• Title/Summary/Keyword: ion composition

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Chemical Composition of Fine Aerosol Associated with Visibility Degradation in Seoul Metropolitan Area in 1994 (1994년 수도권 지역에서의 시정과 미세 입자상물질 화학조성과의 관계해석)

  • 한진석;김병곤;김신도
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.377-387
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    • 1996
  • This study was carried out to monitor the visibility including measurement and analysis of the various parameters such as particle size distribution, chemical composition, and meteorotical conditions to understand the characteristics and causes of this phenomenon. According to the analysis of intensive sampling, $SO_4^{2-}, NO-3^-, Cl^-, NH_4^+$ ion concentration increased together with the mass concentration around 1 $\mu$m in the case of low visibility. $(NH_4)_2SO_4, NH_4NO_3$, and $NH_4Cl$ were thought to be the major components of fine particles. The statistical analysis showed that the scattering effect of particle was 81.2%, the absorption effect was 14.9%. Therefore, these effects were the major factors to reduce the visibility. In conclusion, the visibility was reduced by the fine particle of sulfate (18.6%), nitrate (14.2%), organic carbon (10.8%), element carbon (25.8%), and residual (24.8%) during this study.

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The Effects of Non-Stoichiometry and Sintering Temperature on the Magnetic Properties of Ni-Zn Ferrites (비양론 화학적 조성 및 소결온도가 Ni-Zn Ferrite 의 자기적 성질에 미치는 영향)

  • 박준철;임호빈
    • Journal of the Korean Ceramic Society
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    • v.17 no.2
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    • pp.89-95
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    • 1980
  • The effect of non-stoichimetry and sintering temperature on the magnetic properties of materials in the system $Ni_{0.39}Zn_{0.61}Fe_{2.0+x}O_4$ have been investigated. The value of x used in initial weighing of oxides were varied from -0.04 to -0.12. The value of x, however, appears to be from +0.04 to -0.04 after ferrite powder preparation due to iron pick up during ball mill mixing and grinding. The densities of specimens which were deficientinrion were higher than those with excess ion. Specimens with near stoichiometric composition showed maximum initial permeability an dminimum coercivity whereas high values of quality factor (Q) were observed in iron deficient specimens. The quality factor decreased monotonically with increasing sintering temperature, but the permeability showed maxima with increasing sintering temperature. Thus highest value of figure of merit $\mu$Q was obtained in composition $Ni_{0.39}Zn_{0.61}Fe_{1.98O4}$ sintered at 100$0^{\circ}C$ for 3 hrs. in an air atmosphere.

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Microwave-assisted Synthesis of Mixed Ligand Complexes of Zn(II), Cd(II) and Hg(II) Derived from 4-aminopyridine and Nitrite Ion: Spectral, Thermal and Biological Investigations

  • Dhaveethu, Karuthakannan;Ramachandramoorthy, Thiagarajan;Thirunavukkarasu, Kandasamy
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.341-351
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    • 2013
  • Zn(II), Cd(II) and Hg(II) complexes with a general composition[$M(L)_2(X)_2$], where L=4-aminopyridine (4AP) and $X=NO_2{^-}$ were prepared under microwave irradiation. The metal complexes were characterized by elemental analyses, molar conductance, IR, Far-IR, electronic, NMR ($^1H$, $^{13}C$), XPS spectral and thermal studies. The spectroscopic studies reveal the composition, different modes of bonding, electronic transition, different chemical environment of C and H atoms and the electronic state of the metal atoms. On the basis of the characterization data, tetrahedral geometry is suggested for all the complexes. The free ligand (4-aminopyridine) and their metal complexes were screened against phytopathogenic fungi and bacteria in vitro and the activities were compared.

Switchable Holographic Polymer Dispersed Liquid Crystals for Full Color-Reflective Display

  • Cho, Young-Hee;Kim, Byung-Kyu;Kim, Jae-Chang
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.91-95
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    • 2001
  • Reflective holographic polymer dispersed liquid crystal(HPDLC) device has a multilayer structure consisting of alternate layers of polymer and liquid crystal droplets. Periodic modulation of a refractive index reflects light of a specific wavelength in accordance with Braggs law. Samples cured isotropically were illuminated with an Argon-ion lase at 514nm. We optimized the reflcetion efficiency of HPDLC as a function of monomer functionality, LC composition and irradiation intensity. The properties of the HPDLC films were observed by UV-visible spectroscopy. We found that the maximum reflection efficiency depends on the monomer functionality, LC composition, and laser intensity. We expect these films could be used in full-color reflective display by stacking them to obtain a mixture of colors.

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A Study on the Structure Properties of Plasma Silicon Oxynitride Film (플라즈마 실리콘 OXYNITRIDE막의 구조적 특성에 관한 고찰)

  • 성영권;이철진;최복길
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.5
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    • pp.483-491
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    • 1992
  • Plasma silicon oxynitride film has been applied as a final passivation layer for semiconductor devices, because it has high resistance to humidity and prevents from alkali ion's penetration, and has low film stress. Structure properties of plasma silicon oxynitride film have been studied experimentally by the use of FT-IR, AES, stress gauge and ellipsometry. In this experiment,Si-N bonds increase as NS12TO/(NS12TO+NHS13T) gas ratio increases. Peaks of Si-N bond, Si-H bond and N-H bond were shifted to high wavenumber according to NS12TO/(NS12TO+NHS13T) gas ratio increase. Absorption peaks of Si-H bond were decreased by furnace anneal at 90$0^{\circ}C$. The atomic composition of film represents that oxygen atoms increase as NS12TO/(NS12TO+NHS13T) gas ratio increases, to the contrary, nitrogen atoms decrease.

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Antioxidative Action of Enzymatic Hydrolysates of Mackerel Muscle Protein (고등어 근육단백질 효소 가수분해물의 항산화 작용)

  • 염동민;김영숙
    • The Korean Journal of Food And Nutrition
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    • v.7 no.2
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    • pp.128-136
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    • 1994
  • Mackerel muscle protein hydrolysates, which were prepared from defatted mackerel meal by proteases such as complex enzyme, alcalase, bromelain, pancrease, pepsin, w-chymotrypsin, trypsin and papain, were tested for the antioxidative action against linoleic acid. Among proteases tested, the hydrolysates obtained from the treatment of complex enzyme, bromelain and alcalase showed higher antioxidative effects. Also, the hydrolysates showed the synergistic effects with o-tocopherol and the inhibitory effects for peroxidation of metal ions(Fe3+, Cua+) From the profiles of fractionation of the hydrolysates with Bio-gel P-2 column, the most active fractions, part I(complex enzyme-derived) and part e(bromelain-derived), had below MW 1,400 and the antioxidative effects were closely related to the binding capacity with metal ion(Cua+). Amno acid composition of the part I was abundant in histidine, arginine, phenylalanine and lysine, and the part e was abundant in lysine, glutamic acid and leucine.

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Analysis of TCP packet by Protocol Analysis module Design (프로토콜 분석모듈 설계에 의한 TCP 패킷 분석)

  • Eom, Gum-Yong
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.234-236
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    • 2004
  • Transmission control protocol(TCP) is protocol used in internet. TCP is seldom transmission error and is protocol based on wire environment. TCP uses 3 way handshake ways, data transmission control through windows size, data transmission control through reception confirmation, sliding window for packet delivery. In this study, designed TCP packet ion module for analyze the TCP segments & correct information about TCP. TCP capture in internet using designed TCP module and analysed TCP segments composition. Through this, could analyze the correct information of protocol in network.

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The effects of electrolyte composition and water contents in manganese dioxide cell

  • Lee, Wan-Koo
    • Journal of the Korean Professional Engineers Association
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    • v.18 no.3
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    • pp.45-54
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    • 1985
  • 이산화망간 건전지에 실사용되고 있는 전해액 ZnCl$_2$-$H_2O$의 조성 변화에 따른 건전지의 특성변화를 비교 검토하여, 건전지성능향상의 기본인자 및 그 변화정도를 조사코자 하였다. ZnCl$_2$ 주사용 전지계는 특히 중부하연속방전이 우수하였으며 그 이유로는 농도분극현상이 적음에 기인되며 이는 $Zn^{++}$이 본계에서는 쉽게 이동함에 있다고 간주되며 그 $Zn^{++}$ 이온의 바른 이동은 이론치보다도 다량사용하게 되는 물의 역할에 기인되고 방전에 직접 필요한 수분량과, 기타의 목적 즉 반응 침전물의 재용해, ion carrier 등으로서 이용되는 수분량은, MnO$_2$와의 비율 및 방전 부하크기에 따라 다르다.

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Deposition of copper oxide by reactive magnetron sputtering

  • Lee, Jun-Ho;Lee, Chi-Yeong;Lee, Jae-Gap
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.49.2-49.2
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    • 2010
  • Copper oxide films have been deposited on silicon substrates by direct current magnetron sputtering of Cu in O2 / Ar gas mixtures. The target oxidation occurring as a result of either adsorption or ion-plating of reactive gases to the target has a direct effect on the discharge current and the resulting composition of the deposited films. The kinetic model which relates the target oxidation to the discharge current was proposed, showing the one-to-one relationship between discharge current characteristics and film stoichiometry of the deposited films.

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Study on Size Distribution of Total Aerosol and Water-soluble tons During an Asian Dust Storm Event at Jeju Island (황사기간중 제주지역의 에어로졸과 수용성이온의 크기분포)

  • Park Seong-Hun;Song Chang-Byeong;Kim Min-Cheol;Gwon Sun-Park;Lee Gyu-Won
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.159-160
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    • 2002
  • Soil dust particles transported from loess regions of the Asian continent, called Asian dust, highly influences the air quality of north-eastern Asia and the northern Pacific Ocean. The effects of these dust storms, on the chemical composition of atmospheric aerosol particles with different size, was investigated. Measurements of size distributions of total aerosol and major ion species were carried out on Jeju Island, Korea. (omitted)

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