• Applied Chemistry for Engineering
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• 제33권1호
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• pp.11-16
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• 2022

Metal-organic frameworks (MOFs) are porous materials with nano-sized pores. The degree of gas adsorption and pore size can be controlled according to types of metal ions and organic ligands. Many studies have been conducted on MOFs in the fields of gas storage and separation, and gas sensors. For rapid and quantitative gas adsorption/desorption analyses, it is necessary to form various MOF structures in uniform films on a sensor surface. In this review, some of representative direct methods for uniformly synthesizing MOFs such as MIL-53 (Al), ZIF-8, and Cu-BDC from anodized aluminum oxide, zinc oxide nanorods, and copper thin films, respectively on the surface of a microresonator are highlighted. In addition, the operation principle of quartz crystal microbalance and microcantilever, which are representative microresonators, and the interpretation of signals that change when gas is adsorbed to MOFs are covered. This is intended to enhance the understanding of gas adsorption/desorption analysis of MOFs using microresonators.

• Journal of Energy Engineering
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• 제21권1호
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• pp.55-67
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• 2012

For the development of gas hydrate as new future energy resources, the drilling was carried out at the five locations where have high potential as gas hydrate bearing sediments in Ulleung basin, offshore Korea in 2007. Well log data were obtained from all wells and core data were procured from 3 wells, UBGH1-04, UBGH1-09 and UBGH1-10. In this study, user-friendly software, "KMU GH Logs 2010", is developed and this software is based on the estimation methods developed in previous study for gas hydrate bearing sediments and the properties estimated from UBGH1-04, UBGH1-09 and UBGH1-10. Petrophysical properties in un-cored wells, UBGH1-01 and UBGH1-14, are also estimated by using well log data. Porosity is estimated by density log and gas hydrate saturation is calculated by sonic log and resistivity log. Sedimentary facies are estimated by applying the linear discriminant analysis using both well log and sedimentary facies data from core analysis. It is confirmed that DITM facies and MSS facies appeared signs of gas hydrate disassociation are able to be distinguished by the method.

• The Bulletin of The Korean Astronomical Society
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• 제40권1호
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• pp.60.1-60.1
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• 2015

High energy photons and mechanical energy produced by the process of star formation result in copious FIR molecular and atomic lines, which are important coolants of the system. Photons thermally or mechanically induced could dissociate water in the dense envelope to change relative abundances among the species of O, OH, and H2O. Here we analyze OH emission lines toward embedded young stellar objects (YSOs) observed as part of the Herschel open time key program, 'Dust, Ice, and Gas In Time (DIGIT)' in order to study the physical conditions of associated gas and the energy budget loaded on the OH line emission. According to our analysis of the Herschel/PACS spectra, OH emission peaks at the central spaxel in most of sources, but several sources show spatially extended emission structures. In the extended emission sources, the distribution of OH emission is correlated with that of [OI] emission and extended along the outflow directions. Considering the diversity of source properties, ratios between detected OH lines are relatively constant among sources. In addition, each OH line has strong correlation with bolometric luminosity. In order to determine the physical conditions of YSOs, we adopt several methods for the analysis of the OH lines: rotational diagram, non-LTE LVG analysis, and a 2-D PDR code. From the simple LVG analysis, we find that the thermal solution with the dense ( > $10^7cm^{-3}$) and warm ( ~ 100 K) OH gas reproduces the ratios of detected OH lines. However, our self-consistent PDR 2-D model, which can deal with the IR-pumping effect from the central protostar as well as the warm dust in situ, cannot fit the observational results, suggesting that an irradiated shock model is necessary for a better interpretation.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 한국조명전기설비학회 2007년도 추계학술대회 논문집
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• pp.275-278
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• 2007

Dissolved gases analysis (DGA) is one of the most useful techniques to detect incipient faults in power transformers. Criteria interpreting DGA result is the most important. Because of difference of operation environment, construction type, oil volume, and etc, the interpretative criteria of DGA at KEPCO must be different with other standard like IEC-60599, Rogers and Doernenburg. In this paper, we collected the DGA data of the normal condition transformers and the incipient fault transformer to suggest the most appropriate criteria. Using these data, this paper suggests appropriate condition classification algorithm. Suggested algorithm can help to detect incipient fault earlier without unnecessary sampling.

• Biomolecules & Therapeutics
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• 제1권2호
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• pp.143-150
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• 1993

The metabolic profile of triprolidine, 2-[(4-methylphenyl)-3-(1-pyrrolidinyl-1-propenyl)] pyridine, was determined. Urinary extracts obtained with enzyme hydrolysis were derivatized with MSTFA/TMSCl (N-methyl-N-trimethylsilyl trifluoroacetamide/trimethylchlorosilane) and analyzed by GC/MSD. In human urine, which were obtained after the oral administration with triprolidine, hydroxymethyltriprolidine, triprolidine carboxylic acid, oxotriprolidine carboxylic acid and unchanged triprolidine were detected. The maximum urinary excretion rate of triprolidine and hydroxymethyltriprolidine which were extracted from human urine was at 2 to 4 hours after the drug administration. Triprolidine and hydroxymethyl triprolidine were identified by comparison with authentic standards In chromatographic and mass spectral properties. Triprolidine carboxylic acid was detected as a major metabolite of its metabolites in the urine. Oxotriprolidine carboxylic acid and triprolidine carboxylic acid were tentatively identified by the interpretation of its mass spectral patterns. These data suggest that in human, hydroxylation of either the benzyl or pyrrolidine ring can occur during triprolidine elimination.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제2권1호
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• pp.85-90
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• 1998

The reaction rate of $CO_2$ with 2-amino-2-methyl-1-propanol (AMP), MEA monoethanolamine(MEA) and diethanolamine (DEA) in aqueous solutions has been determined using a stirred vessel with a plane gas-liquid interface over a wide range of concentrations of amines at different temperatures. The results show that the overall reaction rate is first order with respect to both $CO_2$ and amine. The reaction rate constant varies with temperature according to the relationship which agrees with the experimental data. The proposed interpretation is that the kinetic rate determining step is a reaction of $CO_2$ with amine to form carbamic acid which is then totally and immediately ionized.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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• pp.236-245
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• 2000

A laboratory scale fluidized bed reactor was developed to treat the combustion characteristics of some fuels (wood, paper sludge, refuse derived fuel). The aims were to introduce the means of experiment and interpretation of the results and finally determine the particle characteristics on the pyrolysis and combustion process of the fuel. A single particle combustion process in the fluidized bed was closely observed. Understanding experimental facility characteristics and determining parameters were also carried out. The fuel combustion processes were observed by carbon conversion rate, recovery and mean carbon conversion time. They were estimated with the CO, $CO_2$ gas concentration monitored at the exit of the combustor. Fuel drying and pyrolysis process were governed by temperature distribution in the fuel particle. There was a significant overlap of the drying and devolatilization. However, transition process from devolatilization to char combustion seemed to be determined by mechanical solidity of the fuel particle after devolatilization process.

• Journal of the Korean Society of Industry Convergence
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• 제21권3호
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• pp.133-139
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• 2018

Precipitator is the most widespread device used to separate dust particles from the exhaust gas. In the shipyard, welding umbrellas, spark protection covers, and ventilators are not purchased and used for the work place to capture the flames and high temperature metal dust generated during the gardening process. In particular, a thorough analysis of design factors, such as capture rate, collection capacity calculation, filter speed, and materials selection, is required since spatial constraints are followed by structures, etc. In this study, conceived to address problems such as this cyclone and filtration filter system that combines all-in-one gausing collector prototype. Assessed through interpretation through the validity of the design and reliability.

• Food Science and Preservation
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• 제1권2호
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• pp.87-92
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• 1994

For the measurement of the change of respiration rate caused by the gas content of storage atmosphere which furnishes important data for the interpretation of ULO storage, GC was used. It has been shown that the respiration rate and respiratory heat generation rate of Fuji apple is more than doubled in normal low temperature storage when compared with ULO storage, and that in ULO storage the respiration rate and respiratory heat generation rate directly proportional to the concentration of O2 in storage atmosphere as well as inversely proportional to that of CO2. It was possible to establish a functional formula for the respiratory heat generation rate of Fuji apple in all the storage conditions in terms of u=-0.7638+0.0003 O2-0.0007 log(CO2)+0.1369 log(Tb) concerning temperature and the concentration of O2 and CO2

• Journal of the Korean institute of surface engineering
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• 제37권3호
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• pp.185-190
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• 2004

Plasma Display Panel is a display device emitting fluorescent light from gas discharge between a front and a rear panel sealed together. Front and rear panel have multitude of film layers and barrier ribs in the rear panel has the largest area so releasing various gases and affecting light emitting characteristics and lifetime. The remaining gases in a barrier rib were studied by thermal desorption analysis up to $400^{\circ}C$ and main gases were $H_2$ $H_2$O, CO. During sustaining at $300^{\circ}C$, the outgassing rates from other gases were decreased but$ H_2$ kept constantly increasing until 1 hour, which can be originated from the dissociation of organics remained in the inside of barrier rib material. In $H_2$O, two distinct peaks were observed: desorption from physically adsorbed one at $l00^{\circ}C$ and from chemically adsorbed one $400^{\circ}C$. The result can be utilized in interpretation of electronic and optical characteristics and evacuation process control of PDP