• Title/Summary/Keyword: inorganic content

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Tritium Distribution in Leachates from Domestic Solid Waste Landfills (생활폐기물 매립장 침출수의 삼중수소 분포)

  • Park, Soon Dal;Kim, Jung Suk;Joe, Kih Soo;Kim, Jong Gu;Kim, Won Ho
    • Analytical Science and Technology
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    • v.17 no.3
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    • pp.251-262
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    • 2004
  • It is for the purpose of investigating the tritium distribution in the leachates, the raw and treated leachates and the condensates of the methane gas, which have occurred from domestic solid waste landfills. Also it aims to measure the tritium distribution level on the colloid size of the leachates, the raw and treated leachates. It was found that the major inorganic contaminants of the leachates were Na, K, Ca, Mg, $NH{_4}^+$-N and $Cl^-$. The mean tritium level of the raw leachates of the investigated 13 landfill sites for 6 months was 17 ~ 1196 TU. It corresponded to a several scores or hundreds of magnitude higher value than that of the normal environmental sample level except for two landfill sites. Also such a high concentration of the tritium was found in the treated leachates and methane gas condensates as well. Nevertheless it is important to emphasize that the tritium level which was found in this research is about 100 times lower than the tritium limit for the drinking water quality. And most of the tritium existed in the dissolved colloid of the leachate of which the colloid size is below $0.45{\mu}m$. Also, according to the tritium analysis results of the leachates after filtration with $0.45{\mu}m$ membrane filter for some landfills, it is likely that some tritium of the leachate would be distributed in a colloid size over $0.45{\mu}m$. In general the relationship between the tritium and other contaminants in the raw leachate was low, but it was relatively high between the tritium and TOC. However, the tritium content in the leachate had no meaningful relationship with the scale, hydrological characteristics and age of the landfill.

Relationship between Functional Quality of Garlic and Soil Composition (마늘의 기능성 품질과 토양 성분 간의 관계)

  • Lee, Yun-Kyoung;Sin, Hyun-Man;Woo, Koan-Sik;Hwang, In-Guk;Kang, Tae-Su;Jeong, Heon-Sang
    • Korean Journal of Food Science and Technology
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    • v.40 no.1
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    • pp.31-35
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    • 2008
  • This survey was conducted to investigate the functional quality characteristics of garlic based on different soil conditions (Pyungan, Maji, Anmi, Yuga, and Songjung soils). The Pyungan, Maji, and Anmi soils from the Danyang area showed high levels of pH, organic matter, available $P_2O_5$, and inorganic components. For the functional compositions of the garlic harvested from the different soil conditions, the Pyungan garlic contained the highest amounts of alliin and total fructan, with 9.2 and 193.3 mg/g, respectively. The Pyungan garlic also showed the highest amounts of total polyphenol and flavonoids, with 146.5 and 123.5 mg/100 g, respectively. Among the garlics from the different soils, the IC50 values by the DPPH assay ranged from 0.28 to 0.32 g/mL, and the $IC_{50}$ of the Pyungan garlic was 0.28 g/mL. The correlation coefficients between the functional quality of the garlic and the different soil compositions were analyzed. The quality of the garlic was positively affected by the pH and organic matter content (p < 0.01) of the soil. Since the Danyang garlic harvested from the Danyang soil had better functional qualities, these results suggest that the production of garlic in a suitable area for the ecotype is most effective.

Analysis by Environmental Factor of Similar Closed Non-sanitary Landfills (사용종료된 유사비위생 매립지들의 환경인자 분석)

  • Lee, Byungchan;Lee, Minhee;Park, Sangchan;Jeong, Seonki;Han, Yangsu;Yeon, Ikjun
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.6
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    • pp.27-33
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    • 2009
  • In this study, it was analysed physical characteristics, TS, moisture, C/N ratio, leaching test, and element analysis in landfill wastes of 10 years old without landfill pretreatment. The Organic material content was 7.2%~23.5% and soil was the main inorganic materials which it's rate was 54.1%~71.0%, in landfill wastes. The results of TS, VS, and moisture were represented 51.5%~68.1%, 23.6%~56.1%, 32.0%~48.4%, respectively. The analysis of hazardous materials did not indicate Hg, $Cr^{+6}$, CN, Organic Phosphorus, TCE and PCE, however the Pb of leaching materials showed 0.023~0.092 mg/L, which was the highest. As the result of the element analysis, C was 47.74%~56.72%, N was 4.09%~9.92%, the C/N ratio was 5.76~12.57 and the result of soils around landfill was the highest heavy material, Pb, 2.465 mg/kg~10.251 mg/kg. The objectives of this paper are to investigate states, stabilization of these closed landfills and to gain suitable data for post-closure care using some parameters through analysis of landfill environment.

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Study on the Sediment Quality in Bottom Water (I) (수 저층의 저질 조사 (I) - 저질 조사의 중요성과 분석에 관하여 -)

  • Kim, Do-Hee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.1 s.28
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    • pp.93-102
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    • 2007
  • Particle materials sink in bottom and dissolved inorganic substances release from sediment and many kinds of materials continuously exchange in sediment and water column as well as transfer and transformation in sediment. The study of sediment quality means the state of sediment pollution relation of the water quality, sediment biota, materials fluxes between sediment and water column, transformation of materials in sediment is being important in recent. The state of sediment quality imply that the history of water pollution for long time, because the sediment quality does not change temporally. The sediment quality of bottom water can be used as a good indicator of pollution at present and in future. The major index of sediment qualities are the content of nutrients and hazard materials such as metals, Ignition Loss (IL), Total Sulfur (TS), Oxidation Reduction Potential (ORP), sediment COD, color, odor and the release of nutrients from sediment. However, there are some arguments between researchers about compare to estimation of sediment quality and sampling and analysis of sediment. In this study, I will introduce the method of sediment sampling, analyzing and estimating of the sediment pollution.

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Weathering and Deterioration Diagnosis for Conservation Sciences of Stone Pagoda in the Bunhwangsa Temple,Gyeongju, Korea (경주 분황사 모전석탁의 암석학적 풍화와 보존과학적 훼손도 진단)

  • Yi, Jeong-Eun;Lee, Chan-Hee;Lee, Myeong-Seong;Kim, Young-Taek
    • 한국문화재보존과학회:학술대회논문집
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    • 2004.10a
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    • pp.92-100
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    • 2004
  • The host rocks of brick-shaped stone pagoda in the Bunhwangsa temple are lots of kinds andesitic rocks, which has gone through mechanical and chemical weathering. As the overall observation, the pagoda is serious damages by air pollutants, and the northeast parts show the much advanced state of turning white, while the southeast parts are heavily cracked in the materials. The rocks of brick-shaped pagoda body are in a relatively stable condition of weathering and damage except for the abrasion and cracks of the corners. The rocks of the pagoda roof suffer from more symptoms including multiple peel-offs, exfoliation, cracks forming round lines, and falling off stone pieces. The pagoda roof rocks are dominated by the thriving leafy lichens and mosses, especially, there are higher plants (selaginella involvens, dandelions) taking root actively between the brick stones and content mortar. There are even light gray precipitates like stalactites between the rocks of the body, In particular, the 1st and 2nd floor in the east side and the body parts in the north side are the most serious. Their major minerals are calcite, gypsum and clay minerals. The rocks of the stylobate and the tabernacle in all the four directions are composed mainly of granitic rocks. The materials consisting of the tabernacles show the severe splits and distortion, which causes the structural instability. The stylobate rocks are heavily contaminated by some weeds with the often marks of inorganic contamination by secondary hydroxides. The central part of the east stylobate has been sinking, while that of the 1st floor west stylobate is protruded nesting a line of cracks. Accordingly, the inside of the tabernacle is always humid with the constant introduction of rainwater. The stone lion standing in the southeast and northeast side are alkali granite, while that in the southwest and northwest lithic tuff. Each of the stone lion also coated with various colored lichens, mosses, algae, bacteria and bryophyte. The external materials of the pagoda have deteriorated the functions of the rocks and made the loss, falling off, and biological contamination even worse due to the surface weathering. Thus it's urgent to come up with scientific restoration and conservation measures through clinical tests.

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Material Analysis and Coloring Characteristics of Korean Traditional Copper-red Pigment (Jinsa) (동화(진사) 안료의 재료과학적 분석 및 발색특성)

  • Kim, Ji-Young;Cho, Hyun-Kyung;Jun, Byung-Kyu;Cho, Nam-Chul;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.27 no.1
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    • pp.31-40
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    • 2011
  • Copper-red (Dongwha, Jinsa) is Korean traditional inorganic pigment used for red-coloring on the porcelain surface during Goryeo and Joseon Periods. Trace amounts of copper-red porcelains are handed down because of the technical difficulty of making and coloring of the pigment. It is known that copper ore sources were extensively distributed in Korea according to old literatures and some of them are still producing copper ore at this present. Main types of copper-bearing mineral in Korea are chalcopyrite ($CuFeS_2$) and malachite ($Cu_2CO_3(OH)_2$), and they are easily collected from the ground surface. This means Korea had geographical and economic geological advantages for supplying raw material of the pigment. These two minerals showed good red-coloring in color test for porcelain pigment. As a coloring element, copper showed micro size less than $5{\mu}m$ in diameter in glaze matrix. The dispersion of copper particle is the most decisive factor for red chromaticity of copper-red porcelain, as well as copper content of the pigment.

A Study on the Noxious Materials in the Waste Shipped into Solid Recovered Fuel(SRF) Facilities and Their Influence (고형연료(SRF)시설로 반입되는 폐기물의 영향 및 유해성물질 등에 관한 연구)

  • Lee, Seung-Won;Kim, Sang-Hun;Lee, Sang-Seok;Kim, Jung-Kwon
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.91-97
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    • 2018
  • This study carried out first a component survey on the domestic waste shipped into a waste disposal facility in B city, and then heavy metal analysis of each component according to the SRF standards. Based on this, this study explored the problems with domestic waste and measures to improve them. The results are as follows. The result of the survey of physical components show that paper accounted for the largest proportion with 20.5 %~59.9 %, metals (including batteries) among incombustibles accounted for 0.0~8.3 %, other inorganic substances, glass and ceramics accounted for 0.0~43.7 % and 0.0 %~19.6 % respectively. However, the proportion of coated viny and plastics, which have high lead and cadmium content, was rather high with 2.9 %~30.9 %. This suggests the possibility that actual concentration of lead and cadmium within SRF is likely to be higher. Among the 15 components contained in the waste brought into the waste disposal facility, 10 components (food waste, textiles, vinyl, plastics, wood, rubber and leather, paper, metals, electronic substrates, and nail polish) were analyzed according to assay samples (approximately 0.1 g and 0.3 g). The result of analysis shows that the amount of Cd and Pb detected in coated vinyl for 0.109 g of assay sample was 98.6 mg/kg and 20.6 mg/kg respectively; 117.0 mg/kg and 29.0 mg/kg respectively for 0.313 g of assay sample. This is high contents exceeding the Cd standard. As for wooden component, the amount of Pb was 480.0 mg/kg for 0.3 g of assay sample. This suggests that there always exists the possibility of exceeding the exposure level of heavy metals (Cd and Pb) in SRF as long as coated wood and vinyl plastics with high contents of Pb and Cd are shipped into the waste disposal facility; and the local government and the residents need to work hard to improve the situation including development of the machine to sort electronic substrates and batteries for separate collection of the waste of coated vinyl and plastics within domestic waste.

The Monitoring and Ecological Restoration Concept of Ecosystem Conservation Area in Dunchon, Seoul (서울시 둔촌동 습지 생태계보전지역 모니터링 및 생태적 복원구상)

  • 한봉호;김정호;홍석환
    • Korean Journal of Environment and Ecology
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    • v.17 no.3
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    • pp.242-257
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    • 2003
  • This study surveyed an ecosystem conservation area that is wetland area to establish ecological restoration and preservation plan. Monitoring standard have been set up item, method, period, number of times etc. Result that examine according to monitoring standard, Plant field investigated Flora, actual vegetation. Flora is 132 taxa(39 family 116 species 19 variety 1 forma) appeared and wild species were 85 species, and introduced species were 47 species. Grasped monthly(April∼September) actual vegetation, swampy plant community influence were increase and influence of Persicaria thunbergii was big situation specially. Frequency appearance of naturalized plant is much on field. Animal field investigated Birds, Herpetofauna, Insecta. Birds were appeared 34 species 378 individual and Herpetofauna were appeared 4 species 5 individual and insecta investigated 11 order 52 family 153 species. Inorganic environmental field investigated groundwater level, quality of water, soil quality. Groundwater level is high by 0.0∼89.0cm, $Ca^{++}$ content is some high by 2.18∼13.73cmol/kg in soil. Also we suggested basis direction and each space details plan on monitoring as follow : wetland ecosystem restoration plan, eruption area restoration plan, forest ecosystem restoration plan.n.

Changes in Chemical Compositions of Pumpkin(Cucurbita moschata DUCH.) Seed Sprouts (호박(Cucurbita moschata DUCH.)종실의 발아 성장 과정 중 성분 변화)

  • 이병진;장희순;이규희;오만진
    • Food Science and Preservation
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    • v.10 no.4
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    • pp.527-533
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    • 2003
  • This study was performed for increasing the consumption and developing the function of pumpkin(Cucurbita moschata DUCH.) seed. The changes of the contents of general chemical compositions, fatty acids, amino acids, ascorbic acid and ${\beta}$-carotene during sprouting were analyzed. Also, the bitter taste, which was produced during sprouting, were purified by using thin layer chromatography and preparative high pressure liquid chromatography. The purified bitter compound was identified by mass spectrum and nuclear magnetic resonance($^1$H '||'&'||' $\^$13/C-NMR). Weight of pumpkin seed sprout was increased to 348.4% and the length of stem was dramatically increased at 8 days. In each head and stem parts of the pumpkin seed sprout, the contents of protein and lipid were decreased, however, the contents of fiber, ash and soluble inorganic nitrogen were increased. The fatty acids of the pumpkin seed sprout were mainly represented as linoleic acid, oleic acid, palmitic acid and stearic acid. During sprouting, palmitic acid was gradually increased, reversely, linoleic acid was gradually decreased. The general amino acids of head part in the pumpkin seed sprout grown at 23$^{\circ}C$ during 8 days were orderly more contained glycine, alanine, arginine, cystein and proline. Those of free amino acids were orderly more contained arginine, threonine, alanine and glutamine. The contents of L-ascorbic acid and ${\beta}$-camtene of the pumpkin seed sprout were gradually increased with increasing sprouting days. The bitter taste material of head part of the pumpkin seed sprout was detected at Rf value 0.72 on silicagel TLC plate and separuted as one peak by HPLC. The chemical structure of the puified bitter compound was identified as a cucurbitacin glycoside by MS and NMR. The content of bitter compound at 8 days was contained 42.2 mg per 1kg sprout head.

Quality and Volatile-Flavor Compound Characteristics of Hypsizigus marmoreus (느티만가닥 버섯의 품질 및 휘발성 향기 성분 특성)

  • Park, Myoung-Su;Park, Joong-Hyun;Oh, Deog-Hwan
    • Food Science and Preservation
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    • v.18 no.4
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    • pp.552-558
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    • 2011
  • Hypsizigus marmoreus is a wild mushroom commonly consumed in South Korea due to its beneficial effects on health. In the present study, the general chemical and inorganic-element composition, the total amino acid contents, and the volatile-flavor compounds of H. marmoreus were investigated for food uses. The proximate compositions consisted of 60.1% carbohydrate, 32.0% crude protein, 8.98% moisture, 5.0% ash, and 2.0% crude lipid. The minerals in H. marmoreus were found to be as follows; potassium (429.5 mg), phosphorus (101.9 mg), sodium (20.3 mg), magnesium (54.86 mg), calcium (2.7 mg), zinc (0.8 mg), iron (0.7 mg), manganese (0.2 mg), and copper (0.1 mg), based on 100 g of mushroom dry weight. Seventeen kinds of total amino acids were found in H. marmoreus, with the glutamine acid content being the highest (2,340 mg/100 g), followed by the asparagine, serine, arginine, and leucine contents. The volatile-flavor components of H. marmoreus were collected via simultaneous steam distillation extraction (SDE), and were analyzed via gas chromatography-massspectrophotometry (GC-MS). A total of 17 volatile-flavor compounds were identified, including eight aldehydes, seven alcohols, one acids, and one other compounds. The most abundant compound was 2,3,6-trimethy1 pyridine, which accounted for more than 40% of the total volatiles; other important compounds were 1-octen-3-o1, buty1hydroxytoluene (BHT), isoocty1 phthalate, 3-octanal, 1-undecanol, and 2-amylfuran. These results provide preliminary data for the development of H. marmoreus as an edible food material.