• Journal of the Korean Chemical Society
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• v.37 no.9
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• pp.820-825
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• 1993

The ion exchange capacity of HDBPDA ion exchanger, {(4,5) : (13,14)-dibenzo-6,9,12-trioxa-3,15,21-triazabicyclo[15.3.l]heneicosa-(1,17,19)(18,20,21) triene ion exchanger: HDBPDA ion exchanger} was 3.8 meq/g. The distribution coefficients of alkali and alkaline earth metal ions in water and the various concentration of hydrochloric acid were determined. Concentration of hydrochloric acid have almost not influenced on the distribution coefficients of alkali and alkaline earth metal ions, but generally, the distribution coefficient was slightly increased with decrease of concentration of hydrochloric acid. The distribution coefficients of metal ions in water are larger than those of various hydrochloric acid concentrations. Also, alkali and alkaline earth metal ions are separated by column ion exchange chromatography using HDBPDA ion exchange with water as eluent. The distribution coefficents of alkali and alkaline earth metal ions were increased with increase of ionic radii of metal ions.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.7
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• pp.730-737
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• 2010

It is very important to remove fluoride ion before treating semiconductor wastewater containing high concentration of ammonia, phosphates, and fluoride ions by struvite formation. Calcium ion was generally added for the removal of fluoride ion. However, calcium ions remained after removal of fluoride ion can deteriorate the performance of struvite crystalization. It should be removed completely before struvite formation. In this study, the effect of fluoride and calcium ion concentration on the struvite crystalization was investigated. Removal efficiencies of ortho-phosphate with struvite formation were more abruptly decreased than those of ammonium nitrogen, as increase of fluoride ion concentration in synthetic wastewater. The structures of struvite formed in synthetic wastewater containing calcium ion of up to 500 mg/L were identical. Purity of struvite was deteriorated as increase of calcium ion over 500 mg/L. Removal efficiencies of ammonium nitrogen were more decreased than those of phosphate ions as increase of cacium ion in synthetic wastewater.

• Korean Journal of Environmental Biology
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• v.26 no.3
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• pp.183-191
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• 2008

The effect of silver ion solution on the growth of Microcystis aeruginosa UTEX 2388 (cyanobacterium) and Chlorella sp. KCTC AG20136 (green alga) was investigated using separated and mixed culture in filtered natural water and BG11 medium. In separated culture, M. aeruginosa UTEX 2388 and Chlorella sp. KCTC AG20136 were found to be sensitive to 0.01 and 0.1 mg L$^{-1}$ of silver ion, respectively. Also, the silver ion concentrations for the growth inhibition of M. aeruginosa UTEX 2388 and Chlorella sp. KCTC AG20136 in the mixed culture were same in separated culture. Cyanobacteria were more sensitive to the silver ion solution than green algae. In bloom sample, the minimal inhibition concentration of silver ion solution for the low Chl-${\alpha}$ sample (110$\sim$190 ${\mu}g$ L$^{-1}$) and high Chl-${\alpha}$ sample (1,500$\sim$1,900 ${\mu}g$ L$^{-1}$) was about 0.1 and 3.0 mg L$^{-1}$, respectively. The silver ion concentration for the inhibition of algal bloom sample was affected by the algal biomass. In order to use silver ion solution for the control of algal bloom, the silver ion concentration must be determined in consideration of a minimal effect on the environment.

• Journal of Biosystems Engineering
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• v.28 no.4
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• pp.335-342
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• 2003

A simple disposable thick-film potentiometric strip has been developed and evaluated for hydroponics application. The strip consisted of low ion-selective electrodes (ISE) fabricated by screen-printing technology. The electrochemical responses of ion sensors for nitrate, ammonium, potassium, and magnesium were measured with specially designed 16-channel low voltage signal transducers. The analytical characteristics of the sensors were comparable with those of conventional ISE sensors. The thick-film sensors exhibit linear relationships over five concentration decades. The concentration of N $O_3$ - ion in standard solution can be determined by direct potentiometric measurements without any conditioning before measurements. However, measurement of $K^{+}$, N $H_4$$^{+}$, and $Mg^{2+}$ ionic concentrations in nutrient solutions seems not feasible.

• Journal of environmental and Sanitary engineering
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• v.4 no.1 s.6
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• pp.7-15
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• 1989

According to the increase of population and development of industrialization air and water pollution problems are still keeping going to great nuisance to human activities. Specially man should drink 2l clean water to maintain our health every day, but we afraid of drink the city tap water because of the contaminants like heavy metals, bacteria trihalomethane, etc. In the analysis of the anions in potable water, we usually adapt the Standard methods for the Examination of Water and Wastewater. But this method is tedious and time consuming, so the Ion Chromatography method is now used in research of water quality. Author worked with Ion Chromatography in measuring the anions in drinking water by attaching conductivity dector to normal High Performance Liquid Chromatograph. Low-capacity ion-exchange coulmn and dilute eluents, 0.00M phthalic aic was used in this study. The concentration of chloride ion was 1.55 ppm$\~$3 8.81ppm, nitrate ion was 5.45 ppm$\~$18.27ppm, and sulfate ion was 19.64 ppm$\~$28.86 ppm. The phosphate ion was detected only in Apt. tap water as 167.99 ppm whose amount was supposed to be used as a water pipe cleaner.

• Journal of Bio-Environment Control
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• v.7 no.1
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• pp.63-70
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• 1998

This study was carried out to investigate the interaction of selenate and sulfate ion in nutrient solution supplyed with selenate ion. At early growth stage, the growth of Mongolian wormwood was best at 3mM sulfate ion and 2mg/$\ell$Na$_2$SeO$_4$ treatment. As they were grown and matured, at the later growth stage, the effect of antagonism between selenate and sulfate ion on the growth of each plant decreased. At supplying with selenate ion in nutrient solution, the uptake of selenate by plant had negative correlation with sulfate ion concentration in nutrient solution. The higher sulfate ion concentration, the less selenium uptake. However, the effect of antagonistic interaction of selenate and sulfate ion on the selenium uptake increased with plant age. Whereas, the uptake of sulfate ion had positive correlation with sulfate ion concentration in nutrient solution at supplying with selenate ion in nutrient solution. The uptake of sulfate ion increased with increase of sulfate ion concentration in nutrient solution. The effect of this interaction with selenate and sulfate ion increased with growth and maturity of plant. However, at 3mM sulfate ion concentration in nutrient solution, sulfate ion concentration in plant tissue decreased markedly.

• Journal of environmental and Sanitary engineering
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• v.17 no.2
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• pp.1-10
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• 2002

Ammonia is used in the manufacture of fertilizers, refrigerants, stabilizers and many household cleaning agents. The wide applications result in ammonia contamination in water. Ammonia can be removed from water by physical, biological, and chemical methods. Especially ozonation is effective in the treatment of water with low concentration of ammonia. Therefore, this study is undertaken to provide kinetic data for the ozonation of ammonia with bromide. The results were as follows; Ammonia oxidized by ozone with bromide catalysis. The denitrification rate of the ammonia increased proportionally to the concentration of bromide, and the overall reaction order was zero. It was also found that the effect of bromide ion concentration on the denitrification can be expressed by Monod type equation and there was no more effect above a proper bromide ion concentration. The reacted ammonia was converted completely to nitrate ion without bromide, but the denitrification of ammonia by ozone was conducted in the presence of bromide.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.23 no.1
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• pp.11-17
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• 2011

A major source of durability problems in concrete structures is the corrosion of steel by the damage of passivity layer around steel bars. As chloride ion penetration is major cause of the destruction of passivity layer, evaluation of depth and concentration profile of chloride ion is the essential factor for the service-life estimation of concrete structure. To estimate chloride ion penetration characteristics, this paper on the basis of in-situ experimental data investigated the depth and concentration profile of chloride ion penetration. The core specimens are obtained at air-zone, splash zone, and tidal zone in Wando, Masan, Incheon, Gwangyang, and donghae harbors. Colorimentric method measured the chloride ion penetration depth and ASTM C 114 evaluated the concentration profile of chloride ion. Based on experimental data, the influence of harbor location and exposure condition on chloride ion penetration is evaluated.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.3
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• pp.323-332
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• 1996

Precipitation samples were collected by the wet-only sampling method at Seoul from September 1993 to June 1995. Sample were analysed for the anions $(NO_3^-, NO_2^-, SO_4^{2-}, Cl^-, and F^-)$ and cations $(Na^+, K^+, Ca^{2+}, Mg^{2+}, and NH_4^+)$ in addition to pH and electric conductivity. In order to establish the chemical analysis data of high quality, the assurance checks for analytical data of precipitation were performed by considering the ion balance and by comparing the measured conductivity with the calculated conductivity. As we applied the various assurance checking methods by the ion balance used until recently to a data set measured in this study, the f value expressed as $\Sigma C/\Sigma A$ was found to be not appropriate for the data screening. Also, the scattering plot between cations and anions in each sample was found to show the general tendency of ion balance but was proved to not quantitate the standard of data screening at a data set of samples of various concentration levels. The h value defined as (A-C)/C for C $\geq$ A and (A-C)/A for C < A was used to check the ion balance. However, the standard of data screening by h value must very in response to total ion concentration of samples. In this study, the quality assurance of chemical analysis data was checked by considering both the ion balance of evaluating by h value and the conductivity balance. Further the quality control was achieved by these quality assurance methods. As the result, 67 samples among total 77 were obtained as valid. As the central tendency value for a statistical summary in the analytical parametr of samples, the volume-weighted mean value was found to represent more the general chemistry of precipitation rather than the arithmetic mean. The volume-weighted mean pH was 5.0 and 25% of samples was less than this mean. The concentrations of sufate and nitrate in precipitation were 90.4 ueq/L and 32.4 ueq/L which made up 59% and 21% of all anions. The raion of $SO_4^{2-}/(NO_3^- + NO_2^-)$ in precipitation was 2.7, which indicates that the contributions of $H_2SO_4$ and $HNO_3$ to the acidity of precipitation are 70% and 30%, respectively.

• Journal of Korean Society for Geospatial Information Science
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• v.19 no.4
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• pp.23-33
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• 2011

In this study, the data that examined the chloride ion concentration of ground water wells in the west coast of Jeollabukdo applying the GIS spatial estimation method were analyzed. In particular, through the designation of a validation point among ground water wells and then the analysis of error characteristics of the chloride ion concentration by each method of IDW (Inverse Distance Weight), Spline, and Kriging Interpolation method which is proper for estimating salt water intrusion was selected. The main conclusion from this study is as follows. First, as a result of analyzing the error characteristics of various spatial estimation methods by using the data from the chloride ion concentration of 485 ground water wells, the IDW method was found to be the most appropriate for estimating chloride ion concentration by salt water intrusion. Second, analyzing the average chloride ion concentration of the targeted regions has revealed that Gunsan-si with the record of $541mg/{\ell}$ did not meet water quality standards even for industrial use. Both Gimje-si and Gochang-gun satisfied drinking water quality standards and Buan-gun with $272mg/{\ell}$ was slightly below the standards for drinking water. Third, concerning the results of analysis according to administrative districts, as the areas adjacent to the west coast such as Daemyeong-dong, Joong-dong, Jangjae-dong and Guemam-dong in Gunsan-si are found to have very high chloride ion concentration, and both Hoehyeon-myeon and Daeya-myeon bounded by the Mankeong river did not meet water quality standards even for industrial use. From these facts, it is concluded that salt water intrusion has a great effect on Gunsan-si generally.