• Title/Summary/Keyword: inorganic materials

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The Effect of Boric Acid on the Hydration of OPC (보통포틀랜드 시멘트의 수화에 미치는 Boric Acid의 영향)

  • Lee, Eui-Hak;Song, Young-Jin;Song, Myong-Shin;Lee, Kyung-Hee
    • Journal of the Korean Ceramic Society
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    • v.39 no.4
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    • pp.401-408
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    • 2002
  • The influence of $H_3BO_3$ in one of inorganic retarder for the hydration of OPC was investigated. The shape of needdle Ettringite formed in few minitues for a no addition of $H_3BO_3$ but, retarded to form of Ettringite and $Ca(OH)_2$ according to addition of $H_3BO_3$. Hydration was retarded for tranquil of Al ion by to be low of pH.

Studies on Ferroelectric Properties of Crystalline Oriented Pb(Zr, Ti)$\textrm{O}_3$ Thin Films (우선방위를 갖는 Pb(Zr, Ti)$\textrm{O}_3$ 박막의 강유전체 특성에 관한 연구)

  • Go, Ga-Yeon;Park, Jin-Seong;Lee, Jong-Guk;Lee, Eun-Gu;Lee, U-Seon;Lee, Jae-Gap
    • Korean Journal of Materials Research
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    • v.7 no.8
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    • pp.646-649
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    • 1997
  • (111)과 (100)우선방위의 정방정계의 Pb(Zr$_{0.2}$, Ti$_{0.8}$)O$_{3}$박막의 강유전체 특성과 신뢰성특성을 상부 전극의 두께를 변화시키면서 연구하였다. (111)우선방위의 박막이 (100)우선방위의 박막보다 큰 잔류분극과 항전계 값을 갖고 있어 정방형의 이력곡선 특성을 보여주었다. 스위칭전하의 상부전극의 두께 의존성은 상부전극을 열처리 할 때 유도되는 압축응력에 의한 stress효과로 설명할 수 있었다. 상부전극의 두께가 얇은 박막은 초기에는 작은 스위칭 전하를 갖고 있으나 스위칭 횟수가 증대됨에 따라 기계적인 응력의 감소로 인하여 부분 수위칭 영역이 확대되어 내구성이 향상되었다.

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$SrTiO_3$ Single Crystal Growth by Verneuil Method (Verneuil법에 의한 $SrTiO_3$ 단결정 성장)

  • Choi, I.S.;Cho, H.;Choi, J.K.;Orr, K.K.
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.689-694
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    • 1992
  • Strontium Titanate single crystal is grown by Verneuil method. Feed materials were prepared by coprecipitation method which started with Sr(NO3)2 and TiCl4. SrTiO3 can not be grown from feed materials having the stoichiometric components due to volatilization of SrO, when the powder added more 3 wt% SrO used, the crystal can be grown. Growth conditions that the pressure of oxygen and hydrogen gas was 5 psi, the flow rate of oxygen and hydrogen was 7.3 and 30ι/min respectively, the growth rate was 20 mm/hr were optimum. The grown single crystal has the diameter of 10~15 mm and its length is 30~40 mm. The grown crystal was deep brown color and somewhat transparent. The color of grown crystal was lightened after annealing.

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Electrical Properties of Al-doped ZnO Transparent Conducting Thin Films Deposited by RF Magnetron Sputtering (RF 마그네트론 스퍼터링법으로 증착한 Al이 첨가된 ZnO 투명전도막의 전기적 특성)

  • Kim, Jin-Yong;Lee, Yong-Ui;Jo, Hae-Seok;Lee, Dong-Hyeon;Kim, Yeong-Jin;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.5 no.3
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    • pp.280-287
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    • 1995
  • 첨가제로 $Al_{2}$$O_{3}$가 포함된 ZnO 소결체가 타깃을 이용하여 RF 마그네트론 스퍼터링법으로 Al이 첨가된 ZnO박막을 증착하고, 타깃에 첨가된 $Al_{2}$$O_{3}$의 농도와 증착시 스퍼터링장치내의 기판위치에 따른 박막의 물성 변화를 고찰하였다. 타깃의 $Al_{2}$$O_{3}$ 첨가농도가 2wt%인 경우에 비저항치 8 $\times$ $10_{-3}$ $\Omega$-cm인 박막이 증차되었다. 또한 $Al_{2}$$O_{3}$가 2wt%이상 첨가된 경우는 모든 Al이 박막내부에서 Zn를 치환하여 전자주게로의 역할을 하지 못하고, 오히려 치환되지 못한 Al원자의 중성 불순물 산란효과에 의해 박막의 비저항이 증가하였다. 타깃의 마모영역 위에서 증착된 Al을 첨가한 ZnO 박막은 그 영역 KR에서 증착된 박막보다 높은 비저항값을 나타냈으며, 이는 큰 에너지를 가지는 산소입자의 충돌에 기인한 것으로 여겨진다.

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Development of Organic-Inorganic Hybrid Insulating Materials with Semi-Non-Combustible Using by Recycling Gypsum (재활용 석고 부산물을 이용한 준불연 유무기 융합 단열재 개발 연구)

  • Ha, Joo-Yeon;Shin, Hyun-Gyoo;Song, Tae-Hyeob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.431-437
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    • 2019
  • The purpose of this study is to develop an organic-inorganic hybrid insulation materials which has an economic feasibility of organic level and excellent adiabatic performance and fire stability by impregnating organic materials with inorganic binder solutions. The organic base was commercial polyurethane sponge, and the inorganic binder slurry was prepared by mixing water and additives into recycled gypsum byproducts. As a result of evaluation of the developed materials, it was confirmed that it not only has excellent insulation performance of a thermal conductivity of 0.051 W/mK or less but also it is a semi-non-combustible materials specified in the Ministry of Land, Infrastructure and Transport Notice No. 2015-744. The developed materials can also be controlled for thermal conductivity and flame retardance according to density control during manufacturing process, and thus it can be applied to various insulation materials.

High performance Organic-Inorganic Hybrid Materials for Application in OLED Barrier Coating

  • Jung, Kyung-Ho;Yun, Chang-Hun;Bae, Jun-Young;Yoo, Seung-Hyup;Bae, Byeong-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.806-809
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    • 2009
  • Epoxy functionalized organic-inorganic hybrid materials (hybrimers) were synthesized by sol-gel reaction for application in OLED barrier coating. By using the calcium degradation method, the oxygen transition rate (OTR) and water vapor transition rate (WVTR) measured so far is $10^{-2}cc/m^2$-day for oxygen and $10^{-1}g/m^2$-day for water molecules with single hybrimer coating film, respectively. Encapsulated OLED devices have life time of 14hrs of a single hybrimer barrier coating and 29hrs of hybrimer/inorganic double barrier coatings at $25^{\circ}C$ and 60% relative humidity.

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A Fundamental Study on the Influence of Performance of Cementitious Composites of Inorganic Core Material for Self-Healing Capsule of Cracks (균열 자기치유를 위한 캡슐용 무기계 코어재료의 시멘트 복합체 성능에 미치는 영향에 관한 기초적 연구)

  • Choi, Yun-Wang;Oh, Sung-Rok;Choi, Byung-Keol;Kim, Cheol-Gyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.74-82
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    • 2017
  • In this study, we prepared a core material based on the inorganic materials in liquid form for applying an inorganic-based core material to a core material for the self-healing capsules as a part of the basic study to manufacture of self-healing capsule that can heal cracks of cementitious composite. Manufactured core material based on the inorganic materials were applied directly to the cement composite before its encapsulation, were evaluated the effect on performance of cementitious composite as wall as repair performance of the cracks in the cracks. The test results showed that core material based on the inorganic materials was effective to improve the compressive and adhesion strength, had an absorption, permeation water, penetration of chloride iones and freeze-thaw resistance performance. Through the results of this paper, we want to utilize the results as a basis data of the performance of the cement composite that can be obtained when applied to inorganic core materials based on self-healing capsules and future advances localized self-healing capsule technology.

Evaluation of Organic-Inorganic Hybrid Insulation Material Using Inorganic Filler and Polyurethane (무기질 충진재와 폴리우레탄을 활용한 유·무기 복합 단열소재의 특성 평가)

  • Lee, Jong-Kyu;Soh, Jung-Sub;Noh, Hyun-Kyung
    • Korean Journal of Materials Research
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    • v.22 no.11
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    • pp.604-608
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    • 2012
  • Recently, inorganic-organic hybrid materials have attracted much attention not only for their excellent thermal conductivity but also for their flame retardant properties. In this study, the properties of organic-inorganic hybrid insulating materials using inorganic fillers and polyurethane foam with different foaming conditions have been investigated. The addition of 1.5 wt% water to polyurethane as foaming agent shows the best foaming properties. The pore size was decreased in the foaming body with increasing of the $CaCO_3$ addition. The apparent density and thermal conductivity were increased by increasing the $CaCO_3$ addition. With an increasing amount of $CaCO_3$ powder, the flame retardant property is improved, but the properties of thermal conductivity and apparent density tend to decrease. When the addition of fine particles of $CaCO_3$, the apparent density and thermal conductivity were increased and, also, with the addition of coarse particles over $45{\mu}m$ in size, the apparent density and thermal conductivity were increased as well. In this study, the adding of $CaCO_3$ with average particle size of $27{\mu}m$ led to the lowest thermal conductivity and apparent density. After evaluation with different inorganic fillers, $Mg(OH)_2$ showed the highest thermal conductivity; on the other hand, $CaCO_3$ showed the lowest thermal conductivity.

Electrical AC Insulation Breakdown Characteristics of Various Epoxy / Heterogeneous Inorganic Mixed Composite (여러 종류의 에폭시/이종무기물 혼합 콤포지트의 전기적 교류 절연파괴 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.11
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    • pp.1463-1470
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    • 2018
  • In this study, 20 types of samples were prepared by mixing different kinds of inorganic materials to develop insulation materials for epoxy - based GIS substation equipment used under high voltage environmentally friendly insulation gas. One of the electrical characteristics, AC insulation breakdown experiment was performed. As mixing ratio of mixed heterogeneous inorganic materials, the dielectric breakdown strength was increased with increasing filler ratio of micro silica, micro silica : micro Alumina, 1:9, 3:7, 5:5, 7:3, 9:1, and decreased as the filling amount of micro alumina increased. The AC insulation breakdown characteristics were the best when the composition ratio was 9:1. The higher the content of silica, the better the interfacial properties, and the larger the alumina content ratio, the worse the interfacial properties.