• 마이크로전자및패키징학회지
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• 제10권4호
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• pp.61-64
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• 2003

단일이온교환된 유리의 응력 특성을 관찰하기 위하여 파괴분석을 하였다. 프로세스변화로 인하여 이온교환된 유리의 응력층이 유리표면에서 안쪽으로 이동하였다. 깃털모양자국(hackle marker)과 거울면(mirror region)의 크기가 이온교환프로세스의 온도, 시간에 따라 변화하였으며, 파괴강도에 비례하였다. 또한 Indenter를 사용하여 응력층을 파괴하는 경우 일반유리와 같은 파괴특성을 나타냈다.

• 한국군사과학기술학회지
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• 제13권6호
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• pp.1121-1126
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• 2010

Borosilicate glass (81% $SiO_2$-2% $Al_2O_3$-13% $B_2O_3$-4% $Na_2O_3$) was prepared, and the glass was ion exchanged in $KNO_3$ powder containing different temperature and time. The $K^+-Na^+$ ion exchange takes place at the glass surface and creates compressed stress, which raise the mechanical strength of the glass. The depth profile of $Na^+$ and $K^+$ was observed by electron probe micro analyzer. With the increasing heat-treatment time from 0min to 20min, the depth profile was increased from 17.1um to 29.4um, but mechanical properties were decreased. It was also found out that excessive heat treatment brings stress relaxation. The Vickers hardness, Fracture Toughness and bending strength of ion exchanged samples at $570^{\circ}C$ for 10min were $821.8H_v$, $1.3404MPa{\cdot}m^{1/2}$, and 953MPa, which is about 120%, 180%, and 450% higher than parent borosilicate glass, respectively. Transmittance was analyzed by UV-VIS-NIR spectrophotometer. Transmittance of ion exchanged borosilicate glass was decreased slightly at visible-range. It can be expected that transparent bulletproof materials in more light-weight and thinner by ion exchanged borosilicate glass.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 하계학술대회 논문집
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• pp.182-182
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• 2010

The behavior of properties of ion exchanged substrate glasses was investigated in this study. In order to study the effects of ion exchange, ion exchange behavior with ion penetration depth, amount of ion exchange, density and thermal expansion was measured according to the time and temperature. The mechanical properties were evaluated by the three point bending test and curvature change, and then fracture patterns were investigated by optical microscope.

• 한국군사과학기술학회지
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• 제16권4호
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• pp.507-513
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• 2013

Transparent bulletproof windows play an important role in the munitions industry. The thickness of bulletproof windows including soda-lime silicate(SLS) glass, polyvinyl butyral, poly urethane, main defense(200MD), and safety film was reduced from 40mm to 29mm by adjustment of SLS glass laminated array. Borosilicate glasses generally have lower surface density and more excellent mechanical properties than SLS glass. Borosilicate glass was strengthened by ion exchange in the $KNO_3$ powder. The maximum mechanical properties were observed at $550^{\circ}C$ for 10min. The Vickers hardness, fracture toughness and 3-point bending strength of ion exchanged samples were about $775kg/mm^2$, $1.91MPa{\cdot}m^{1/2}$ and 764MPa each, which are about 27%, 149% and 249% higher than parent borosilicate glass, respectively. The penetration depth of K+ ion at $550^{\circ}C$ for 10min was $59.8{\mu}m$. As a result, the transparent bulletproof windows were predicted to be more lightweight by ion exchange of borosilicate glass. If the SLS glass for bulletproof windows is replaced by ion exchanged borosilicate glass, the bulletproof windows can be expected to be lightweight and thinner.

• 한국세라믹학회지
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• 제33권2호
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• pp.242-250
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• 1996

Glasses of Na2O-Al2O3-SiO2 system were prepared and ion-exchange characteristics change of properties and bactericidal effects by Na+↔Ag+ ion exchange were studied. Parent glasses with three compositions of varying Na2O in the 20~30 wt% were ion-exchanged in the molten salt of 2 mol% AgNO3+98 mol% NaNO3 at 320~36$0^{\circ}C$ for 15~16min. Amount of ion exchange and penetration depth of Ag+ ion increased with Na2O content in the parent glass ion exchange temperature and time. After ion exchange densities and Vickers hardness of the glasses increased and the glasses showed yellow-brown color and as amount of ion exchange increased the color turned deep because partial reduction and agglomeration of Ag+ into Ag0 results in absorption of visible light. After ion exchange chemical durability of the glass to wter was enhanced compara-bly that weight loss and change of surface of the glass were not found for the leaching test in 5$0^{\circ}C$ K.I water for 240hrs. Bactericidal effect of ion exchanged glass on Staphylococcus aureus and E. coli was determined by microorganism test and bactericidal effect increased with amount of ion exchange and incubation time.

• 한국세라믹학회지
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• 제52권2호
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• pp.123-127
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• 2015

Soda-lime silicate (SLS) glass was strengthened by ion exchange for application of thin and lightweight bulletproof windows. The optimal conditions for ion exchanged SLS glass (thickness of 3 and 10 mm) at $480^{\circ}C$ were 10 and 17 min, respectively. The Vickers hardness values of the strengthened SLS glass samples with thicknesses of 3 and 10 mm were $5.9{\pm}0.22$ and $6.7{\pm}0.17GPa$, respectively, which values were about 22% higher than those of parent SLS glass. By laminating a multilayer defense film and polycarbonate sheet with ion exchanged SLS glass, we were able to make a thin and lightweight bulletproof window (24.25 mm, 4.57 kg, $50.06kg/m^2$, $V_{50}$ 901.8 m/s). As a result, the thickness of the bulletproof window was decreased by about 39% from 40 to 24.25 mm. The light transmittance in the visible range satisfied the standard (over 76%) for bulletproof windows.

• 한국세라믹학회지
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• 제52권2호
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• pp.133-136
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• 2015

The outward diffusion of $Na^+$ ions in iron-bearing soda lime silicate glass via oxidation heat treatment before the ion exchange process is artificially induced in order to increase the amount of ions exchanged during the ion exchange process. The effect of the addition process is analyzed through measuring the bending strength, the weight change, and the inter-diffusion coefficient after the ion exchange process. The glass strength is increased when the outward diffusion of $Na^+$ ions via oxidation heat treatment before the ion exchange process is added. For the glass subjected to the additional process, the weight change and diffusion depth increase compared with the glass not subjected to the process. The interdiffusion coefficient is also slightly increased as a result of the additional process.

• 한국광학회지
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• 제3권3호
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• pp.198-202
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• 1992

은 이온 교환법으로 만든 유리 도파로는 표면 굴절율 차가 크고 도파로 깊이가 얕기 때문에 반도체 박막 이식법을 이용한 반도체 소자와 유리 도파로의 혼성 집적에 사용되기에 적합하다. 이 노문은 묽게한 잘산화은 용액에서 이온 교환으로 만들어진 평면 및 채널 유리 도파로의 가시광선 및 적외선 파장영역에서의 특성을 보고한다. 특히 광통신에 중요한 파장인 1.5.$\mu$m에서의 단일 모우드 채널 도파로의 제작 조건을 결정하였다. 또한 여러가지 다른 구성 형태의 방향성 결합기가 제작되어 파장과 편광 방향에 따른 3dB 결합 길이가 결정되었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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• pp.130-132
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• 1994

We fabricated Ag ion exchange glass waveguide. Generally, ion-exchange glass waveguide. are suitable for passive integrated optical components such as directional and star couplers. Its advantages include low loss, ease of fabrication, and low material cost. So, we faricated Ag ion-exchange glass waveguides in AgNO$_3$ melt solution from 2 mole %. And we used Sodalime glass as a substrate in the fabrication process. As the results, we observed multivalent ion-exchange in a typical sodalime glass. Diffusion coefficient and depth are predicted by actual experimental data of Stewart. The exchange rate in silver-ion-exchanged waveguides are compared to the exchange time of waveguide fabrication.

• E2M - 전기 전자와 첨단 소재
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• 제9권3호
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• pp.284-290
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• 1996

The electrical properties of bulk galsses in the system Na$_{2}$O-CaO-Al$_{2}$O$_{3}$-B$_{2}$O$_{3}$-SiO$_{2}$ containing 20 to 30mol% sodium which have been subjected to a sodium .tautm. silver ion exchange reaction for 24, 36 and 48 hrs. were analysed by impedance spectroscopy method. Ion exchanged glasses exhibit activation energy values lower than those of the untreated ones. The electrical conductivity increase with sodium content and ion exchanging time. In this experiment the electrical conductivity exhibits a manximum value of 1.78*10$^{-4}$ S/cm at 200.deg. C which contains 30mol% sodium and subjects ion exchange reaction for 48hrs.