• Title/Summary/Keyword: internal reaction rate

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Effect of Operating Variables on the Morphology of Precipitated Calcium Carbonate in a Slurry Bubble Reactor (슬러리 기포탑 반응기에서 침강성 탄산칼슘의 모폴로지에 대한 조업변수들의 영향)

  • Hwang, Jung-Woo;Lee, Yoong;Lee, Dong-Hyun
    • Clean Technology
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    • v.16 no.2
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    • pp.124-131
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    • 2010
  • Effects of $Ca(OH)_2$ concentration (0.16~0.64 wt%), surfactant concentration (2~16 wt%), total volumetric flow rate (3~6 L/min) and $CO_2$ volume fraction $(0.3{\sim}0.6)$ on morphology, crystal structure, mean particle diameter, aggregation and specific surface area of the precipitated $CaCO_3$ were investigated in the slurry bubble column reactor. Experiments were carried out in acrylic reactor ($0.11\;m-ID{\times}1.0\;m-high$) with a internal tube ($0.04\;m-ID{\times}1.0\;m-high$h). The reaction time of $CaCO_3$ synthesis decreased with adding Dispex N40 of the anionic surfactant. The reaction rate of $Ca(OH)_2$ increased with increasing the volumetric flow rate of $CO_2$. From SEM images, the single crystal of $CaCO_3$ increased with increasing the reaction rate in the saturated concentration of $Ca(OH)_2$ (0.16 wt %) and the concentration of Dispex N40 (2 wt%). The mean particle size of $CaCO_3$ varied with adding Dispex N40. In addition, the specific surface area of $CaCO_3$ increased with adding of surfactant (2 wt%) from $35m^2/g$ to $44m^2/g$ at the volumetric flow rate of $CO_2$ (0.9 L/min) and the concentration of $Ca(OH)_2$(0.64 wt %).

Biomechanical Characteristic on Lower Extremity with or without Chronic Ankle Instability during Double Leg Drop Landing (양발 드롭랜딩 시 만성적인 발목 불안정성 유무에 따른 하지주요관절의 역학적 특성)

  • Jeon, Kyoungkyu;Park, Jinhee
    • Korean Journal of Applied Biomechanics
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    • v.31 no.2
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    • pp.113-118
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    • 2021
  • Objective: The purpose of this study was to investigate differences of landing strategy between people with or without chronic ankle instability (CAI) during double-leg drop landing. Method: 34 male adults participated in this study (CAI = 16, Normal = 18). Participants performed double-leg drop landing task on a 30 cm height and 20 cm horizontal distance away from the force plate. Lower Extremities Kinetic and Kinematic data were obtained using 8 motion capture cameras and 2 force plates and loading rate was calculated. Independent samples t-test were used to identify differences between groups. Results: Compared with normal group, CAI group exhibits significantly less hip internal rotation angle (CAI = 1.52±8.12, Normal = 10.63±8.44, p = 0.003), greater knee valgus angle (CAI = -6.78±5.03, Normal = -12.38 ±6.78, p = 0.011), greater ankle eversion moment (CAI = 0.0001±0.02, Normal = -0.03±0.05, p = 0.043), greater loading Rate (CAI = 32.65±15.52, Normal = 18.43±10.87, p = 0.003) on their affected limb during maximum vertical Ground Reaction Force moment. Conclusion: Our results demonstrated that CAI group exhibits compensatory movement to avoid ankle inversion during double-leg drop landing compared with normal group. Further study about how changed kinetic and kinematic affect shock absorption ability and injury risk in participants with CAI is needed.

Clinical Evaluation of Exudative Pleural Effusion (삼출성 늑막염의 임상적 고찰)

  • Kwon, Kyeong-Soon;Yang, Chang-Heon;Lee, Kwan-Ho;Lee, Yeung-Hyun;Chung, Jae-Chun;Lee, Hyun-Woo
    • Journal of Yeungnam Medical Science
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    • v.6 no.1
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    • pp.69-80
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    • 1989
  • From December 1987 to September 1988, clinical evaluation were performed at the Yeungnam University Hospital on 138 patients with exudative pleural effusion comparing with biochemical, bacteriologic, cytologic and pathologic studies. The results were as follows 1. Among thease 138 cases, Incidence of tuberculosis was 57.3%, neoplasm 26.8%. High tendency in malignant pleural effusion occured in elder age. 2. In tuberculosis pleural effusion, the rate of positive smear and culture for acid-fast bacilli in the pleural fluid was 3.7% and positive biopsy for granuloma 75%. 3. In malignant pleural effusion, the rate of positive cytology for cancer cell in the fluid was 42% and positive biopsy 60%. 4. Analysis in tuberculosis and malignancy showed the tendency of high pH, WBC, protein and of low glucose, but there were clinically not significant in differentiating malignant pleural effusion from tuberculous pleural effusion. 5. Among 23 cases in which the pleural tissue findings were chronic nonspecific reaction pathologically, tuberculosis(52.2%), malignancy(26%) and idiopathic(21.8%) eventually in follow up studies.

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Effect on clothing color preference of seasonal variations in physiology and psychology (계절에 따른 생리와 심리의 변화가 의복색 선호에 미치는 영향)

  • Kim Sook-Hee;Lee Won-Ja
    • Journal of the Korea Fashion and Costume Design Association
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    • v.7 no.3
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    • pp.75-81
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    • 2005
  • The experiment aimed at knowing the effect of physiology and psychology according to season on color preference. Two tests, one of the spring and the other of the autumn was conducted. Seventy subjects with normal color vision served as subjects. The subjects entered a bioclimatic chamber controlled at a temperature of $25\pm1^{\circ}C$, a relative humidity of $50\pm5\%$ and a light of 1000 1x. The subjects wearing white shirts and trousers sat quietly on a sofa for one our. Sensation from warm to cool colors might be possibly different individually Therefore, a subject asked to array 41 randomly placed cloth colors from very warm to very cool colors during rest quietly for one our. All subjects arrayed these cloth colors in the order from red through yellow and green to blue, which had the reproducibility. After rest, they were instructed to choose a single one out of 41 cloth colors, preferred by themselves, every 10min during one our 0-ring test were measured to red, yellow, white, blue, black, favorite color, and dislike color. Most subjects preferred warmer color in April than in December. Tympanic temperature was significantly lower in December than in April. Finger presser was significantly higher in like color than in dislike color but it was no significant differences between spring and autumn. The preferring the warm color in April toward summer when basal metabolic rate is decreased than in December toward winter when it is increased can explain that physiology reaction by load error between actual core temperature and set-point induces psychological reaction to pursue visual alliesthesia. Our present experiment revealed that the preferred color could be determined by the relationship between the internal temperature and its set point according to season. It should be emphasized that the alliesthesia was observed also in the realm of visual system.

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Prevalence of Theileria sergenti infection in Korean native cattle by polymerase chain reaction

  • Song, Kun-Ho;Sang, Byung-Chan
    • Parasites, Hosts and Diseases
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    • v.41 no.3
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    • pp.141-145
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    • 2003
  • This study was performed to investigate the prevalence of theileriosis and to compare the prevalence of this disease in Korean native cattle reared under different environmental conditions, namely, in a grazing area and a non-grazing area by polymerase chain reaction. Three hundred and one Korean native cattle (276 cows and 25 bulls) that had not received prior treatment or been vaccinated to prevent theileriosis were examined by PCR for Theileria sergenti infection from 2001 to 2002. In our study, the parasitemia range in T. sergenti-positive cattle by microscopy were from 0.1 to 3% (mean 0.8%). In terms of mean prevalence, 204 of the 301 Korean native cattle (67.8%) were positive reaction by PCR. Our results also revealed that the infection rate among cows (70.3%) was significantly higher than that among bulls (40.0%) (p < 0.01). T. sergenti infection among the over 3 year-old-group (75%) had a significant higher prevalence than that among the less than 3 year-old-group (61.8%) (p < 0.05). Our data also showed that grazing areas (76.1%) had the significant higher prevalence than non-grazing areas (51%) (p < 0.001). In conclusion, this study demonstrates that the prevalence of T. sergenti infection is high and that its prevalence in grazing cattle is higher than that in non-grazing cattle, Therefore, life-long treatment and the development of an optimal vaccine are needed to reduce the numbers of bovine theileriosis in both grazing and non-grazing areas.

Effects of EGR and Premixedness on NO Formation of Methane/Air Flames (EGR 및 예혼합 정도가 메탄/공기 화염의 NO 생성에 미치는 영향)

  • Lee, Won-Nam;Lee, Woong-Jae
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.63-74
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    • 1999
  • The effects of EGR and premixedness on NO formation have been numerically investigated. The flame structure is classified into three categories; premixed flame($=1)$, rich/lean premixed flame(${\alpha}=0.6$ and 0.8) and diffusion flame(${\alpha}=0$). NO formation/destruction mechanisms are assorted to thermal, reburn and Fenimore mechanisms. The temperature of unburned gas is arranged to 298 and 500 K to have access to the condition in a real internal combustion engine. The results show that all three NO formation/destruction reaction rates in the fuel rich flame zone could be decreased by EGR for rich/lean premixed flames, while those in the fuel lean flame zone are not significantly changed. Near the stagnation plane, however, only the thermal NO reaction rate is decreased. The contribution of reburn and Fenimore mechanisms for the net NO production becomes less significant as the premixedness of a flame increases. The larger amount of NO reduction with EGR is expected under the higher temperature and/or higher fuel/air premixedness conditions due to the increased contribution of the thermal mechanism. The role of Fenimore and reburn mechanisms could be important for rich premixed and diffusion flames; therefore, the effect of EGR on NO reduction could vary with fuel/air premixedness. The premixedness of a partially premixed flame changes the flame structure and could affect the NO production characteristics.

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Activity test of post-reforming catalyst for removing the ethylene in diesel ATR reformate (디젤 자열개질 가스 내 포함된 $C_2H_4$ 제거를 위한 후개질기 촉매 활성 실험)

  • Yoon, Sang-Ho;Bae, Joong-Myeon;Lee, Sang-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.218-221
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    • 2009
  • Solid oxide fuel cells (SOFCs), as high-temperature fuel cells, have various advantages. In some merits of SOFCs, high temperature operation can lead to the capability for internal reforming, providing fuel flexibility. SOFCs can directly use CH4 and CO as fuels with sufficient steam feeds. However, hydrocarbons heavier than CH4, such as ethylene, ethane, and propane, induce carbon deposition on the Ni-based anodes of SOFCs. In the case of the ethylene steam reforming reaction on a Ni-based catalyst, the rate of carbon deposition is faster than among other hydrocarbons, even aromatics. In the reformates of heavy hydrocarbons (diesel, gasoline, kerosene and JP-8), the concentration of ethylene is usually higher than other low hydrocarbons such as methane, propane and butane. It is importatnt that ethylene in the reformate is removed for stlable operation of SOFCs. A new methodology, termed post-reforming was introduced for removing low hydrocarbons from the reformate gas stream. In this work, activity tests of some post-reforming catalysts, such as CGO-Ru, CGO-Ni, and CGO-Pt, are investigated. CGO-Pt catalyst is not good for removing ethylene due to low conversion of ethylene and low selectivity of ethylene dehydrogenation. The other hand, CGO-Ru and CGO-Ni catalysts show good ethylene conversion, and CGO-Ni catalyst shows the best reaction selectivity of ethylene dehydrogenation.

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Hyperthermal Collision-induced Dissociation of Bromotoluene Radical Cations at Self-Assembled Monolayer Surfaces

  • Jo, Sung-Chan;Augusti, Rodinei;Cooks, R. Graham
    • Mass Spectrometry Letters
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    • v.2 no.1
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    • pp.24-27
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    • 2011
  • Hyperthermal ion/surface collisions of bromotoluene radical cations were studied using perfluorinated (F-SAM) and hydroxyl-terminated (OH-SAM) self-assembled monolayer surfaces in a tandem mass spectrometer with BEEQ geometry. The isomers were differentiated by ion abundance ratios taken from surface-induced dissociation (SID). The dissociation rate followed the order of ortho > meta > para isomers. The peak abundance ratio of m/z 51 to m/z 65 showed the best result to discern the isomers. A dissociation channel leading to tolylium ion was suggested to be responsible for the pronounced isomeric differences. The capability of SID to provide high-energy activation with narrow internal energy distribution may have channeled the reaction into the specific dissociation pathway, also facilitating small differences in reaction rates to be effective in the spectral time window of this experiment. All of the molecular ions experiencing reactive collisions with the F-SAM surface undergo transhalogenation, in which a fluorine atom on the surface replaces the bromine in the incoming ions. This reactive collision was dependent on the laboratory collision energy occurring in ca. 40.75 eV range.

A Case of Acute Respiratory Distress Syndrome with Pulmonary Embolism Induced by Injection of Silicone at Vaginal Wall (질벽의 실리콘 액 주사에 의한 폐색전종 및 급성 호흡곤란 증후군 1예)

  • Kang, Moon-Bo;Kim, Seong-Tae;Lee, Jung-Gu;Seo, Chan-Jong;Lee, Hwa-Eun;Jeong, Jung-Bae;Kim, Sung-Gwon;Kim, Chul;Park, Jeong-Woong;Jeong, Seong-Whan;Nam, Gui-Hyun
    • Tuberculosis and Respiratory Diseases
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    • v.46 no.3
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    • pp.414-419
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    • 1999
  • Silicone fluid(polydimethylsiloxane) is widely used in breast augmentation and other cosmetic procedures because of little incidence of complications and low mortality rate. However, local reaction following silicone injections can be occurred sometimes leading to serious complications. Especially, illicit silicone injections have resulted in severe reactions within the pulmonary area, and some have resulted in acute respiratory distress syndrome subsequently. We experienced a case of acute respiratory distress syndrome induced by subcutaneous injections of silicone at vaginal wall. The patients was 39-year-old, previously healthy woman who had complained of dyspnea related to silicone injection at vaginal wall. Chest X-ray and chest CT scan show diffuse air consolidation with ground glass opacities and perfusion lung scan revealed likelihood of pulmonary embolism as showing multiple perfusion defects. We report a case of acute respiratory distress syndrome occured after silicone injection with review of literature.

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Microstructure and Critical Current Density of $Nb_3$Sn wire processed by Internal Tin Method (내부확산법으로 제조한 $Nb_3$Sn선재의 미세조직 및 임계전류밀도특성)

  • 김상철;오상수;하동우;하홍수;류강식;권해웅
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.11
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    • pp.1022-1026
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    • 1998
  • The mutifilamentary $Nb_3$Sn wire containing 135 Nb filaments was manufactured by the internal tin method. The critical current density ($J_C$) in magnetic fields for the wires heat-treated at $660^{/circ}C$ and $700^{/circ}C$ were investigated. The Non-Cu $J_C$ and n-value of 0.82 mm$\phi$ $Nb_3$Sn wire heat-treated at $700^{/circ}C$ for 240 hours was approximately 450 A/$mm^2$ at 12T, 4.2K and 14, respectively. Also the $B_{C2}$ of $Nb_3$Sn wire extrapolated by Kramer plot was 27.2T. The wire heat-treated at $700^{/circ}C$ for 240 hours showed smaller residual tin concentration in the matrix and the larger area of $Nb_3$Sn layer as comparison with the wire heat-treated at $660^{/circ}C$.

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