• Title/Summary/Keyword: interfacial analysis

Search Result 634, Processing Time 0.031 seconds

Effect of Pretense (Subtilisin Carlsberg) on the Removal of Blood Protein Soil (II) -The Detergency of Hemoglobin from Cotton Fabics- (Protease (Subtilisin Carlsberg) 가 혈액 단백질 오구의 제거에 미치는 영향(II) -헤모글로빈 오구포의 세척성-)

  • 이정숙;김성연
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.20 no.4
    • /
    • pp.655-666
    • /
    • 1996
  • The effect of protease (subtilisin Carlsberg) on the removal of hemoglobin as protein soil was studied. The relation between the renloval and the hydrolysis of hemoglobin by subtilisin Carlsberg was discussed. The soiled babric was prepared by spotting of hemoglobin solution evenly on the cotton fabric and was denatured by steaming. The soiled fabric was washed by using Terg-0-Tometer at various conditions. The removal efficiency was evaluated by analysis of protein on the fabrics before and after washing by means of copper-Folin method. 1. The removal of hemoglobin was increased in proportion to increasing of the enzyme concentration up to a certain point, but it began to decrease above the point. 2. The hemoglobin was removed effectively by adding of subtilisin Carlsberg, and more effectively removed by adding of AOS in the enzyme solution. 3. The removal of hemoglobin deviated from the first order reaction in detergency. 4. The renloval of hemoglobin was highest at $50^{\circ}C$ in detergency, Even at low temperature the removal efficiency of enzyme was relatively higher compared with the hydrolysis of hemoglobin by the enzyme. However the removal of hemoglobin was apparently decreased with the increase of temperature over $60^{\circ}C$. 5. The removal of hemoglobin was relatively high at pH 7.0~8.0 and increased continuously with the increase of pH in detergency 6. In detergency, the removal mechanism of hemoglobin by subtilisin Carlsberg could be explained as follows: Fisrt of all, the enzyme hydrolyzed hemoglobin substrates partially by forming E-S complex at the surface of hemoglobin on the cotton fiber, and decomposed cooperative binding of hemoglobin. Subsequently, the fragments of hemoglobin were easily removed by washing. According as the enzyme penetrated to inner part of hemoglobin gradually, the hemoglobin on the cotton fiber was effectively removed by the repetition of these process. The removal of hemoglobin was more effectively increased by adding both the enzyme and AOS in the washing solution. Therefore, it was regarded that AOS molecules were adsorbed at the hydrophobic surface of denatured hemoglobin, subsequently, decomposed more effectively cooperative binding of hemoglobin, and the fragments of hemoglobin were removed more efficiently by means of the interfacial reaction of AOS.

  • PDF

Convergence-confinement method of a tunnel with the consideration of seepage forces (침투력을 고려한 터널의 내공변위 제어 미케니즘)

  • Lee, In-Mo;Yoo, Seung-Youl;Nam, Seok-Woo;Shin, Young-Jin
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.7 no.3
    • /
    • pp.187-195
    • /
    • 2005
  • When a tunnel is excavated below groundwater table, the groundwater flow occurs towards the tunnel resulting in the seepage pressure. In this paper, the effect of groundwater flows on the behavior of shotcrete lining installed between ground-liner interfaces was studied considering permeability ratio between the ground and the shotcrete into account. Three-dimensional coupled finite element analysis was performed for this assessment. Seepage forces will seriously affect the shotcrete behavior since arching phenomena do not occur in seepage forces. A parametric study was conducted on the various tunnelling situations including interfacial properties between ground and shotcrete lining, the shape of tunnel cross-section and the thickness of liner, etc. Moreover, the convergence-confinement method (CCM) of a NATM tunnel considering seepage forces was proposed. The result showed that the more water tight is the shotcrete, the smaller is the convergence and the larger is the internal pressure. Therefore, the watertight fiber-reinforced shotcrete is found to be even more advantageous when used in under water tunnel.

  • PDF

Bond Slip Relationship between GFRP Plank and Cast-in-place High Strength Concrete (현장타설 고강도콘크리트와 유리섬유 FRP 판 사이의 부착슬립관계에 관한 연구)

  • Park, Chan-Young;Yoo, Seung-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.16 no.3
    • /
    • pp.2279-2286
    • /
    • 2015
  • Recently it has been actively studied that the use of hybrid GFRP-concrete structure with dual purpose of both a permanent forwork and main tensile reinforcement of GFRP plank. In applying general analysis and design technique to evaluate the performance of hybrid structures with cast-in-place high strength concrete and GFRP plank, it is essential that the characteristics of the bond slip model is identified. In this study a simplified bilinear bond slip model for hybrid structure with GFRP plank and cast-in-place high strength concrete is proposed. Maximum average bond stress of simple bond slip relationship that has been proposed in this study is 3.29MPa, initial slope is 35.66MPa/mm, the total slip is 0.23mm and interfacial fracture energy is 0.37kN/m.

A Study on Effect of Plasma Treatment for Waste Wood Application (폐목재(廢木材) 활용(活用)을 위한 플라즈마 처리(處理) 효과(效果)에 대한 연구(硏究))

  • Kim, MiMi;Lim, Joong Yeon
    • Resources Recycling
    • /
    • v.22 no.2
    • /
    • pp.18-21
    • /
    • 2013
  • In this study, surface modification of wood powder by atmospheric pressure plasma treatment was investigated. The composites were manufactured using wood powder and polypropylene(wood powder : PP = 55 wt% : 45 wt%). Atmospheric pressure plasma was treated as condition of 3KV, $17{\pm}1$KHz, 2 g/min. Helium was used as carrier gas and monomer such as hexamethyl-disiloxane(HMDSO) was used to modify surface property by plasma polymerization. The tensile strength of untreated waste wood powder(W3) and homogeneous wood powder(H3) were about 18.5 MPa, 21.5 MPa while the tensile strength of plasma treated waste wood powder(PW3) and homogeneous wood powder(PH3) were about 21.2 MPa, 23.4 MPa, respectively. And tensile strength of W3 and H3 were improved by 14.6% and 8.8%, respectively. From the results for mechanical property, morphological analysis, we obtained improved interfacial bonding of polypropylene and wood powder modified by plasma treatment.

Effect of Reflow Number on Mechanical and Electrical Properties of Ball Grid Array (BGA) Solder Joints (BGA 솔더 접합부의 기계적.전기적 특성에 미치는 리플로우 횟수의 효과)

  • Koo, Ja-Myeong;Lee, Chang-Yong;Jung, Seung-Boo
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.14 no.4
    • /
    • pp.71-77
    • /
    • 2007
  • In this study, the mechanical and electrical properties of three different ball grid array (BGA) solder joints, consisting of Sn-37Pb, Sn-3.5Ag and Sn-3.5Ag-0.75Cu (all wt.%), with organic solderability preservative (OSP)-finished Cu pads were investigated as a function of reflow number. Based on scanning electron microscopy (SEM) analysis results, a continuous $Cu_6Sn5$, intermetallic compound (IMC) layer was formed at the solder/substrate interface, which grew with increasing reflow number. The ball shear testing results showed that the shear force peaked after 3 reflows (in case of Sn-Ag solder, 4 reflows), and then decreased with increasing reflow number. The electrical property of the joint gradually decreased with increasing reflow number.

  • PDF

A Study on the Characteristics of Cell Reaction for the MCMB Carbon as Anode in Li-ion Batteries (리튬이온 전지용 카본(MCMB) 부극재료의 전지반응 특성)

  • 박영태;류호진;김정식
    • Journal of the Korean Ceramic Society
    • /
    • v.36 no.2
    • /
    • pp.172-177
    • /
    • 1999
  • Graphite and carbonaceous materials showed an excellent capability as a negative electrode in Li-ion batteries because Li-ion can be intercalated and de-intercalated reversibly within most carbonaceous materials of layered structure. Also, the electrochemical potential of Li-intercalated carbon anode is almost identical with that of Li metal. In the present study, mesocarbon microbeads(MCMB) were used as anode electrode and its properties of charge/discharge and interfacial reaction with electrolyte were studied by Potentiostat/Galvanostat test, FT-IR analysis, XRD and SEM. The passivation film of solid-state was formed as the interface between electrode and electrolyte as the cell reaction began and, once formed, became thicker with repeated charge/discharge process. Also, the relationship between the passivation film formed at the electrode interface and storage capacity was discussed.

  • PDF

Effects of Hydrocarbon Additions on Gas-liquid Mass Transfer Coefficients in Biphasic Bioreactors

  • Silva, Teresa Lopes da;Calado, Vitor;Silva, Nadia;Mendes, Rui L.;Alves, Sebastiao S.;Vasconcelos, Jorge M.T.;Reis, Alberto
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • v.11 no.3
    • /
    • pp.245-250
    • /
    • 2006
  • The effects of aliphatic hydrocarbons (n-hexadecane and n-dodecane) on the volumetric oxygen mass transfer coefficient $(k_L\;a)$ were studied in flat alveolar airlift reactor and continuous stirred tank reactors (CSTRs). In the flat alveolar airlift reactor, high aeration rates (>2vvm) were required in order to obtain efficient organic-aqueous phase dispersion and reliable $k_La$ measurements. Addition of 1% (v/v) n-hexadecane or n-dodecane increased the $k_La$ 1.55- and 1.33-fold, respectively, compared to the control (superficial velocity: $25.8{\times}10^{-3}m/s$, sparger orifice diameter: 0.5 mm). Analysis of the gas-liquid interfacial area a and the liquid film mass transfer coefficient $k_L$ suggests that the observed $k_La$ increase was a function of the media's liquid film mass transfer. Addition of 1% (v/v) n-hexadecane or n-dodecane to analogous setups using CSTRs led to a $k_La$ increase by a factor of 1.68 and 1.36, respectively (superficial velocity: $2.1{\times}10^{-3}m/s$, stirring rate: 250 rpm). These results propose that low-concentration addition of oxygen-vectors to aerobic microbial cultures has additional benefit relative to incubation in purely aqueous media.

AN EVALUATION OF THE CRACK PROPAGATION CHARACTERISTICS OF PORCELAIN AND THE BOND STRESS OF CERAMO-METAL SYSTEM (치과용 도재의 균열전파 특성과 도재 -금속간의 응력분석)

  • Park, Ju-Mi;Bae, Tae-Sung;Song, Kwang-Yeob;Park, Charn-Woon
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.32 no.1
    • /
    • pp.47-76
    • /
    • 1994
  • This study was carried out to evaluate the effect of the crack propagation characteristics and bond stress of ceramo-metal system. In order to characterize the crack propagation, the static crack propagation stored in $37^{\circ}C$ distilled water of two commerical porcelains and the dynamic crack propagation under cyclic flexure load of ceramo-metal system were examined. In order to characterize the bond stress, the shear bond test, the 3-point flexure bond test, and the finite element stress analysis of ceramo-metal system were conducted. The results obtained were as follows : 1. Bulk densities and Young's moduli of opaque porcelains increased with repeated firing. 2. Maximum fracture toughness during 4 firing cycles showed at the group of 4 firing cycles in Ceramco porcelain and 2 firing cycles in Vita porcelain. 3. Shear bond strength and flexure bond strength of Ceramco-Verabond specimen were larger than those of Ceramco-Degudent G specimen (p<0.05). 4. Interfacial stresses under three point flexure bond test were concentrated at the edges of ceramometal system. 5. When a cyclic flexure load was applied, the crack growth rate of porcelain surface of ceramometal specimens was decreased as load cycles increased.

  • PDF

Biaxial flexural strength of bilayered zirconia using various veneering ceramics

  • Chantranikul, Natravee;Salimee, Prarom
    • The Journal of Advanced Prosthodontics
    • /
    • v.7 no.5
    • /
    • pp.358-367
    • /
    • 2015
  • PURPOSE. The aim of this study was to evaluate the biaxial flexural strength (BFS) of one zirconia-based ceramic used with various veneering ceramics. MATERIALS AND METHODS. Zirconia core material (Katana) and five veneering ceramics (Cerabien ZR; CZR, Lava Ceram; LV, Cercon Ceram Kiss; CC, IPS e.max Ceram; EM and VITA VM9; VT) were selected. Using the powder/liquid layering technique, bilayered disk specimens (diameter: 12.50 mm, thickness: 1.50 mm) were prepared to follow ISO standard 6872:2008 into five groups according to veneering ceramics as follows; Katana zirconia veneering with CZR (K/CZR), Katana zirconia veneering with LV (K/LV), Katana zirconia veneering with CC (K/CC), Katana zirconia veneering with EM (K/EM) and Katana zirconia veneering with VT (K/VT). After 20,000 thermocycling, load tests were conducted using a universal testing machine (Instron). The BFS were calculated and analyzed with one-way ANOVA and Tukey HSD (${\alpha}$=0.05). The Weibull analysis was performed for reliability of strength. The mode of fracture and fractured surface were observed by SEM. RESULTS. It showed that K/CC had significantly the highest BFS, followed by K/LV. BFS of K/CZR, K/EM and K/VT were not significantly different from each other, but were significantly lower than the other two groups. Weibull distribution reported the same trend of reliability as the BFS results. CONCLUSION. From the result of this study, the BFS of the bilayered zirconia/veneer composite did not only depend on the Young's modulus value of the materials. Further studies regarding interfacial strength and sintering factors are necessary to achieve the optimal strength.

Time-Domain Solutions of the VV, HV, VH Problems at the Surface of a Normally Uniaxial Half-Space Dielectric (수직 단축성을 갖는 반공간 유전체 표면에서 VV, HV, VH 문제의 시간영역 해)

  • Lihh Won-Seok;Nam Sang-Wook
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.16 no.12 s.103
    • /
    • pp.1246-1254
    • /
    • 2005
  • Theoretical investigation is made on the electromagnetic fields generated by an impulsive point current source, fur the VV, HV, and VH problems at the interface between an isotropic upper half-space medium and a normally uniaxial lower half-space medium. The electric fields of these problems are associated only with the extraordinary-wave components in the Fourier-Laplace domain. Applying the Cagniard-de Hoop method to each problem, the time-domain solutions of the wave fields are obtained. The fields of the VV case can be expressed in explicit(integral-free) forms. The fields of the HV and VH cases are not integral-free, but the major singularities implicit in the integral solutions can be analytically extracted. The interfacial far fields in the frequency domain are determined by the singularities in the time domain.