• Title/Summary/Keyword: internal bond

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The Effects of Blending Starches on the Development of Plybond Strength of Two-ply Linerboard (삼성분 전분혼합에 의한 이겹지의 층간결합강도 개선)

  • Lee, Hak-Lae;Ryu, Jeong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.4
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    • pp.14-20
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    • 2007
  • The effects of blending starches with different gelatinization temperatures on the development of ply-bond strength were systematically investigated using a three component mixture design technique. Oxidized corn starches with different gelatinization temperatures were blended with natural corn starch and sprayed for plybonding. Optimum blend ratio for maximizing plybond strength improvement for the starch blends was 40% of natural starch, 27% of oxidized starch with low gelatinization temperature and 33% of oxidized starch with high gelatinization temperature. Starch granules with the lowest gelatinization temperature gelatinizes at the lowest temperature, while the natural corn starch gelatinizes at later stage of drying. The improvement of plybond strength with starch blends were verified on machine trial as well. Plybond strength improvement obtained from the machine trial was lower than that achievable with handsheets, which was attributed to the lower internal bond strength of the linerboards made from recycled fibers.

A Study on the Electrical-Fire Analysis and Firing Characteristics of Power Cord by Thermal Stress (열적 피로에 의한 전원코드의 발화 특성과 전기화재 분석에 관한 연구)

  • 최충석;송길목;김향곤;김동욱;김동우
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2003.04a
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    • pp.164-170
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    • 2003
  • In this paper, we studied on the firing characteristics and electrical fire analysis of power cord deteriorated by thermal stress. The cross section of PVC insulating cord deteriorated by indirect flame decreased through heat convection. PVC insulating cord deteriorated by direct flame was bumpy shape. The exothermic peak of normal cord was shown at ($526.7^{\circ}C$), but the peaks or on(heat treatment temperature) ($150^{\circ}C$) cord was shown at ($299.6^{\circ}C$) and [$502.2^{\circ}C$]. The exothermic peaks according to high temperature were similar to those of amorphous carbon. In the FT-IR analysis, the absorption peak of normal cord indicated double bond of oxygen and carbon in benzene ring at 1720.0$cm^{1}$. As the HTT was high, the height of characteristic peak decreased and the peak of carbonyl group was shown at about 1625.7$cm^{-1}$. The characteristic peak of single bond(O-H) was shown at about 3479.2$cm^{-1}$. In case of the internal part of wire covering deteriorated by over current, the characteristic peak were shown at about 3417.3$cm^{-1}$ and 1600.2$cm^{-1}$. The above results show that we can distinguish the differences according to the fire pattern through the internalㆍexternal analysis of wire covering deteriorated by heat.

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A Study on Magnetic Abrasive Using Sr-Ferrite (Sr-Ferrite를 이용한 자기 연마재에 관한 연구)

  • Kim, Hee-Nam;Kim, Dong-Wook
    • Journal of the Speleological Society of Korea
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    • no.79
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    • pp.77-81
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    • 2007
  • In this paper deals with behavior of the magnetic abrasive using Sr-Ferrite on polishing charateristiccs in a internal finishing of staninless steel pipe a tying magnetic abrasive polishing. The magnetic polishing is the useful method to finish some machinery fabrications by using magnetic power. This method is one of the precision techniques and has in aim for clean technology in the transportation of the pure gas in the clean pipes. The magnetic abrasive polishing method is not so common in the field of machine that it is not known to widely. There are rarely researcher in this field because of non-effectiveness of magnetic abrasive. Therefore, in this paper we deals with the development of the magnetic abrasive with the use of Sr-Ferrite. In this development, abrasive grain SiC has been made by using the resin bond fabricated at low temperature. And magnetic abrasive powder was fabricated from the Sr-Ferrite which was crushed into 200 mesh. The XRD analysis result shows that only SiC abrasive and Sr-Ferrite crystal peaks were detected, explaining that resin bond was not any more to contribute chemical reaction. From MACRO analysis, we found that SiC abrasive and Sr-Ferrite were strongly bonding with each other.

A STUDY ON THE SHEAR BOND STRENGTH OF THE PORCELAIN LAMINATE ACCORDING TO SURFACE ROUGHNESS OF THE CUT ENAMEL (삭제된 법랑질의 표면거칠기에 따른 도재 라미네이트의 전단결합강도에 관한 연구)

  • Park, Bong-Seok;Cho, Young-Gon
    • Restorative Dentistry and Endodontics
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    • v.19 no.1
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    • pp.159-168
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    • 1994
  • The purpose of this study was to evaluate the shear bond strength of the porcelain laminate specimens according to the surface roughness of the cut enamel of human anterior teeth. Flat enamel surfaces were prepared in 30 extracted human anterior teeth with diamond disc which were divided into two groups. Group 1 Coarse enamel surface group prepared with LVS-3 bur. Group 2 Fine enamel surface group prepared with superfine diamond bur. 30 teeth specimens of two group were stored in normal saline during 24 hours. 30 disk - type porcelain laminate specimens with diameter 4mm and thickness 1mm were made and sand - blasted on internal surface which were to cemented on enamel surface. Porcelain laminate specimens were cemented on enamel surface with Choice Veneer System (Bisco Dental, U.S.A) according to manufacture's instructions. All teeth specimens of two groups were manipulated with same method and stored In normal saline before testing. An Universal Testing machine (Model No.UTM-4206,Instron, U.S.A) was used to apply shear loads in the vertical directed, and the force required for separation was recorded with a cross head speed of 3mm/min and 500kg in full scale. The results were as follow ; 1. The mean shear bond strength of coarse surface group was 36.30kg and that of fine surface group was 44.39 kg, but there was no significant difference in breaking strength of two groups(p>0.05).

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Effects of Process Temperature on the Tribological Properties of Tetrahedral Amorphous Carbon (ta-C) Coating (공정 온도에 따른 사면체 비정질 카본 (ta-C) 코팅의 트라이볼로지적 특성연구)

  • Kang, Yong-Jin;Kim, Do Hyun;Ryu, Hojun;Kim, Jongkuk;Jang, Young-Jun
    • Tribology and Lubricants
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    • v.35 no.6
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    • pp.362-368
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    • 2019
  • In this study, mechanical and tribological properties were investigated by varying the process temperature (50, 100, 125 and 150℃) to reduce internal stress. The internal stress reduction by thermal dissociation ta-C coating film with increasing temperature is confirmed through the curvature radius of the ta-C coating according to the temperature of the SUS plate. As the coating temperature increased, the mechanical properties (hardness, modulus, toughness) deteriorated, which is in agreement with the Raman analysis results. As the temperature increased, the sp2 phase ratio increased owing to the dissociation of the sp3 phase. The friction and wear properties are related to the process temperature during ta-C coating. Low friction and wear properties are observed in high hardness samples manufactured at 50℃, and wear resistance properties decreased with increasing temperature. The contact area is expected to increase owing to the decrease of hardness(72 GPa to 39 GPa) and fracture toughness with increasing temperature which accelerated wear because of the debris generated. It was confirmed that at process temperature of over than 100℃, the bond structure of the carbon film changed, and the effect of excellent internal stress was reduced. However, the wear resistance simultaneously decreased owing to the reduction in fracture toughness. Therefore, in order to increase industrial utilization, optimum temperature conditions that reduce internal stress and retain mechanical properties.

Characteristics of Diamondike Carbon thin Films by Low Discharging Frequency(450KHz) PECVD (저주파수(450 KHz) PECVD에 의한 Diamondlike Carbon박막의 특성)

  • Kim, Han-Ju;Ju, Seung-Gi
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.227-232
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    • 1994
  • Diamondlike carbon thin film has been fabricated with low discharging frequency, 450KHz by plasma enhanced chemical vapor deposition. Its physical properties such as optical band gap, microhardness and internal stress have been compared with 13.56MHz film. Optical band gap of 450KHz DLC thin film was less than 13.56MHz film and it was found that C-H bond concentration and total hydrogen contents in the film decreased greatly as the result of FT-IR and CHN analysis. Also, when DLC thin film was fabricated with low discharging frequency, it was expected that the adhesion of the film to the substrate was improved by the great decrease of internal stress without any considerable decrease of microhardness.

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Applying Novel Mean Residual Life Confidence Intervals

  • Guess, F.M.;Steele, J.C.;Young, T.M.;Leon, R.V.
    • International Journal of Reliability and Applications
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    • v.7 no.2
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    • pp.177-186
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    • 2006
  • Typical confidence intervals for a mean or mean residual life (MRL) are centered about the mean or mean residual life. We discuss novel confidence intervals that produce statements like "we are 95% confident that the MRL function, e(t), is greater than a prespecified $\mu_o$ for all t in the interval [0, $\hat{\theta})$)" where $\hat{\theta}$ is determined from the sample data, confidence level, and $\mu_o$. Also, we can have statements like 'we are 95% confident that the MRL of population 1, namely $e_1$(t), is greater than the MRL of population 2, $e_2$(t), for all t in the interval [0, $\hat{\theta}$)" where $\hat{\theta}$ is determined from the sample data and confidence level. We illustrate these one and two sample confidence intervals on internal bonds (tensile strengths) for an important modem engineered wood product, called medium density fiberboard (MDF), used internationally.

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Effect of HPAM on Calcium Carbonate Crystallization

  • Jing, Guolin;Tang, Shan;Li, Xiaoxiao
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.365-369
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    • 2013
  • With the wide application of ASP (alkaline-surfactant-polymer) flooding, the scaling becomes more and more serious, which is harmful to the oilfield and environment. In order to investigate the effects of HPAM on calcium carbonate crystallization, the crystallization behaviors of $CaCO_3$ in HPAM (Hydrolyzed polyacrylamide) solutions were studied and the composition and morphology of $CaCO_3$ crystal were investigated in different concentrations of polyacrylamide solutions. The crystal forms and morphologies of $CaCO_3$ were characterized by Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. The results show that the crystallization of $CaCO_3$ is strongly influenced by the HPAM. The paper analyzed the internal cause, and the results show: The reasons leading to the change of morphology are carboxyl groups in polyacrylamide molecule and $Ca^{2+}$ in solution form chelates by coordination bond. And the chelates are adsorbed on the calcium hydroxide surfaces of solid-liquid interfaces so as to change the formation rate of calcium carbonate crystal nucleus. The research provides a reliable basis for the mechanism research of the scaling problem in the oil extraction process of ASP flooding and the adoption of scale inhibition and scale inhibitor.

Nonlinear Finite Element Analysis of Containment Vessel by Considering the Tension stiffening Effect

  • Lee, Hong-Pyo;Choun, Young-Sun;Seo, Jeong-Moon;Shin, Jae-Chul
    • Nuclear Engineering and Technology
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    • v.36 no.6
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    • pp.512-527
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    • 2004
  • This paper describes the finite element (FE) analysis results of a 1/4 scale model of a prestressed concrete containment vessel (PCCV) by considering the tension stiffening effect, which is a result of the bond effect between the concrete and the steel. The tension stiffening model is assumed to be an exponential form based on the relationship between the average stress and the average strain of the concrete. The objective of the present FE analysis is to evaluate the ultimate internal pressure capacity of the PCCV, as well as its failure mechanism, when the PCCV model is subjected to a monotonous internal pressure beyond is design pressure capacity. With the commercial code ABAQUS, the FE analysis used two concrete failure criteria: a 2-dimensional axi-symmetric model with modified Drucker-Prager failure criteria and a 3-dimensional model with a damaged plasticity mod디. The results of our FE analysis on the ultimate pressure capacity and failure modes of PCCV have a good agreement with the experimental data.

Integrated Thermochemical Approach to Collision-Induced Dissociation Process of Peptides

  • Shin, Seung Koo;Yoon, Hye-Joo
    • Mass Spectrometry Letters
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    • v.12 no.4
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    • pp.131-136
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    • 2021
  • Collision-induced dissociation of peptides involves a series of proton-transfer reactions in the activated peptide. To describe the kinetics of energy-variable dissociation, we considered the heat capacity of the peptide and the Marcus-theory-type proton-transfer rate. The peptide ion was activated to the high internal energy states by collision with a target gas in the collision cell. The mobile proton in the activated peptide then migrated from the most stable site to the amide oxygen and subsequently to the amide nitrogen (N-protonated) of the peptide bond to be broken. The N-protonated intermediate proceeded to the product-like complex that dissociated to products. Previous studies have suggested that the proton-transfer equilibria in the activated peptide affect the dissociation kinetics. To take the extent of collisional activation into account, we assumed a soft-sphere collision model, where the relative collision energy was fully available to the internal excitation of a collision complex. In addition, we employed a Marcus-theory-type rate equation to account for the proton-transfer equilibria. Herein, we present results from the integrated thermochemical approach using a tryptic peptide of ubiquitin.