• Title/Summary/Keyword: initial curing time

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Fundamental Properties of Low-Heat Concrete According to the Mixing Rate of Super Retarding Agent (초지연제 혼입률에 따른 저발열 콘크리트의 양생온도별 기초물성평가)

  • Park, Byoung-Joo;Choi, Yoon-Ho;Hyun, seung-Yong;Kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.90-91
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    • 2020
  • As the construction site has become narrower recently, the importance of mass concrete is naturally being highlighted as skyscrapers become popular. However, it is not possible to install the entire volume per day if the mass concrete is installed due to the Remicon 8⦁5 system and the 52-hour workweek system. When the mass concrete base is divided into several days, cold joints occur because the consolidation of joints is not integrated due to different degree of hardening in the case of the previous layer and the next day. As a result, existing research has shown that if super retarding agent are mixed into Ready Mixed Concrete (hereinafter referred to as Remicon) using sugar as a raw material to delay the curing time of concrete, cold joints are inhibited and cracks are inhibited by reducing the initial hydration heat.

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A STUDY ON THE CHANGES IN DEGREE OF CONVERSION OF DUAL-CURE RESTORATIVE MATERIALS WITH TIME-ELAPSE (이중중합 수복재의 시간경과에 따른 중합도 변화)

  • Yang, Chul-Ho;Kim, Shin;Jeong, Tae-Sung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.26 no.3
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    • pp.554-563
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    • 1999
  • For the purpose of elucidating the polymerization modes of dual-cure restorative materials and comparing them with single-cure restorative materials, a study was performed on the light-cured composite resin, dual-cure composite resin, dual-cure glass ionomer cement and chemical-cure glass ionomer cement. By measuring the microhardness of each material at 0mm, 1mm and 3mm depth during initial 24 hours with predetermined interval, the state of polymerization and degree of conversion was indirectly evaluated for each material, and obtained results are as follows : 1. All of four materials tested showed significant increase in microhardness after 24hrs compared with just after curing starts. 2. In all materials except Ketac-fil, there showed a significant difference in microhardness between each depth at each time interval. 3. In the test of lap time till final curing for each material, the polymerization process was revealed to last longer in the dual-cure type materials than in single-cure type materials at 3mm depth. Based on the results above, it was demonstrated with materials of dual-cure mode that the degree of conversion increases by successive curing reactions even in the deeper layers where sufficient curing light is impermeable.

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Effect of Modification of SeO2/Acrylamide Ratios on Diffraction Efficiencies in PVA/AA Photopolymer Films

  • Kim, Dae-Heum;Lim, Ji-Yun;Nam, Seung-Woong;Chung, Dae-Won
    • Journal of the Optical Society of Korea
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    • v.11 no.4
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    • pp.183-191
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    • 2007
  • The highest diffraction efficiency(DE) value after illumination and post-curing of photopolymer films were obtained at the $SeO_2$/Acrylamide(AA) Ratios of AA 3.0 g, $SeO_2$ 1.0g and the DE's were stable values of over 90%. By the addition of $SeO_2$, the maximum DE at the initial stage of illumination was reached at 300 seconds, which suggests $SeO_2$ slows down the photopolymerization of AA, which enhances the maximum DE value by giving more migration time. DE variation curve for the optimum composition during extended-time illumination of 9,000 seconds resembles a sine curve due to the combination of the monomer diffusion and the photopolymerization, and the photopolymer film expanded by about 8% after photopolymerization due to monomer migration.

Experimental Study of Leaching Phenomena of Cs-137 From a Cement Matrix Generated at PWR Plant (가압 경수로에서 생성된 시멘트 고화체로부터 Cs-137의 용출 현상의 실험적 연구)

  • Doh, Jeong-Yeul;Lee, Kun-Jai
    • Journal of Radiation Protection and Research
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    • v.11 no.2
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    • pp.91-103
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    • 1986
  • Experimental study for the leaching behavior of Cs-137 was carried out using the simulated evaporator bottom product of PWR plant. The method of leach test proposed by the IAEA was partially modified using ANS method. The effect of various factors, i.e., sampling method, curing temperature, curing time, leachant temperature, vermiculite addition and volume-to-surface ratio, was considered in this experiment. Diffusion model in semi-infinite slab was in a good agreement with the data obtained from 4-weeks cured specimens. The effective diffusion coefficient of the specimens which were cured at the temperature of $24^{\circ}C$ for 4 weeks was found to be $1.20{\sim}1.47{\times}10^{-11}cm^2/sec$. With the experimentally obtained diffusion coefficient ($1.47{\times}10^{-11}cm^2/sec$), long-term prediction for the leaching of Cs-137 was carried out using finite-slab approximation. The estimated fraction of Cs-137 which remains in the environment is found to be less than 0.25 percent of initial amount after 100 years. About 25 years after the beginning of leaching, its fractional amount in the environment reachs the maximum value, 0.66 percent of initial amount.

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The influencing factors for the strength enhancement of composite materials made up of fine high-calcium fly ash

  • Olga M. Sharonova;Leonide A. Solovyov;Alexander G., Anshits
    • Advances in concrete construction
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    • v.16 no.3
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    • pp.169-176
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    • 2023
  • The aim of the study was to establish the influence of particle size, chemical and phase composition of fine microspherical high-calcium fly ash (HCFA), as well as superplasticizer content on the strength of cementless composite materials based on 100% HCFA and mixtures of HCFA with Portland cement (PC). For the initial HCFA fractions, the particle size distribution, chemical and quantitative phase composition were determined. The compressive strength of cured composite materials obtained at W/B 0.4 and 0.25 was determined at a curing time of 3-300 days. For cementless materials, it was found that a change in the particle size d90 from 30 ㎛ (fraction 3) to 10 ㎛ (fraction 4) leads to an increase in compressive strength by more than 2 times. Compressive strength increases by at least another 2.2 times with the addition of Melflux 5581F superplasticizer (0.12%) and at W/B 0.25. The HCFA-PC blends were investigated in the range of 60-90% HCFA and the maximum compressive strength was found at 80% HCFA. On the basis of 80% HCFA-20% PC blend, the samples of ultra-high strength (108 and 150 MPa at 28 and 100 days of hardening) were obtained with the addition of 0.3% Melflux 5581F and 5% silica fume. The quantitative phase composition was determined for composite materials with a curing age of 28 days. It has been established that in a sample with ultra-high strength, a more complete transformation of the initial phases of both HCFA and PC occurs as compared to their transformation separately.

Performance Analysis of Strength Development of FRC Base Depending on Maturity (적산온도에 의한 FRC 기층의 강도발현 성능 분석)

  • Choi, Sung-Yong;Park, Young-Hwan;Jung, Woo-Tai
    • International Journal of Highway Engineering
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    • v.18 no.1
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    • pp.13-21
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    • 2016
  • PURPOSES : In this study, we analyzed the compressive strength characteristics of lean base concrete in relation to changes in the outdoor temperature after analyzing the cold and hot weather temperature standards and calculated the minimum and maximum temperatures when pouring concrete. We examined the rate of strength development of lean base concrete in relation to the temperature change and derived an appropriate analysis formula for FRC base structures by assigning the accumulated strength data and existing maturity formula. METHODS : We measured the strength changes at three curing temperatures (5, 20, and $35^{\circ}C$) by curing the concrete in a temperature range that covered the lowest temperature of the cold period, $5^{\circ}C$, to the highest temperature of the hot period, $35^{\circ}C$. We assigned the general lean concrete and FRC as test variables. A strength test was planned to measure the strength after 3, 5, 7, 14, and 28 days. RESULTS : According to the results of compressive strength tests of plain concrete and FRC in relation to curing temperature, the plain concrete had a compressive strength greater than 5 MPa at all curing temperatures on day 5 and satisfied the lean concrete standard. In the case of FRC, because the initial strength was substantially reduced as a result of a 30% substitution of fly ash, it did not satisfy the strength standard of 5 MPa when it was cured at $5^{\circ}C$ on day 7. In addition, because the fly ash in the FRC caused a Pozzolanic reaction with the progress into late age, the amount of strength development increased. In the case of a curing temperature of $20^{\circ}C$, the FRC strength was about 66% on day 3 compared with the plain concrete, but it is increased to about 77% on day 28. In the case of a curing temperature of $35^{\circ}C$, the FRC strength development rate was about 63% on day 3 compared with the plain concrete, but it increased to about 88% on day 28. CONCLUSIONS : We derived a strength analysis formula using the maturity temperatures with all the strength data and presented the point in time when it reached the base concrete standard, which was 5 MPa for each air temperature. We believe that our findings could be utilized as a reference in the construction of base concrete for a site during a cold or hot weather period.

Hydration-Setting Property of β-Hemihydrate Gypsum by Adding of Accelerator and Ground Gypsum (경화촉진제 및 마쇄 이수석고 첨가에 의한 β-반수석고의 수화응결 특성)

  • Choi, Jeong-Bong;Kim, Jong-Pal
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.822-829
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    • 1997
  • When $Al_2(SO_4)_3$ as an accelerator was added to $\beta$-hemihydrate gypsum, the setting time, mobility and compressive strength properties of $\beta$-hemihydrate gypsum were examined with the adding of two types grounded gypsum crushed by ball mill. By 15wt% adding of 7% $Al_2(SO_4)_3$ dilute solution, the setting time of $\beta$-hemihydrate gypsum was sharply accelerated than that of non-added $\beta$-hemihydrate gypsum. When ground phospho gypsum(PG) and chemical gypsum(CG) were added to $\beta$-hemihydrate gypsum, the initial and final setting time of $\beta$-hemihydrate gypsum were accelerated markedly with the increasing of grinding time and added amount of ground phospho gypsum. Especially, this trend largely presented when ground phospho gypsum was added to $\beta$-hemihydrate gypsum. The compressive strength of $\beta$-hemihydrate gypsum added by ground phospho and chemical gypsum was largely increased at initial curing time such as 1, 3 days. Particularly, the compressive strength of $\beta$-hemihydrate gypsum added by ground phospho gypsum was increased by 15~20% than that of ground chemical gypsum.

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A STUDY OF THE EFFECT OF LOW INTENSITY INITIAL LIGHT CURING ON THE BOND STRENGTH OF RESIN RESTORATION (초기 저광도 광중합이 레진 수복물의 결합강도에 미치는 영향에 관한 연구)

  • Han, Mi-Ran;Kwon, Soon-Won;Kim, Jong-Soo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.1
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    • pp.45-53
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    • 2001
  • Recently some studies have shown that low light intensity followed by final cure at high light intensity may result in a smaller marginal gap and may be no negative effect on material properties. The purpose of this study was to evaluate the influence of the initial cure with low intensity on the shear bond strength of dentin and the microhardness of composite resin. Twenty intact bovine teeth were prepared for shear bond strength test and each tooth sectioned to three specimens. The specimens were randomly divided into three groups according to the light intensity and curing time as follows; Group I. $450mmW/cm^2$ 40sec Group II. $300mmW/cm^2$ 20sec and $600mmW/cm^2$ 20sec Gropu III. $250mmW/cm^2$ 20sec and $450mmW/cm^2$ 20sec. Samples of each group were restored with light-cured composite resin after dentin bonding and then the shear bond strength of each specimen were measured using universal testing machine. Ten resin specimens per group were prepared. After 24 hours, the Vickers microhardness value was measured at the top and bottom surfaces. The result are as follows; 1. Mean value of low initial intensity groups(II, III) were higher than the control group(I) in shear bond strength, but no significant difference could be found. 2. No significant difference could be found between three groups in microhardness.

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Effects of Tape Thickness and Inorganic Fillers on the Adhesion Properties of Double-sided Acrylic Adhesive Tape by Ultraviolet Curing (자외선 경화형 아크릴 양면 점착테이프의 두께 및 무기물 충전제 종류에 따른 접착특성)

  • Kim, Dong-Bok
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.397-405
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    • 2014
  • To manufacture of high-performance semi-structural double-sided adhesive tape, 2-ethylhexyl acrylate (2-EHA) and acrylic acid (AAC) were used, and the syrup was prepared by UV irradiation in this study. The effects of the thickness, various inorganic filler contents, and filler types on the semi-structural properties of acrylic double-sided adhesive tape were investigated. The peel strength increased with increasing thickness and wetting time. In case of the thin thickness (under $250{\mu}m$) with decreasing true density of inorganic filler, the peel strength increased with increasing wetting time. The initial peel strength showed a higher value at a big size of inorganic filler, and the filler's size in adhesive tapes was confirmed by SEM images. The peel strength and dynamic shear strength increased as a proportional relationship with various inorganic fillers and contents, and these inorganic fillers in $0.1{\mu}m$ thickness indicated more effect on the dynamic shear strength of double-sided adhesive tape. From these results the thin acrylic double-sided adhesive tape determined to be use for applications as a high-performance semi-structural.

Early Strength Properties of EVA Polymer Powder-Modified Mortars with Quick Setting Agent (급결제를 이용한 EVA 분말수지 혼입 폴리머 시멘트 모르타르의 초기강도 특성)

  • Jo, Young-Chul;Choi, Nak-Woon;Lee, Chol-Woong;Yang, Suk-Woo;So, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.309-312
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    • 2005
  • Admixture compounds for shortening setting time and accelerating early strength development of EVA polymer powder-modified mortars were made by mixing various quick setting agents. As a result, the quick setting agents contribute to strength development of the mortars in the early curing age of 168h or less. In the viewpoint of early strength development of EVA polymer powder-modified mortars, an quick setting agent content of 20$\%$ is recommended. Early strength of EVA polymer powder-modified mortars expresses the excellent strength with 5$\%$, 10$\%$ of rates of polymer mixing. The rate of polymer mixing was able to be adjusted and flexural strength which is a predeterminded initial strength was also able to satisfy 3MPa(s).

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