• Title/Summary/Keyword: induced anisotropy

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Photodissociation Dynamics of$H_2O_2$ at 280-290 nm

  • Baek, Seon Jong;Sin, Seung Geun;Park, Chan Ryang;Kim, Hong Rae
    • Bulletin of the Korean Chemical Society
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    • v.16 no.3
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    • pp.256-260
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    • 1995
  • Laser induced fluorescence spectra of OH produced from photodissociation of $H_2O_2$ at 280-290 nm in the gas phase have been observed. By analyzing the Doppler profiles, the anisotropy parameter($\beta$ =-0.7) and the center of mass translational energy of the fragments have been measured. The measured energy distribution is well described by an impulsive model. The excited state leading to dissociation is found to be of 1Au symmetry. The dissociation from this state is prompt and direct with the fragment OH rotating in the plane perpendicular to the O-O bond axis.

Fluorescence Anisotropy Study on the Effect of Phellodendri Cortex's Berberine on Regulation of the Function of DNA (황백(黃柏)의 berberine이 DNA의 기능조절에 미치는 영향에 관한 형광이방성 연구)

  • Lee, Seong Kyung;Han, Hyo Sang;Huh, Sung Ho
    • The Korea Journal of Herbology
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    • v.33 no.5
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    • pp.105-110
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    • 2018
  • Objectives : We tried to observe the fluorescence anisotropy and intensity of ethidium ion in the intercalating binding interaction between DNA and ethidium ions in the presence of berberine, and then tried to explain the effect of berberine on the intercalating interaction of ethidium ion with DNA. Methods : DNA(calf thymus DNA), berberine and ethidium bromide(EtBr) were purchased from Sigma-Aldrich Co. Proper amount of each compound was dissolved in 20 mM sodium phosphate buffer(pH 7.0) containing 100 mM of NaCl to prepare stock solutions. Collections of the fluorescence anisotropy and intensity data were performed on JASCO FP-8300 spectrofluorometer equipped with a polarizer and a Peltier temperature controller. The excitation of ethidium ion was done at 550 nm and the emission data were collected at 600 nm. For Stern-Volmer plot, the fluorescence data were collected at $18^{\circ}C$ and $30^{\circ}C$. Results : According to the results of this research, the weak competitive binding pattern between ethidium ion and berberine appeared in binding with DNA at low ratio of DNA to ethidium ion. But at high ratio of DNA to ethidium ion, this weak competition disappeared. Instead, berberine might bind to DNA by intercalating way. In other words, berberine could de-intercalate ethidium ion from DNA at low concentration of DNA relative to ethidium ion, but could not at high concentration of DNA relative to ethidium ion. In addition, the mechanism of fluorescence quenching of ethidium ion could also proceed differently, depending on the ratio of the amount of DNA to that of ethidium ion. Conclusions : The effect of berberine on the DNA-ethidium ion intercalating interaction could work differently, depending on the relative ratio of the amount of DNA to that of ethidium ion. This study also showed that fluorescence anisotropy analysis is very useful method to obtain detailed information for investigation of the complex binding interactions. In order to fully understand the mechanism of action of the pharmacological effect by berberine, studies on the effect of berberine on the action of proteins such as various enzymes closely related to berberine-induced medicinal effects should be continued.

Grain Boundary Microcracking in ZrTiO4-Al2TiO5 Ceramics Induced by Thermal Expansion Anisotropy

  • Kim, Ik-Jin;Kim, Hyung-Chul;Lee, Kee-Sung;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.109-112
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    • 2003
  • The grain-boundary microcracking materials in the system $Al_2$TiO$_{5}$ -ZrTiO$_4$(ZAT) is influenced by the thermal expansion anisotropy. The range of ZAT compositions investigated had showed very low thermal expansions of 0.3~1.3$\times$10$^{-6}$ K loin compared to 8.29$\times$10$^{6}$ K of pure ZrTiO$_4$and 0.68$\times$10$^{6}$ K of polycrystalline $Al_2$TiO$_{5}$ , respectively, compared with the theoretical thermal expansion coefficient for a single crystal of $Al_2$TiO$_{5}$ , 9.70$\times$10$^{6}$ K. The low thermal expansion and microcraking temperature are apparently due to a combination of thermal contraction and expansion caused by the large thermal expansion anisotropy of the crystal a ies of the $Al_2$TiO$_{5}$ phase.

VOIDS LENSING OF THE CMB AT HIGH RESOLUTION

  • SANGKA, ANUT;SAWANGWIT, UTANE;SANGUANSAK, NUANWAN
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.397-399
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    • 2015
  • Recently, cosmic voids have been recognized as a powerful cosmological probe. A number of studies have focused on the effects of the gravitational lensing by voids on the temperature (and in some cases polarization) anisotropy of the Cosmic Microwave Background (CMB) background at relatively large to medium scales, l ~ 1000. Many of these studies attempt to explain the unusually large cold spot in CMB temperature maps and dynamical evidence of dark energy via detections of late-time integrated Sachs Wolfe (ISW) effect. Here, the effects of lensing by voids on the CMB temperature anisotropy at small scales, up to l = 3000, will be investigated. This work is carried out in the light of the benefits of adding large catalogues of cosmic voids, to be identified by future large galaxy surveys such as EUCLID and LSST, to the analysis of CMB data such as those from Planck mission. Our numerical simulation utilizes two methods, namely, the small-de ectionangle approximation and full ray-tracing analysis. Using the fitted void density profiles and radius (RV ) distribution available in the literature from N-body simulations, we simulated the secondary temperature anisotropy (lensing) of CMB photons induced by voids along a line of sight from redshift 0 to 2. Each line of sight contains approximately 1000 voids of effective radius $RV_{,eff}=35h^{-1}Mpc$ with randomly distributed radial and projected positions. Both methods are used to generate temperature maps. The two methods will be compared for their accuracy and effciency in the implementation of theoretical modeling.

Erratum to: "Grain Boundary Microcracking in ZrTiO4-Al2TiO5 Ceramics Induced by Thermal Expansion Anisotropy"

  • Kim, Ik-Jin;Kim, Hyung-Chul;Lee, Kee-Sung;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.317-321
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    • 2003
  • The grain-boundary microcracking materials in the system A1$_2$Ti $O_{5}$ -ZrTi $O_4$(ZAT) is influenced by the thermal expansion anisotropy. The range of ZAT compositions investigated had showed very low thermal expansions of 0.3~1.3$\times$10$^{-6}$K compared to 8.29$\times$10$^{-6}$K of pure ZrTi $O_4$and 0.68$\times$10$^{-6}$K of polycrystalline A1$_2$Ti $O_{5}$ , respectively, compared with the theoretical thermal expansion coefficient for a single crystal of A1$_2$Ti $O_{5}$ , 9.70$\times$10$^{-6}$K. The low thermal expansion and microcraking temperature are apparently due to a combination of thermal contraction and expansion caused by the large thermal expansion anisotropy of the crystal axes of the A1$_2$Ti $O_{5}$ phase.

Analysis of Analytical Models and Numerical Model for Evaluating Induced Infiltration Rate (유도침투량의 정량화를 위한 해석모형과 수치모형의 분석)

  • Lee, Do-Hun;Lee, Eun-Tae
    • Journal of Korea Water Resources Association
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    • v.32 no.3
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    • pp.301-310
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    • 1999
  • In this paper a numerical model and two analytical models in the hydraulically connected stream-aquifer system were analyzed to compare the induced infiltration rate curves derived from each model. And we also examined the effects of anisotropy of hydraulic conductivity and the direction of the ambient ground water flow on the quantification of the induced infiltration rate. The induced infiltration rate curve determined by models is very simple and useful for estimating the induced infiltration rate since it contains only four physical variables such as the induced infiltration rate, the pumping rate, the distance between the pumping well and the stream, and the ambient ground water flow rate. Under the conditions tested in this paper the induced infiltration rate curves resulted from the Wilson's analytical model and FEWA numerical model were in good agreement, and the anisotropic ratio of hydraulic conductivity was evaluated as a physical factor which influences the behaviour of the induced infiltration rate curve. The methods and results of the paper might Icad to improve the understanding of the induced infiltration phenomenon and can be applied to the planning and disign of pumping well and the optimal determination of the induced infiltration rate and pumping rate for water quality management of the water supply wells.

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Papers : Thermally Induced Vibration Analysis of Flexible Spacecraft Appendages (논문 : 위성체 유연 구조물의 열진동 해석)

  • Yun,Il-Seong;Song,O-Seop
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.1
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    • pp.56-64
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    • 2002
  • Thermally induced vibration response of composite thin-walled beams is investigated in this paper. The flexible spacecraft appendages modeled as thin-walled beam incorporates a number of nonclassical effects of transverse shear, primary and secondary warping, rotary inertia and anisotropy of constitute materials. Thermally induced vibration responds characteristics of a composite thin walled beam exhibiting the circumferantially uniform system(CUS) configuration are exploited in connection with the structural flapwise bending lagwise bending coupling resulting from directioal properties of fiber reinforced composite materials and ply stacking sequence. A coupled thermal structure gradient is investigated.

Combination of engineering geological data and numerical modeling results to classify the tunnel route based on the groundwater seepage

  • Aalianvari, A.
    • Geomechanics and Engineering
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    • v.13 no.4
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    • pp.671-683
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    • 2017
  • Groundwater control is a significant issue in most underground construction. An estimate of the inflow rate is required to size the pumping system, and treatment plant facilities for construction planning and cost assessment. An estimate of the excavation-induced drawdown of the initial groundwater level is required to evaluate potential environmental impacts. Analytical and empirical methods used in current engineering practice do not adequately account for the effect of the jointed-rock-mass anisotropy and heterogeneity. The impact of geostructural anisotropy of fractured rocks on tunnel inflows is addressed and the limitations of analytical solutions assuming isotropic hydraulic conductivity are discussed. In this paper the unexcavated Zagros tunnel route has been classified from groundwater flow point of view based on the combination of observed water inflow and numerical modeling results. Results show that, in this hard rock tunnel, flow usually concentrates in some areas, and much of the tunnel is dry. So the remaining unexcavated Zagros tunnel route has been categorized into three categories including high Risk, moderately risk and low risk. Results show that around 60 m of tunnel (3%) length can conduit the large amount of water into tunnel and categorized into high risk zone and about 45% of tunnel route has moderately risk. The reason is that, in this tunnel, most of the water flows in rock fractures and fractures typically occur in a clustered pattern rather than in a regular or random pattern.

Applications of Diffusion Tensor MRI to Predict Motor Recovery of Stroke Patients in the Chronic Stages

  • Tae, Ki-Sik;Song, Sung-Jae;Kim, Young-Ho
    • Journal of Biomedical Engineering Research
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    • v.29 no.2
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    • pp.114-121
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    • 2008
  • Within 2 to 5 months after stroke, patients recover variable degrees of function, depending on the initial deficit. An impaired hand function is one of the most serious disability in chronic stroke patients. Therefore, to evaluate the extent of motor dysfunction in the hemiplegic hand is important in stroke rehabilitation. In this paper, motor recoveries in 8 chronic stroke patients with Fugl-Meyer (FM) and white matter changes before and after the training program with a designed bilateral symmetrical arm trainer (BSAT) system were examined. The training was performed at 1 hr/day, 5 days/week during 6weeks. In all patients, FM was significantly improved after the 6-week training. Diffusion tensor imaging (DTI) results showed that tractional anisotropy ratio (FAR) and fiber tracking ratio (FTR) in the posterior internal capsule were significantly increased after the training. It seemed that the cortical reorganization was induced by the 6 week training with the BSAT. In all parameters proposed this study, a significant correlation was found between these parameters (FAR and FTR) and motor recoveries. This study demonstrated that DTI technique could be useful in predicting motor recovery in chronic hemiparetic patients.

The Effects of Heat-treatment on Magnetic Properties for Gas-atomized MPP Dust Cores (가스분무법으로 제조한 MPP 분말코어의 자기적 특성에 미치는 열처리 효과)

  • 노태환;김구현;김광윤;정인범;최광보
    • Journal of the Korean Magnetics Society
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    • v.11 no.4
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    • pp.173-178
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    • 2001
  • The effects of heat-treatment with magnetic or non-magnetic field on magnetic properties of gas-atomized MPP dust cores subjected to various cooling processes after annealing were investigated. Upon magnetic-field annealing, ac permeability and core loss decreased with the increase of cooling rate, which were attributed to the generation of inhomogeneous internal stress and anomalous eddy current loss, respectively. It was not observed the formation of ordered phase and the related change in magnetic properties at the cooling stage for MPP dust cores. In MPP alloys, magnetic anisotropy was easily induced through the directional order, and permeability and core loss were changed under the conditions of low cooling rate and magnetic annealing.

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