• 제목/요약/키워드: induced polarization

검색결과 302건 처리시간 0.025초

Corrosion Inhibition of Steel Rebar in Concrete with the Coated MCI 2022

  • Bezad Bavarian;Lisa Reiner;Kim, Chong Y.
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.63-67
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    • 2002
  • The induced chemical and salt solution in water or admixture are originated to the corrosion process of the steeo rebar. These liquids penetrate into concrete as the accompanied by the chemical reaction and cause to attack the steel rebar in concrete. Concrete surfaces which it exposed to deicing, water and sea water is allowed to enter the chlorides in the structures. To prevent from the source of corrosion and deterioration Is subjected to put an end to corrode or reduce to contaminate on the steel rebar. As this reason the MCI 2022 products are applied to the surface of concrete and steel rebar. The concrete samples were made of to the kind of four, i.e. RF, MR, MS, and MM. Corrosion inhibitor is applied to coat on the surface of concrete after it had been cured for 28days. Specimen were immersed in a 3.5% sodium chloride solution. Concrete specimen were tested to determine the changes of the resistance polarization, Rp, over a 22 weeks period. MCI 2022 is significantly shown the corrosion inhibition of steel rebar in 3.5% NaCl solution. In the each different concrete sample, MS and MM is seemed to be better than others. The results are proofed that MCI 2022 is promised to maintain the inhibition of corrosion with high resistance polarization of the steel rebar in concrete.

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Transmission Characteristics of Long-Period Fiber Gratings Using Periodically Corroded Single-Mode Fibers

  • Lee, Jonghwan;Bang, Ngac An;Han, Young-Geun
    • Journal of the Optical Society of Korea
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    • 제19권4호
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    • pp.376-381
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    • 2015
  • Transmission characteristics of long-period fiber gratings (LPFGs) fabricated by periodically etching a conventional single-mode fiber (SMF) are investigated. After coating the SMF with photoresist, the cladding of the SMF is symmetrically and periodically removed by using a wet etching technique resulting in the formation of the LPFG. Tensile strain reinforces the coupling strength between the core and the cladding mode based on the photoelastic effect. The extinction ratio of the SMF-based LPFG at a wavelength of 1550.8 nm is measured to be -15.1 dB when the applied strain is $600{\mu}{\varepsilon}$. The ascent of ambient index shifts the resonant wavelength to shorter wavelength because of the increase of the effective refractive index of the cladding mode. The extinction ratio is diminished by increase in the ambient index because of the induction of the optical attenuation of the cladding mode. The transmission characteristics of the proposed LPFG with variations in torsion are also measured. The photoelastic effect based on torsion changes the extinction ratio and the resonant wavelength of the proposed SMF-based LPFG. The polarization-dependent loss of the LPFG is also increased by torsion because of the torsion-induced birefringence. The polarization-dependent loss of the LPFG at torsion of 8.5 rad/m is measured to be 3.9 dB.

한반도에서 관측된 MT(Magnetotelluric)장의 분극 특성 (Polarization characteristics of magnetotelluric fields in the Korean peninsula)

  • 이춘기;권병두;이희순
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2006년도 공동학술대회 논문집
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    • pp.35-38
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    • 2006
  • 한반도 심부 지전기 구조 연구를 목적으로 실시된 MT 탐사자료의 분극 특성을 분석하였다. 대기권에서 발생하는 1Hz 이상의 전자기파들은 대부분 분극 방향이 불규칙 하지만 8Hz 부근의 슈만 공명은 $N20^{\circ}E$ - NS 방향으로 우세한 특성을 가진다. 반면, 0.1Hz 이하의 전자기파는 남북 방향으로 강하게 분극되는 특성을 나타내고 있다. 이는 자기권의 Alfv.n 파동에 의해 발생하는 지자기장 맥동이 남북방향으로 우세하게 나타나기 때문이다. 남북 방향의 강한 분극 현상은 XY 임피던스(X는 북쪽)의 추정을 불량하게하는 원인이다.

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12%Cr강 인성열화도의 전기화학적 평가법에 대한 연구(II) (A Study on Electrochemical Evaluation Method of Toughness Degradation for 12%Cr Steel (II))

  • 김창희;서현욱;윤기봉;박기성;김승태
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.268-273
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    • 2001
  • Fossil power plants operated in high temperature condition are composed of components such as turbine, boiler, and piping system. Among these components, turbine blades made with 12%Cr steel operate at a temperature above $500^{\circ}C$. Due to the long term service, turbine blades experience material degradation manifested by change in mechanical and microstructural properties. The need to make life assessment and to evaluate material degradation of turbine blade is strongly required but in reality, there is a lack of knowledge in defining failure mechanism and fundamental data for this component. Therefore, in making life assessment of turbine blade, evaluation of material degradation must be a priority. For this purpose, evaluation of toughness degradation is very important. The major cause of toughness degradation in 12Cr turbine blade is reported to be critical corrosion pitting induced by segregation of impurity elements(P etc.), coarsening of carbide, and corrosion, but the of materials for in-service application. In this study, the purpose of research is focused on evaluating toughness degradation with respect to operation time for 12%Cr steel turbine blade under high temperature steam environment and quantitatively detecting the degradation properties which is the cause of toughness degradation by means of non-destructive method, electrochemical polarization.

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SrTiO3기판 위에 증착한 BiFeO3박막의 강유전 및 자기적 특성 (Ferroelectric and Magnetic Properties of BiFeO3 Thin Films Deposited on SrTiO3 Substrate)

  • 이은구;김선재;이재갑
    • 한국세라믹학회지
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    • 제45권6호
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    • pp.358-362
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    • 2008
  • $BiFeO_3$ films were hetero-epitaxially grown on $SrTiO_3$ substrate with a various orientation by pulse laser deposition. $BiFeO_3$ films grown on (111) $SrTiO_3$ substrate have a rhombohedral structure, identical to that of single crystals. On the other hand, films grown on (110) or (001) $SrTiO_3$ substrate are monoclinically distorted from the rhombohedral structure due to the epitaxial constraint. The easy axis of spontaneous polarization is close to [111] for the variously oriented films. Dramatically enhanced polarization and magnetization have been found for $BiFeO_3$ thin films grown on $SrTiO_3$ substrate comparing to that of $BiFeO_3$ crystals. The results are explained in terms of an epitaxially-induced transition between cycloidal and homogeneous spin states, via magneto-electric interactions.

ZnO 박막의 증착 두께에 따른 Photon Energy 특성에 관한 연구 (A Study on the Photon Energy Characteristics of ZnO Thin Film According to Coating Thickness)

  • 이정일;서장수;정성교;김병인
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 기술교육전문연구회
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    • pp.75-81
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    • 2003
  • This study evaporates ZnO layer thickness differently with RF sputtering method on Si Wafer(n-100). This study is performed to examine the characteristics of photon energy and dielectric loss according to the thickness of ZnO and increase the reliability and reproduction of ZnO thin film. It is confirmed that the variation of electric Permittivity by frequency is resulted from the formation of particles within thin film, the particle size and the polarization on grain boundary. Peak of electric Permittivity value of thin film has slower and less value in early low wavelength by the coulomb force involved in carrier combination according to the increase of frequency. Reversal of electric Permittivity values is induced by dipole polarization shown in the dielectric of thin film. Complex electric constant $({\varepsilon}_1{\varepsilon}_2)$ has larger peak values as it’s thickness is thinner and then it is larger according to the increase of frequency. Electric Permittivity by photon energy has large value in imaginary number and is reduced exponentially by the increase of carrier density according to that of photon energy.

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편광 자외선이 조사된 액정 디스플레이용 폴리이미드 필름의 열 안정성 (Thermal Stability of Polarized UV Exposed Polyimide Films for Liquid Crystal Display)

  • 김일형;김욱수;하기룡
    • 폴리머
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    • 제26권4호
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    • pp.431-438
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    • 2002
  • 편광 푸리에 변환 적외선 분광법을 이용하여 액정 디스플레이의 배향막으로 널리 사용되는 폴리이미드 필름의 편광 자외선 조사에 따른 액정의 배향성과 열적 안정성을 연구하였다. 편광자외선이 조사된 폴리이미드의 경우, 조사된 편광자외선의 극성 방향에 평행한 폴리이미드 분자들의 우선적인 광분해 반응으로 인하여 편광자외선 조사 후 남아 있는 폴리이미드 분자들은 조사된 편광자외선 극성 방향과 수직 배향을 나타내었다. 하지만 러빙 처리된 폴리이미드 필름은 러빙 방향과 평행하게 폴리이미드 분자들의 재배향이 유도됨을 확인하였다. 또한 편광자외선이 조사된 폴리이미드 배향막이 편광자외선 조사를 통한 폴리이미드 분자들의 단편화 반응 때문에 러빙 처리된 폴리이미드 배향막 보다는 열적 안정성이 저하됨을 확인하였다.

Ferroelectric Liquid Crystals from Bent-Core Molecules with Vinyl End Groups

  • Kwon, Soon-Sik;Kim, Tae-Sung;Lee, Chong-Kwang;Shin, Sung-Tae;Oh, Lee-Tack;Choi, E-Joon;Kim, Sea-Yun;Chien, Liang Chy
    • Bulletin of the Korean Chemical Society
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    • 제24권3호
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    • pp.274-278
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    • 2003
  • New banana-shaped achiral compounds, 1,3-phenylene bis [4-{4-(alkenyloxy) phenyliminomethyl}benzoate]s were synthesized by varying the length of alkenyl group; their ferroelectric properties are described. The smectic mesophases, including a switchable chiral smectic C $(Sm\;C^*)$ phase, were characterized by differential scanning calorimetry, polarizing optical microscopy and triangular wave method. The presence of vinyl groups at the terminals of linear side wings in the banana-shaped achiral molecules containing Schiff's base mesogen induced a decrease in melting temperature and formation of the switchable $(Sm\;C^*)$ phase in the melt. The smectic phases having the octenyloxy group such as $(CH_2)_6CH=CH_2$ showed ferroelctric switching, and their values of spontaneous polarization on reversal of an applied electric field were 120 nC/cm² (X=H) and 225 nC/ cm² (X=F), respectively. We could obtain ferroelectric phases by controlling the number of carbon atom in alkenyloxy chain of a bent-core molecule.

Numerical Study of Polarization-Dependent Emission Properties of Localized-Surface-Plasmon-Coupled Light Emitting Diodes with Ag/SiO2 Na

  • Moon, Seul-Ki;Yang, Jin-Kyu
    • Journal of the Optical Society of Korea
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    • 제18권5호
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    • pp.582-588
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    • 2014
  • We study polarization-dependent spontaneous emission (SE) rate and light extraction efficiency (LEE) in localized-surface-plasmon (LSP)-coupled light emitting diodes (LEDs). The closely packed seven $Ag/SiO_2$ core-shell (CS) nanoparticles (NPs) lie on top of the GaN surface for LSP coupling with a radiated dipole. According to the dipole direction, both the SE rate and the LEE are significantly modified by the LSP effect at the $Ag/SiO_2$ CS NPs when the size of Ag, the thickness of $SiO_2$, and the position of the dipole source are varied. The enhancement of the SE rate is related to an induced dipole effect at the Ag, and the high LEE is caused by light scattering with an LSP mode at $Ag/SiO_2$ CS NPs. We suggest the optimum position of the quantum well (QW) in blue InGaN/GaN LEDs with $Ag/SiO_2$ CS NPs for practical application.

초고속화염용사법으로 제조된 Ni-Cr-W-Mo-B 합금 코팅의 미세조직과 특성에 미치는 열처리 효과 (Effect of Heat Treatment on the Microstructures and Properties of HVOF Sprayed Ni-Cr-W-Mo-B Alloy Coatings)

  • 민경오;이창희
    • Journal of Welding and Joining
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    • 제18권6호
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    • pp.48-54
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    • 2000
  • The corrosion properties of Ni-Cr-W-Mo-B alloy sprayed by the high velocity oxy-fuel spraying (HVOF) was studied as a function of heat treatment by using both potentiodynamic polarization and immersion tests in the H₂SO₄ solution. The mechanical property was also evaluated by a microhardness tester. Microstructural characteristics of te as-sprayed and annealed coatings at 550, 750 and 950℃ have been analyzed by means of OM, XRD, SEM and TEM. The results showed that the corrosion resistance was improved by increasing the annealing temperature. As-sprayed coating had metastable and heterogeneous phases such as amorphous, nanocrystalline and very refined grain and precipitates, which induced a localized corrosion. The localized corrosion occurred preferentially at the unmelted particles which were composed of Ni matrix and Cr, W and Mo riched phase segregated in the boundaries. As annealing temperature was increased, the microstructure had shown some changes - reduction of porosity and s[plat boundary decomposition and crystallization of amorphous/nanocrystalline phases, grain coarsening,, formation and growth of precipitates such as {TEX}$M_{23}C_{6}${/TEX} and {TEX}$M_{7}C_{3}${/TEX}. In addition, the compositional difference between matrix and boundary phases gradually disappeared, which changed the corrosion type from localized corrosion to general corrosion and thus enhanced corrosion resistance.

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