• Title/Summary/Keyword: inert materials

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A study on the effects of fine sludge powder addition on portland cement-limestone sludge system (포틀랜드시멘트-석회석슬러지계에서의 슬러지 미분말첨가반응 효과에 대한 연구)

  • Ahn, Ji-Whan;Kim, Hwan
    • Resources Recycling
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    • v.3 no.3
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    • pp.27-31
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    • 1994
  • We tested the limestone sludge produced in Pohang Iron & Steel Co., Ltd. as a filler powder for the effective use of portland cement. Hydration process was investigated by measuring the hydration rate, the amounts of non-evaporable water and compressive strength of cement-limestone sludge paste prepared by mixing limes-tone sludge with cement. The results obtained in this study can be summarized as follows: 1. There is no significant difference between the cases of adding up to 10% limestone sludge and those of unmixed cement system. However the reaction rate increases in the 5% limestone sludge system(due to the effects of fine). 2. The compressive strength increases proportionally with increasing the measured amount of non-evaporable water, Adding 5% limestone sludge also increases the strength a little higher, and the compressive strength and calcium silicate hydrates. In the case of the mixed limestone sludge, $2\theta$=$11.7^{\circ}$ peak appears in the samples of 28 days hydration. This peak indicted the presence of calcium carboaluminate hydrate. Although limestone sludge is generally regarded as a inert materials, some kinds of cement can produce a calcium carboaluminate by reacting with aluminate in cement pastes.

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The Study for Cell Morphology with Gas Cocktail in Microcellular Foaming Process (초미세 발포 공법 시 가스 혼합에 따른 셀 형상 연구)

  • Cha Sung Woon;Yoon Jae Dong;Lee Yoon Sung;Kim Hak Bin
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.6 s.171
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    • pp.168-174
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    • 2005
  • Nowadays, the companies use polymer materials for many purposes fur they have many advantages. The costs of these materials take up too high a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2,\;N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. In previous research, many facts of microcellular foaming process are founded its characteristics. But previous researcher found the characteristics of microcellular foaming process with pure gas, for example $CO_2,\;N_2$ and so on, they did not found the characteristics of microcellular foaming process with one more gases. If one more gases inlet the resin, the characteristics of microcellular foaming process is changed very amazingly. In this paper, discuss on the characteristics of microcellular foaming process wi th gas cocktail about cell morphology.

Comparison for Torrefaction Properties and Combustion Behaviors of Several Biomass Materials (바이오매스 물질에 따른 반탄화 특성 및 연소 거동)

  • Ryu, Geun-Yong;Kim, Sun-Joong
    • Resources Recycling
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    • v.30 no.4
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    • pp.46-53
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    • 2021
  • Biomass can be considered as chemical energy obtained from nature, and includes all living organisms such as plants, animals, and microorganisms. Biomass is eco-friendly, is easily obtainable from the environment, and can be recycled without special treatment processes. Biomass can also be converted into bioenergy fuel through pyrolysis and fermentation. Therefore, it has been considered as a renewable energy source, which prevents the depletion of natural resources such as fossil fuels. In this study, torrefaction to increase the carbon content in various types of biomass sources (sawdust, rice straw, rice bristles, coffee ground, and waste wood) was conducted under an inert atmosphere and at a temperature of 523~573K. The possibility of using torrefied biomass as an alternative to solid fuel for industrial purposes was analyzed by examining the carbon concentration and combustion behaviors.

Reactivity of aluminosilicate materials and synthesis of geopolymer mortar under ambient and hot curing condition

  • Zafar, Idrees;Tahir, Muhammad Akram;Hameed, Rizwan;Rashid, Khuram;Ju, Minkwan
    • Advances in concrete construction
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    • v.13 no.1
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    • pp.71-81
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    • 2022
  • Aluminosilicate materials as precursors are heterogenous in nature, consisting of inert and partially reactive portion, and have varying proportions depending upon source materials. It is essential to assess the reactivity of precursor prior to synthesize geopolymers. Moreover, reactivity may act as decisive factor for setting molar concentration of NaOH, curing temperature and setting proportion of different precursors. In this experimental work, the reactivities of two precursors, low calcium (fly ash (FA)) and high calcium (ground granulated blast furnace slag (GGBS)), were assessed through the dissolution of aluminosilicate at (i) three molar concentrations (8, 12, and 16 M) of NaOH solution, (ii) 6 to 24 h dissolution time, and (iii) 20-100℃. Based on paratermeters influencing the reactivity, different proportions of ternary binders (two precursors and ordinary cement) were activated by the combined NaOH and Na2SiO3 solutions with two alkaline activators to precursor ratios, to synthesize the geopolymer. Reactivity results revealed that GGBS was 20-30% more reactive than FA at 20℃, at all three molar concentrations, but its reactivity decreased by 32-46% with increasing temperature due to the high calcium content. Setting time of geopolymer paste was reduced by adding GGBS due to its fast reactivity. Both GGBS and cement promoted the formation of all types of gels (i.e., C-S-H, C-A-S-H, and N-A-S-H). As a result, it was found that a specified mixing proportion could be used to improve the compressive strength over 30 MPa at both the ambient and hot curing conditions.

Fabrication and Electrochemical Characterization of N/S co-doped Carbon Felts for Electric Double-Layer Capacitors (전기이중층 커패시터용 질소/황이 동시에 도핑된 탄소 펠트의 제조 및 전기화학적 성능 평가)

  • Lee, Byoung-Min;Yun, Je Moon;Choi, Jae-Hak
    • Korean Journal of Materials Research
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    • v.32 no.5
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    • pp.270-279
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    • 2022
  • In this study, N/S co-doped carbon felt (N/S-CF) was prepared and characterized as an electrode material for electric double-layer capacitors (EDLCs). A commercial carbon felt (CF) was immersed in an aqueous solution of thiourea and then thermally treated at 800 ℃ under an inert atmosphere. The prepared N/S-CF showed a large specific surface area with hierarchical pore structures. The electrochemical performance of the N/S-CF-based electrode was evaluated using both 3-electrode and 2-electrode systems. In the 3-electrode system, the N/S-CF-based electrode showed a good specific capacitance of 177 F/g at 1 A/g and a good rate capability of 41% at 20 A/g. In the 2-electrode system (symmetric capacitor), the freestanding N/S-CF-based electrode showed a specific capacitance of 275 mF/cm2 at 2 mA/cm2, a rate capability of 62.5 % at 100 mA/cm2, a specific power density of ~ 25,000 mW/cm2 at an energy density of 23.9 mWh/cm2, and a cycling stability of ~ 100 % at 100 mA/cm2 after 20,000 cycles. These results indicate the N/S co-doped carbon felts can be a promising candidate as a new electrode material in a symmetric capacitor.

Improved adsorption performance of heavy metals by surface modification of polypropylene/polyethylene media through oxygen plasma and acrylic acid

  • Hong, Jeongmin;Lee, Seungwoo;Ko, Dongah;Gwon, Eunmi;Hwang, Yuhoon
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.231-235
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    • 2020
  • Industrialization and modern developments have led to an influx of toxic heavy metals into the aquatic environment, and the accumulation of heavy metals has serious adverse effects on humans. Among the various heavy metal treatment methods, adsorption is very useful and frequently used. Plastic materials, such as polypropylene and polyethylene, have been widely used as filter media due to their mechanical and chemical stability. However, the surface of plastic material is inert and therefore the adsorption capability of heavy metals is very limited. In this study, granular media and fiber media composed of polypropylene and polyethylene are used, and the surface modification was conducted in order to increase adsorption capability toward heavy metals. Oxygen plasma generated hydroxyl groups on the surface of the media to activate the surface, and then acrylic acid was synthesized on the surface. The grafted carboxyl group was confirmed by FT-IR and SEM. Heavy metal adsorption capability of pristine and surface modified adsorbents was also evaluated. Overall, heavy metal adsorption capability was increased by surface modification due to electrostatic interaction between the carboxyl groups and heavy metal ions. Fibrous PP/PE showed lower improvement compared to granular PP media because pore blockage occurred by the surface modification step, thereby inhibiting mass transfer.

The Development of UV-IR Combination Flame Detector (UV-IR 복합형 화재감지장치 개발)

  • 이복영;권오승;정창기;박상태
    • Journal of the Korean Society of Safety
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    • v.16 no.1
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    • pp.1-8
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    • 2001
  • All objects emit thermal radiation and this radiation is the basis of the techniques used to detect flames. The usual phenomena occurring in the initial stage of the fire are generally invisible products of a combustion and visible smoke. Liquid or gaseous materials do not undergo a smoldering stage so that fires develop very rapidly. Also, the heat generated by the initial flames is usually not sufficient to activate a heat detector. In this case the most effective criterion for automatic fire detection is the flame. According to the fire regulation of korea, the compulsory standard provided that a flame detector shall be installed in a place that the attachment height of detector is higher than 20 m, chemical plants, hangar, refinery, etc.. The results of the research and development are discriminated between a flame and other radiant emitters, developed a UV detector tube contains an inert gas which absorbs UV radiation, developed PZT pyroelectric element is based on the use of photovoltanic cell, developed IR band-pass filter that only allow a 4.3 $\mu\textrm{m}$ radiation wavelength to reach the sensors and developed UV-IR combination flame detector combined into a single detection device.

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Characterization of Fracture Toughness and Wear Behavior for Plasma Ceramic Coated Materials (플라즈마 코팅재료의 파괴인성과 마모 거동)

  • Ha, Sun-Ho;Lee, Dong-Woo;Rehman, Atta Ur;Wasy, Abdul;Song, Jung-Il
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.4
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    • pp.123-130
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    • 2013
  • Zirconia is well known in industrial applications for its mechanical characteristics. DLC (diamond-like carbon) have high elastic modulus, high electric resistivity, high dielectric constant, high wear resistance, low friction coefficient, bio compatibility, chemically inert and thermally stable. Because of all these physical and chemical properties these types of coatings have become key procedure for thin coating. Friction coefficient of DLC films is already evaluated and the current work is a further advancement by calculating the fracture toughness and wear resistance of these coatings. In the present study DLC thin film coatings are developed on $ZrO_2$ alloy surface using Plasma Enhanced Chemical Vapor Deposition (PECVD) method. Vicker hardness test is employed and it was concluded that, DLC coatings increase the Vickers hardness of ceramics.

Mold technology with 3D printing for manufacturing of porous implant (다공성 임플란트 제조를 위한 3D 프린팅 응용 금형기술)

  • Lee, Sung-Hee;Kim, Mi-Ae;Yun, Eon-Gyeong;Lee, Won-Sik
    • Design & Manufacturing
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    • v.11 no.1
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    • pp.30-33
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    • 2017
  • In this study, the mold technology for manufacturing of porous implant was investigated. Firstly, we considered the concept of insert molding technology with 3D printing of porous inert part. The part on implant was designed in the end region of the implant. And then main implant bodies were manufactured using conventional machining method. The other porous parts were designed and optimized with molding simulation. As the feature size of porous implant was so small that perfect feature of it using 3D printing technology could not be obtained. So, we proposed another scheme for manufacturing of the porous implant in the replace of the former approach. Polymer mold cores with 3D printing technology were considered. The effects of addictive manufacturing process parameters on the properties of mechanical and dimensional accuracy were investigated. Direct 3D printed polymer mold cores were designed and manufactured under the simulation of thermal and molding analysis. It was shown that 3D printed mold core with polymer could be adapted to the injection molding for porous implant.

Study on the Performance of an SI Gas Engine by Fuel Composition and Spark Plug Variation (연료 조성 및 스파크 플러그 위치 변경으로 인한 가스 엔진의 성능에 관한 연구)

  • Kim, Yongrae
    • Journal of the Korean Institute of Gas
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    • v.18 no.6
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    • pp.21-26
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    • 2014
  • Renewable gas fuels such as biogas and landfill gas have carbon-neutral nature which can reduce carbon dioxide. However, it is necessary to make stable combustion when this fuel is used in power generating SI(spark ignition) gas engines due to its low heating value and non-uniformity. In this study, it was shown that addition of hydrogen can increase combustion stability of gas engine which is running with high inert gas composition. Thermal efficiency and emission characteristics of this engine was also investigated. In addition, a new spark plug with a long electrode was tested and compared with a base spark plug as a way to improve engine efficiency and reduce exhaust emissions.