• Bulletin of the Korean Chemical Society
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• 제12권3호
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• pp.249-251
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• 1991

• Bulletin of the Korean Chemical Society
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• 제20권10호
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• pp.1149-1152
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• 1999

1H NMR spectrum of a DMF-d7 solution containing 4-aminopyrimidine and [SiW11CoIIO39]6- (SiW11Co) shows separate peaks from two linkage isomers, a and b, in which N(1) and N(3) of the pyrimidine ring are coordinated to SiW11Co, respectively. The signal from the amine group in the isomer a exhibits temperature dependence that is characteristic of a two-site exchange problem. Rates of internal rotation of the amine group were determined by simulating the NMR spectra at 5-35℃. The amine group of free 4-aminopyrimidine also shows temperature-dependent spectra at lower temperatures; rates of internal rotation at (-25)-25℃ were determined. The internal rotation of the amine group in the complex is much slower than that for free 4-aminopyrimidine, indicating that π-character of the C-N bond increases on coordination to SiW11Co. The amine group in the isomer b does not show such behavior. It is probable that hydrogen bonding between N-H and a bridging oxygen atom of SiW11Co prevents it from rotating at low temperatures.

• 한국정밀공학회지
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• 제17권4호
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• pp.155-162
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• 2000

전해 인프로세스 드레싱(ELID)의 응용기술로써 간헐적 드레싱(ELID II) 및 무전극 드레싱(ELID III)이 원통내면 마무리 연삭에 이용되고 있다. 주철본드(CIB-D) 및 메탈레진본드 다이아몬드 숫돌(HRB-D)이 이 방식들에 사용되고 있다. 경면 가공에 있어서 이 두방식은 미립의 숫돌이용으로 일반연삭기에 정밀부속 장치의 보완없이 이용될 수 있다. ELID II 연삭에서 CIB-D숫돌은 파이프 형상의 전극에 의하여 간헐적으로 드레싱되고, 반면에 MRB-D 숫돌은 인프로세스 드레싱 되며 전극은 필요로 하지 않는다. 본 연구에서는 ELID II 및 ELID III 방식에 있어서, 연삭조건 및 연삭입자크기에 대한 연삭특성을 비교검토 하였다. 그 결과, ELID II, III방식 공히 대단히 작은 표면거칠기를 갖는 경면이 얻어짐을 확인하였다.

• 펄프종이기술
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• 제42권4호
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• pp.78-83
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• 2010

In this study, the possibility of the use of a new raw material in paperboard industry was investigated. Fly ash is one of the residues generated in the combustion of coal and generally captured from the chimney of coal-fired power plant. This material is utilized in many industries including cement, soil stabilization, composite etc., but it is not used in paper industry. Three types of fly ashes were collected from Hadong, boryeong and Seocheon steam power plants and we investigated their properties by scanning electron micrographs and particle size distribution. Papers were manufactured with KOCC and fly ashes, and the physical properties such as bulk, tensile strength, internal bond strength and ISO brightness were measured to identify the effects of fly ash on the paper properties.

• Journal of the Korean Wood Science and Technology
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• 제23권4호
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• pp.74-84
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• 1995

Eight types of thin composite panels were manufactured by press-lam and mat-forming process applied to optimum manufacturing condition, studied in former first research by author (1995). They were tested and compared with control boards on dimensional stability, internal bond strength, tensile strength, Screw withdrawal strength, and bending properties. These thin composite panels manufactured by mat-forming process were generally superior to those by press-lam in dimensional stability and mechanical properties. In the dimensional stability and mechanical properties of thin composite panels manufactured by mat-forming process, the thin composite panels (A and E type) composed of particle or sawdust core and veneer face with polyethylene film, were as good as those of common plywood (control board). Internal bond strength showed highest value in the thin composite panel(D type) which composed of particle core and polypropylene screen face with polyethylene film. The thin composite panels(G and H type) composed of sawdust or particle core and polypropylene screen face with polyethylene film by press-lam and mat-forming process, showed most highest value in dimensional stability and water absorption.

• International Journal of Reliability and Applications
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• 제8권1호
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• pp.111-124
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• 2007

In this paper, we apply insightful statistical reliability tools to manage and seek improvements in the strengths of Oriented Strand Board (OSB). As a part of the OSB manufacturing process, the product undergoes destructive testing at various intervals to determine compliance with customers' specifications. Workers perform these tests on sampled cross sections of the OSB panel to measure the tensile strength, also called internal bond (IB), in pounds per square inches until failure. Additional stiffness strength tests include parallel and perpendicular elasticity indices (EI), which are taken from cross sectional samples of the OSB panel in the parallel and perpendicular directions with respect to the orientation of the wood strands. We explore both graphically and statistically these "pressure-to-failures" of OSB. Also, we briefly comment on reducing sources of variability in the IB and EI of OSB.

• Journal of the Korean Wood Science and Technology
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• 제24권1호
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• pp.17-26
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• 1996

This research was accomplished to evaluate possibility of using paper sludge for the raw materials of wood based panel products. The experimental panels were manufactured by four mixed ratios, the proportion of paper sludge to wood particle: 20:80, 30:70, 40:60, 50:50% (oven dry weight basis) and by three composition types, sludge-particle mixed board, three layered sludge-particle board and three layered particle board. They were tested mechanical (bending strength and internal bond) and physical properties (water absorption, thickness swelling and linear expansion). From the results they were shown that bending strength of mixed and three layered sludge-particle board were decreased with increasing of composition ratios of sludge. And the mechanical and physical properties of the boards of three layered composition types have superior to those of mixed composition type. Although composition ratios of sludge increased, the internal bond strength and dimensional stability of sludge-particle board not decreased quantitatively. We concluded that the mechanical and physical properties of three layered sludge-particle board were similar w those of three layered particle-board (control) made by our laboratory design. Therefore, it was recognized that paper sludge can be used as potential raw material in particle-board manufacturing industry.

• International Journal of Reliability and Applications
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• 제5권4호
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• pp.129-145
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• 2004

We use a novel, forced censoring technique that closer fits the lower tails of strenth distributions to better estimate extremly smaller percentiles for measuring progress in continuous improvement initiatives. These percentiles are of greater interest for companies, government oversight organizations, and consumers concerned with safely and preventing accidents for many products in general, but specifically for medium density fiberboard (MDF). The international industrial standard for MDF for measuring highest quality is internal bond (IB, also called tensile strengh) and its smaller percentiles are crucial, especially the first percentile and lower ones. We induce censoring at a value just above the median to weight lower observations more. Using this approach, we have better fits in the lower tails of the distribution, where these samller percentiles are impacted most. Finally, bootstrap estimates of the small percentiles are used to demonstrate improved intervals by our forced censoring approach and the fitted model. There was evidence from the study to suggest that MDF has potentially different failure modes for early failures. Overall, our approach is parsimonious and is suitable for real time manufacturing settings. The approach works for either strengths distributions or lifetime distributions.

• Journal of the Korean Wood Science and Technology
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• 제50권6호
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• pp.427-435
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• 2022

For effective applicability of reinforced cork, cork composites reinforced with metal, glass fiber, and carbon fiber were developed, and the effects of the reinforcing materials on the mechanical properties of cork composites were investigated. The bending moduli of elasticity (MOE) of cork composites were in the 32.7-35.9 MPa range, while the bending strength values were in the 1.62-1.73 MPa range. The strength performance decreased in the order cork-metal > cork-carbon fiber > cork-glass fiber. The bending MOEs were improved by 29%-41% compared with simple cork boards, while the bending strengths of reinforced cork were 35%-45% higher. The strength performance significantly improved following the incorporation of thin mesh materials into the middle layer of the studied cork composites. The bending strains of the cork composites were remarkably higher compared with oak wood, making them promising for applications that require bending processing, such as curved jointing. The internal bond strengths of the cork composites were 0.26-0.44 MPa, approximately 0.36-0.60 times lower compared with medium-density fiber boards.

• 한국산학기술학회논문지
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• 제12권5호
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• pp.2108-2114
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• 2011

한국기업에는 한국특유의 기업집단 형태인 재벌기업집단이 있고 그 영향도 매우 크다. 재벌의 경제에 미치는 영향도 매우 커서 이에 따른 경제정책도 많은 변화가 있어 왔다. Propping은 지배주주가 일방적 이익을 위해 계열사의 소수주주의 부를 착취하는 tunneling의 개념과는 달리 재벌기업집단의 전체이익을 위해 재벌기업내의 자원을 공유하며 상호 지원과 위험의 공유할 수 있다는 개념이다. 재벌계열기업 간 propping을 분석하는 것은 그룹내의 여러가지 중요문제를 풀고 재벌에 대한 규제정책에 대한 중요한 핵심을 주는 결정적 키가 될 수 있다. 본 논문의 사건연구결과를 보면 신용등급변경 전후의 누적초과수익률(CAR)은 신용등급이 상향 조정되었우 때에 유의한 주가반응이 없었으나 하향변경의 경우 재벌, 비재벌 모두 유의한 음의 반응을 보였고 특히, 하향변경의 경우 재벌그룹에 속한 기업군이 상대적으로 평균적 초과수익률의 하락 정도가 매우 낮음을 보여주고 있어서 재벌집단기업의 propping 현상이 존재한다는 것을 입증하고 있다. 2002년 실시한 상호출자제한제도를 전후한 다중회귀분석에서도 상호출자제한제도 이후 신용등급 하향조정시 propping 효과를 크게 감소시킨 것으로 나타나 재벌기업에 대한 규제정책과 propping효과와 매우 관계가 깊은 것으로 분석되었다.