• Title/Summary/Keyword: initial relative density

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ReaxFF and Density Functional Theory Studies of Structural and Electronic Properties of Copper Oxide Clusters

  • Baek, Joo-Hyeon;Bae, Gyun-Tack
    • Journal of the Korean Chemical Society
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    • v.64 no.2
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    • pp.61-66
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    • 2020
  • In this study, we investigate the structural and electronic properties of copper oxide clusters, CunOn (n = 9 - 15). To find the lowest energy structures of copper oxide clusters, we use ReaxFF and density functional theory calculations. We calculate many initial copper oxide clusters using ReaxFF quickly. Then we calculate the lowest energy structures of copper oxide clusters using B3LYP/LANL2DZ model chemistry. We examine the atomization energies per atom, average bond angles, Bader charges, ionization potentials, and electronic affinities of copper oxide clusters. In addition, the second difference in energies is investigated for relative energies of copper oxide clusters.

An Extended Force Density Method for the form finding of cable systems with new forms

  • Malerba, P.G.;Patelli, M.;Quagliaroli, M.
    • Structural Engineering and Mechanics
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    • v.42 no.2
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    • pp.191-210
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    • 2012
  • The Force Density Method (FDM) is a well known and extremely versatile tool in form finding of cable nets. In its linear formulation such method makes it possible to find all the possible equilibrium configurations of a net of cables having a certain given connectivity and given boundary conditions on the nodes. Each singular configuration corresponds to an assumed force density distribution. Its improvement as Non-Linear Force Density Method (NLFDM) introduces the possibility of imposing assigned relative distances among the nodes, the tensile level in the elements and/or their initial undeformed length. In this paper an Extended Force Density Method (EFDM) is proposed, which makes it possible to set conditions in terms of given fixed nodal reactions or, in other words, to fix the positions of a certain number of nodes and, at the same time, to impose the intensity of the reaction force. Through such extension, the (EFDM) enables us to deal with form findings problems of cable nets subjected to given constraints and, in particular, with mixed structures, made of cables and struts. The efficiency and the robustness of method are assessed through comparisons with other form finding techniques in dealing with characteristic applications to the prestress design of cable systems. As a further extension, the EFDM is applied to structures having some parts not yet geometrically defined, as can happen in designing new creative forms.

Field study of the process of densification of loose and liquefiable coastal soils using gravel impact compaction piers (GICPs)

  • Niroumand, Bahman;Niroumand, Hamed
    • Geomechanics and Engineering
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    • v.30 no.5
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    • pp.479-487
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    • 2022
  • This study evaluates the performance of gravel impact compaction piers system (GICPs) in strengthening retrofitting a very loose silty sand layer with a very high liquefaction risk with a thickness of 3.5 meters in a multilayer coastal soil located in Bushehr, Iran. The liquefiable sandy soil layer was located on clay layers with moderate to very stiff relative consistency. Implementation of gravel impact compaction piers is a new generation of aggregate piers. After technical and economic evaluation of the site plan, out of 3 experimental distances of 1.8, 2 and 2.2 meters between compaction piers, the distance of 2.2 meters was selected as a winning option and the northern ring of the site was implemented with 1250 gravel impact compaction piers. Based on the results of the standard penetration test in the matrix soil around the piers showed that the amount of (N1)60 in compacted soils was in the range of 20-27 and on average 14 times the amount of (1-3) in the initial soil. Also, the relative density of the initial soil was increased from 25% to 63% after soil improvement. Also the safety factor of the improved soil is 1.5-1.7 times the minimum required according to the two risk levels in the design.

Effects of Breeder Age and Stocking Density on Performance, Carcass Characteristics and Some Stress Parameters of Broilers

  • Onbasilar, E.E.;Poyraz, O.;Cetin, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.2
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    • pp.262-269
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    • 2008
  • The aim of this study was to determine the effects of breeder age and stocking density on performance, carcass characteristics and some stress parameters (H-L ratio, serum glucose, cholesterol and triglyceride levels, tonic immobility test (TI), antibody production, relative asymmetry (RA) and external appearances). This experiment was carried out with 705 one-day old male broiler chicks (Ross 308) obtained from three different ages of broiler breeder (32, 48 and 61 wks). Each age group was randomly divided into two stocking density groups (11.9 and 17.5 broilers per $m^2$) with 5 replications per group. The experimental period was 6 weeks. Broilers from 32 wk-old breeders had lower initial weight (p<0.001), body weight gain of the first 3 week of rearing (p<0.01), the percentage of abdominal fat (p<0.001) and serum cholesterol level (p<0.01); higher percentage of gizzard (p<0.01) and longer TI duration (p<0.001) than those from 48 and 61 wk-old breeders. Broilers reared at 17.5 b/m2 had lower final BW, body weight gain, feed consumption, feather condition and foot health (p<0.001), higher percentage of heart, H-L ratio, serum glucose and cholesterol levels (p<0.001), and longer TI durations (p<0.001). There were no significant interactions in examined parameters except for feed to gain ratio between breeder age and stocking density.

Spark Plasma Sintering of Stainless Steel Powders Fabricated by High Energy Ball Milling

  • Chang, Si Young;Oh, Sung-Tag;Suk, Myung-Jin;Hong, Chan Seok
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.97-101
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    • 2014
  • The 304 stainless steel powders were prepared by high energy ball milling and subsequently sintered by spark plasma sintering, and the microstructural characteristics and micro-hardness were investigated. The initial size of the irregular shaped 304 stainless steel powders was approximately 42 ${\mu}m$. After high energy ball milling at 800 rpm for 5h, the powders became spherical with a size of approximately 2 ${\mu}m$, and without formation of reaction compounds. From TEM analysis, it was confirmed that the as-milled powders consisted of the aggregates of the nano-sized particles. As the sintering temperature increased from 1073K to 1573K, the relative density and micro-hardness of sintered sample increased. The sample sintered at 1573K showed the highest relative density of approximately 95% and a micro-hardness of 550 Hv.

Characteristics of Undrained Shear Behavior for Nak-Dong River Sand Due to Aging Effect (Aging 효과에 따른 낙동강 모래의 비배수 전단거동 특성)

  • Kim, Young-Su;Kim, Dae-Man
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.916-923
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    • 2005
  • In this study, to observe aging effect of undrained shear behavior for Nak-Dong River sand, undrained static and cyclic triaxial tests were performed with changing relative density ($D_r$), consolidation stress ratio($K_c$) and consolidation time. As a result of the test, the modulus of elasticity to all samples estimated within elastic zone by the micro strain of about 0.05% in case of static shear behavior increased with the lapse of consolidation time significantly, so aging effect was shown largely. Also strength of phase transformation point(S_{PT}$) and strength of critical stress ratio point($S_{CSR}$) increased with the lapse of consolidation time. Undrained cyclic shear strength($R_f$) obtained from the failure strain 5% increased in proportion to relative density($D_r$) and initial static shear stress($q_{st}$), $R_f$ of consolidated sample for 1,000 minutes increased about 10.6% compared to that for 10 minutes at the loose sand, and $R_f$ increased about 7.0% at the medium sand. In situ application range of $R_f$ to the magnitude of earthquake for Nak-Dong River sand was proposed by using a increasing rate of $R_f$ as being aging effect shown from this test result.

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Liquefaction Resistance of Gravel-Sand Mixtures (자갈-모래 혼합토의 액상화 거동)

  • Kim, Bang-Sig;Kang, Byung-Hee;Yoon, Yeo-Won
    • Journal of the Korean Geotechnical Society
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    • v.23 no.10
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    • pp.47-56
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    • 2007
  • In this research, the effects of the gravel content on the liquefaction behavior for both of the isotropically and $K_0-anisotropically$ consolidated gravel-sand mixtures are investigated. for this purpose, the cyclic triaxial tests for the specimens with the same relative density (Dr=40%) and variations of gravel content were performed. On the other hand, a series of undrained cyclic triaxial tests were carried out on the isotropically consolidated gravel-sand mixtures with the same void ratio (e=0.7) and from 0% to 30% gravel contents. Void ratios of gravel-sand mixtures with the same relative density (Dr=40%) are found to decrease significantly with the increase of the gravel content from 0% to about 70% and increase thereafter. But the void ratio of the sand matrix among the gravel skeleton increases with the increase of the gravel contents. Test results are as follows : for the isotropically consolidated specimen with 40% of relative density and low gavel contents (GC=0%, 20%, 40%), pore water pressure development and axial strain behavior during undrained cyclic loading show similar behavior to those of the loose sand because of high void ratio, and the specimens with high gravel content (70%) both pore pressure and strata behaviors are similar to those of dense sand. And the isotropically consolidated specimens with the same void ratio (e=0.7) and higher gravel contents show the same behavior of pore water pressure and axial strain as that of the loose sand, but for the lower gravel content this behavior shows similar behavior to that of dense sand. The liquefaction strength of the isotropically consolidated specimens with the same relative density increases with gravel content up to 70%, and the strength decreases with the increase of the gravel content at the same void ratio. Thus, it is confirmed that the liquefaction strength of the gravel-sand mixtures depends both on relative density and void ratio of the whole mixture rather than the relative density of the sand matrix filled among gravels. On the other hand, the behavior of pore water pressure and axial strain for the $K_0-anisotropically$ consolidated gravel-sand mixtures shows almost the same cyclic behavior of the sand with no stress reversal even with some stress reversal of the cyclic loading. Namely, even the stress reversal of about 10% of cyclic stress amplitude, the permanent strain with small cyclic strain increases rapidly with the number of cycles, and the initial liquefaction does not occur always with less than maximum pore water pressure ratio of 1.0. The liquefaction resistance increases with the gravel contents between 0% and 40%, but tends to decrease beyond 40% of gravel content. In conclusion, the cyclic behavior of gravel-sand mixtures depends on factors such as gravel content, void ratio, relative density and consolidation condition.

Strength and Stiffness of Silty Sands with Different Overconsolidation Ratios and Water Contents (과압밀비와 함수비를 고려한 실트질 사질토 지반의 강도 및 변형 특성)

  • Kim Hyun-Ju;Lee Kyoung-Suk;Lee Jun-Hwan
    • Journal of the Korean Geotechnical Society
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    • v.21 no.9
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    • pp.53-64
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    • 2005
  • For geotechnical design in practice, soils are, in general, assumed to behave as a linear elastic or perfect plastic material. More realistic geotechnical design, however, should take into account various factors that affect soil behavior in the field, such as non-linearity of stress-strain response, stress history, and water content. In this study, a series of laboratory tests including triaxial and resonant column tests were peformed with sands of various silt contents, relative densities, stress states, OCR and water contents. This aims at investigating effects of various factors that affect strength and stiffness of sands. From the results in this study, it is found that the effect of OCR is significant for the intermediate stress-strain range from the initial to failure, while it may be ignored for the initial stiffness and peak strength. For the effect of water content, it is observed that the initial elastic modulus decreases with increasing water content at lower confining stress and relative density At higher confining stresses, the effect of water content Is found to become small.

On the maintenance of Semimanufactured Tobacco(cut tobacco) quality during Shipping or Long Term Straging (수송 또는 보관중 반제품(각초) 담배의 품질유지에 관하여)

  • 민영근;정한주;김기환;양광규
    • Journal of the Korean Society of Tobacco Science
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    • v.14 no.1
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    • pp.57-65
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    • 1992
  • The quality of cut tobacco will be deteriorated due to weather conditions such as temperature and relative humidity, when shipping and long term storaging. The change of equilibrium moisture contents in cut tobacco were under influence of relative humidity and temperature but not humectants. Therefore internal packing materials are necessary for cut tobacco to maintain initial quality, including taste, flavour and musty smell during shipping or storaging. When packing cut tobacco for shipping or long term storaging, desiralbe packing density was 200/$m^2$, For the long term storage under R.H 90% and 3$0^{\circ}C$, polyethylene film thickness suitable for packing material are above 100$\mu$, which resulted in 42days of shelf life.

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Effect of Grain Boundary Energy on the Shrinkage Rate of Solid State Sintering (고상소결중의 수축률 변화에 미치는 입계에너지의 영향)

  • 윤한호;김도연
    • Journal of the Korean Ceramic Society
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    • v.23 no.1
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    • pp.1-6
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    • 1986
  • The shrinkage rate of solid state sintering has been theoretically derived by combining the rate equation of material transport and the net free energy change resulting from the decrease of solid-vapor interface and the increase of grain boundary during sintering. For a sinteing model an idealized situation of the spherical particles with BCC packing was taken as the initial condition and the shrinkage was assumed to occur by forming the flat circualr grain boundaries on each particle. The plotted shrinkage rates as a function of grain boundary to surface energy ratio $(gamma_g/gamma_s)$ have shown that the relative density increases linearly at the initial stage of sintering but the shrinkage rate is decreased upon further sintering due to a decrease in driving force for densificaton. It has been also shown that the densification is critically affected by the $gamma_g/gamma_s$ ratio. In order to get the complete densificatin the ratio should be less than $sqrt{3}$. Any additive or atmospheric condition causing the decrease of$_g/gamma_s$ ratio will enhance sintering.

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