• Title/Summary/Keyword: ion exchange treatment

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Livestock Wastewater Treatment by Zeolite Ion Exchange and Gamma-ray Irradiation (제올라이트와 감마선을 이용한 축산 폐수 처리)

  • Lee, Sang-Ryul;Kim, Tak-Hyun;Lee, Myun-joo
    • Journal of Radiation Industry
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    • v.2 no.1
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    • pp.9-14
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    • 2008
  • Livestock wastewater containing high concentrations of organic matters and ammonia-nitrogen has been known as one of the recalcitrant wastewater. It is difficult to treat by conventional wastewater treatment techniques. This study was carried out to evaluate the feasibility of zeolite ion exchange and gamma-ray irradiation treatment of livestock wastewater. The removal efficiencies of $SCOD_{Cr}$ and $NH_3-N$ were significantly enhanced by gamma-ray irradiation after zeolite ion exchange as a pre-treatment. However, the effects of zeolite particle size on the $SCOD_{Cr}$ and $NH_3-N$ removal efficiencies were insignificant. These results indicate that the combined process of zeolite ion exchange and gamma-ray irradiation has potential for the treatment of livestock wastewater.

Study of Electrochemical Cs Uptake Into a Nickel Hexacyanoferrate/Graphene Oxide Composite Film

  • Choi, Dongchul;Cho, Youngjin;Bae, Sang-Eun;Park, Tae-Hong
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.123-130
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    • 2019
  • We investigated the electrochemical behavior of an electrode coated with a nickel hexacyanoferrate/graphene oxide (NiPB/GO) composite to evaluate its potential use for the electrochemical separation of radioactive Cs as a promising approach for reducing secondary Cs waste after decontamination. The NiPB/GO-modified electrode showed electrochemically switched ion exchange capability with excellent selectivity for Cs over other alkali metals. Furthermore, the repetitive ion insertion and desertion test for assessing the electrode stability showed that the electrochemical ion exchange capacity of the NiPB/GO-modified electrode increased further with potential cycling in 1 M of $NaNO_3$. In particular, this electrochemical treatment enhanced Cs uptake by nearly two times compared to that of NiPB/GO and still retained the ion selectivity of NiPB, suggesting that the electrochemically treated NiPB/GO composite shows promise for nuclear wastewater treatment.

The Limiting Current Density and the Regeneration of a Heterogeneous Ion Exchange Membrane in a Nickel Plating Rinse Waters Treatment Process by Electrodialysis (전기투석에 의한 니켈도금 폐수처리 공정에서 한계전류밀도와 불균질 이온교환막의 재생)

  • 윤용수
    • Journal of environmental and Sanitary engineering
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    • v.16 no.2
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    • pp.38-46
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    • 2001
  • In this work, the heterogeneous ion exchange membrane was used in a electrodialysis apparatus to treat a Ni planting rinse water because the heterogeneous ion exchange membrane was excellent efficiency as compared with low manufacturing cost, was easy to make, and had a good mechanical properties. For a regeneration of membrane and to obtain the optimal condition for a scale-up of apparatus after treating Ni plating rinse water, we would find about the limiting current density and the concentration polarization. When the Ni plating rinse water 150mg/L was treated with the electrodialysis apparatus using the heterogeneous ion exchange membrane, the limiting current density was about $1.49{\;}mA/\textrm{cm}^2$. And the limiting current density increased with the flow rate and concentration of Ni plating rinse water. We recognized that the used membrane could be reused by periodic backwashing because efficiency was constant when the membrane was backwashed after treating wastewater.

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Applicability Evaluation of the Wastewater Treatment System Using Magnetic Ion Exchange Resin in the Existing Wastewater Treatment Plant (기존하수처리장에서 자성체 이온교환수지를 이용한 하수처리공정 적용가능성 평가)

  • Park, Chan G.;Kim, Hee S.;Lee, Jung M.
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.2
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    • pp.35-40
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    • 2014
  • The optimal removal efficiency to develop wastewater treatment system using the magnetic ion exchange resin. The secondary sedimentation effluent of wastewater in W wastewater treatment plant located in Gyeong-gi Province was used as the influent. To compare the sedimentation effluent reacted with the magnetic ion exchange resin to the influent, the concentrations of CODmm, TN, $NO{_3}^-$-N and TP were measured. The flux of the influent and HRT were set to 250 mL/min, 10 min, respectively, and BVTR has adjusted to 200, 150, 100. The removal efficiency of CODmn, TN, $NO{_3}^-$-N and TP in the 200 BVTR from 71%, 40.37%, 46.34%, 42.03%, 150 BVTR from 55.22%, 37.83%, 50.38% 41.6% and 100 BVTR from 74%, 59.15%, 79.94%, 79.16%, respectively. The results on 200 BVTR, 150 BVTR, 100 BVTR tests show that 100 BVTR is the optimal factor capable of the highest rate of rejection of the organic material.

Effects of Extraction Method on the Carnosine, Protein, and Iron Contents of Eel (Anguilla japonica) Extracts (뱀장어 (Anguilla japonica) 추출물 중의 Carnosine, 단백질 및 철분 함량에 미치는 추출방법의 영향)

  • Song, Ho-Soo;Lee, Keun-Tai;Kang, Ok-Ju
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.39 no.5
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    • pp.384-390
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    • 2006
  • To improve the extractability of carnosine and the levels of pro-oxidants such as iron in eel (Anguilla japonica) extracts, we examined the effects of extraction time, temperature, ion exchange chromatography and ultrafiltration (UF). The respective protein and total iron were reduced approximately 55 and 60% at 60$^{\circ}C$, 63 and 70% at 80$^{\circ}C$, 68 and 76% at 100$^{\circ}C$ and 82 and 48% with ion exchange chromatography, respectively, compared to the untreated extract. However, there was no significant difference in the carnosine levels in the eel extracts. Ultrafiltration reduced the protein content of the extract by 52% compared with the untreated extract. UF reduced the protein contents of the samples from 60, 80, and 100% heat treatment and ion exchange chromatography treatment by 27, 50, 46 and 47%, respectively. UF reduced the total iron contents of the identical four treatments by 14, 22, 23, and 43%, respectively, while UF increased the carnosine by 23, 17, 20, and 6%, respectively.

Preparation of Cation-exchange Resin from Lignin

  • Kamelt S.
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.5 s.108
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    • pp.78-84
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    • 2004
  • Lignin precipitated from black liquor of soda pulping of bagasse was used to prepare cation-exchange resin. The effect of sulfuric acid treatment, concentration of phenol and formaldehyde on the properties of the prepared cation-exchange resin was investigated. It was found that sulfonated resinified phenolated lignin gave a resin with an ion-exchange capacity higher than that of resin, which resulted from sulfonation of resinified lignin at zero phenol concentration. Infrared spectroscopy of the prepared ion-exchange resin shows anew bands at 1060, 1160, 1280 and $1330\;cm^{-1}$ which indicated to the presence of $SO_{3}$.

The Effect of Rapid Freeze Pretreatment on Grinding of Organic Ion Exchange Resins (금속동결 전처리에 의한 유기이온 교환수지의 분쇄효과)

  • Yim, Sung-Pal;Kim, Joun-Hyeong;Son, Jong-Sik
    • Applied Chemistry for Engineering
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    • v.1 no.1
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    • pp.23-29
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    • 1990
  • The effect of a rapid freeze pretreatment of organic ion exchange resins on their grinding properties was studied. It was found that the structure of ion exchange resins was defected by freezing pressure formed in the process of rapid freezing. The defected resins didn't recover their own structure after thawing and those could be easy to be broken at room temperature by small force. Therefore, organic ion exchange resins could be ground readily at room temperature after rapid-freezing the fully swelled resins using by solid carbon dioxide, or liquid nitrogen. The rapid freeze pretreatment of cation exchange resins was very effective on grinding in particular. However, the effect of the pretreatment of anion exchange resins on grinding was less than that of cation exchange resins. In case of anion exchange resins, the ionic form of affected the grindability remarkably.

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Preparation and Characterization of ion Exchange Membrane for Direct Methanol Fuel Cell(DMFC) Using Sulfonated Polysulfone (설폰화 폴리설폰을 이용한 직접메탄올연료전지용 이온교환막의 제조 및 특성 연구)

  • 신현수;이충섭;전지현;정선영;임지원;남상용
    • Membrane Journal
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    • v.12 no.4
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    • pp.247-254
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    • 2002
  • In order to develop the ion exchange membranes which would be used in direct methanol fuel cell (DMFC), the polysulfone polymer was sulfonated using chlorosulfonic acid (CSA) and trimethylchlorosilane(TMCS). It has been characterized in terms of ion conductivities, methanol crossover, swelling degree and ion exchange capacities for the heat untreated and treated membranes at $150^{\circ}C.$ Typically, the methanol permeability and ion conductivity at the mole ratio of 1.4 between polysulfone repeating unit and sulfonating agents showed $2.87{\times}10^{-7}\; cm^2/s$(without heat treatment), $1.52{\times}10^{-7}\; cm^2/s$(with heat treatment) and $1.10{\times}10^{-2}\; S/cm$(without heat treatment), $0.87{\times}10^{-2}\;$ S/cm(with heat treatment), respectively. After the mole ration of 1.4 both values indicated mild increase.

Comparison of the Ion-exchange Method and Evaporation Method for the Detection of Radioactivity in Water (수중 방사능 측정시 이온교환농축법과 증발건조법의 비교)

  • Ji, Pyung-Gook;Park, Chong-Mook;Ro, Seung-Gy
    • Journal of Radiation Protection and Research
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    • v.13 no.2
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    • pp.52-56
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    • 1988
  • An ion-exchange method for the detection of radioactivity in water using ion-exchange resin in concentrating radioactive nuclides was compared with an evaporation method. The loss of the radioactive materials in the sample treated by the ion-exchange method was less by about 20% than that by the evaporation method. In addition, the evaporation method needed about 20 hours for evaporating one liter of the sample at $70^{\circ}C$, while the ion-exchange method spent 6 hours to adsorb and adsorb the same amount of the sample on the resin. Consequently, the ion-exchange method is more effective than the evaporation method for the treatment of the radioactively contaminated water and is especially suitable for detecting the low-level radioactivity in water.

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Characterization of Glasses by Ion-Exchange (III) : Behavior of Optical Properties (이온교환에 따른 유리의 특성화(III) : 광학적 특성 거동)

  • 이동인
    • Journal of the Korean Ceramic Society
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    • v.27 no.1
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    • pp.67-73
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    • 1990
  • The behavior of optical properties of ion exchanged glasses was investigated inthis study. The used glasses were soda-lime-silica glasses that were produced by float process. The coloring effect by Ag colloids is measrued by spectral transmittance, color coordinates, dominant wavelength and excitation purity resulting from silver ions exchange of glasses immersed into the mixed molten salt with AgNO3. Ion exchange coloring of glasses made it possible to obtain glasses with a range from yellow to brown, and transmittance was decreased with increasing the amount of Ag colloids which reduced from Ag+ions. Also, obtain from yellow to reddish brown with increasing purity by reheating treatment in air for ion exchanged glasses. The size of Ag colloids are 0.02~0.1${\mu}{\textrm}{m}$ with ion exchange conditions.

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