• Title/Summary/Keyword: iron bearing

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SHRIMP U-Pb Geochronology of Detrital Zircons from Iron-bearing Quartzite of the Seosan Group: Constraints on Age and Stratigraphy (서산층군 함철규암의 쇄설성 저어콘에 대한 SHRIMP U-Pb 연대: 시대와 층서의 제한)

  • Cho, Deung-Lyong;Kim, Yong-Jun;Armstrong, Richard
    • The Journal of the Petrological Society of Korea
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    • v.15 no.3 s.45
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    • pp.119-127
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    • 2006
  • Detrital zircons in iron-bearing quartzite of the Seosan Croup from southeastern part of the Cyeonggi Hassif were analysed for SHRIHP U-Pb ages. Among 42 analyses, 38 data yield concordant ages (less tan 10 % discordancy), and they concentrated at 1781~1898 Ma (n=19), $1781{\sim}1898\;Ma(n=19),\;1935{\sim}1941\;Ma(n=4),\;1996\;Ma,\;2120\;Ma\;2403{\sim}2459\;Ma(n=5)$, 2661 Ma and 3198 Ma. The data indicate that sedimentation of iron-bearing quartzite should be after ca 1.78 Ga (the youngest detrital zircon age), and argue against some of conventional idea that iron-bearing quartzite of the Seosan Group might be correlated with the Archean iron-bearing quartzite in the North China Craton.

Study on Carbon Pick-up in molten iron (I);Effect of Crystallization heat treatment of Carbon-bearing materials on Carbon Pick-up in molten iron (용철(熔鐵)에서의 가탄(加炭)에 관(關)한 연구(硏究)(1);가탄(加炭)에 미치는 탄소재(炭素材)의 결정화열처리(結晶化熱處理)의 영향)

  • Cho, Won-Il;Lee, Jong-Nam
    • Journal of Korea Foundry Society
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    • v.3 no.3
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    • pp.159-166
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    • 1983
  • In order to develope domestic carburizers, the experiment was carried out by applying crystallization heat treatment to domestic anthracites and also to foreign products to compare with domestic anthracites.The present work was mainly concerned with the effect of their degree of crystallization of carbon-bearing materials on carbon pick-up in molten iron.Those effects were evaluated by the measurement of density, chemical composition, specific electric resistivity, and X-ray intensity of carbon-bearing materials. Experimental results thus obtained were summurized as follows. 1. The degree of crystallization of domestic anthracites and foreign products was increased with increasing heat treatment temperature. 2. The more degree of crystallization, the shorter the dissolving time of domestic anthracites in molten iron was obtained, while that of foreign products was remained constant. 3. As the degree of crystallization of domestic anthracites and foreign products was increased, the carbon content as well as carbon recovery in molten iron was increased.

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Effect of Spinning Speed on 29Si and 27Al Solid-state MAS NMR Spectra for Iron-bearing Silicate Glasses (시료의 회전 속도가 함철 비정질 규산염의 고상 NMR 신호에 미치는 영향)

  • Kim, Hyo-Im;Lee, Sung Keun
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.4
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    • pp.295-306
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    • 2018
  • Despite the utility of solid-state NMR, NMR studies of iron-bearing silicate glasses remain a challenge because the variations in the peak position and width with increasing iron content reflect both paramagnetic effect and iron-induced structural changes. Therefore, it is essential to elucidate the effect of temperature on the NMR signal for iron-bearing silicate glasses. Here, we report the $^{29}Si$ and $^{27}Al$ MAS NMR spectra for $(Mg_{0.95}Fe_{0.05})SiO_3$ and $Fe_2O_3$-bearing $CaAl_2Si_2O_8$ (anorthite) glasses with varying spinning speed to interpret the NMR spectra for iron-bearing silicate glasses. The increase in the spinning speed results in an increase in the sample temperature. The current NMR results allow us to understand the origins of the changes in NMR signal with increasing iron content and to provide information on the dipolar interaction between nuclear spins. The $^{29}Si$ NMR spectra for $(Mg_{0.95}Fe_{0.05})SiO_3$ glass and $^{27}Al$ NMR spectra for $Fe_2O_3$-bearing $CaAl_2Si_2O_8$ glasses show that the peak shape and position of iron-bearing glasses do not change with increasing spinning speed up to 30 kHz. These results suggest that the NMR signal in the Fe-bearing glasses may stem from the 'survived nuclear spins' beyond the cutoff radius from the Fe, not from the paramagnetic shift. Based on the current results, the observed apparent shifts toward lower frequency of Al peak for $Fe_2O_3$-bearing $CaAl_2Si_2O_8$ glasses with increasing $Fe_2O_3$ at all spinning speed (15 kHz to 30 kHz) indicate the increase in the fraction of ${Q^4}_{Al}$(nSi) with lower n (i.e., 1 or 2) with increasing $Fe_2O_3$ and the spatial proximity between Fe and ${Q^4}_{Al}$(nSi) with higher n (i.e., 3 or 4). The present results show that changes in the NMR signal for iron-bearing silicate glasses reflect the actual iron-induced structural changes. Thus, it is clear that the applications of solid-state NMR for iron-bearing silicate glasses hold strong promise for unraveling the atomic structure of natural silicate glasses.

Removal of Iron Bearing Minerals from Illite (일라이트에 함유된 Fe 불순물 제거)

  • Kim, Yun-Jong;Cho, Sung-Baek;Park, Hyun-Hae;Kim, Sang-Bae
    • Korean Journal of Materials Research
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    • v.16 no.8
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    • pp.497-502
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    • 2006
  • Recently, many attention have been focused on illite as a material for the well-being industry. Illite contains various kinds of iron bearing materials and they restrict their usage. In this study, Fe impurities in the illite produced in Yeongdong-gun, Chungcheongbuk-do were characterized and their removal experiments were performed. According to the characterization of illite raw ore, it contained 1.54 wt.%$Fe_2O_3$ due to the existence of iron oxide($Fe_2O_3$) and pyrite($FeS_2$). The raw ore was crushed into 3 mm or less using cone crusher and then ground by rod mill for the liberation of impurity mineral. For the removal of iron bearing minerals, an acid treatment, a flotation, a magnetic separation, and a flotation combined with magnetic separator were performed respectively. When the illite raw ore was treated with magnetic separation and various kinds of acid, 1.54wt.%. $Fe_2O_3$ content was reduced to 0.78 and 1.0 wt.%, respectively. On the other hand $Fe_2O_3$ content was reduced to be 0.52 wt.% after flotation. These results indicate that iron bearing minerals cannot be reduced below 0.3wt.%$Fe_2O_3$. However, combination of magnetic separation and flotation enable us to get 0.24wt.% of illite concentrate. It is concluded that, for the refinement of illite from Yeongdong-gun, the flotation combined with magnetic separation is good for high purity illite.

Comparative Studies between Chungju and Seosan Groups (충주층군(忠州層群)과 서산층군(瑞山層群)의 비교연구(比較硏究))

  • Na, Ki Chang;Kim, Hyung Shik;Lee, Dong Jin;Lee, Sang Hun
    • Economic and Environmental Geology
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    • v.15 no.4
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    • pp.177-188
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    • 1982
  • The Chungju and Seosan Groups have been known usually as Precambrian formations in Korea. But their relative and absolute ages have been controvericial problem in relation with other geologic system such as so-called Ogcheon and Yeoncheon Systems in Korea. This study has mainly focused on the corelation of the Chungju Group with the Seosan Group in their stratigraphy, structure, metamorphism, and iron ore deposits. In the process of study, the auther surveyed and reclassified the Chungju and Seosan Groups and corelated with Gyeonggi and Ogch cheon metamorphic belts and got some new data. The Chungju iron-bearing formations showing transtitional relation with the Gyeonggi Gneiss Complex and the Jangamri Formation consisting mainly of pebble bearing calcarious phyllite, should be seperated from the Gyemyeongsan formation which is mainly composed of metavolcanic rocks. The Jangamri Formation and the coaly phyllite, which can be corelated respectively with the Hwaggangri Formation and Changri Formation in Ogcheon Group, are repeated in the Gyemyeonsan and Munjuri Formations with the overturned anticlinal folding(F1). So the Chungju Group which was defined as an indipendant geologic unit from the Ogcheon Group should be limited only on the Chungju iron Formation. The Seosan Group can be classified stratigraphically such as Seosan Formation consisting of iron-bearing quartzite and mica schist, Daesan Formation overlying unconformably on the Seosan Formation and Gyeonggi Gneiss Complex. Taean Formation overlying unconformably on the Daesan Formation should be seperated from Seosan Group. There are many similarity in the stratigrphy, structure, and metamorphic facies between Chungju and Seosan Groups exept the metavolcanic rocks in the Gyemyeongsan and Munjuri Formations and the pebble bearing calcareous phyllite in the Jangamri Formation. The two Groups were deformed with two kinds of differant stages, the first shows $N30^{\circ}-40^{\circ}E$ trend of fold axis, the second $N70^{\circ}-80^{\circ}W$ respectively. The Seosan Formation, which is the lowest formation in Seosan Group and bearing the iron formation, was metamorphosed at 2500 m. y. before. These age is similar with the metamorphic age of Gyeonggi metamorphic belt and with the age of Algoman and Kenoran Orogenies which devide the Precambrian into Archean and Proterozoic Era. So the Seosan Formation, which is included in some migmatitic rocks of Gyeonggi Gneiss Complex, is the oldest formation in Korea and can be corelated with the Anshan Group which bears the oldest iron formation in China. The metamorphic facies of the Precambrian metamorphism in Seosan area is simillar with that of Chungju area, showing high temperature-low pressure amphibolite facies which is corelated with the Gyeonggi metamorphic belt, the oldest metamorphic belt in Korea ($650^{\circ}-680^{\circ}C$, 3.2-4.4 Kb). The high temperature intermediate pressure amphibolite facies in Seosan area with the low temperature-intermediate presure greenschist facies of Taean formation is corelated with that of Ogcheon Group ($590^{\circ}-640^{\circ}$ C, 5.2-6.3 Kb). The Chungju and Seosan iron formations were deposited in Archean, showing geochemical composition of Precambrian iron formations. The Chungju iron formation was mainly formed by the chemical precipitation, on the other hand, the Seosan iron formation was formed by alternated action of chemical and detrital depositions.

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The Effect of Iron Content on the Atomic Structure of Alkali Silicate Glasses using Solid-state NMR Spectroscopy (비정질 알칼리 규산염 원자구조의 철 함량 효과에 관한 고체 NMR 분광학 연구)

  • Kim, Hyo-Im;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.4
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    • pp.301-312
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    • 2011
  • The study on the atomic structure of iron-bearing silicate glasses has significant geological implications for both diverse igneous processes on Earth surface and ultra-low velocity zones at the core-mantle boundary. Here, we report experimental results on the effect of iron content on the atomic structure in iron-bearing alkali silicate glasses ($Na_2O-Fe_2O_3-SiO_2$ glasses, up to 16.07 wt% $Fe_2O_3$) using $^{29}Si$ and $^{17}O$ solid-state NMR spectroscopy. $^{29}Si$ spin-lattice ($T_1$) relaxation time for the glasses decreases with increasing iron content due to an enhanced interaction between nuclear spin and unpaired electron in iron. $^{29}Si$ MAS NMR spectra for the glasses show a decrease in signal intensity and an increase in peak width with increasing iron content. However, the heterogeneous peak broa-dening in $^{29}Si$ MAS NMR spectra suggests the heterogeneous distribution of $Q^n$ species around iron in iron-bearing silicate glasses. While nonbridging oxygen ($Na-O-Si$) and bridging oxygen (Si-O-Si) peaks are partially resolved in $^{17}O$ MAS NMR spectrum for iron-free silicate glass, it is difficult to distinguish the oxygen clusters in iron-bearing silicate glass. The Lorentzian peak shape for $^{29}Si$ and $^{17}O$ MAS NMR spectra may reflect life-time broadening due to spin-electron interaction. These results demonstrate that solid-state NMR can be an effective probe of the detailed structure in iron-bearing silicate glasses.

Analysis of the Sliding Wear Mechanism of Pure Iron Tested Against Different Counterparts in Various Atmospheres (상대재와 분위기에 따른 순철의 미끄럼 마멸 기구 분석)

  • Koo, B.W.;Gwon, H.W.;Kim, Y.S.
    • Transactions of Materials Processing
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    • v.26 no.6
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    • pp.365-371
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    • 2017
  • During sling wear of a ferrous metal, a surface layer is formed. Its microstructure, constituting phases, and mechanical property are different from those of the original wearing material. Since wear occurs at the layer, it is important to characterize the layer and understand how wear rate changes with different layers. Various layers are formed depending on external wear conditions such as load, sliding speed, counterpart material, and environmental conditions. In this research, sliding wear tests of pure iron were carried out against two different counterparts (AISI 52100 bearing steel and $Al_2O_3$) in the air and in an inert Ar gas atmosphere. Pure iron was employed to exclude other effects from secondary phases in steel on the wear. Wear tests were performed at room temperature. Worn surfaces, wear debris, and cross-sections were analyzed after the test. It was found that these two different counterparts and environments produced diverse layers, resulting in significant changes in wear rate. Against the bearing steel, pure iron showed higher wear rate in an Ar atmosphere due to severe adhesion than that in the air. On the contrary, the iron showed much higher wear rate in the air against $Al_2O_3$. Different layers and wear rates were analyzed and discussed by oxidation, severe plastic deformation, and adhesion at wearing surfaces.

Understanding the Concept of Iron Deficiency Anemia in Athletes: A Narrative Review

  • RANA, Anvi
    • Journal of Sport and Applied Science
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    • v.6 no.4
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    • pp.11-23
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    • 2022
  • New insights into the aetiology of anaemia in athletes have been discovered in recent years. From hemodilution and redistribution, which are thought to commit to so-called "sports anaemia," to iron deficiency triggered by higher requirements, dietary requirements, decreased uptake, enhanced losses, hemolysis, and sequester, to genetic factors of different types of anaemia (some related to sport), anaemia in athletes necessitates a careful and multisystem methodology. Dietary factors that hinder iron absorption and enhance iron bioavailability (e.g., phytate, polyphenols) should be considered. Celiac disease, which is more common in female athletes, may be the consequence of an iron deficiency anaemia that is unidentified. Sweating, hematuria, gastrointestinal bleeding, inflammation, and intravascular and extravascular hemolysis are all ways iron is lost during strength training. In training, evaluating the iron status, particularly in athletes at risk of iron deficiency, may work on improving iron balance and possibly effectiveness. Iron status is influenced by a healthy gut microbiome. To eliminate hemolysis, athletes at risk of iron deficiency should engage in non-weight-bearing, low-intensity sporting activities.

A Study on Nutrient Intakes and Hematological Status in Women of Child-Bearing Age Comparison between Non-Pregnant and Pregnant Women (가임기 여성의 영양섭취상태 및 혈액성상 : 비임신여성과 임신여성의 비교)

  • 이은정;김미현;조미숙;김영주;김화영
    • Journal of Nutrition and Health
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    • v.36 no.2
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    • pp.191-199
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    • 2003
  • This study was conducted to evaluate nutritional status of Korean women of child-bearing age. A comparison was made between 113 non-pregnant and 200 pregnant women. Pregnant women of 24-28 weeks of gestation were recruited from prenatal clinic in Seoul. Nonpregnant women were included college students, nurses, office employers, and sales women. General characteristics, anthropometric measurements, dietary intakes, and hematological values were assessed. There was no difference in mean BMI for nonpregnant and pregnant (pre-gravid) women, which were 20.2 kg/m$^2$and 20.6 kg/m$^2$respectively. The pregnant women showed a tendency of better health-caring behavior, evidenced by stop smoking and drinking, and in taking nutrient supplements. The mean intakes of energy, vitamin A, vitamin B$_2$, calcium, and iron did not meet Korean RDA for adult women. In particular, calcium and iron intakes of both nonpregnant and pregnant women were under 60% of the Korean RDA. Judging by MDA score, dietary quality was better in pregnant than in nonpregnant women. Mean serum values of albumin, total cholesterol, LDL-cholesterol, HDL-cholesterol, Hb, IgA, IgG were in normal range. However, more than 13% of the nonpregnant subjects showed mild hypercholesterolemia (cholesterol > 200 mg/dl) and anemia (Hb < 12.0 g/dl) . The percentage of anemia in pregnant women were much higher; the subject with Hb < 11.0 g/dl were approximately 30%. The pregnant subjects showed significantly higher serum concentrations of triglycerides and cholesterol, and significantly lower concentrations of albumin, IgA, and IgG compared to nonpregnant women. Correlation analysis showed that Hb concentrations were correlated with the intakes of iron- and protein- containing foods such as meat and vegetables. This study strongly suggest that iron-deficient anemia is a major nutrition problem in Korean child-bearing women and this condition is correlated with dietary intakes.

Structural Analysis on the Heavy Duty Diesel Engine with Compacted Graphite Iron (CGI를 이용한 대형 디젤엔진의 구조해석)

  • Lee, Jae-Ok;Lee, Young-Shin;Lee, Hyun-Seung;Kim, Jae-Hoon;Jun, Joon-Tak;Kim, Chul-Goo
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.602-607
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    • 2007
  • The heavy duty diesel engine must have a large output for maintaining excellent mobility. The compacted graphite iron (CGI) is a material currently under study for the engine demanded for high torque, durability, stiffness and fatigue. In this study, three dimensional finite element model of a heavy-duty diesel engine was developed to conduct the stress analysis by using property of CGI. The FE model of the heavy duty diesel engine section consisting with four half cylinder was selected. The heavy duty diesel engine section include cylinder block, cylinder head, liner, bearing cap, bearing and bolt. The loading conditions of engine are pre-fit load, assembly force and gas force.

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