• Title/Summary/Keyword: ionic viscosity

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A Study on the Curing Behaviors of Glass/Epoxy Prepreg by Dielectrometer and the Thermal Properties of Cured Glass/Epoxy Composites (Dielectrometer를 이용한 Glass/Epoxy 프리프레그의 경화거동 및 경화물의 열적 특성연구)

  • 제갈영순;이원철;전영재;윤남균
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.350-357
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    • 2000
  • Curing behaviors of glass/epoxy prepreg for printed circuit boards (PCB) were studied by using dielectrometer and differential scanning calorimeter. This prepreg was showed the lowest ionic viscosity at about 115$^{\circ}C$, and then the ionic viscosity was gradully increased up to 15$0^{\circ}C$. This indicated that the curing reaction of this prepreg started at 115$^{\circ}C$ and the molecular weight was increased by the accelerated thermal cross-linking reaction. The loss factor and tan $\delta$ values were also measured and discussed. The dielectric behaviors of this prepreg system were also measured according to the cure cycle for PCB. This material was found to be thermally stable up to about 30$0^{\circ}C$ and then was showed an abrupt decomposition beyond this temperature.

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Preparation and Properties of Water-borne PU Having Ionic Center onto Flexible Side Chain (유연한 곁가지 말단에 이온성 작용기를 가지는 양이온성 수분산 PU의 제조와 물성)

  • Kim, Dong-Min;Bang, Moon-Soo;Kim, Hyung-Joong
    • Journal of Adhesion and Interface
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    • v.7 no.1
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    • pp.3-9
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    • 2006
  • Three isocyanate groups of IP-$75^{(R)}$ and one hydroxyl group of various amino alcohols were applied for preparing cationic type water-borne polyurthane (PU) having ionic center onto flexible side chains. Average particle size, dispersion stability, viscosity, contact angle, surface energy, glass transition temperature ($T_g$), and adhesion strength of prepared water-borne PUs were measured and analyzed with different NCO/OH mol ratios, ionomers, and neutralizing agents. It was characterized that the prepared PU has a smaller particle size and a better dispersion stability than the conventional cationic water-borne PU containing ionic centers onto main chains.

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Application of Ionic Liquids in Biotechnology (생물공학에서 이온성 액체의 응용)

  • Lee Sang-Mok;Chang Woo-Jin;Koo Yoon-Mo
    • KSBB Journal
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    • v.20 no.3
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    • pp.183-191
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    • 2005
  • Ionic liquids, composed of organic cations and either organic or inorganic anions remain liquid over a wide range of temperature. ionic liquids are a new group of solvents or extractants of great interest as a potential 'green solvent'. Ionic liquids are gaining wide recognition as novel solvents in many research fields, such as chemistry, chemical engineering, electrochemitry, etc. However, not much researches have been done related to biotechnology using ionic liquids, while a lot of researches have been performed in chemistry. The merits of ionic liquids in bioseparation technology are originated from some unique properties of ionic liquids, such as negligible vapor pressure, good thermal stability, controllable viscosity and miscibility with water and organic solvents. An appropriate selection of ionic liquid for bioprocesses requires basic knowledge on physicochemical properties of ionic liquids. This review gives a brief overview on the application of ionic liquids in biotechnology, including bioconversion and bioseparation.

Study for Addition Effect of Propylene Carbonate to 1-ethyl-3-methylimidazolium in Electric Double Layer Capacitors (Propylene Carbonate 첨가된 1-ethyl-3-methylimidazolium의 전기이중층 커패시터에서의 효과)

  • Kim, Hyun-Chul;Yang, Jeong-Jin;Kim, Han-Joo;Sin, Dal-Woo;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.14 no.1
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    • pp.38-43
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    • 2011
  • Because the ionic liquid added with Propylene carbonate(PC) at room temperature has lower viscosity than original, we considered electrochemical behavior of it in EDLC. The ionic liquid without PC which does not have ions has no problem in capacity since it has enough ions. The electrolyte resistance was decreased with decreasing viscosity. As a result of identifying high current discharge capacity, we observed that the ionic liquid had capacity of 73.12% at current density of $80\;mA/cm^{-2}$, but it increased to 81.94% at PC content of 40 vol%.

Ettect of Electrolytes on Flow Properties of Aqueous Bentonite Suspension

  • Kisoon Park;Taikyue Ree;Henry Eyring
    • Journal of the Korean Chemical Society
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    • v.15 no.6
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    • pp.303-312
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    • 1971
  • Dependence of the flow behavior of aqueous suspension of Black Hills bentonite on the concentration and the types of electrolytes was stydied. The flow properties were measured with a Couette-type totational viscometer. On addition of monovalent cations, the apparent viscosity determined from the reproducible flow curves (shear rate vs. shear stress) decreased followed by a rise as the ionic concentration further increased. Addition of multivalent cations (di- and tri-) resulted in the viscosity which increased to a maximum then decreased to a constant value. Anions of different chatges produced essentially the same relationship between viscosity and electrolyte concentration. The flow behavior of the electrolyte-containing suspensions was rationalized in terms of the Derjaguin-Landau-Verwey-Overbeek theory of colloidal stability and the generalized theory of viscosity.

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Systematic study on calcium-dissolved organic matter interaction in a forward osmosis membrane-filtration system (정삼투 멤브레인 공정에서 칼슘이온과 용존 유기물 상호작용에 의한 플럭스 변화 연구)

  • Heo, Jiyong;Han, Jonghun;Kim, Yejin;Her, Namguk
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.737-744
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    • 2016
  • The investigation of effects on fouling propensity with various viscosity of feed solutions would be better understanding for forward osmosis (FO) performance since the fouling propensity was directly influenced with solution viscosity. Therefore, this study was focused on the FO fouling with model foultants (humic acid, alginate) by altering solution viscosity with change of ionic strength (I.S) and $Ca^{2+}$ concentrations. In the comparison between humic acid and alginate, as expected, the alginate generally caused more severe fouling (almost 35.8 % of flux reduction) based on the solution characteristics (high viscosity) and fouling patterns (coil and gel layer). However, interesting point to note is that the fouling propensity of alginate was more severe even though it was applied with low viscosity of feed conditions (I.S = 20 mM, $Ca^{2+}=1mM$). This might be due to that crossed linked gel layer of alginate on the FO membrane surface could be best formed in the condition of $Ca^{2+}$ presence and higher I.S, and that is more dominant to fouling propensity than the low viscosity of feed solutions.

Synthesis and Characterization of Quaternary Ammonium-based Ionic Liquids Containing an Alkyl Carbonate Group

  • Nguyen, Dinh Quan;Oh, Ji-Hee;Kim, Chang-Soo;Kim, Seung-Wook;Kim, Hong-Gon;Lee, Hyun-Joo;Kim, Hoon-Sik
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2299-2302
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    • 2007
  • A series of quaternary ammonium-based ionic liquids (ILs) containing an alkyl carbonate group on the cation was first prepared and their physical and electrochemical properties including density, viscosity, thermal stability, electrochemical stability, and ionic conductivity were reported. These ILs exhibited wide electrochemical windows of at least 5.0 V and relatively high conductivities. In contrast to dialkyl-substituted ionic liquids, the ILs with an alkyl carbonate group on the cation showed much smaller drop in conductivities when mixed with a lithium salt, due to the interaction of lithium ions with carbonate groups. Upon interaction with a Li salt, the carbonyl stretching frequency of the carbonate group shifted to a lower frequency whereas the peak associated with C-O single bond moved to a higher frequency.

Ionic Liquid/Styrene-Acrylonitrile Copolymer Nanofibers as Chemiresistor for Alcohol Vapours

  • Kim, Min-Jae;Kang, Eun-Soo;Park, Dong-Wha;Shim, Bong-Sup;Shim, Sang-Eun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2867-2872
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    • 2012
  • SAN/$BMIPF_6$ nanofibers were fabricated by an electrospinning process and used as chemiresistors for sensing alcohol vapours. A hydrophobic and air-stable ionic liquid, $BMIPF_6$, was used to impart electrical conductivity to insulating SAN nanofibers. The effects of $BMIPF_6$ addition on the morphology of the nanofibers were explained in terms of surface tension, viscosity and conductivity. After exposing the SAN/$BMIPF_6$ nanofibers collected on an interdigitated electrode to alcohol vapours (ethanol, 1-propanol and 1-butanol), the resistance of the nanofibers decreased due to adsorption of alcohol molecules. The electrospun SAN/$BMIPF_6$ nanofibers sensor exhibited good sensitivity and reproducibility.

Dielectric Properties of Eicosamethyl Eneasiloxane (Eicosamethyl Eneasiloxane의 유전특성)

  • Cho, Kyung-Soon;Kim, Jae-Hwan;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1177-1179
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    • 1993
  • A study has been carried out on the characteristics of dielectric consent and the dissipation factor of Eicosamethyl Eneasiloxane as a function of frequency($30{\sim}10^5$[Hz]) and temperature(-70[$^{\circ}C$] to 65[$^{\circ}C$]). The result shows that a well-defined maxima of the absorption curves characterized by a dipole loss mechanism at a low temperature range. For temperatures in the vicinity of room temperature and higher, the loss in the range of power frequencies are predominantly of ionic nature. The increase of ionic conduction is attributed to the presence of ionizable oxidation products and their increased dissocation feature. The effect of viscosity upon the dipole loss intensity appeared to be considerably less pronounced than that upon ionic conduction loss.

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Heat-Induced Denaturation of Salt Soluble Protein Extracted from Spent Layer Meat (산란 노계육에서 추출한 염용성 단백질의 열변성에 관한 연구)

  • 이성기;장호선;김희주
    • Food Science of Animal Resources
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    • v.18 no.3
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    • pp.209-215
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    • 1998
  • Effects of protein concentration, ionic strength, pH, and temperature range on the heat-induced denaturation of salt soluble protein extracted from spent layer meat were investigated. Viscosity of salt soluble protein heated at 65$^{\circ}C$ for 30 min began to increase sharply above 7 mg/ml of breast protein concentration, and above 21 mg/ml of leg protein concentration, respectively. Both turbidity and viscosity showed the highest value in cooked protein solution with pH 6.0 and 1% NaCl. The turbidity of salt soluble protein started to increase continuously from 40$^{\circ}C$ to 80$^{\circ}C$. The viscosity increased rapidly from 45$^{\circ}C$ to 60$^{\circ}C$ in breast protein, and increased from 50$^{\circ}C$ to 55$^{\circ}C$ in leg protein, respectively, and then kept relatively constant. Breast protein had higher viscosity than leg protein during heat-induced gelation. Therefore, salt soluble protein from spent layer meat was associated with denatured protein (turbidity change) prior to gelation (viscosity change) during heating. Breast protein showed lower thermal transition temperature, and better gel formation than leg protein during heating.

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