• 제목/요약/키워드: internal pores

검색결과 117건 처리시간 0.037초

NFC의 자기차폐용 Ni-Zn-Cu 페라이트의 자기특성에 미치는 소결온도의 영향 (Influence of Sintering Temperature on Magnetic Properties of Ni-Zn-Cu Ferrites Used for Mangetic Shielding in NFC)

  • 류요한;김성수
    • 한국분말재료학회지
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    • 제23권2호
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    • pp.132-135
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    • 2016
  • This study investigates the influence of sintering temperature on the magnetic properties and frequency dispersion of the complex permeability of Ni-Zn-Cu ferrites used for magnetic shielding in near-field communication (NFC) systems. Sintered specimens of $(Ni_{0.7}Zn_{0.3})_{0.96}Cu_{0.04}Fe_2O_4$ are prepared by conventional ceramic processing. The complex permeability is measured by an RF impedance analyzer in the range of 1 MHz to 1.8 GHz. The real and imaginary parts of the complex permeability depend sensitively on the sintering temperature, which is closely related to the microstructure, including grain size and pore distribution. In particular, internal pores within grains produced by rapid grain growth decrease the permeability and increase the magnetic loss at the operating frequency of NFC (13.56 MHz). At the optimized sintering temperature ($1225-1250^{\circ}C$), the highest permeability and lowest magnetic loss can be obtained.

고온 열분해 환경의 다공성 탄소/페놀릭 복합재의 열기계적 거동 (Thermomechanical Behavior of Porous Carbon/Phenolic Composites in Pyrolysis Environments)

  • 김성준;한수연;신의섭
    • 한국항공우주학회지
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    • 제39권8호
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    • pp.711-718
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    • 2011
  • 본 논문에서는 열화학적 분해 및 열기계학적 변형이 고려된 구성 방정식을 사용하여 다공성 탄소/페놀릭 복합재료의 열탄성 거동을 예측하였다. 다공성 복합재료의 온도 의존성 및 열화학적 분해 과정에서의 기공도, 분해 가스에 의한 기공 압력, 재료의 수축을 고려하였다. 기공도와 기공 압력이 고려된 대표 체적 요소 모델의 유한요소 해석을 통해 산출된 거시적 기공 탄성 계수를 구성 방정식에 적용하였다. 간단한 수치 실험을 통해 기공탄성 계수가 다공성 재료의 열탄성 거동에 미치는 영향을 분석하였으며, 재료 내부에 형성된 기공과 기공 압력에 의한 응력 구배 및 변형을 확인하였다.

자기 냉동 재료 응용을 위한 MOF의 연구 동향 (Research Trend of Metal-Organic Frameworks for Magnetic Refrigeration Materials Application)

  • 김수환;손광효;오현철
    • 한국재료학회지
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    • 제30권3호
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    • pp.136-141
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    • 2020
  • The magnetocaloric effect (MCE), which is the reversible temperature change of magnetic materials due to an applied magnetic field, occurs largely in the vicinity of the magnetic phase transition temperature. This phenomenon can be used to induce magnetic refrigeration, a viable, energy-efficient solid-state cooling technology. Recently, Metal-organic frameworks (MOFs), due to their structural diversity of tunable crystalline pore structure and chemical functionality, have been studied as good candidates for magnetic refrigeration materials in the cryogenic region. In cryogenic cooling applications, MCE using MOF can have great potential, and is even considered comparable to conventional lanthanum alloys and magnetic nanoparticles. Owing to the presence of large internal pores, however, MOF also exhibits the drawback of low magnetic density. To overcome this problem, therefore, recent reports in literature that achieve high magnetic entropy change using a dense structure formation and ligand tuning are introduced.

왕겨재를 혼입한 콘크리트의 동결융해 저항성에 관한 실험적 연구 (An Experimental Study on the Resistance of Concrete Included Rice Husk Ash Against Rapid Freezing and Thawing)

  • 이준구;박광수;이응찬;김한중
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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    • pp.294-300
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    • 1999
  • After researching the physical properties of the concrete included Rice Husk Ash(RHA concrete) and workability of fresh concrete admixed RHA, we have tested durability of RHA-concrete against freeaing and thawing in the winter using rapid freezing and thawing test method(KS F 2456) . There aretwo hypotheses to explain the failure mechanism of a freezing and thawing action. First, the hydraulic pressure in the pores of freezing concrete make an internal stress of concrete structures outbreaking micro crack in the face of concrete, Second, Frost action causing damage to cement paste repeatedly come from soil frost action, freezing water in the capillaries. Initial Relative Dynamic Modulus of Elasticity (DME) was biggest in cae of unit binder weight 600kgf/㎥ and relative dynamic modulus of elasticity increased until 300cycles. In general , initial relative DME was proportional to unit binder weight . Relative DME was decreased in proportion to unit binder weight in the case of 300, 400, 500kgf/㎥ , but relative DME fo the others remained more than 90% until 300 cycles. It was not good effect of intermixed RHA to concrete in case of below unit binder weight 300kgf/㎥ and the resistance of freezing and thawing was not good either.

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고온 가열에 따른 섬유혼입 고강도 콘크리트의 강도특성 변화 (Strength Properties of the Fiber Mixed High Strength Concrete at Elevated Temperature)

  • 김상식;김성수
    • 한국건축시공학회지
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    • 제8권5호
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    • pp.53-58
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    • 2008
  • This study is to investigate experimentally residual strength properties of the high strength concrete containing the hybrid of nylon and polypropylene fiber at elevated temperature. Test results showed that specimens heated up to $300^{\circ}C$ exhibited similar strength properties to the one at room temperature. This result is significantly different from previous studies. but specimens heated over $400^{\circ}C$ showed dramatic decrease indicating similar tendency. For the residual strength properties, one at $300^{\circ}C$ even increased 10%, which is also different from previous studies, but it significantly decreased in $400^{\circ}C$ as widely expected. Melted pores by organic fibers in concrete specimens was observed with FE-SEM. For the density of concrete in elevated temperature, internal system in $200^{\circ}C$ had even denser than in $20^{\circ}C$, but was collapsed in $400^{\circ}C$.

저탄소강의 대기중 1050~1180℃의 산화에 미치는 합금원소 Si, S, Cu, Sn, Ni의 영향 (Effect of Alloying Elements Si, S, Cu, Sn, and Ni on Oxidation of Low Carbon Steels between 1050 and 1180℃ in Air)

  • 박상환;이동복;백선필
    • 대한금속재료학회지
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    • 제48권8호
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    • pp.749-756
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    • 2010
  • Low carbon steels were oxidized isothermally at 1050 and $1180^{\circ}C$ for 4 hr in air in order to determine the effect of alloying elements Si, S, Cu, Sn, and Ni on oxidation. For oxidation resistance of low carbon steels, the beneficial elements were Si, Cu, and Ni, whereas the harmful elements were S and Sn. The most active alloying element, Si, was scattered inside the oxide scale, at the scale-alloy interface, and as an internal oxide precipitate. The relatively noble elements such as Cu and Ni tended to weakly segregate at the scale-alloy interface. Sulfur and Sn were weakly, uniformly distributed inside the oxide scale. Excessively thick, non-adherent scales containing interconnected pores formed at $1180^{\circ}C$.

Thermomechanical behavior of alkali-activated slag/fly ash composites with PVA fibers exposed to elevated temperatures

  • Kim, J.S.;Lee, H.K.
    • Advances in concrete construction
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    • 제11권1호
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    • pp.11-18
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    • 2021
  • The present study fabricated polyvinyl alcohol (PVA) fiber-reinforced alkali-activated slag/fly ash (AASF) composites with varying mixture ratios of slag and fly ash. The thermomechanical behaviors of the AASF composites exposed to 200, 400, 600, or 800℃ were evaluated by means of compressive strength test, visual observation, and fire resistance tests. X-ray diffractometry, mercury intrusion porosimetry, and thermogravimetry tests were performed to analyze the microstructure change of the AASF composites upon exposure to high temperatures. Specimens exhibited a gradual strength loss up to 600℃, while also showing a significant decrease in the strength above 600℃. The fire resistance test revealed the occurrence of an inflection point as indicated by an increase in the internal temperature at around 200℃. In addition, specimens showed the dehydration of C-S-H gel, the presence of åkermanite, gehlenite, and anorthite upon exposure to 800℃, which is associated with the formation of macropore population with pores having diameters of 1-3 ㎛ and 20-40 ㎛. Visual observation indicated that the PVA fibers mitigated the cracking and/or spalling of the specimens upon exposure to 800℃.

Stabilization of cement-soil utilizing microbially induced carbonate precipitation

  • Shuang Li;Ming Huang;Mingjuan Cui;Peng Lin;Liudi Xu;Kai Xu
    • Geomechanics and Engineering
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    • 제35권1호
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    • pp.95-108
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    • 2023
  • Soft soil ground is a crucial factor limiting the development of the construction of transportation infrastructure in coastal areas. Soft soil is characterized by low strength, low permeability and high compressibility. However, the ordinary treatment method uses Portland cement to solidify the soft soil, which has low early strength and requires a long curing time. Microbially induced carbonate precipitation (MICP) is an emerging method to address geo-environmental problems associated with geotechnical materials. In this study, a method of bio-cementitious mortars consisting of MICP and cement was proposed to stabilize the soft soil. A series of laboratory tests were conducted on MICP-treated and cement-MICP-treated (C-MICP-treated) soft soils to improve mechanical properties. Microscale observations were also undertaken to reveal the underlying mechanism of cement-soil treated by MICP. The results showed that cohesion and internal friction angles of MICP-treated soft soil were greater than those of remolded soft soil. The UCS, elastic modulus and toughness of C-MICP-treated soft soil with high moisture content (50%, 60%, 70%, 80%) were improved compared to traditional cement-soil. A remarkable difference was observed that the MICP process mainly played a role in the early curing stage (i.e., within 14 days) while cement hydration continued during the whole process. Micro-characterization revealed that the calcium carbonate filling the pores enhanced the soft soil.

The surface stress effects on the buckling analysis of porous microcomposite annular sandwich plate based on HSDT using Ritz method

  • Mohsen Emdadi;Mehdi Mohammadimehr;Borhan Rousta Navi
    • Computers and Concrete
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    • 제32권5호
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    • pp.439-454
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    • 2023
  • In this article, the surface stress effects on the buckling analysis of the annular sandwich plate is developed. The proposed plate is composed of two face layers made of carbon nanotubes (CNT) reinforced composite with assuming of fully bonded to functionally graded porous core. The generalized rule of the mixture is employed to predict the mechanical properties of the microcomposite sandwich plate. The derived potentials energy based on higher order shear deformation theory (HSDT) and modified couple stress theory (MCST) is solved by employing the Ritz method. An exact analytical solution is presented to calculate the critical buckling loads of the annular sandwich plate. The predicted results are validated by carrying out the comparison studies for the buckling analysis of annular plates with those obtained by other analytical and finite element methods. The effects of various parameters such as material length scale parameter, core thickness to total thickness ratio (hc/h), surface elastic constants based on surface stress effect, various boundary condition and porosity distributions, size of the internal pores (e0), Skempton coefficient and elastic foundation on the critical buckling load have been studied. The results can be served as benchmark data for future works and also in the design of materials science, injunction high-pressure micropipe connections, nanotechnology, and smart systems.

광물질 혼화재를 함유한 고성능 콘크리트의 자기수축 (Autogenous Shrinkage of High-Performance Concrete Containing Mineral Admixture)

  • 이창수;박종혁;김용혁;김영욱
    • 한국방재학회 논문집
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    • 제7권3호
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    • pp.19-31
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    • 2007
  • 플라이 애쉬와 고로슬래그를 함유하고 물-결합재비가 낮은 고성능 콘크리트의 자기건조에 의한 습도감소와 수축과의 연관성을 파악하기 위하여 내부 습도와 변형률을 측정하였다. 그 결과 일반 콘크리트 내부 습도 감소는 약 10% 수축변형률은 약 $320{\times}10^{-6}$까지 진행하였으며 플라이 애쉬 10%, 20% 혼입한 콘크리트의 경우 각각 10%, 7%의 습도 감소와 $274{\times}10^{-6}$, $231{\times}10^{-6}$의 변형률을 나타내었다. 고로슬래그 40%, 50%를 혼입한 콘크리트는 11%, $371{\times}10^{-6}$, O30G50은 11%, $350{\times}10^{-6}$의 습도감소와 수축 변형률을 나타내었으며 플라이 애쉬 혼입 콘크리트는 일반 콘크리트에 비해 습도 감소량과 변형률이 감소하며 고로슬래그 혼입 콘크리트는 증가하는 경향을 보였다. 자기수축의 경우 내부 습도와 변형률의 관계만을 고려할 때 플라이 애쉬, 고로슬래그 혼입 유무에 상관없이 모두 습도와 변형률은 강한 선형성을 보였다. 콘크리트 내부 습도 변화와 수축변형률의 관계를 보다 구체화하기 위하여 콘크리트 내부 공극을 단일 네트워크로 가정하고 확장 메니스커스 생성 가정 하에 공극수에서 발생하는 모세관 압력과 수화조직체에서 발생하는 표면에너지 변화를 습도의 함수로 모델링하여 수축의 구동력으로 작용시킨 결과 실험값과 비교적 일치하는 값을 나타내었다. 이를 근거로 물-결합재비가 낮은 고성능 콘크리트에서 자기건조에 의한 습도감소는 20nm이하의 소형공극에서 발생함을 파악할 수 있었으며 따라서 자기수축에 대한 제어 방안은 이러한 소형공극에서의 공극수 표면장력과 포화도에 초점을 맞추어야 함을 확인할 수 있었다.