• Title/Summary/Keyword: ion-exchange reaction

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Purification and Some Physicochemical Study of Bacillus cereus $\beta$-Amylase (Bacillus cereus $\beta$-아밀라아제의 정제 및 이화학적 성질)

  • 송예헌
    • The Korean Journal of Food And Nutrition
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    • v.6 no.4
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    • pp.307-313
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    • 1993
  • Bacillus cereus $\beta$-amylase was purified by Sephadex G-100 gel filtration, CM Sephadex C-50 ion exchange chromatography and CM Sephadex C-50 ion exchange rechromatography The purified enzyme showed 871 unit/mg of specific activity. The purified enzyme was identified as homogenious by disc PAGE, SDS-PAGE and analysis of reaction product. The purified enzyme showed optimum pH 7.0. optimum temperature 5$0^{\circ}C$, and was stable at 0~5$0^{\circ}C$ and at pH range of 6~10.

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A Comparative Analysis of Pseudophase Ion-Exchange (PIE) Model and Berezin Pseudophase (BPP) Model: Analysis of Kinetic Data for Ionic Micellar-mediated Semi-ionic Bimolecular Reaction

  • Cheong, May-Ye;Ariffin, Azhar;Khan, M.Niyaz
    • Bulletin of the Korean Chemical Society
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    • v.28 no.7
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    • pp.1135-1140
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    • 2007
  • Pseudo-first-order rate constants (kobs) for the reaction of N-benzylphthalimide (NBPT) with HO- have been determined at 2.0 × 10?4 M NBPT, 1.0 × 10?3 and 2.0 × 10?3 M NaOH as well as varying concentrations of cetyltrimethylammonium bromide ([CTABr]T = 0.0-1.7 × 10?1 M). The effects of [CTABr]T ? CMC (with CMC representing the critical micelle concentration of CTABr) on kobs have been analyzed in terms of Berezin's pseudophase (BPP) model and pseudophase ion-exchange (PIE) model. Although both models give the best observed data fit with least-squares values not significantly different from each other, the calculated values of KS from BPP model appear to be more reliable compared to those from PIE model because the values of KS from BPP model are similar to the corresponding KS values determined spectrophotometrically.

An Experimental Study on the Ion Reaction and the Electrochemical Rebar-Corrosion in Aqueous Solution Mixed with Sulfate and Chloride Ion-Reactive Material (황산, 염소이온 반응 소재 혼입 수용액에서의 이온반응성 및 전기화학적 철근 부식에 관한 실험적 연구)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Kang, Tae-Won;Lim, Chang-Gil;Kim, Hong-Tae
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.1
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    • pp.31-38
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    • 2019
  • In this study, amine derivatives and ion exchange resins were selected to actively control penetration ions ($SO{_4}^{2-}$, $Cl^-$) as the element technology of repair materials for concrete structures in drainage environments. Ions ($SO{_4}^{2-}$, $Cl^-$) adsorption performance and corrosion resistance of calcium hydroxide solution with amine derivative and ion exchange resin were confirmed by ion chromatography and potentiostat analysis. As a result of the experiment, it was confirmed that the amine derivative is excellent in the adsorption of chlorine ion and the ion exchange resin is excellent in the adsorption of sulfate ion. It has been confirmed that corrosion resistance can be increased by proper combination of two materials in the calcium hydroxide solution containing sulfate ion and chloride ion simulating sewage environment.

Synthesis of Cation-Exchange Membrane by the Monomer Sorption

  • Park, Yong-Jin;Moon, Seung-Hyeon
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.1-4
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    • 2003
  • LDPE/polystyrene cation exchange membranes were prepared through a monomer-sorption method and UV radiation polymerization. The reaction behaviors in the preparation were investigated. The membranes prepared were characterized in terms of physical and electrochemical properties. The membranes exhibited reasonable properties for an ion-exchange membrane with weight gain (Wr) of above 0.3, electrical resistance of below 1.0 Ω $\textrm{cm}^2$ and ion-exchange capacity of 1.8 meq/g-dry membrane. DSC studies and FE-SEM image revealed the formation of a homogeneous membrane. Both the current-voltage and the chronopotentiometric curves of the membranes indicated that LDPE/polystyrene membranes can be properly used at a high current density, and the surface homogeneity of cation-exchange sites in the membrane was comparable to that in a commercial membrane.

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The Effects of Zeolite Structure and Ion-exchange Material on NH3-SCR Reaction (제올라이트 종류 및 이온교환 물질에 따른 NH3-SCR 촉매 반응 특성)

  • Hwang, Inhye;Lee, Junho;Kim, Hongsuk;Jeong, Youngil
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.1
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    • pp.135-141
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    • 2014
  • $NH_3$-SCR has high NOx removal efficiency approximately 80~90%. Recently, the copper or iron ion-exchanged zeolite catalysts are widely used as automobile SCR catalysts. In this paper, the effect of the space velocity, temperature of reaction and $NO_2$ addition on the $NH_3$-SCR reaction were studied using various zeolite SCR catalysts. The test was conducted with small sized fresh catalysts in a laboratory fixed-bed flow reactor system using simulated gases. It is found that the activity of the BEA is better than MFI. It seems that three-dimensional framework and a wide pore entrance of BEA enhances the SCR activity. It is also found that low temperature activity of Cu-zeolites was better than Fe-zeolites. Once $NO_2$ was added, the NOx conversion activity of the Cu-zeolite was slightly enhanced, whereas remarkable improvement was achieved by Fe-zeolite.

Heavy Metal Son Exchange Reaction in Boron-Rich Containing Plants (다량의 붕소원소를 함유하는 식물의 중금속 이온 교환반응)

  • 배계선;성대동
    • Journal of Environmental Science International
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    • v.5 no.6
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    • pp.757-762
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    • 1996
  • The removal effectiveness of various heavy metal ions in boron-rich containing plants has been studied by means of spectroscopic and pH methods. Treatment of the boron-rich containing sample which was collected from cherry and root of cabbage to heavy metal ions is resulted in that an excellent removal effect shows in the case of large ionic size of heavy metal. Stability constants are depended on the variation of pH.

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Application of Capacitive Deionization Packed Ion Exchange Resins in Two Flow Channels (두 가지 유로 형태에 따라 이온교환수지를 채운 축전식 탈염기술)

  • Lee, Dong-Ju;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.18 no.1
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    • pp.24-30
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    • 2015
  • To desalinate the aqueous solutions with high salt concentration using the capacitive deionization technology, two resin/membrane capacitive deionization(RMCDI) cells were fabricated by filling mixed ion exchange resins in two different flow channels (spacer and spiral type). The salt removal efficiency of the spacer- and spiral-RMCDI was 77.21 and 99.94%, respectively. Many ions were significantly removed in a spiral RMCDI cell because the feed solution could be more evenly contacted with the ion exchange resins filled on the spiral type flow channel. As the result of the changes of pH and accumulative charges, it was observed that Faradaic reaction was diminished for a spiral RMCDI cell filled by the mixture of cation and anion exchange resins. Therefore, the desalination of the aqueous solutions with high salt concentration by the capacitive deionization technology was proven. In addition, further studies on the optimization of the mixing ratio with ion exchange resins and the introduction of the regeneration process generally occurred in the continuous electrodeionization (CEDI) technology are required to improve the RMCDI technology.

Drug Release Characteristics of Famotidine-Cationic Exchange Resin Complexes and Their Pharmacokinetics in Rats (파모티딘-양이온 교환수지 복합체의 약물방출 특성 및 흰쥐에서의 체내동태)

  • Shin, Dong-Sun;Song, Woo-Heon;Choi, Young-Wook
    • Journal of Pharmaceutical Investigation
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    • v.27 no.4
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    • pp.313-321
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    • 1997
  • Ion exchange resin complexes of famotidine have been prepared by the reaction of famotidine solution with activated ion exchange resins. Complex formation efficiency between famotidine and ion exchange resin was about $80{\sim}90%$ in average, calculated by HPLC determination. Drug release characteristics from the resin complexes were evaluated by the modified percolation method. Famotidine release was dependent on the type of ion exchange resins. In the case of weakly acidic resin complexes, the cumulative released amount of famotidine was more than 90% for 1hr in pH 1.2 buffer solution. However, in the case of strongly acidic resin complexes, it was less than 5% for 3hr in the same medium. Strongly acidic resins revealed some advantages over weakly, acidic resins for overcoming instability of famotidine in gastric juice. In addition, strongly acidic resin complexes showed controlled release of famotidine in pH 6.8 buffer solution, showing the result of about 60 to 70% of drug release for 5hr. After oral administrations of famotidine-resin complexes to rats as dose of 40 mg equivalent/kg, the pharmacokinetic parameters of famotidine were obtained by model independent analysis and compared with those of famotidine solution or suspension. $C_{max}$ of famotidine-resin complex was lower than that of famotidine solution or suspension. MRT, MAT, and MDT of the complexes were greater than those of famotidine solution or suspension. From these results, it was expected that famotidine was released slowly from the complexes and absorbed continuously into systemic circulation. It was recognized that drug release from the complexes was the rate-limiting step in drug absorption, since there were close correlations between in vitro drug release and in vivo pharmacokinetic parameters.

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Preparation and Properties of Sulfonated Polyvinylchloride (PVC) Membrane for Capacitive Deionization Electrode by Ultra Sonication Modification (초음파 표면개질에 의한 CDI 전극용 술폰화 염화비닐(PVC) 멤브레인의 제조 및 특성)

  • Hwang, Chi Won;Oh, Chang Min;Hwang, Taek Sung
    • Journal of Adhesion and Interface
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    • v.15 no.1
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    • pp.1-8
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    • 2014
  • Ion exchange membrane is widely used in various fields such as electro dialysis, diffusion dialysis, redox flow battery, fuel cell. PVC cation exchange membrane using ultrasonic modification was prepared by sulfonation reaction in various sulfonation times. Sulfuric acid was used as a sulfonating agent with ultrasonic condition. We've characterized basic structure of sulfonated PVC cation exchange membrane by FT-IR, EDX, water uptake, ion exchange capacity (IEC), electrical resistance (ER), conductivity, ion transport number and surface morphology (SEM). The presence of sulfonic groups in the sulfonated PVC cation exchange membrane was confirmed by FT-IR. The maximum values of water uptake, IEC, electrical resistance and ion transport number were 40.2%, 0.87 meq/g, $35.2{\Omega}{\cdot}cm^2$ and 0.88, respectively.

Electrical Conductivity in oxide glasses subjected to a sodium silver ion-exchange treatment (산화물유리에서의 $Na^{+}$이온과 $Ag^{+}$이온 교환에 따른 전기전도도 변화에 관한 연구)

  • 한준수;강원호;이효경
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.100-105
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    • 1995
  • Bulk glasses in the system $Na_2O$-CaO-$Al_2O_3$-$B_2O_3$-$SiO_2$ containing 20 to 30 mol% sod-ium hav been subjected to a sodium silver ion-exchange reaction for 0, 24, 36, 48 jr were analysed by electrical characterization Ion-exchanged glasses exhibit resistivity and activation energy values lower than those of the untreated ones. The electrical conductivity increase with sodium content and ion-exchanged time. In this experiment the electrical conductivity exhibit a maximum value of 1.78${\times}$10$^{-4}$S/cm at $200^{\circ}C$ which contains 30 mol% sodium and subjects ion-exchange reaction for 48hr.

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