• 제목/요약/키워드: internal materials

검색결과 3,134건 처리시간 0.035초

리튬이온배터리 열폭주 조건에서 전해질 Dimethyl Carbonate(DMC) 반응 특성 분석 (Investigating the Reaction Characteristics of Electrolyte Dimethyl Carbonate(DMC) under Thermal Runaway Conditions of Lithium-Ion Battery)

  • 전민규;이은송;윤홍식;길상인;박현욱
    • 한국산업융합학회 논문집
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    • 제25권6_3호
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    • pp.1275-1284
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    • 2022
  • This study provides an investigating the electrolyte reaction characteristics during thermal runaway of a lithium-ion battery(LIB). Dimethyl carbonate(DMC) is known as the main substance that makes up the electrolyte. The mono-molecular decomposition characteristics of DMC were derived through numerical analysis. Cobalt oxide can release oxygen under high temperature conditions. Also, DMC is converted to CH4, H2, CO, and CO2. Especially, it was found that the decomposition of the DMC begins at a temperature range of 340-350℃, which dramatically increases the internal pressure of the LIB. In the by-products gases, the molar ratio of CO and CO2 changed according to the molecular structure of DMC and temperature conditions. The correlation of the [CO]/[CO2] ratio according to the temperature during thermal runaway was derived, and the characteristics of the reaction temperature could be estimated using the molar ratio as an indicator. In addition, the oxidation and decomposition characteristics of DMC according to the residence time for each temperature were estimated. When DMC is exposed to low temperature for a long time, both oxidation and decomposition may occur. There is possibility of not only increasing the internal pressure of the LIB, but also promoting thermal runaway. In this study, internal environment of LIB was identified and the reaction characteristics between the active materials of the cathode and electrolyte were investigated.

Characteristics of ZnO Varistors with Praseodymium Oxide

  • Lee, Sang-Ki;Cho, Sung-Gurl;Shim, Young-Jae
    • The Korean Journal of Ceramics
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    • 제5권4호
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    • pp.357-362
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    • 1999
  • ZnO varistors containing cobalt, praseodymium and calcium oxides were prepared. The current-voltage charcteristics and microstructures of the specimens were investigated with respect to calcium addition and sintering temperature. The potential barrier heights and the carrier densities were estimated from C-V relations. The compatibility of Ag-Pd as an internal electrode for multilayer chip varistor was also examined.

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양이온 성분이 수산화철 형성에 미치는 영향 조사 (Studying the Effect of Cation to the Formation of Iron Oxyhydroxide)

  • 오세진;이재영;권순주;유장용;주웅용
    • 한국재료학회지
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    • 제12권10호
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    • pp.796-802
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    • 2002
  • Effect of nine different cations to the formation of iron oxyhydroxide was studied using Mossbauer spectroscopy, XRD and BET. The Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the present of different cations in solution. Although the oxyhydroxide compound were composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.

불순물 입자의 유형에 따른 내접기어 펌프에서의 마모열화 특성 연구 (A Study on the Effects of Contaminant Types on the Wear Degradation Characteristics in Internal Gear Pumps)

  • 신정훈;지경렬;김형의
    • Tribology and Lubricants
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    • 제27권3호
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    • pp.134-139
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    • 2011
  • The mechanical equipments which are exposed to impure environment undergo significant reductions in their own lifetimes. Several environmental test procedures have been developed to analyze these phenomena. Moreover in the industry to require shorter development duration, accelerated life testers artificially add test containments into machines. In this research JIS Z 8901 test powder was added into internal gear pumps which are used as oil pumps in vehicles and thus the effects of the addition on the degradation of the pumps were examined. Three kinds of contaminants were selected. Two of the contaminants are identical in particle size but different in the composition of the ingredients. The other pair have identical ingredients and composition but different particle size. The quantity of contaminants was also an interesting factor in this study. The results show that each JIS contaminant caused notable degradation in the discharge flow characteristic of pumps while friction torque degradation did not have any tendency. Finally leakage rates were deduced and equivalent wear volume ratios were calculated.

초경합금재의 내면연삭에서 가공능률 향상에 관한 연구 (A Study on the Internal Grinding of Tungsten Carbide Materials to Improve the Machining Performance)

  • 허성중
    • 한국정밀공학회지
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    • 제13권6호
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    • pp.52-58
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    • 1996
  • This paper described on the effect of residual stocks in internal grinding of tungsten carbide materials in order to improve the grinding efficiency as well as grinding accuracy. Through the fundamental investigation is carried out for tungsten carbide materials using electroplated diamond wheel, the residual stock after grinding process is effective to the grinding efficiency. The obtained results are as follows: (1) Under the depth of cut(t) is constant and decreasing the workpiece velocity(Vw), the residual stock after grinding is increased, but the difference is little less than the difference by table speed. (2) Increasing the wheel velocity, the residual stock after grinding is decreased. Therefore in order to minimize the residual stock, the wheel velocity should be increased as far as possible. (3) The surface roughness and out-of roundness increased with depth of cut and table speed, and decreased with wheel velocity, but it may as well adopt as much as possible under the dimensional tolerance which is required for high efficiency grinding. (4) In order to remove residual stock, the spark-out grinding shoule be done, and it also can be improved about 20~25% throughout spark-out grinding, and the number of optimal spark-out times were within 10 times.

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Alloy 600의 결정립계 산화에 대한 표면 변형의 영향 (Effects of Surface Deformation on Intergranular Oxidation of Alloy 600)

  • 하동욱;임연수;김동진
    • Corrosion Science and Technology
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    • 제19권3호
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    • pp.138-145
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    • 2020
  • Immersion tests of Alloy 600 were conducted in simulated primary water environments of a pressurized water reactor at 325 ℃ for 10, 100, and 1000 h to obtain insight into effects of surface deformation on internal and intergranular (IG) oxidation behavior through precise characterization using various microscopic equipment. Oxidized samples after immersion tests were covered with polyhedral and filamentous oxides. It was found that oxides were abundant in mechanically ground (MG) samples the most. The number density of surface oxides increased with time irrespective of the method of surface finish. IG oxidation occurred in mechanically polished (MP) and chemically polished (CP) samples with thin internal oxidation layers. However, IG oxidation was suppressed with relatively thick internal oxidation layers in MG samples compared to MP and CP samples, suggesting that MG treatment could increase resistance to primary water stress corrosion cracking (PWSCC) from the standpoint of IG oxidation. As a result, appropriate surface treatment for Alloy 600 could prevent oxygen diffusion into grain boundaries, inhibit IG oxidation, and finally induce its high PWSCC resistance.

병원의 진료비 청구 자체심사 과정과 이의신청 사례 (Hospital's Internal Review Procedure of Health Insurance Reimbursement)

  • 최길림;김원중
    • 한국병원경영학회지
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    • 제7권3호
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    • pp.121-136
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    • 2002
  • The main purpose of this study is to examine the overall procedure of hospital's internal review of health insurance reimbursement, to present the case of protest against reimbursement cut, and hence to provide some information on hospital's management of medical revenue. The object of the case study is 'P' university medical center, possessing 5 different hospitals under its system. Presentation of the case of protest against reimbursement cut has following meanings: Firstly, to the hospitals that already have internal review departments, information on the details of the protest process and results can be exchanged. Secondly, to the Government and National Health Insurance Corporation, useful data are provided for the improvement of the rules and procedures of health insurance reimbursement. Thirdly, to the hospitals without internal review departments, fundamental materials on the internal review process are provided for the effective management of medical revenue.

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선박엔진 배관 플랜지용 세미금속 가스켓의 열전달 및 구조해석 (Thermal and Structural Analyses of Semi-metallic Gasket Joined with Graphite Seal for Ship Engine Piping Flange)

  • 오정석;이인섭;윤한기;성흥경
    • 한국해양공학회지
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    • 제31권5호
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    • pp.352-356
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    • 2017
  • We performed thermal and structural analyses to evaluate the structural integrity of a semi-metal gasket for a flange with increases in the internal fluid temperature and pressure using a commercial FEA program. As a thermal analysis result, the temperature distribution of the gasket body increased with an increase in the internal fluid temperature until the maximum fluid temperature of $600^{\circ}C$. In addition, the structural analysis showed that contact pressures of more than 35 MPa occurred uniformly in the graphite seal regions. It was found that no fluid leakage occurred under the load conditions for the structural analysis because the contact pressure in the graphite seal region was greater than the maximum internal fluid pressure of 35 MPa. Therefore, we demonstrated the structural integrity of the semi-metal gasket by performing the thermal and structure analyses under the maximum fluid temperature of $600^{\circ}C$ and the internal fluid pressure of 35 MPa.

단삼(丹蔘) 추출액이 Urethan으로 유발된 생쥐의 폐암에 미치는 영향 (Effect of Salvia miltiorrhiza Extract in Urethane-induced Lung Tumorigenesis in A/J Mice)

  • 박재석;김희철
    • 대한한방내과학회지
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    • 제29권3호
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    • pp.595-607
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    • 2008
  • Objectives: The aim of this study was to determine the effects of Salvia miltiorrhiza (SM) extract in urethane-induced lung tumorigenesis in A/J mice. Methods : We examined change of body weight, histological, apoptosis, immunohistochemical and gene expression of cyclooxygenase (COX-2) in lung tumors. Mice were divided into 3 groups: normal, saline, and experimental group administered SM extract after injection with urethane. Results : Histological observation showed shrunken alveoli in the control group, but recovered from damage in the SM extract administered group. The COX-2 positive materials were observed in the smooth muscle of terminal bronchiole and alveoli from the control group, but these positive materials decreased in the SM extract treatment group. The results of electron microscopical observation, dilated capillary and degenerated endothelia were observed in the control group. The apoptotic nuclei increased more in the control group compared with the normal and SM extract administered groups. Serial sections of the whole lung showed solid and papillary tumors. The size and number of tumors decreased in the SM groups compared with the control groups. Conclusions : These results suggest the possibility that SM may exert an anti-tumor effect on urethane-induced lung tumorigenesis.

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도시호텔 공용공간 실내건축의 내장재 특성에 관한 연구 - 서울시 특1급 호텔을 중심으로 - (A Study on the Characteristics of Interior Materials for the Public Area in the City Hotels - Focused on First Class Hotels in Seoul -)

  • 전유경;이창노
    • 한국실내디자인학회:학술대회논문집
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    • 한국실내디자인학회 2007년도 추계학술발표대회 논문집
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    • pp.149-154
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    • 2007
  • The city hotel of today lodges and, from eating and drinking putting first cultural exchange, information transmission and sports and the leisure back to be various the open community of the city which equips a composition facility as the market fixation it is being turning out. Like this regional and culture flow scope of the user fall in love, width widely try to be diffused the data about the internal organs re-analysis our country hotel plan the place where it is the actual condition where the system and diverse royal tomb city hotel plan is coming to be demanded regarding very is the actual condition which is insufficient. The research which it sees hereupon from domestic is erected in existing and the city hotel which is coming to be operated re- internal organs in the object it investigate, analyze re- internal organs and new city hotel plan hour to present a plan fundamental data and the guide regarding the internal organs re-quality of the crew-serve space interior construction it could be applied there is an objective of the research by the box sleep.

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