• Title/Summary/Keyword: instrumental analysis

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THE DISTRIBUTION CHARACTERISTICS OF TRACE ELEMENTS IN AIRBORNE PARTICULATES FROM AN URBAN INDUSTRIAL COMPLEX AREA OF KOREA USING INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS

  • LIM JONG-MYOUNG;LEE JIN-HONG;CHUNG YONG-SAM
    • Nuclear Engineering and Technology
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    • v.37 no.5
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    • pp.503-510
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    • 2005
  • An instrumental neutron activation analysis was used to measure the concentrations of about 24 elements associated with airborne particulates (PM10) that were collected in the most polluted urban region of Daejeon city, Korea from 2000 to 2002. Using the measurement data for various elements, both the extent of elemental pollution in the study area and the seasonality in their distribution characteristics were examined. Examinations of their distribution patterns indicated that most elements with crustal origin tend to exhibit seasonal peaks during spring, while most elements with anthropogenic origin tend to exhibit seasonal peaks during fall or winter. In order to explain the factors regulating their mobilization properties, the data were processed by a factor analysis. Results of the factor analysis suggested competing roles of both industrial and natural source processes, despite that the study site is located at a downwind position of the industrial complex. Based on the overall results of this study, it is concluded that the site may be strongly impacted by man-made sources but the general patterns of elemental distributions in the study area inspected over a seasonal scale are quite consistent with those typically observed from natural environment.

The Effects of elderly's Perceived Health and Social Support on Social Capital Formation (노인의 주관적 건강과 사회적 지지가 사회적 자본 형성에 미치는 영향)

  • Back, Jeong Man;Jeon, Sang Nam
    • The Journal of Korean Society for School & Community Health Education
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    • v.21 no.2
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    • pp.1-14
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    • 2020
  • Objectives: The purpose of this study was to identify factors(perceived health and social support) affecting social capital formation of the elderly. Methods: Samples consisted of 184 people aged over 65 years old in one county of Kyungsangbukdo. Data were analyzed with t-test, ANOVA and regression analysis. Results: First, social support(both emotional support and instrumental support) were significantly different by economic status. Secondly, regression analysis showed that perceived health affected a positive influence on social capital in Model1, which analyzed only perceived health. However, Model2, which analyzed perceived health and social support(emotional support, instrumental support) at the same time, showed that only instrumental support affected social capital formation. Conclusions: It was suggested to develop customized health promotion and job creation are required for social capital formation of the elderly.

Analysis of Regional Seismic Characters for Establishing Seismic Zone Factor (지역계수 설정을 위한 지역별 지진발생특성 분석)

  • Kwon, Ki-Hyuk;Hwang, Wan-Seon;Seo, Chee-Ho
    • Journal of the Korean Society of Hazard Mitigation
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    • v.6 no.3 s.22
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    • pp.1-8
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    • 2006
  • The seismic zone factor is evaluated according to the regional characteristics of seismic response based on the historical and instrumental earthquake data. This study aims at arranging regional seismic characteristics by the analysis of earthquake data recorded in the Korean Peninsula and providing the fundamental data to be used for establishing seismic zone factor considering the domestic seismic characteristics. This paper provides the seismic characteristics in the Korean Peninsula according to the historical and instrumental records and then presents fundamental data for establishing seismic zone factors in domestic region.

Data intercomparison and determination of toxic and trace elements in Algae using Instrumental Neutron Activation Analysis (중성자방사화분석에 의한 Algae중의 독성미량원소의 정량 및 실험실간 비교검증)

  • Chung, Yong-Sam;Moon, Jong-Hwa;Park, Kwang-Won;Lee, KiI-Yong;Yoon, Yoon-Yeol
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.346-353
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    • 1999
  • For the non-destructive multi-elemental analysis of environmental and biological materials, instrumental neutron activation analysis (INAA) was applied for the determination of toxic and trace elements in a set of three Algae samples provided by the International Atomic Energy Agency (IAEA). The analytical quality control was evaluated by comparing the analytical results of two standard reference materials of the National Institute of Standards and Technology (NIST); Oyster Tissue (SRM 1566a) and Citrus Leaves (SRM 1572). According to given analytical procedure, the concentration of 15-25 elements including spiked elements such as As, Cd, Cr and Hg in Algae samples were determined. To identify and validate these results, a data intercomparison program using more than 35 analytical methods in 150 laboratories was carried out and the estimated statistical data are summarized. Result of INAA is favorable, therefore, it is illustrated that can be applied for routine analysis of essential and toxic elements in algae samples as well as analytical quality assurance.

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Studies on Analysis of Gallium and Indium in Zinc Ores by Inductively Coupled Plasma Atomic Emission Spectrometry (유도결합 플라즈마 원자방출 분광법에 의한 아연광 중 Ga 및 In의 분석에 관한 연구)

  • Hwang, Youn-Ok;Sim, Sang-Kwon;Sung, Hack-Je;Yang, Myung-Kwon
    • Analytical Science and Technology
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    • v.6 no.1
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    • pp.131-139
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    • 1993
  • The separation of gallium and indium from the matrix elements such as zinc and other ions, especially form Fe(III) ion was studied for the determination of trace level of them in zinc ores and zinc blendes by inductively coupled plasma atomic emission spectrometry(ICP-AES). Gallium and indium were extracted from the sample solution with a solvent of tributyl phosphate(TBP). The type and concentration of acid, interferences of other ions, the ratio of aqueous phase to organic phase, TBP concentration, sripping efficiency were optimized for the effective extraction. Gallium and indium were separated from other ions in the 5N hydrochloric acid solution of the samples by the extraction with 100% TBP. In this time, Fe(III) was reduced to Fe(II) with hydroxylamine hydrochloride to prevent its coextraction prior to the main extraxtion. After stripped from organic phase by the back-extraction with 0.02N HCl, they were determined in the aqueous phase by ICP-AES. This method was known to be quantitative from the overall extraction of more than 95%.

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Characteristics of Respirable Particulate Matter from the Third and Fourth Industrial Complex Area of Daejeon City Using Instrumental Neutron Activation Analysis (기기중성자방사화분석을 이용한 대전 3, 4 공단지역의 호흡성입자의 특성)

  • Lim, Joung-Myoung;Lee, Jin-Hong
    • Journal of Environmental Impact Assessment
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    • v.15 no.6
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    • pp.425-433
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    • 2006
  • Instrumental neutron activation analysis was used to measure the concentrations of 27 elements associated with respirable particulate matter (PM10) that were collected from the Third and Fourth Industrial Complex Area of Daejeon City. The distribution patterns of elements were clearly distinguished with their concentrations varying across more than four orders of magnitude. The mean for Al were recorded to be the highest value of 1,527 $ng/m^3$, while that for In showed the lowest value of 0.1 $ng/m^3$. If compared in terms of enrichment factors, it was found that certain elements (e.g., As, Br, Cl, Cr, I, In, Sb, Se, and Zn) are enriched in PM10 samples of the study site. The results of factor analysis indicated six factors with statistical significance, which may exert dominant controls on regulating the elemental concentration levels in the study area.

An Analysis on the Employment Relationship of Domestic and Foreign Workers in the Regional Labor Market Using Instrumental Variable Method (도구변수법을 이용한 지역 노동시장의 내외국인근로자 고용관계 분석)

  • Cho, Eunji;Lee, Chanyoung
    • Journal of Labour Economics
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    • v.44 no.2
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    • pp.33-69
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    • 2021
  • This study estimates the employment relationship of domestic and foreign workers by establishing 16 municipal and provincial panel data for the period 2010-2018. It attempts to analyze industry-specific (manufacturing and construction), scale-specific (5-29, 5-29, 5-299 and 5 above) and uses the foreign worker's national share (foreigner's concentration index) as an instrumental variable to control the endogeneity of foreign workers. Finally, it compares the results of panel GLS, which does not consider the endogeneity of foreign workers, with the results using instrumental variable method that considers it. As a result of the analysis, the complementary relationship between domestic and foreign workers was confirmed in the panel GLS analysis. However, although the employment relationship between domestic and foreign workers was not statistically significant in the instrumental variable method, the analysis of the combination of manufacturing and construction industry showed a statistically significant substitute relationship. This study is highly regarded for the first time in Korea that an instrumental variable method was created to identify and control the endogeneity of foreign workers in estimating employment relationships between domestic and foreign workers.

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Perceived social support, Instrumental support Needs, and Depression of Elderly women (여성 노인의 사회적지지 및 도구적 지지요구과 우울에 관한 연구)

  • Tak, Young-Ran;Kim, Soon-Ae;Lee, Bong-Suk
    • Women's Health Nursing
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    • v.9 no.4
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    • pp.449-456
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    • 2003
  • Purpose: The purpose of this study was investigate the relationships among perceived social support, instrumental support needs, and depression of healthy, community dwelling elderly women. Method: This study was designed to examine whether the perceived social support and instrumental support were correlated with depression in elderly women. Data were cross-sectional and community-dwelling elderly individuals. The subject was 98 elderly women recruited from Elderly Welfare Center and Community center for Elderly. The instruments for this study were Personal Resource Questionnaire-part II, Geriatric Depression Scale (Short Form), and Instrumental Support Activities Checklist. Data were gathered by means of structured personal interviews. The internal consistency of the instruments was relatively good. Result: The participants' perceived social support was moderately high and instrumental support needs was low. Depression was mild and moderate relatively. The correlation analysis showed that the perceived social support was negatively related to depression and negatively related with instrumental support needs. Conclusion: The findings suggested that more perceived social support, less their depressive symptom in elderly women. It also revealed that the age, marital status, and socioeconomic status of elderly women also are important indicator of the elderly depression. Therefore nursing assessment and the design of intervention that incorporate the determinants supported in this study, such as perceived social support of the elderly women are needed in adopting and maintain health promoting lifestyle for the mental health and effective functioning in later life in women.

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Application of the JMA instrumental intensity in Korea (일본 기상청 계측진도의 국내 활용)

  • Kim, Hye-Lim;Kim, Sung-Kyun;Choi, Kang-Ryong
    • Journal of the Earthquake Engineering Society of Korea
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    • v.14 no.2
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    • pp.49-56
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    • 2010
  • In general, the seismic intensity deduced from instrumental data has been evaluated from the empirical relation between the intensity and the PGA. From the point of view that the degree of earthquake damage is more closely associated with the seismic intensity than with the observed PGA, JMA developed the instrumental seismic intensity (JMA instrumental intensity) meter that estimate the real-time seismic intensity from the observed strong motion data to obtain a more correct estimate of earthquake damage. The purpose of the present study is to propose a practical application of the JMA instrumental intensity in Korea. Since the occurrence of strong earthquakes is scarce in the Korean Peninsula, there is an insufficiency of strong motion data. As a result, strong motion data were synthesized by a stochastic procedure to satisfy the characteristics of a seismic source and crustal attenuation of the Peninsula. Six engineering ground motion parameters, including the JMA instrumental intensity, were determined from the synthesized strong motion data. The empirical relations between the ground motion parameters were then analyzed. Cluster analysis to classify the parameters into groups was also performed. The result showed that the JMA acceleration ($a_0$) could be classified into similar group with the spectrum intensity and the relatively distant group with the CAV (Cumulative Absolute Velocity). It is thought that the $a_0$ or JMA intensity can be used as an alternative criterion in the evaluation of seismic damage. On the other hand, attenuation relation equations for PGA and $a_0$ to be used in the prediction of seismic hazard were derived as functions of the moment magnitude and hypocentral distance.

Discrimination Analysis of the Geographical Origin of Foods (식품의 원산지 판별분석)

  • Choi, Jin-Young;Bang, Kyong-Hwan;Han, Kee-Young;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.44 no.5
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    • pp.503-525
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    • 2012
  • Consumers are increasingly concerned about the origin of foods, so the geographical origin of foods has been a major topic of debate and extensive research. Various instrumental methods (e.g. high performance liquid chromatography (HPLC), gas chromatography (GC), capillary electrophoresis (CE), electronic nose, near-infrared spectroscopy (NIRS), nuclear magnetic resonance spectroscopy (NMR), DNA analysis, multi-isotope analysis) in conjunction with statistical analysis, were developed and applied in attempt to provide reliable answers to their geographical origin. This study reviews current developments in the application of various methods for a clear geographical origin of foods. The limitation of discrimination analysis for geographical origin was also discussed.