• Journal of Oral Medicine and Pain
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• 제39권3호
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• pp.90-95
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• 2014

Purpose: To investigate viscosity and wettability of hyaluronic acid (HA) solutions according to supplementation of lysozyme and/or peroxidase, and different ionic strength and pH conditions. Methods: Solutions containing HA were prepared using distilled deionized water (DDW) and simulated salivary buffer (SSB) in different conditions. Different concentrations of hen egg-white lysozyme and bovine lactoperoxidase was added into HA solutions. HA solutions with antimicrobials in different ionic strength and pH conditions were prepared. Viscosity was measured using cone-and-plate digital viscometer at six different shear rates and wettability on acrylic resin and Co-Cr alloy was determined by contact angle. Results: The viscosity values of HA dissolved in DDW were decreased in order of HA, HA containing lysozyme, HA containing peroxidase, and HA containing lysozyme and peroxidase. The viscosity values for HA in DDW were decreased as the concentration of lysozyme and/or peroxidase increased. However, the viscosity values for HA in SSB showed no significant changes according to the concentration of lysozyme and/or peroxidase. The viscosity values of HA solutions were inversely proportional to ionic strength and pH. The contact angle of HA solutions showed no significant differences according to tested surface materials, addition of lysozyme and/or peroxidase, and different ionic strength and pH conditions. Contact angles on acrylic resin by HA solutions in all tested conditions were much higher than those by human saliva. Conclusions: The rheological properties of HA supplemented with lysozyme and/or peroxidase in different ionic strength and pH conditions were objectively confirmed, indicating the possibility of HA with lysozyme and/or peroxidase as main components in the development of effective saliva substitutes.

• 전기화학회지
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• 제13권3호
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• pp.198-202
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• 2010

Lithium co-polyelectrolyte-ionic liquid systems, using poly (lithium 2-acrylamido-2-methyl propanesulfonate; PAMPSLi) and polyvinyl formamid (PVF) were prepared and their electrochemical and physical properties were measured. The conductivity of co-polymer systems, PAMPSLi/PVF/N, N-dimethyl-N-propyl-N-butylammonium tricyanomethanide (PAMPSLi/PVF/$N_{1134}$TCM) and PAMPSLi/PVF/N, N-dimethyl-N-propyl-N-butylammonium dicyanamide (PAMPSLi/PVF/$N_{1134}$DCA) exhibited low viscosity ($N_{1134}$TCM:$N_{1134}$DCA 28.6cP, 28.7cP) and higher conductivity ($2.48{\times}10^{-3}Scm^{-1}$, $2.2{\times}10^{-3}Scm^{-1}$) than homopolymer system. The ionic conductivity PAMPSLi/PVF/1-ethyl-3-methyl imidazolium dicyanamide (PAMPSLi/PVF/emImDCA) exhibited $1.54{\times}10^{-3}Scm^{-1}$ and low viscosity (emImDCA: 28.09cP). High flexibility of imidazolium cation and dissociation of lithium cation from the co-polymer chains were affected by high conductivity and low viscosity.

• 전기화학회지
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• 제11권4호
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• pp.304-308
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• 2008

Noble Poly (lithium 2-acrylamido-2-methyl propane sulfonate) and its copolymer with N-vinyl formamide based on trihexyl (tetradecyl) phosphonium acetate [$(C_6H_{13})_3$ P ($C_{14}H_{29}$) $CH_3COO$; $P_{66614}$ $CH_3COO$] and trihexyl (tetradecyl)phosphonium bis(trifluoromethane sulfonyl) amide ([$(C_6H_{13})_3P(C_{14}H_{29})$] [TFSA];$P_{66614}TFSA$) were prepared and analyzed to determine their characteristics and properties. The ionic conductivity of a copolymer based $P_{66614}TFSA$ ionic liquid system exhibits a higher conductivity ($8.9{\times}10^{-5}Scm^{-1}$) than that of a copolymer based $P_{66614}CH_3COO$ system ($1.57{\times}10^{-5}Scm^{-1})$. The charge on the TFSA anion is spread very diffusely through the S-N-S core and particularly in the trifluoromethane groups, and this diffusion results in a decreased interaction between the cation and the anion. The viscosity of $P_{66614}TFSA$ (39 cP at 343 K) and $P_{66614}CH_3COO$ (124 cP at 343 K), which is very hydrophobic, was fairly high. High viscosity leads to a slow rate of diffusion of redox species. The ionic conductivity of copolymer of a phosphonium ionic liquid system also exhibits higher conductivity than that of a homopolymer system. Phosphonium ionic liquids were thermally stable at temperatures up to $400^{\circ}C$.

• 한국응용과학기술학회지
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• 제31권2호
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• pp.225-230
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• 2014

Several nitrile-functionalized ionic liquids have been prepared and characterized. An attempt was made to systematically characterize nitrile-functionalized ionic liquids on the basis of a few kinds of cations and anions. The detailed comparison of the differences in physicical characteristics such as UV-Vis spectroscopy, thermal stability, viscosity, solubility property, and electrochemical property before and after incorporation of a nitrile group were studied. The results showed that the incorporation of a nitrile group to cations could result in remarkable changes in these properties.

• 전기화학회지
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• 제12권3호
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• pp.271-275
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• 2009

Five novel lithium polyelectrolyte-ionic liquid systems, using poly (lithium 2-acrylamido-2-methyl propanesulfonate; PAMPSLi) were prepared and their electrochemical properties were measured. The ionic conductivity of the PAMPSLi/1-ethyl-3-methylimidazolium tricyano methanide (emImTCM) system was exhibited high conductivity (1.28 $\times$ $10^{-3}$ $S/cm^{-1}$). The high conductivity and low viscosity of PAMPSLi/emImTCM system is due to the high flexibility of imidazolium cation and dissociation of lithium cation from the polymer chains. The PAMPSLi/N,N-dimethyl-N-propyl-Nbutylammonium tricyanomethanide ($N_{1134}TCM$) and PAMPSLi/N, N-dimethyl-N-propyl-N-butylammonium dicyanamide ($N_{1134}DCA$) systems showed fairly high conductivity (6.3 $\times$ $10^{-4}$ $S/cm^{-1}$, 6.0 $\times$ 10.4 S/cm.1). PAMPSLi/Trihexyl (tetradecyl) phosphonium bis (trifluoromethane sulfonyl) amide ($P_{66614}TFSA$) exhibited low conductivity (2.22 $\times$ $10^{-5}$ $Scm^{-1}$) and thermally stable over 400$^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• 제20권11호
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• pp.1329-1334
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• 1999

The curing characteristics of diglycidyl ether of bisphenol A (DGEBA) with diaminodiphenylmethane (DDM) as a curing agent were studied using differential scanning calorimetry (DSC), rheometrics mechanical spectrometry (RMS), and dielectric analysis (DEA). The isothermal curing kinetics measured by DSC were well represented with the generalized auto-catalytic reaction model. With the temperature sweep, the inverse relationship between complex viscosity measured by RMS and ionic conductivity obtained from DEA was established indicating that the mobility of free ions represented by the ionic conductivity in DEA measurement and the chain segment motion as revealed by the complex viscosity measured from RMS are equivalent. From isothermal curing measurements at several different temperatures, the ionic conductivity contribution was shown to be dominant in the dielectric loss factor at the early stage of cure. The contribution of the dipole relaxation in dielectric loss factor became larger as the curing further proceeded. The critical degrees of cure, at which the dipolar contribution in the dielectric loss factor starts to appear, increases as isothermal curing temperature is increased. The dielectric relaxation time at the same degree of cure was shorter for a sample cured at higher curing temperature.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.378-378
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• 2009

The ionic liquid-based sulfonated hydrocarbon composite membranes was prepared for use in anhydrous high temperature-polymer electrolyte fuel cells (HT-PEFCs). Ionic liquid behaves like water in the composite membranes under anhydrous condition. However the composite membranes show a low conductivity and high gas permeability as the content of ionic liquid increases due to its high viscosity and content of ionic liquid, respectively. Hence, in order to enhance the proton conductivity and to reduce the gas permeability of the composite membranes with low content of ionic liquids, the acid containing a common ion of ionic liquid was added to the composite membranes. The characterization of composite membranes was carried out using small-angle X-ray scattering (SAXS), thermogravimetric analyzer (TGA) and impedance spectroscopy. As a result, the composite membranes containing acid showed higher proton conductivity than those with no acid under the un-humidified condition due to a decrease in viscosity. In addition, the proton conductivity of composite membranes increased with increasing mole concentration of acid.

• 폴리머
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• 제32권5호
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• pp.409-414
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• 2008

전기방사법으로 이온염을 함유하는 TFE/증류수 혼합용매를 이용하여 젤라틴 나노섬유를 제조하였으며, 얻어진 나노섬유의 평균직경은 $110{\sim}125\;nm$였다. 이온염의 농도가 증가할수록 비드의 발생이 줄어들고 균일한 나노섬유 제조가 가능하였다. 이는 이온염의 첨가에 의한 젤라틴 용액의 점도 및 전도도가 증가함에 기인하는 것으로 확인되었다. 특히 일가이온보다 이가이온을 사용할 경우 점도 및 전도도의 증가에 더 효과적이었으며 이들 이온염은 분자간 소수성 상호작용뿐만 아니라 젤라틴 분자의 입체구조 정렬에도 영향을 주었다. 그러나 이온염 농도에 따른 나노섬유의 직경변화는 관찰되지 않았다. 제조된 나노섬유를 이용한 XRD분석 결과 이온염의 농도가 증가할수록 젤라틴 분자의 재결정화에 의해 나노섬유의 결정화도가 높아졌다.

• 한국군사과학기술학회지
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• 제25권3호
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• pp.285-291
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• 2022

In order to use the liquid rocket fuel, 1,5-diamino-4-methyltetrazolium azide, [DMT]⁺[N₃]^- and 1,5-diamino-4-methyltetrazolium cyanide, [DMT]⁺[CN]^- were synthesized and prepared the ionic liquid rocket fuel after dissolving the synthesized solid-type energetic chemicals in hydrazine, respectively. The thermal decomposition temperatures(T_d) and densities(d) of the prepared ionic liquid rocket fuels were about 200 ℃ and above 1.0 g/cm³ respectively. The ignition delay times(I_dt) of the ionic liqud rock fuels with [DMT]⁺[N₃]^- and [DMT]⁺[CN]^- were in a range of 26.6 - 82.5 ms and the 44.0 - 98.5 ms, respectively. These results mean that the synthesized tetrazolium salts could be used as an ionic liquid rocket fuels. The viscosities of the ionic liqud rock fuels with [DMT]⁺[N₃]^- and [DMT]⁺[CN]^-, which were dissolved in mixture solution of hydrazine/2-hydroxyethylhydrazine were to be 1.34 - 101 cP, and 1.29 - 80.5 cP, respectively. The synthesized ionic liquid rocket fuels in this study could be used as rocket fuel because the [I_dt(100 ms or less), T_d(150 ℃ or more), d(1.00 g/cm³ or more), and η(40.0~ 100 cP)] were achieved to satisfy the range of the used liquid rocket fuels.

• 융복합기술연구소 논문집
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• 제4권2호
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• pp.23-26
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• 2014

As an effective separation method for biomolecules, aqueous two-phase systems based on ionic liquids were suggested. Hydrophobic ionic liquids are more expensive and viscous in spite of their usage in the ionic liquid/water biphasic extraction compared with hydrophilic ionic liquids. In case of aqueous two-phase systems using hydrophilic ionic liquids, they can be diluted in aqueous phase. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of ionic liquids to aqueous salts solutions. The viscosity of ionic liquid aqueous phase is proportional to the cation chain length in ionic liquids. It is founded that the ionic liquid based aqueous two phase systems are effective for the separation of biomolecules such as acrylic acid.