location optimization algorithm of radio-navigation transmitter. The DOP for an each receiver is decided by the location of a transmitter. We provide various results that give an optimum DOP according to propagation characteristics. We use the DTED(Digital Terrain Elevation Data) to improve the accuracy.

Significance of Dissolved Nucleic Acids in Dissolved Organic Phosphorus (DOP) Pool and Their Dynamics in oceanic Phosphorus Cycle (용존 유기인 종 용존 핸산의 중요성 및 대양 인 순환에서의 의미)

  • CHO, BYUNG C.
    • 한국해양학회지
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    • v.25 no.3
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    • pp.145-150
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    • 1990
  • An analysis of collected data on components of dissolved organic phosphorus (DOP) and DOP is made to search for important components of DOP pool and their implications in phosphorus (P) cycling. The significance of dissolved nucleic acids (D-NA) apparently tends to increase with increasing trophic status of oceanic waters. Interestingly the sum of all 5-nucleotide and D-NA seems to dominate the DOP pool. Thus, materialization of D-NA could be a significant pathway of P cycling in surface oceanic waters and it might be of great importance in lakes where P limits primary production. Processes related to death of Microbes are responsible for D-NA and DOP production in surface waters, and incomplete digestion of preys by grazers seems to be an important mechanism in D-NA production.

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Improving INS/GPS Integrated System Position Error using Dilution of Precision (Dilution of Precision 정보를 이용한 INS/GPS 결합시스템 위치오차 개선)

  • Kim, Hyun-seok;Baek, Seung-jun;Cho, Yun-cheol
    • Journal of Advanced Navigation Technology
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    • v.21 no.1
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    • pp.138-144
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    • 2017
  • A method for improving the integrated navigation performance in the INS/GPS navigation system by the considering that the condition that the geometric arrangement of the satellite is degraded due to limitation of the line of sight of the satellite such as geographic feature and GPS signal jamming is proposed. A variable covariance extended Kalman filter (VCEKF) that correlated to the measured covariance to the DOP of GPS is suggested. The navigation performance of integrated navigation system using EKF and VCEKF is analyzed by Monte-Carlo simulations. The result is verified that VCEKF has better estimation performance than EKF using fixed covariance on condition that DOP value is larger than the smaller value.

Dilution of Precision (DOP) Based Landmark Exclusion Method for Evaluating Integrity Risk of LiDAR-based Navigation Systems

  • Choi, Pil Hun;Lee, Jinsil;Lee, Jiyun
    • Journal of Positioning, Navigation, and Timing
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    • v.9 no.3
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    • pp.285-292
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    • 2020
  • This paper introduces a new computational efficient Dilution of Precision (DOP)-based landmark exclusion method while ensuring the safety of the LiDAR-based navigation system that uses an innovation-based Nearest-Neighbor (NN) Data Association (DA) process. The NN DA process finds a correct landmark association hypothesis among all potential landmark permutations using Kalman filter innovation vectors. This makes the computational load increases exponentially as the number of landmarks increases. In this paper, we thus exclude landmarks by introducing DOP that quantifies the geometric distribution of landmarks as a way to minimize the loss of integrity performance that can occur by reducing landmarks. The number of landmarks to be excluded is set as the maximum number that can satisfy the integrity risk requirement. For the verification of the method, we developed a simulator that can analyze integrity risk according to the landmark number and its geometric distribution. Based on the simulation, we analyzed the relationship between DOP and integrity risk of the DA process by excluding each landmark. The results showed a tendency to minimize the loss of integrity performance when excluding landmarks with poor DOP. The developed method opens the possibility of assuring the safety risk of the Lidar-based navigation system in real-time applications by reducing a substantial amount of computational load.

A Study on the Manufacturing of Cellurar Rubber Products with NR, NBR and EPDM (NR, NBR 및 EPDM 발포(發泡)고무의 제조(製造) 연구(硏究))

  • Kim, Hong-Seon;Choi, Sei-Young
    • Elastomers and Composites
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    • v.29 no.3
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    • pp.213-225
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    • 1994
  • The Purpose of this dissertation is to study the preparation technique and physical properties of expanded rubber. The respective samples of NR, NBR and the standard compounds of EPDM rubber were prepared by mixing plasticizer DOP and LCR in various ratio. And their vulcanization characteristics, physical properties and foaming states were studied. Vulcanization characteristics were investigated using cure curve that had been obtained from Oscillating Disk Rheometer study, and the microscopic photographs of foaming states were obtained using electron microscope. The vulcanization characteristics of the samples, DOP 30phr and LCR 30phr, were found to be suitable. The tests, like hardness test and resilience, tensile test on the physical properties of each sample showed that plasticizing efficiencies of DOP and LCR were almost the same. Oil resistance test exhibited DOP was better than LCR and compression set test showed LCR was excellent plasticizer. The foaming states of NR, EPDM compounds were uniform, but those of NBR compounds were not uniform. Consequently vulcanization characteristics, physical properties and foaming states of all the samples satisfied the SAE requirements.

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Synthesis and Properties of Novel Flame Retardant Poly(butylene terephthalate)

  • Park Jong Min;Park Yun Heum
    • Macromolecular Research
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    • v.13 no.2
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    • pp.128-134
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    • 2005
  • The phosphorus comonomer [(6-oxido-6H-dibenz<1,2>oxaphosphorin-6-yl)methyl]-methyl butane-dioate (DOP-MBDA) was synthesized through the addition reaction of dimethyl itaconate (DMI) with 9,10-dihydro­9-oxa-10-phosphaphenan threne-10-oxide (DOP). A series of novel flame retardant poly(butylene terephthalate)s (PBTs) containing different amounts of phosphorus were prepared using DOP-MBDA as a comonomer. These novel polymers were characterized by $^{1}H-NMR$, IR, and differential scanning calorimetry (DSC). The novel phosphorus­containing poly(butylene terephthalate)s, referred to as FR-PBTs, exhibited interesting thermal and mechanical behavior, as well as superior flame retardancy. These properties are attributed to the effect of incorporating the rigid structure of DOP-MBDA and the pendant phosphorus group into the poly(butylene terephthalate) (PBT) homopolymer. The UL 94-V2 rating could be achieved with this novel flame retardant PBT, which has a phosphorus content as low as $0.5 wt\%$, and the FR-PBTs emitted less fumes and toxic gases than the PBT homopolymer.

An Analysis on Recent Construction of Galileo System (Galileo 시스템 추진현황 분석)

  • Choi, Chang-Mook;Ko, Kwang-Soob
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2017.05a
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    • pp.765-766
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    • 2017
  • 본 논문은 유럽의 Galileo 시스템에 대한 특성을 분석하고, 추진 계획된 30기의 위성(24+예비6) 중에서 현재까지 구축된 18기 위성으로 위치측정이 가능한지 기하학적 배치 상태를 확인하기 위하여 DOP를 분석하였다. 분석결과, 하루 24시간 중 17시간은 양호한 DOP로 정상적인 위치측정이 가능하였으며, 7시간은 위성 수가 3개로 부족하여 위치측정이 제한되었다.

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Gas Permeation Properties of Polymeric Membranes for Biosensor Prepared from Poly(vinyl chloride) Derivatives (Poly(vinyl chloride) 유도체로부터 제조된 바이오센서용 고분자막의 기체 투과특성)

  • Lim, Chun-Won;Kim, Wan-Young;Lee, Youn-Sik;Yoon, Jeong-Won;Jeong, Yong-Seob
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.362-366
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    • 1999
  • Membranes for biosensor were prepared from poly(vinyl chloride) (PVC)l derivatives using the solution casting method, and their gas permeabilities were studied. The polymer membranes dried slowly in air showed higher permeability coefficients than those dried in vacuum. The permeabilily coefficients of carboxylated poly(vinyl chloride) (CPVC) membranes for $O_2$ and $CO_2$ decreased as the pressure of the feed gas increased. The addition of dioctylphthalate (DOP) enhanced the permeation rates for $O_2$ and $CO_2$. For example, the permeability coefficients of CPVC membranes containing 30 wt. % DOP for $O_2$ and $CO_2$ at 100 psig were 2.03 and 0.96 Barrer, respectively, which were about 4~5 times higher than those of the membranes without DOP. Poly(vinyl chloride-co-vinyl acetate-co-vinyl alcohol) (Syn-PVCAcAl) obtained by hydrolysis of poly(vinyl chloride-co-vinyl acetate (PVCA) showed a higher permeability coefficient for $CO_2$ in the presence of DOP than that for commercial PVCAcAl, but did not show any significant difference in permeability for $O_2$.

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