• Title/Summary/Keyword: internal stability

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Effect of Lubricants on the Physical Properties of Poly(butylene terephthalnte) (폴리(부틸렌 테레프탈레이트)의 물성에 대한 윤활제의 효과)

  • Kim, Hoy-Gap;Kim, Jun-Kung;Lim, Soon-Ho;Lee, Kun-Wong;Park, Min;Kang, Ho-Jang
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.239-244
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    • 2004
  • Effect of lubricants on the rheological and thermal properties of poly(butylene terephthalate) [PBT] were investigated. Calcium stearate and adipic acid glycol polyester (AhGP) were used as processing lubricants for PBT. Decrease of melt viscosity was accomplished by the addition of 1 wt% of lubricants. It was understood that melt viscosity was affected by the enhancement of chain mobility of PBT with AhGP as an internal lubricant as well as the lubricity on processing equipment developed by calcium stearate as an external lubricant. Lubricants also influenced chain scission of PBT which caused the viscosity drop as well. In addition, lubricant is resulted in the lowering of thermal stability, however, this might be minimized by adding less than 3 wt% of calcium stearate as a lubricant. As a consequence, calcium stearate as an external lubricant is more effective to control the melt viscosity of PBT with minimizing of chain scission and thermal instability in PBT.

Comparison of the Hydrolysis Rate of Several Polyol Ester Oils as a Candidate for Environmentally Adapted Synthetic Base Oil (환경친화적인 합성기유 후보물질로서의 몇가지 폴리올에스터 오일의 가수분해속도 비교)

  • 한두희;마사부미마스꼬
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.162-177
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    • 2001
  • The hydrolysis rates of seven kinds of polyol ester base oils 〔POEs〕 of different branch shape were investigated by using a simple apparatus under mild acidic condition. Seven polyol ester base oils were made of poly hydric alcohols of two-four valence, normal or branched fatty acids of different carbon number. p-Toluene sulfonic acid was used as acid catalyst to accelerate the rate of hydrolysis. Partial esters and fatty acid produced by sequential hydrolysis of POEs were identified and their concentrations were determined by calibrated-internal standard method using Gas Chromatography. The rate constants of each step in sequential hydrolysis were determined by the least square method from rate equation and the concentration of each component, were compared with one another. It was shown that the rate of hydrolysis of POEs was strongly affected by whether molecular structure of fatty acid was straight chain or branch chain and which position was branched. The hydrolysis stability for all the POEs can be reasonably explained by using a steric hindrance effect anticipated fi:om their molecular structures affecting as water molecule makes an attack on the carbonyl carbon of POEs.

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A Study on Physicochemical Properties of Epoxy Coatings for Liner Plate in Nuclear Power Plant (원자력발전소 격납건물 철재면 에폭시 도장시편의 물리화학적 특성 평가)

  • Lee, Jae-Rock;Seo, Min-Kang;Lee, Sang-Kook;Lee, Chul-Woo;Park, Soo-Jin
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.809-814
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    • 2005
  • In this work, the thermal properties of epoxy coating system on the liner plate in the containment structure of nuclear power plants had been examined by irradiation and design basis accident (DBA) conditions. The effect of immersion in hot water on adhesion strength of the coating system had been also studied. The glass transition temperature ($T_g$) and thermal stability of ET-5290/carbon steel A 32 epoxy coating systems were measured by DSC and TGA analyses, respectively. Contact angle measurements were used to determine the effect of immersion on the surface energetics of epoxy coating system, with a viewpoint of surface free energy. Adhesion tests were also executed to evaluate the adhesion strength at interfaces between carbon steel plate and epoxy resins. As a result, it was found that the irradiation led to an improvement of internal crosslinked structure in cured epoxy systems, resulting in significantly increasing the thermal stability, as well as the $T_g$. Also, the immersion in hot water made a role in the post-curing of epoxy resins and increased the mechanical interlocking of the network system, resulting in increasing the adhesion strength of the epoxy coating system.

Study on Optimum Design for Embankment Construction on Soft Ground Treated by SCP (SCP개량지반상에 성토시공 시 최적설계에 관한 연구)

  • Chae, Jong-gil;Park, Yeong-Mog;Jung, MinSu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.6C
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    • pp.251-258
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    • 2009
  • In this study, the optimum design conditions for embankment construction on soft clay layer improved by soil compaction pile (SCP) are discussed by comparing the practical design method to the reliability design which is based on the loss function and advanced first order second moment (AFOSM) method. The results are summarized as follows; 1) the relationship between safety factor and failure probability becomes heavy exponentially, failure probability decreases rapidly till 1% approximately until safety factor is smaller than 1.2 and after then, failure probability decrease gradually along the increase of the safety factor. The design safety factor of 1.2 may be the critical value that has been established on considering both relationships appropriately, 2) the safety factor of 1.15 at the minimum expected total cost is a little smaller than the design safety factor of 1.2 and the failure probability is about 1%, 3) the sensitivities of the ratio of stress share and the internal friction angle of sand is larger than the variables related the undrained shear strength of soft layer. This result means that the distribution characteristic of n and ${\phi}$ influences on the stability analysis considerably and they should be considered necessarily on stability analysis of embankment on soft layer improved by SCP, 4) new failure points of the input variables at the design safety factor of 1.2(below failure probability of 0.1~0.3%) is far 1~2 times of standard deviation from the initial design values of themselves.

Influence of bearing surface angle of abutment screw on mechanical stability of joint in the conical seal design implant system (내부 원추형 연결형태 임플란트에서 지대주 나사머리의 좌면각도가 연결부 기계적 안정성에 미치는 영향)

  • Kim, Joo-Hyeun;Huh, Jung-Bo;Yun, Mi-Jung;Kang, Eun-Sook;Heo, Jae-Chan;Jeong, Chang-Mo
    • Journal of Dental Rehabilitation and Applied Science
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    • v.30 no.3
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    • pp.206-214
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    • 2014
  • This study is to evaluate how different bearing surface angles of abutment screw affect the mechanical stability of the joint in the conical seal design implant system. Materials and Methods: Internal connection type regular implants, two-piece cemented type abutments and tungsten carbide/carbon-coated titanium alloy abutment screws were selected. Titanium alloy screws with conical ($45^{\circ}$) and flat ($90^{\circ}$) head designs which fit on to abutment were fabricated. The abutments were tightened to implants with 30 Ncm by digital torque gauge. The loading was applied once to the central axis of abutment. The mean axial displacement was measured using micrometer before and after the tightening and loading (n = 5). The abutment was tightened to implants with 30 Ncm and T-shape stainless steel crown was cemented. Then the change in the amount of reverse-torque was measured after the repeated loading to the central axis, and the place 5 mm away from the central axis. Compressive bending and fatigue strength were measured at the place 5 mm away from the central axis (n = 5). Results: Both groups showed the largest axial displacement when abutment screw tightening and total displacement was greater in the flat head group compared to conical head group (P < 0.05). However, there were no significant differences in reverse torque value, compressive bending and fatigue strength (P > 0.05). Conclusion: Within the limitations of this study, the abutment screw head design had no effect on two groups regarding the joint stability, however the conical head design affected the settlement of abutment resulting in the reduced total displacement.

CLINCAL ANALYSIS OF SKELETAL STABILITY AFTER BSSRO FOR CORRECTION OF SKELETAL CLASS III MALOCCLUSION PATIENTS WITH ANTERIR OPEN BITE (전치부 개방교합을 동반한 골격성 제3급 부정교합 환자에 대한 양측 하악지 시상분할 골절단술후 안정성에 관한 임상적 분석)

  • Kim, Hyun-Soo;Kwon, Tae-Geon;Lee, Sang-Han;Kim, Chin-Su;Kang, Dong-Hwa;Jang, Hyun-Jung
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.33 no.2
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    • pp.152-161
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    • 2007
  • This study was conducted to patients visited oral maxillo-facial surgery, KNUH and the purpose of the study was to assess skeletal and dento-alveolar stability after surgical-orthodontic correction treated by skeletal Class III malocclusion patients with open bite versus non-open bite. This retrospective study was based on the examination of 40 patient, 19 males and 21 females, with a mean age 22.3 years. The patients were divided into two groups based on open bite and non-open bite skeletal Class III malocclusion patients. The cephalometric records of 40 skeletal Class III malocclusion patients (open bite: n = 18, non-open bite: n = 22) were examined at different time point, i.e. before surgery(T1), immediately after surgery(T2), one year after surgery(T3). Bilateral sagittal split ramus osteotomy was performed in 40 patients. Rigid internal fixation was standard method used in all patient. Through analysis and evaluation of the cephalometric records, we were able to achieve following results of post-surgical stability and relapse. 1. There was no significant statistical differences between open bite and non-open bite with skeletal Class III malocclusion patients in maxillary occlusal plane angle of pre-operative stage(p>0.05). 2. Mean vertical relapses of skeletal Class III malocclusion patients with open bite were $0.02{\pm}1.43mm$ at B point and $0.42{\pm}1.56mm$ at Pogonion point. In skeletal Class III malocclusion patients with non-open bite, $0.12{\pm}1.55mm$ at B point and $0.08{\pm}1.57mm$ at Pogonion point. There was no significant statistical differences between open bite and non-open bite with skeletal Class III malocclusion patients in vertical relapse(p>0.05). 3. Mean horizontal relapses of skeletal Class III malocclusion patients with open bite were $1.22{\pm}2.21mm$ at B point and $0.74{\pm}2.25mm$ at Pogonion point. In skeletal Class III malocclusion patients with non-open bite, $0.92{\pm}1.81mm$ at B point and $0.83{\pm}2.11mm$ at Pogonion point. There was no significant statistical differences between open bite and non-open bite with skeletal Class III malocclusion patients in horizontal relapse(p>0.05). 4. There were no significant statistical differences between open bite and non-open bite with skeletal Class III malocclusion patients in post-surgical mandibular stability(p>0.05). and we believe this is due to minimized mandibular condylar positional change using mandibular condylar positioning system and also rigid fixation using miniplate 5. Although there was no significant relapse tendency observed at chin points, according to the Pearson correlation analysis, the mandibular relapse was influenced by the amount of vertical and horizontal movement of mandibular set-back(p=0.05, r>0.304).

The Estimation Method of Empirical Formula of Strength Parameters by RMR System and Uniaxial Strength (RMR과 일축강도를 이용한 암반 강도정수 추정식의 적용방법)

  • Oh, Sewook;Ahn, Byungchul
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.1
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    • pp.13-18
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    • 2010
  • It is crucial to decide reasonably the parameters necessary for design through research on the characteristics of rock in order to analyze stability of rock structure. This article has conducted both pressure meter test, uniaxial and triaxial compression test to the areas of andesite or tuff located in local regions such as Yeosu, Gwangju, Yangsan, Busan, and Daejeon and has comparatively analyzed previously proposed estimative formulas. According to the result of estimating the deformation modulus through using the damping coefficient suggested by Nicholson & Bieniawski, when RMR is less than 60, it is desirable to use the result of the pressure meter test considering the damping coefficient. If the RMR value is over 60, however, the formula suggested by Kim Gyo-won has been proved to be the most applicable. Moreover, according to the result of comparing the RMR, adhesion, and angle of internal friction, both the adhesion and angle of internal friction best correspond to the formula proposed by Tsuchiya. Comparatively analyzing the relations between the rock deformation modulus and RMR and also suggesting the formula of calculating the shear strength parameter to use the RMR value, this study did not include the deformation modulus and shear strength parameter as factors to decide the RMR index. Since result can differ by several factors, it will be necessary afterwards to suggest practical estimative formulas applicable to the actual spots of Korea.

Partial Pediculectomy for Spondylolisthesis with Radicular Pain Combined with Severe Osteoporosis (하지 방사통과 심한 골다공증을 동반하는 척추전전위증을 위한 척추경 부분절제술)

  • Park, Myoung Jin;Shin, Ho;Cho, Ha Young;Lee, Seung Myoung;Jeong, Seong Hun;Song, Jin Kyu;Jang, Suk Jung
    • Journal of Korean Neurosurgical Society
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    • v.29 no.1
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    • pp.51-57
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    • 2000
  • Objective : For relief of back pain related to spondylolisthesis, fusion with or without internal fixation may be necessary. Currently, bilateral wide posterior decompression and fusion with or without internal fixation are used for treatment of spondylolisthesis. In case of severe osteoporosis, discectomy may be done without fusion to decompress the nerve roots. However, the procedure may aggravate radicular symptom because slippage may increase and thus foramen may become narrower. In these settings, inferomedial partial pediculectomy has been done in our institution, The object of this study was to evaltuate such cases with regard to per- and postoperative clinical courses. Patients and Methods : Fifteen patients complaining radicular pain with mild or no back pain underwent inferomedial partial pediculectomy. It was done in lytic spondylolisthesis after extension of isthmic defect. In degenerative spondylolisthesis of L4-5 interspace, intertransverse pediculectomy was done via paraspinal approach not to injure the posterior segment with intact isthmus. But, in degenerative spondylolisthesis of L5-S1 interspace however, partial pediculectomy was done after making artificial isthmic defect via midline approach. Then, reconstructive laminoplasty of L5 was performed to avoid iatrogenic instability resulted from artificial isthmic defect. They were followed up for average 14.4 months(3-31 months). Results : Radiating pain was relieved in all cases(100%). Postoperative result was excellent in 7 cases(46.7%), good in 7(46.7%) and fair in 1(6.6%). Only 1 case(6.7%) showed increase in slippage during follow-up period. Conclusion : Inferomedial partial pediculectomy is considered as a useful procedure for severely osteoporotic patients with spondylolisthesis with regards to keeping stability and decompressing the nerve roots.

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Seismic and Stress Analysis of 72.5kV GIS for Technical Specification of KEPCO (72.5kV GIS 전력 장비의 KEPCO 기준 내진 및 응력 해석)

  • Lee, Jae-Hwan;Kim, Young-Joong;Kim, So-Ul;Bang, Myung-Suk
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.3
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    • pp.207-214
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    • 2017
  • High voltage electric power transmitter GIS(Gas Insulated Switchgear) above 72.5kV needs to satisfy domestic Korean peninsular standard(ES-6110-0002) in KEPCO with respect to normal and special operation conditions which include internal gas pressure, dead weight, wind and seismic load. Some other requirements not described in Korean standard can be applied from other international standards such as IEC(International Electronical Committee) 62271-203 and 62271-207. The GIS is a kind of pressure vessel structure made of aluminum and filled with SF6 gas of internal pressure 0.4~0.5MPa. Finite element analysis of GIS is performed with such operational loads including seismic loading and the stability and reliability is determined according to ASME BPVC(Boiler and Pressure Vessel Code) SEC. VIII standard where the allowable stress level of the pressure vessel is suggested. The result shows that the stress of GIS is satisfied the allowable stress level and the safety factor is about 2.3 for Korean peninsular standard.

Mock-up Test of Improving Super Retarding Concrete to Control of Hydration Heat Crack of Foundation Mat Mass Concrete (기초매트 매스콘크리트의 수화열 균열제어로서 초지연콘크리트 활용에 관한 Mock-up 실험)

  • Lee, Jae-Sam;Bae, Yeoun-Ki;Noh, Sang-Kyun;Kim, Suk-Il;Chung, Sung-Jin;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.777-780
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    • 2008
  • According to the recent tendency that the buildings in the downtown are gradually Manhattanized, the very thick massive concrete is selected as the foundation of architectures. By the way, because this mass concrete cannot be simultaneously pour in a great quantity due to the circumstance at the field, not only the questions on the unification between the concretes pour on the upper layer and the lower layer are presented but also the cracks by the internal force from the difference of hydration exothermic period are occurred, which are pointed out as the problems. Thus, this study performed Mock-up test to apply the hydration heat controlling method of massive concrete for horizontal partition pouring construction to the building sites for the purpose of securing the stability on the cracks by the internal force from the difference of hydration exothermic period on the upper layer and the lower layer of massive concrete and checked the efficiency. As the results of test, in case of setting time difference method by super retarder with 2 layers and 4 layers, the effect that temperature gaps between upper part and lower part were lowered and the possibility of crack occurrence was decreased as the peak time of the heat of hydration became delayed to the latter term could be confirmed.

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