• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.920-925
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• 2008

In this presentation, a leaching experiment which is followed the pH changes(pH=4, pH=7) and the mixing rates(1%, 3%, 5%, 7%) was carried out to examine the arsenic reduction effects and the leaching characteristics on arsenic contaminated soil after stabilization treatment in which 5 materials were used as stabilization agencies, i.e. ZVI(zero valent iron), blast furnace slag, steel refining slag, quick lime, and oyster shell meal. Except for blast furnace slag, the arsenic removal rate increased as the mixing rate increases of stabilization agencies. Arsenic leaching concentration was indicated that pH=7 condition is higher than pH=4 condition. This result shows because arsenic immobilization reaction increases as pH decreases, and arsenic adsorption takes place as pH decreases.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.2139-2144
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• 2003

In steel-making processes of iron and steel industry, the purity and quality of steel can be dependent on the amount of CO contained in the molten metal. Recently, the supersonic oxygen jet is being applied to the molten metal in the electric furnace and thus reduces the CO amount through the chemical reactions between the oxygen jet and molten metal, leading to a better quality of steel. In this application, the supersonic oxygen jet is limited in the distance over which the supersonic velocity is maintained. In order to get longer supersonic jet propagation into the molten metal, a supersonic coherent jet is suggested as one of the alternatives which are applicable to the electric furnace system. It has a flame around the conventional supersonic jet and thus the entrainment effect of the surrounding gas into the supersonic jet is reduced, leading to a longer propagation of the supersonic jet. The objective of the present study is to investigate the supersonic coherent jet flow. A computational study is carried out to solve the compressible, axisymmetric Navier-Stokes equations. The computational results of the supersonic coherent jet are compared with the conventional supersonic jet.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.514-519
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• 2001

Converter has been slag produced 10 million tons per year in Japan. It is a steel making by product produced in the same way as the blast-furnace slag. Though blast-furnace slag is being used effectively as a concrete admixture, the converter stag has never been used effectively because of the expansion action of contained free lime and iron oxide. This is an important environmental problem in the steel industry. Beta-2CaOSiO$_2$(beta-C$_2$S) is contained 40 percent in converter slag, therefore it is very promising as a concrete admixture. We proposed an accelerated aging processes capable of stabilizing the converter slag in a short time. The converter slag is dipped into alkali aqueous solution after heating at low temperature. It was subsequently ground to a grain size of 75 ${\mu}{\textrm}{m}$ , inner 30 percent of OPC. The properties of mortar and concrete using the blended cement were determined. As a result, it has become apparent that the expansion was reduced and long term compressive strength was increased while that at early ages was not so remarkable. The hydration exotherm rate was lower than that of the OPC.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.490-495
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• 2003

In steel-making process of iron and steel industry, the purity and quality of steel can be dependent on the amount of CO contained in the molten metal. Recently, the supersonic oxygen jet is being applied to the molten metal in the electric furnace and thus reduces the CO amount through the chemical reactions between the oxygen jet and molten metal, leading to a better quality of steel. In this application, the supersonic oxygen jet is limited in the distance over which the supersonic velocity is maintained. In order to get longer supersonic jet propagation into the molten metal, a supersonic coherent jet is suggested as one of the alternatives which are applicable to the electric furnace system. It has a flame around the conventional supersonic jet and thus the entrainment effect of the surrounding gas into the supersonic jet is reduced, leading to a longer propagation of the supersonic jet. In this regard, gasdynamics mechanism about why the combustion phenomenon surrounding the supersonic jet causes the jet core length to be longer is not yet clarified. The present study investigates the major characteristics of the supersonic coherent jet, compared with the conventional supersonic jet. A computational study is carried out to solve the compressible, axisymmetric Navier-Stokes equations. The computational results of the supersonic coherent jet are compared with the conventional supersonic jets.

• 자원리싸이클링
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• 제27권2호
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• pp.68-76
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• 2018

전기로 제강분진은 아연, 연, 철의 2차자원으로서 매우 중요하다. 또한 제강분진의 리싸이클링은 분진 중에 함유되어 있는 증금속 성분 등의 유해원소에 의한 환경문제의 처리에 유용한 방법이다. 본 조사는 기존의 전기로 제강분진을 처리하는 방법의 개선이나 새로운 처리방법의 개발을 위해 건식처리 방법에 대하여 알아보았다. 상업중인 처리방법은 노의 형상 등에 따라 로터리 킬른형, 회전노상형, 샤프트형, 용융환원로형 등으로 구분할 수 있었다. 이러한 처리에서의 생성물은 ZnO와 환원철 또는 슬래그이다. 제강분진으로부터 ZnO를 만드는 기구는 탄소 열환원과 공기에 의한 아연증기의 산화에 의한 것이다.

• 콘크리트학회논문집
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• 제23권2호
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• pp.195-201
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• 2011

이 연구에서는 나선 철근으로 횡 구속된 전기로 산화 슬래그 골재를 사용한 콘크리트의 구조적 성능을 평가한다. 전기로 산화 슬래그는 철강 산업의 부산물로서, 그동안 유리석회와 유리마그네슘의 팽창성질 때문에 저부가가치적인 용도로만 이용되어 왔지만 최근 제강 기술의 발달에 힘입어 안정화된 전기로 산화 슬래그 골재의 생산이 가능하여 졌다. 구조용 콘크리트에 대한 전기로 산화 슬래그 골재의 적용성을 검증하기 위하여, 직경이 150 mm이고 높이가 300 mm인 실린더형 실험체를 총 27개 제작하고 횡 구속 실험을 수행하였다. 실험 변수는 골재의 종류와 나선 철근의 항복 강도로 하였다. 실험 결과, 전기로 산화 슬래그 골재를 사용한 실험체의 구조적 성능이 천연골재를 사용한 횡 구속된 콘크리트와 비교하여 동등 이상인 것을 확인할 수 있었다.

• 한국세라믹학회지
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• 제51권3호
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• pp.184-189
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• 2014

Electric arc furnace dust (EAFD) is a solid waste generated by the steel-scrap recycling process. It mainly consists of zinc oxides (ZnO), alumina ($Al_2O_3$), iron oxides ($Fe_2O_3$), and silica ($SiO_2$). Here we report the preparation and characterization of blue ceramic pigments using EAFD powder as a starting material. $(Zn(EAFD),Co)Al_2O_4$ blue ceramic pigment was prepared by the solid-state reaction method. The color characteristics of the pigment obtained were compared with those of pure $CoAl_2O_4$. The new pigment was characterized using XRD, CIE-$L^*a^*b^*$ color-measurements, SEM, and EDX. The XRD analysis revealed that the $(Zn(EAFD),Co)Al_2O_4$ pigment was composed of mainly the spinel phase of $(Zn,Co)Al_2O_4$. The $Zn(EAFD)_{0.25}Co_{0.75}Al_2O_4$ pigments showed a vivid blue color with a $b^*$ value of -28.64 and a good glaze stability with a transparent glaze.

• 한국세라믹학회지
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• 제15권4호
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• pp.213-223
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• 1978

The purpsoe of this study was to produce domestic stamping materials; sling mass which could be used as unburned refractory for iron melt'ladle. Batch compositions were based on Belgian Ladelite; mineral compositions were composed of 84 wt% of quartz and 16 wt% of clay, and particle sizes were divided into 12 wt% of 1410/297㎛, 18wt% 297/149㎛, 20wt% of 149/74㎛, 11wt% 74/44㎛ and 39wt% 44㎛ under. The effect of variable batch compositions were also investigated such as substitution of pyrophylite or industrial grade alumina for quartz and of zircon for portion of quartz and clay, increase of clay and addition on sericite. Samples were pressed at 100kg/㎠ with 7.4wt% of water or 7.4wt% of 4 wt% PVA solution. Dried and Fired properties of samples such as linear shrinkage, apparent porosity, modulus of rupture, refractoriness and corrosion resistance to blast furnace slag were investigated. The results are summarized as follows. 1. Dried samples are shrinked, but fired at 700-1400℃ expanded. Samples fired at 700-1000℃ and 1200-1400℃ tended to expand with incresing of firing temperature, but fired at 1000-1200℃ tended to shrink with increase of firing temperature. 2. Apparent porosity of samples fired at 700℃ is increased, but fired at 1200-1400℃ decreased with increasing of firing temperature. 3. Modulus of rupture of samples fired at 700℃ is decreased, but fired at above 700℃ increased with increasment of firing temperature. 4. Dried samples with 7.4 wt% of 4 wt% PVA solution better improve modulus of rupture than with 7.4 wt% of water, but the firing strength of the sampels fired at 700-1000℃ is showed reversely. 5. In quartz-clay system, mineral phases of samples fired at above 1200℃ are consisted of α-quartz, α-cristobalite and mullite. Respectively as firing temperature was rising up, intensity of α-cristobalite and mullite is in creased. 6. Quartz-Kibushi clay system, Kimcheun quartz(substitutuion of portion of industrial grade alumina for quartz) Hampyeung clay system and pyrophyllite-clay system are better in corrosion resistance to blast furnace slag than burned pyrophyllite brick. 7. 84 wt% of pyrophyllite-16wt% of clay system is superior in modulus of rupture and corrosion resistance to blast furnace slag to 84 wt% of quartz-16 wt% of clay system.

• 보존과학회지
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• 제34권6호
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• pp.581-593
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• 2018

최근 고대 제철기술 연구를 위한 복원실험이 활발하게 이루어짐에 따라 세부 기술체계나 조업방식 등에 대한 해석이 가능해지는 등 성과를 이루었다. 이에 본 연구에서는 고대 제련-단야기술 복원실험을 위한 적정 온도조건을 확인하여 고대 기술의 복원에 근접하기 위한 적정한 실험 방향을 제시하고자 하였다. 복원대상은 고대 중원지역의 출토 사례를 기본으로 하였으며 기존의 연구 자료를 참고하여 최대한 변수를 통제한 실험을 설계하였다. 저온으로 조업한 실험A와 고온으로 조업한 실험B를 실시한 결과 실험A에서 생성된 철은 탄소함량이 적고 단야조업에도 적합한 것으로 확인되었다. 또한 슬래그의 미세조직 및 성분조성과 노벽의 침식 등 전반적인 양상도 실험A가 고대 제련기술에 근접한 결과를 보였다. 실험을 통한 고대 제철기술의 복원은 유적에서 나타나는 현상의 복원될 때 이루어질 수 있으므로 고대제련-단야 기술체계의 복원을 위한 실험은 실험A와 같은 저온조업을 중심으로 진행되는 것이 적절할 것으로 판단된다.

• 보존과학회지
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• 제33권2호
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• pp.75-83
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• 2017

본 연구는 고대 제철로 재현실험의 제련 슬래그를 대상으로 성분을 분석하고, 기존의 연구방법 대신 슬래그의 주성분에 대한 다른 성분들의 상대적인 비율을 활용한 해석 방법을 제시하여 슬래그 간의 경향성을 파악함으로써 노(爐)내에서 슬래그가 기인된 성분 출처를 연구하고자 하였다. 분석 데이터를 이변량 및 삼각좌표 비교 분석 그래프로 작성한 결과 기준시료의 주요 성분에 따라 일정한 경향성을 띠며 그룹을 형성하는 것이 확인되었다. 기준시료인 광석을 중심으로 형성된 광석 슬래그군은 CaO와 $TiO_2$함량이 높았고, 점토와 마사토를 중심으로 형성된 점토 슬래그군은 $Al_2O_3$와 $SiO_2$함량이 높았다. 또한 그래프 상에서 군집에 속하지 못하는 경우 어느 군집에 더 근접한가에 따라 슬래그가 기인한 성분의 추정이 가능한 것으로 판단하였다. 실험에 사용된 광석 및 점토, 첨가제와 제련 슬래그에서 공통적으로 $TiO_2$함량이 1.6% 이상으로 비교적 높게 나타났고, 모든 슬래그 분석 결과에서 $CaO/SiO_2$값이 0.4 이하로 분석되었다. 복원실험이 철광석 제련이었다는 점과 조업 시 조재제를 첨가하지 않았다는 것을 고려했을 때, 슬래그를 해석하는데 있어 단순 함량보다 성분 간 비율을 종합적으로 파악하는 방법이 더욱 정확한 해석 방법이 될 수 있을 것으로 판단된다.