• Journal of Adhesion and Interface
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• v.11 no.2
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• pp.63-69
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• 2010

In this study, acryl resin PSA containing hydroxyl group based on 2-EHA (2-ethyl hexyl acrylate), 2-EHMA (2-ethyl hexyl methacrylate), 2-HEA (2-Hydroxy ethyl acrylate), acrylic acid was synthesized and then, isocyanate modified acryl resin PSA prepared with adduct reaction according to the amount of MOI (Methacryloyloxyethyl isocyanate) or 2-isocyanatoethyl methacrylate that can improve the curing property. This research shows that the initial PSA and peel adhesion are decreased according to the increase of the amount of the MOI and isocyanate curing agent. After UV irradiating, the peel adhesion is decreased with increasing the amount of the MOI (Methacryloyloxyethyl isocyanate) and isocyanate curing agent, because of the high curing property.

• Journal of the Korean Wood Science and Technology
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• v.28 no.4
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• pp.83-93
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• 2000

This study was carried out to improve the physico-mechanical properties of board products by applying the technique of high frequency heating, and find out the optimum conditions of high frequency heating, compared with the technique of hot platen heating. The possibility of isocyanate resin application to board production was also considered to solve the problem of free formaldehyde emission from urea resin which is generally used in wood industry. For this study, 30 mm thick MDP (medium density fiberboard) with isocyanate resin were manufactured by the techniques of hot platen heating, high frequency heating and the combination techniques of both heating methods, and compared in several point of views.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.568-573
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• 2010

Adhesive strength was evaluated for the polyester fabric treated with various concentration of polymeric isocyanate to introduce functional group on the surface. Also experiments were performed to find out the type of latex, F/R mole ratio, and FR resin/latex weight ratio for the RFL solution to optimize adhesion between HNBR compound and the treated polyester fabric. Optimum adhesion strength was obtained when 7 wt% of the concentration of polymeric isocyanate, NBR latex because of the compatibility of HNBR compound, 1/1 of F/R mole ratio, and 20 wt% of FR resin/latex were applied. Optimum cure temperature for the RFL solution was $200^{\circ}C$ according to the results of peel test and the reason was determined by analyzing the ATR FTIR spectra of the RF resin according to the curing temperature.

• Elastomers and Composites
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• v.47 no.4
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• pp.318-328
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• 2012

In this study, the one-component curable polyurethane resin was manufactured using blocked isocyanate and hybrid technology. To prepare the one-component curable hybrid polyurethane, silica hybrids including hydroxyl group was synthesized, and the size, shape and distribution of hybrid particle in polyurethane resin were confirmed. Then the dissociation property, mechanical property and molding property of blocked isocyanate were investigated. The dissociation property of blocked isocyanate in one-component curable polyurethane became better as the heating temperature and treatment time increased. The synthesized silica hybrid had spherical appearance and size of 23~27 nm in diameter, and it was observed that the hybrid particles were homogeneously distributed in polyurethane structure. In the case of hybrid polyurethane, the mechanical property, anti-abrasion and thermal property were higher than those of general polyurethane, and it was observed that the mechanical property was maintained when the plasticizer was introduced.

• Journal of the Korean Wood Science and Technology
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• v.31 no.5
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• pp.23-34
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• 2003

This study was carried out to investigate the mechanical properties of fabric E-glass fiber reinforced laminated timber. Specimens used to Korean red pine(Pinus densiflora) and Japanese larch(Larix kaemferi). Fabric E-glass fiber was inserted in the solid wood with aqueous polymer-isocyanate resin(MPU-500). The results were as follows: 1. Aqueous polymer-isocyanate resin(MPU-500) was good resin to manufacture laminated timber. specially, it was satisfied to property standard of construction laminated timber(KS F 3021) except for two ply glass fiber. 2. Bending and shear strengths of solid wood inserted with fabric glass fibers were not different from control solid wood. But, proportional limit bending stress was increased following the number of fabric glass fibers. Therefore, it was considered that to improve the bending and shear strength of fabric glass fiber reinforced laminated timber, the glass fiber thickness and its mesh should be modified to fitness following working conditions.

• Elastomers and Composites
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• v.54 no.2
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• pp.128-134
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• 2019

Many scientific approaches have been developed for the preparation of alternative crosslinker system of amino resins and isocyanate prepolymers. Herein, copolymerization of trimethoxy silane with N-butoxymethyl acrylamide was performed, and the product was reacted with hydroxyl groups in the alkyl main chain without the need for an additional crosslinker. For the crosslinker synthesized herein, the molecular weight, glass transition temperature, and viscosity increased with increasing content of N-butoxymethyl acrylamide.

• Journal of the Korean Wood Science and Technology
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• v.34 no.4
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• pp.31-36
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• 2006

This study was conducted to improve the bond strength of plywood bonded with F/U molar ratio urea-formaldehyde (UF) resins modified with the selected FGMDI prepolymer contents for various purposes. The amount of FGMDI was mixed with liquid UF resin at 0 wt% (as control), 2 wt%, 5 wt%, 10 wt%, 25 wt%, and 50 wt% based on the resin solids. As results, in bonding strength, plywood with F/U molar ratio of 1.4 showed the highest value in Type 2 test and all molar ratio UF resins modified with over 25 wt% of the FGMDI showed more than $11kgf/cm^2$, which was satisfied the minimum requirement of KS standard, $7.5kgf/cm^2$, after Type1.5 testing. As F/U molar ratio was increased and the FGMDI addition in the UF resin was increased, average reduction rate of Type 1.5 bonding strength compared with Type 2 was significantly decreased.

• Journal of Adhesion and Interface
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• v.15 no.3
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• pp.109-115
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• 2014

In this study, we synthesized and identified microcapsule containing isocyanate, and investigated the mechanical and adhesion properties of polyurethane resin by adding microcapsule. We found out that the core material of microcapsule and the component weight fraction of microcapsule from the FT-IR and TGA analysis. From the results of adhesion and mechanical property tests, we confirmed that in case of using microcapsule for adhesive resin composition, adhesion strength, tensile strength and abrasion were improved by cross-linking reaction between urethane and IPDI in microcapsule.

• Restorative Dentistry and Endodontics
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• v.32 no.3
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• pp.236-247
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• 2007

The purpose of this study was to evaluate the effects of cyanate methacylate on the shear bond strengths to bovine dentin surfaces as a dentin primers. Seven experimental adhesives were made with different mass fraction of Isocyanatoetylme-thacrylate (IEM), 40wt% HEMA (Wako Pure Chemical Industries Osaka, Japan), 0.6% camphoroquinone, 0.4% amine and ethanol as balance dentin bonding agents (0, 2, 4, 6, 8, 10, 12%) were made and applied on the surface of bovine dentin specimens of 7 experimental groups. Shear bond strengths were measured using a universal testing machine (Instro 4466). To identify the ratio and modes of cohesive failures, microscopic examinationn was performed. The ultra-structure of resin tags were observed under scanning electron microscope. The results were as follows ; 1) A higher shear bond strengths (33.62 MPa) in group 8% of Cyanate methacrylate to dentin were found, but there were no statistically significancy between Groups (p > 0.05). 2) The higher ratio of cohesive failures mode in group 2, 6, an 10% could be seen than that in any other groups. 3) A shorter resin tags were observed in all experimental groups. This could be resulted that the preventing from the cyanate methacrylate penetrate into dentin owing to reacting it with dentin collagen. Therefore the resin tags were shorter in lengths. Whether the higher bonding strengths of dentin bonding agents can be affected was not been assured with statistic results. The results indicated that the relation between tensile strengths of the dentin adhesives to bovine dentin and resin tags formed into the dentin could not affected. The main reason of increasing the shear bond strength to bovine dentin in experimental groups could not be assured.

• Journal of the Korean Wood Science and Technology
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• v.21 no.1
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• pp.51-58
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• 1993

The phenol resorcinol formaldehyde resin (PRF) adhesives which are curing at ambient temperature for structural purposes were synthesized. A PRF resin is produced according to the two-stage reaction system. In first stage, a low-condensed resol or methylolated phenol were prepared from phenol by reaction with a formaldehyde in alkaline condition. The molar ratio of phenol to formaldehyde was 1.0~1.4. And in second-stage, resorcinol was added to combine with the methylol group of a low-condensed resol(R/P molar ratio 0.3). The glue-joint strength, pot-life and workability of this synthetic PRF resin were superior to conventional ambient temperature setting adhesives such as oilic urethane or water based polymer-isocyanate resin for wood adhesives.