• Title/Summary/Keyword: inorganic carbon

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The Influence of Graphitic Structure on Oxidation Reaction of Carbon Materials (탄소재료의 산화반응에 미치는 흑연구조의 영향)

  • ;Eiichi Yasuda
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.816-822
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    • 1996
  • Dependence of graphitic structure on oxidation of carbon materials was discussed using furan resin-derived carbon with inorganic compounds such as SiC and TiO2 Oxidation of carbon was governed by active site. I. e surface area regardless of the degree of graphitization. When oxidation was considered for not unit weight but unit area graphitization was important factor for oxidation so that the degree of graphitization increased the oxidation rate was delayed. Graphite (tiO2 addition) and turbostratic graphite(SiC addition) were oxidized through the same mechanism. In carbon materials with different structure components more than 2 oxidation of each component was different and amorphous component without the influence of additives on the surface was selectively oxidized in the intial oxidation stage.

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Effect of electrical aging on emission stability of carbon nanotube paste

  • Park, J.H.;Moon, J.S.;Jeong, J.S.;Yoo, J.B.;Park, C.Y.;Moon, H.S.;Nam, J.W.;Kim, J.M.;Park, J.H.;Choe, D.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1466-1469
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    • 2005
  • We report effects of electrical aging on the emission stability of carbon nanotube (CNT) paste for low cost and high low-cost and large area field emission devices or displays. Photosensitive carbon nanotube paste was formulated by using of spin on glass (SOG) as an inorganic binder and investigated emission properties and stability depending on electrical aging condition.

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Application of Ultrasounds for the Removal of Chlorobenzene and Chlorinated Phenols in Water (Chlorobenzene 및 Chlorinated Phenol류의 분해에 미치는 초음파의 응용)

  • 우영억;황규탁
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.35-43
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    • 2000
  • Aqueous solutions of chlorobenzene and chlorinated phenols were exposed to 200kHz ultrasound with a power of $6.0W/\textrm{cm}^2$ per unit volume on sonochemical reactor under ambient temperature and pressure conditions. The concentration of chlorobenzene and chlorinated phenols decreased with ultrasound, indicating first-order kinetics. Degradation rate constants are calculated from the slope of plots. The order of the rate constants is as follows : 2-chlorphenol(2-CP)$\leq$ 4-chlorophenol(4-CP)<3-chlorophenol(3-CP)$5.63~9.96({\times}10^{-2})min^{-1}$ under argon. The degradation was suppressed by the addition of t-BuOH and the suppressed yield was agreed with their reactivity for hydroxy radical. The main products of these systems were formic acid, acetic acid, small amount of methane and inorganic carbon forms as carbon dioxide, carbon monoxide in sonolysis of chlorinated phenols, and also these results agreed with change of TOC.

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New Inorganic Vertical Alignment Material Suitable for Large Area LCD Panel

  • Rho, Soon-Joon;Hiroyuki, Kamiya;Jeon, Baek-Kyun;Kim, Kyeong-Hyeon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.330-333
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    • 2005
  • We investigated the liquid crystal (LC) alignment phenomena using a-C:H and a-C:F:H thin films. Homogeneous alignment is obtained using ion beam treated hydrogenated amorphous carbon (a-C:H) thin films. Homeotropic alignment is obtained using F treated a-C:H thin films, namely, fluorinated amorphous carbon (a-C:F:H) thin films. We investigated the relationship between the surface properties of amorphous carbon based alignment layer and LC alignment phenomena.

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Synthesis of new black pigment; Carbon black pigment capsulated into the meso-pore of silica as black pigment in cosmetic

  • Jang, Hye-In;Lee, Kyung-Chul;Park, Jong-Eul;Lyoo, Hee-Chang
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.308-312
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    • 2003
  • Recently the trend of new materials development is extensively and very actively progressing in the study of physical and chemical characteristics developing a totally new material along with the study field of recently discovered material modifying physically and chemically characteristics. Among these fields of studies, one method to improve adaptation of inorganic material is the study of mesoporous materials. The most general way to synthesize mesoporous materials is to mold the very systematical mesopore into a corpuscle by using templates(omitted)

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Effects of permeation test conditions on $CO_2$/$N_2$ separations of NaY zeolite membranes

  • Cho, Churl-hee;Ahn, Young-soo;Han, Moon-hee;Hyun, Sang-hoon
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.105-108
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    • 2004
  • Since Kyoto protocol in 1997, carbon dioxide recovery using membranes has been attended due to its potential applications to recover high purity carbon dioxide with low processing cost. Because carbon dioxide membrane should operate in chemically and thermally severe conditions and requires high permeance, an inorganic membrane is more favorable than a polymeric membrane.(omitted)

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Fabrication of polymer thick film resistor and study on resistance variation regarding curing temperature (폴리머 후막 저항체의 제작 및 경화 온도에 따른 저항 값 변화에 대한 연구)

  • Yoo, Myong-Jae;Lee, Sang-Myong;Park, Seong-Dae;Kang, Nam-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.212-213
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    • 2006
  • Polymer thick film resistor paste was fabricated using various materials. Inorganic materials of carbon black and graphite were selected as fillers and epoxy resin was selected as organic material. Solvent with high boiling temperature was applied to adjust viscosity. A designed test coupon pattern was used to evaluate fabricated resistors. Aspect ratio of 1 was selected for evaluating resistor values. Electrical properties of fabricated resistors were measured and their values analyzed in relation to paste composition. PTF fabricated using carbon black as fillers achieved resistor value of $530{\Omega}/sq$.

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Mixed matrix membranes for dye removal

  • Evrim Celik-Madenli;Dilara Kesiktas
    • Membrane and Water Treatment
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    • v.14 no.4
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    • pp.175-180
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    • 2023
  • Mixed matrix membranes (MMMs) can be a promising alternative for the solution of dye removal from coloured effluents. Polymeric membranes are widely used due to their good film-forming ability, flexibility, separation properties, and cost. However, they have low mechanical, chemical, and thermal resistances. Moreover, the fouling of polymeric membranes is high because of their hydrophobic nature. Hence, there is an increasing interest in organic-inorganic hybrid membranes as a new-generation membrane material. It has been shown that carbon nanotubes have the potential to increase the material properties of polymers with their low density, high strength, hardness, and exceptional aspect ratio. In this work, carbon nanotubes blended MMMs were prepared and methyl orange removal efficiency of them was investigated. Compared to the bare membranes, MMMs showed not only increased hydrophilicity, water content, and pure water flux but also increased methyl orange rejection and flux recovery

Variations in Nutrients and CO2 Uptake with Growth of Undaria pinnatifida from the South Coast of Korea (미역 (Undaria pinnatifida)의 생장에 따른 영양염과 CO2 흡수율 변화)

  • Shim, Jeong-Hee;Hwang, Jae-Ran;Lee, Jae-Seong;Kim, Jong-Hyun;Kim, Sung-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.43 no.6
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    • pp.679-686
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    • 2010
  • To investigate the contribution of macroalgae to biogeochemical nutrients and carbon cycles, we measured the uptake rates of nutrients and $CO_2$ by Undaria pinnatifida using an incubation method in an acrylic chamber. From January to March 2010, U. pinnatifida was sampled at Ilkwang, a well-known area of macroalgae culture in Korea. The initial and final concentrations of nutrients, dissolved oxygen, total alkalinity, and pH of the chamber water were measured, and production/uptake rates were calculated using concentration changes, chamber volume, and incubation time. The production rate of dissolved oxygen by U. pinnatifida (n = 32) was about $5.4{\pm}4.0\;{\mu}mol\;g_{fw}^{-1\;}h^{-1}$. The uptake rate of total dissolved inorganic carbon (TDIC), calculated by total alkalinity and pH, was $7.9{\pm}6.5\;{\mu}mol\;g_{fw}^{-1}\;h^{-1}$. Nutrients uptake averaged $141.7{\pm}119.2$ nmol N $g_{fw}^{-1}\;h^{-1}$ and $15.0{\pm}9.1$ nmol P $g_{fw}^{-1}\;h^{-1}$. A positive linear correlation ($r^2$ = 9.6) existed between the production rate of dissolved oxygen and the uptake rate of total dissolved inorganic carbon, suggesting that these two factors serve as good indicators of U. pinnatifida photosynthesis. The relationships between fresh weight and uptake rates of nutrients and $CO_2$ suggested that younger specimens (<~50 g fresh weight) are much more efficient at nutrients and $CO_2$ uptake than are specimens >50 g. The amount of carbon uptake by the total biomass of U. pinnatifida in Korea during the year of 2008 was about 0.001-0.002% of global ocean carbon uptake. Thus, more research should be focused on macroalgae-based biogeochemical cycles to evaluate the roles and contributions of macroalgae to the global carbon cycle.

Preparation of TiO2-SiO2 Organic-Inorganic Hybrid Coating Material by Sol-gel Method and Evaluation of Corrosion Characteristics (졸-겔법에 의한 유·무기 TiO2-SiO2 혼성(Hybrid)코팅재료의 제조 및 부식 특성 평가)

  • Noh, J.J.;Maeng, W.Y.
    • Corrosion Science and Technology
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    • v.14 no.2
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    • pp.64-75
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    • 2015
  • Single $TiO_2$ coating prepared by sol-gel process usually experiences cracks in coating layer. In order to prevent cracks, an inorganic-organic hybrid $TiO_2-SiO_2$ coating was synthesized by combining precursors with an organic functional group. Five different coatings with various ratios of (1:8, 1:4, 1:1, 1:0.25 and 1:0.125) titanium alkoxide (TBOT, Tetrabutylorthotitanate) to organo-alkoxysilane (MAPTS, ${\gamma}$-Methacryloxy propyltrimethoxysilane) on carbon steel substrate were made by sol-gel dip coating. The prepared coatings were analyzed to study the coating properties (surface crack, thickness, composition) by scanning electron microscope (SEM), focused ion beam (FIB), and Fourier transform infrared spectroscopy (FT-IR). Potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) were also performed to evaluate the corrosion characteristics of the coatings. Crack free $TiO_2-SiO_2$ hybrid coatings were prepared with the optimization of the ratio of TBOT to MAPTS. The corrosion rates were significantly decreased in the coatings for the optimized precursor ratio without cracks.