• Title/Summary/Keyword: internal oxidation

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The corrosion-resistant of Al-coated xstainless in molten carbonate (알루미늄 코팅처리 스테인레스강의 융탄산염 내부식성)

  • 조남웅;장세기;전재호;신정철
    • Journal of the Korean institute of surface engineering
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    • v.31 no.1
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    • pp.3-11
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    • 1998
  • Molten Carbonate Fuel cell is a promising new type electric power generation system which can achieve high efficiency, lower matrrial cost and high operating temperature Making internal reforming possible. Although the development of the MCEC is progressing rapidly toward commercialization, two important tchological problems such as dissolution of NiO cathode and not corrosion of metallic separator plate must be resolved. Because MCFC is operated at $650^{\circ}C$ and the electrolyte is very corrosive, corrosion-resistance of separator plated against oxidation abd molten carbonate is required. Al-coating on separator material for corrosion-resistance was carried out by painting, thermal spraying. hot dipping and vacuum vapour deposition. The corrosion of Al-coated STS 316S and 316L in molten carbonate at $700^{\circ}C$was studied. Vacuum vapour deposition and thermal spraing for Al-coating on STS 310S and 316L were the most effective methods for protecting thestainless steel corrosion in molten carbonate.

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A Study on Characteristics of Mild Combustion using the Radiative Flamelet Model (비단열 화염편 모델을 이용한 Mild Combustor의 연소특성 해석)

  • Kim Gunhong;Kim Yongmo;Ahn Kookyoung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.1
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    • pp.60-67
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    • 2005
  • Mild combustion or Flameless oxidation(FLOX) have been considered as one of the most prospective clean-combustion technologies to meet both the targets of high process efficiency and low pollutant emissions. A mild combustor with high air preheating and strong internal exhaust gas recirculation is characterized by relatively low flame temperature, low NOx emissions, no visible flame and no sound. In this study, the Steady Flamelet Approach has been applied to numerically analyze the combustion processes and NOx formation in the mild combustor. The detailed discussion has been made f3r the basic characteristics of mild combustor, numerical results and limitation of the present combustion modeling.

Failure Behavior of Piercing Plug during Seamless Tube Manufacturing Process (심리스 튜브 제조공정 시 피어싱 플러그의 파손거동)

  • Lim, Young-Bin;Yoon, Jeong-Mo
    • Journal of the Korean Society for Heat Treatment
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    • v.30 no.5
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    • pp.207-214
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    • 2017
  • In this study, failure behavior of piercing plug for seamless tube manufacturing process was studied. Three different kinds of passed piercing plugs (10, 90, 215 times) were prepared. The shape deformation of the passed piercing plugs was observed by 3D coordinate measuring machine, and the oxidized layer on the surface of piercing plug was observed by optical microscopy. The length reduction of piercing plug presented at 215 times passed plug. It was found that the oxidized layer consisted of outer scale, inner scale and internal oxidation layers, and the inner scale layer had vertical cracks, and interfaces had horizontal cracks. We proposed the failure mechanism of piercing plug during seamless tube manufacturing process based on the formation of vertical and horizontal crack.

Electrode of Low Impedance by Polypyrrole Addition for Supercapacitor (폴리피롤 첨가에 의한 supercapacitor용 저 임피던스 전극)

  • 김경민;장인영;강안수
    • Proceedings of the Safety Management and Science Conference
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    • 2003.11a
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    • pp.343-350
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    • 2003
  • The best Ppy weight ratio was 7 wt% and the optimal electrode composition ratio was 78 : 17 : 5 wt.% of (MSP-20 : BP-20 =1 : 1), (Super P : Ppy =10 : 7) and P(VdF-co-HFP). Implantation of Ppy as the conducting agents have led to superior electrochemical characteristics because of the low of internal resistance and faradaic capacitance. The result of unit cell with Ppy 7 wt% were as follows: 28.02 Fig of specific capacitance, 1.34 Ω of DC-ESR and 0.36 Ω of AC-ESR. Unit cell showed a good stability up to 200 charge-discharge cycles, retaining 82% of their original capacity at 200 cycles. From the analysis of impedance, the electrodes with Ppy 7 wt% showed low ESR, low charge transfer resistance and quick reaction rate. It was inferred that quick charge-discharge was possible. As compared with the specific capacitance (rectangular shape) of CV, it was also concluded that the specific capacitance originated from thecompound phenomena of the faradaic capacitance by oxidation and reduction of Ppy and the non-faradaic capacitance by adsorption-desorption of activated carbon.

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A Numerical Study of Combustion Characteristics for HCCI Engine with Detailed Diesel Surrogate Chemical Mechanism (Diesel Surrogate 상세 반응 기구를 이용한 HCCI 엔진의 연소 특성에 관한 수치해석 연구)

  • Lee, Won-Jun;Lee, Seung-Ro;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.16 no.2
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    • pp.9-15
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    • 2011
  • Homogeneous charge compression ignition(HCCI) is the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process is mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. In this paper, combustion characteristics of HCCI engine with suggested diesel surrogate(heptane/toluene mixture fuel) reaction mechanism were numerically investigated by heptane/toluene mixture ratio and EGR ratio. As results, the ignition timing became faster with increasing of heptane, and an initial oxidation and the ignition timing of the mixture fuel were affected by heptane and toluene, respectively.

FRAPCON analysis of cladding performance during dry storage operations

  • Richmond, David J.;Geelhood, Kenneth J.
    • Nuclear Engineering and Technology
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    • v.50 no.2
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    • pp.306-312
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    • 2018
  • There is an increasing need in the United States and around the world to move used nuclear fuel from wet storage in fuel pools to dry storage in casks stored at independent spent fuel storage installations or interim storage sites. Under normal conditions, the Nuclear Regulatory Commission limits cladding temperature to $400^{\circ}C$ for high-burnup (>45 GWd/mtU) fuel, with higher temperatures allowed for low-burnup fuel. An analysis was conducted with FRAPCON-4.0 on three modern fuel designs with three representative used nuclear fuel storage temperature profiles that peaked at $400^{\circ}C$. Results were representative of the majority of US light water reactor fuel. They conservatively showed that hoop stress remains below 90 MPa at the licensing temperature limit. Results also show that the limiting case for hoop stress may not be at the highest rod internal pressure in all cases but will be related to the axial temperature and oxidation profiles of the rods at the end of life and in storage.

Thermal behavior of Cu-Cr Alloy Films sputter-deposited onto polyimide (폴리이미드에 스퍼터 증착된 Cu-Cr 합금박막의 열처리 거동)

  • 임준홍;이태곤;김영호;한승희
    • Journal of the Korean institute of surface engineering
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    • v.27 no.5
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    • pp.273-284
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    • 1994
  • Thermal behavior of Cu-Cr thin alloy films has been investigated by SEM, AES, and TEM. Cu-Cr alloy films containing 3wt% Cr, 8wt% Cr have been sputter-deposited onto polyimide substrates and heat treated at $400^{\circ}C$ for 2hrs in the various atmosphere. Before heat treatment, Cu and Cr content in the film are uniform through the thickness and oxygen content in the film is negligible. Redistribution of Cr, Cu, and O in the film due to heat treatment depends on the Cr content and heat treatment atmoshpere. There kinds of thermal behavior are ascribed to the formation of surface and interface oxides as well as internal oxidation. Hillocks are observed on the surface of Cu-Cr alloy films which have been heat treated in N2. The hillocks are composed of large grainss of Cu.

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Behavior of Initial Formation of Iron Nitride on Carbon Steel at Low Pressure Gas Nitriding (저압가스질화에서 탄소강의 초기 화합물층 형성 거동)

  • Kim, Yoon-Kee;Kim, Sang-Gweon
    • Journal of the Korean institute of surface engineering
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    • v.44 no.3
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    • pp.75-81
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    • 2011
  • Growth behaviors of iron-nitride on S45C steels at low pressure gas nitriding were examined. Surfaces of the steels covered with fine and porous oxide during the pre-oxidation using $N_2O$ gas. Well faceted particles connected with them were observed after 1 min nitriding. They grew steadily and filled inter-pores during additional nitriding process. From the X-ray diffraction analysis, ${\gamma}'$-iron nitride was dominantly formed at the initial stage but the amount of ${\varepsilon}$-iron nitride was rapidly increased as nitriding treatment time. The porous layer was formed on the particles and thickened up to half of nitride layer after 60 min nitriding. The observed growth behaviors were discussed in internal stress related with volume expansion involved in transforming from iron to iron-nitrides.

Characteristics of Partial Oxidation Reforming with Various Sorts of Hydrocarbon Fuel (연료의 종류에 따른 부분산화 반응 특성에 관한 연구)

  • Park, Cheol-Woong;Choi, Young;Oh, Seung-Mook
    • Journal of the Korean Institute of Gas
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    • v.13 no.4
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    • pp.46-52
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    • 2009
  • Hydrogen can extend the lean misfire limit to a large extent when it is mixed with conventional fuels for an internal combustion engine. This study is about fuel reforming to produce hydrogen enriched gas as a fuel for engine. Especially gasoline, which consists of numerous hydrocarbon fuels, considered as source of reformed gas. Various hydrocarbons, including commercial fuel were reformed and potentialities of reformed gas on vehicles were accessed. The reforming efficiency and hydrogen yield were observed. Maximum hydrogen yield were found with different gas hourly space velocity(GHSV) and O2/C ratio of reforming conditions.

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Antioxidant Effects of Sagunja-Tang (Sijunzi-Tang) (사군자탕(四君子湯)의 항산화(抗酸化) 효과(效果))

  • Lee Yong-Tae;Cho Su-In;Kim Young-Kyun
    • Journal of Society of Preventive Korean Medicine
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    • v.4 no.2
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    • pp.170-192
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    • 2000
  • Objectives : This study was carried out to research antioxidant effects of Sagunja-Tang(SA) through in vitro and vivo experiments, and tried to investigate the relation between oxidation of tissues and deficiency of Qi. Methods and results : HPLC analysis of glycyrrhizine - known to be the main compound of Radix Glycyrrhizae - was done to certify the quality of SA. Chemiluminescence was initiated by adding tort-butyl hydroperoxide (t-BHP) to rabbit polymorphonuclear leukocytes (neutrophils), and generated reactive oxygen species (superoxide anion) decreased significantly by SA as dose dependent manner. Cell injury during 60 minutes tissue incubation was initiated by adding t-BHP, a hydrophobic hydroperoxide and $H_2O_2$, an water soluble oxidant to rat renal cortical and liver slices. Percentage cell death and lipid peroxidation were estimated by measuring lactate dehydrogenase (LDH) and malondialdehyde (MDA), a product of lipid peroxidation. t-BHP induced % cell death of renal cortical slices and lipid peroxidation of renal cortical and liver slices were decreased significantly by SA. SA decreased significantly % cell death and lipid peroxidation of renal cortical and liver slices induced by $H_2O_2$, too. Acute renal and liver injury induced by $HgCl_2\;and\;CCl_4$, which initiated from free radical, were applied to mice and metabolic data were obtained. Data showed protective effects of SA on acute renal injury caused by decrease of glomerular filtration. SA protected acute liver injury too. Conclusions Through this study, we found that SA have antioxidant effects and tissue oxidation was similar to deficiency of Qi. And further studies have to be followed to certify the mechanisms.

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