• Title/Summary/Keyword: influence surfaces

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Surface-enhanced Raman Spectroscopy of Ethephone Adsorbed on Silver Surface

  • Lee, Chul-Jae;Kim, Hee-Jin;Karim, Mohammad Rezaul;Lee, Mu-Sang
    • Bulletin of the Korean Chemical Society
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    • v.27 no.4
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    • pp.545-548
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    • 2006
  • We investigated the Surface-enhanced Raman Spectroscopy (SERS) spectrum of ethephone (2-chloroethylphosphonic acid). We observed significant signals in the ordinary Raman spectrum for solid-state ethephone as well as when it was adsorbed on a colloidal silver surface, strong vibrational signals were obtained at a very low concentration. The SERS spectra were obtained by silver colloids that were prepared by the $\gamma$-irradiation method. The influence of pH and the influence of anion $(Cl^-,\;Br^-,\;I^-)$ on the adsorption orientation were investigated. Two different adsorption mechanisms were deduced, depending on the experimental conditions. The chlorine atom or the chlorine and two oxygen atoms were adsorbed on the colloidal silver surface. Among halide ions, $Br^-$ and $I^-$ were more strongly adsorbed on the colloidal silver surfaces. As a result, the adsorption of ethephone was less effective due to their steric hinderance.

Influence of Unsteady Wake on Flow Characteristics and Heat Transfer from Linear Turbine Cascade (비정상후류가 선형터빈익렬의 유동 특성 및 익혀의 열전달에 미치는 영향에 관한 연구)

  • Yoon, Soon-Hyun;Sim, Jae-Kyung;Lee, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1998.11b
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    • pp.713-716
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    • 1998
  • To examine the influence of unsteady wake on the flow and heat transfer characteristics, an experiment has been conducted in a four-vane linear cascade. Flow and heat transfer measurements are made for the inlet Reynolds number of 66000(based on chord length and free-stream velocity). Turbulent intensity and stress were measured using hot wire anemometer, and to measure the convective heat transfer coefficients on the blade surfaces liquid crystal/gold film Intrex technique was used. The disturbance by the unsteady wake is characterized by the unresolved unsteadiness. The unsteady wake enhances the turbulent motion of flow in the cascade passage. It also promotes the boundary layer development and transition. The results show that heat transfer coefficients on the suction surface increase with increasing unresolved unsteadiness.

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Influence of Unsteady Wake on Flow Characteristics and Heat Transfer from Linear Turbine Cascade (비정상후류가 선형터빈익렬의 유동 특성 및 익형의 열전달에 미치는영향에 관한 연구)

  • Yoon, Soon-Hyun;Sim, Jae-Kyung;Lee, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1998.11a
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    • pp.393-396
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    • 1998
  • To examine the influence of unsteady wake on the flow and heat transfer characteristics, an experiment has been conducted in a four-vane linear cascade. Flow and heat transfer measurements are made for the inlet Reynolds number of 66000(based on chord length and free-stream velocity). Turbulent intensity and stress were measured using hot wire anemometer, and to measure the convective heat transfer coefficients on the blade surfaces liquid crystal/gold film Intrex technique was used. The disturbance by the unsteady wake is characterized by the unresolved unsteadiness. The unsteady wake enhances the turbulent motion of flow in the cascade passage. It also promotes the boundary layer development and transition. The results show that heat transfer coefficients on the suction surface increase with increasing unresolved unsteadiness.

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Development of multi-cell flows in the three-layered configuration of oxide layer and their influence on the reactor vessel heating

  • Bae, Ji-Won;Chung, Bum-Jin
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.996-1007
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    • 2019
  • We investigated the influence of the aspect ratio (H/R) of the oxide layer on the reactor vessel heating in three-layer configuration. Based on the analogy between heat and mass transfers, we performed mass transfer experiments to achieve high Rayleigh numbers ranging from $6.70{\times}10^{10}$ to $7.84{\times}10^{12}$. Two-dimensional (2-D) semi-circular apparatuses having the internal heat source were used whose surfaces of top, bottom and side simulate the interfaces of the oxide layer with the light metal layer, the heavy metal layer, and the reactor vessel, respectively. Multi-cell flow pattern was identified when the H/R was reduced to 0.47 or less, which promoted the downward heat transfer from the oxide layer and possibly mitigated the focusing effect at the upper metallic layer. The top boundary condition greatly affected the natural convection of the oxide layer due to the presence of secondary flows underneath the cold light metal layer.

Study and analysis of porosity distribution effects on the buckling behavior of functionally graded plates subjected to diverse thermal loading

  • Abdelhak Zohra;Benferhat Rabia;Hassaine Daouadji Tahar
    • Coupled systems mechanics
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    • v.13 no.2
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    • pp.115-132
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    • 2024
  • This paper introduces an improved shear deformation theory for analyzing the buckling behavior of functionally graded plates subjected to varying temperatures. The transverse shear strain functions employed satisfy the stress-free condition on the plate surfaces without requiring shear correction factors. The material properties and thermal expansion coefficient of the porous functionally graded plate are assumed temperature-dependent and exhibit continuous variation throughout the thickness, following a modified power-law distribution based on the volume fractions of the constituents. Moreover, the study considers the influence of porosity distribution on the buckling of the functionally graded plates. Thermal loads are assumed to have uniform, linear, and nonlinear distributions through the thickness. The obtained results, considering the effect of porosity distribution, are compared with alternative solutions available in the existing literature. Additionally, this study provides comprehensive discussions on the influence of various parameters, emphasizing the importance of accounting for the porosity distribution in the buckling analysis of functionally graded plates.

INFLUENCE OF APPICATION TIME OF SELF-ETCHING PRIMERS ON DENTINAL MICROTENSILE BOND STRENGTH (자가 산부식 프라이머의 적용시간이 상아질의 미세인장 결합강도에 미치는 영향)

  • Cho, Young-Gon;Lee, Young-Gon;Kim, Jong-Uk;Park, Byung-Cheul;Kim, Jong-Jin;Choi, Hee-Young;Jin, Cheul-Hee;Yoo, Sang-Hoon
    • Restorative Dentistry and Endodontics
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    • v.29 no.5
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    • pp.430-438
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    • 2004
  • This study evaluated the influence of application time of self-etching primers on microtensile bond strength (${\mu}$TBS) to dentin using three self-etching primer adhesive systems. Dentin surfaces were exposed from forty-eight human molars. They were conditioned with three self-etching primers (Clearfil SE Bond [SE], Unifil Bond [UF], Tyrian SPE + One Step Plus [TY]) and different primining times (10s, 20s, 30s and 40s). Composite resins were bonded to dentin surfaces and specimens were made. ${\mu}TBS$ was tested and statistically compared using by one-way ANOVA and Tukey's Test. The results of this study presented that priming time for 10s in SE and UF groups and for 30s and 40s in TY group was highly decreased ${\mu}TBS$ to dentin.

Finite Element Modeling of Contact Joints by Flexibility Influence Coefficient (유연도 영향계수법을 이용한 접촉 결합부의 모델링)

  • 오제택;조성욱;이규봉
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.814-819
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    • 2003
  • Machine tool design concepts have evolved towards high efficiency, accurate precision. high structural integrity, and multi-functional systems. Like many other structures, machine tools are also composed of many parts. When these parts are assembled, many kinds of joints are used. In the finite element analysis of these assembled structures, most joints are commonly considered as rigid joints. But, to get the more accurate solution, we need to model these joints in a appropriate manner. In this study, rational dynamic modeling and analysis method for complex structures are studied with special attention to slide way joints. For modeling of slide way joints, a general modeling technique is used by influence coefficients method which is applied to the conversion of detailed finite element model to the equivalent reduced joint model. The theoretical part of this method is illustrated and the method is applied to the structure with slide way joint. In this method. the non-linearity of the contact surfaces is considered within a proper range and the boundary effect of the joint model can be eliminated. The proposed method was applied to finite element modal analysis of a clamp jointed cantilever beam and slide way joints of the vertical type lathe. The method can also be used to other kinds of joint modeling. The results of these analysis were compared with those of Yoshimura models and rigid joint models. which demonstrated the practical applicability of the proposed method.

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The Static Performance Analysis of Foil Journal Bearings Considering Coulomb friction (마찰을 고려한 포일 저널베어링의 정특성 해석)

  • Kim, Kyung-Woong;Lee, Dong-Hyun;Kim, Young-Cheol
    • Tribology and Lubricants
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    • v.24 no.6
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    • pp.378-385
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    • 2008
  • In foil bearings, the friction between bumps and their mating surfaces is the major factor which exerts great influence on the bearing performance. From this point of view, many efforts have been made to improve the understanding of the influence of the friction on the foil bearing performance by developing a number of analytical models. However, most of them did not consider the hysteretic behavior of the foil structure resulting from the friction. The present work developed the static structural model in which hysteretic behavior of the friction was considered. The foil structure was modeled using finite element method and the algorithm which determines the conditions of the contact nodes and the directions of the friction forces was used to take into account the friction. The developed model was integrated into the foil bearing prediction code to investigate the effects of the friction on the static performance of the bearing. The results of analysis show that multiple static equilibrium positions are presented for the one static load under the influence of the friction, inferring its great effects on the dynamic performance. However, the effect of friction on the minimum film thickness which determines load capacity of the bearing is negligible.

The Influence of Pulse Frequency and Duty Factor on Surface Characteristics during Low Temperature Plasma Nitrocarburizing Treatment of Duplex Stainless Steel (Duplex Stainless Steel의 저온 플라즈마 침질탄화시 Pulse Frequency 및 Duty Factor에 따른 표면 특성평가)

  • Cheon, Chang-Seok;Lee, Insup
    • Journal of the Korean institute of surface engineering
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    • v.47 no.5
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    • pp.221-226
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    • 2014
  • A low temperature plasma nitrocarburizng was implemented on the duplex stainless steel to achieve the enhancement of surface hardness without degradation of its corrosion resistance. Attempts were made to investigate the influence of Pulse frequency and Duty factor of pulsed power in a high Pulse frequency regime on the surface characteristics of the hardened layer. The hardened layer (S-phase) was formed on all of the treated surfaces. Surface hardness reached up to 1300 $HV_{0.1}$ which is about 4.6 times higher than that of the untreated material (280 $HV_{0.1}$). The thickness of the hardened layer tends to increase lightly with the higher Pulse frequency and the higher Duty factor. The corrosion resistance of nitrocarburized duplex stainless steel was almost similar to that of the untreated material. Both the Pulse frequency and the Duty factor do not have a significant influence on the corrosion property of plasma treated duplex stainless steel.

Heat Transfer Characteristics of Radiation-Mixed Convection in a Three-Dimensional PCB Channel (3차원 PCB 채널내에서의 복사-혼합대류 열전달 특성)

  • Lee, J.H.;Park, K.W.;Pak, H.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.561-575
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    • 1996
  • The interaction of turbulent mixed convection and surface radiation in a three-dimensional channel with the heated blocks is analyzed numerically. Two blocks are maintained at high temperature and the other bottom and horizontal walls are insulated. S-4 method is employed to calculate the effect of the radiative heat transfer. The low Reynolds number k-$\varepsilon$ model proposed by Launder and Sharma is used to estimate the turbulent influence on the heat transfer enhancement. From above modeling, the effects of various channel specifications on the flow and heat transfer characteristics are investigated. The variables used for the present study are Reynolds number, block spacing, the channel height spacing for block and the emissivity. Average Nusselt numbers along the block surfaces are correlated and presented in terms of Reynolds number, emissivity and dimensionless geometric parameters. For the range of conditions in this study, average Nusselt numbers along the block surfaces are strongly influenced by the Reynolds numbers and channel height spacing for block but weakly influenced by the block spacing and the emissivity of the adiabatic walls.

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