• Applied Chemistry for Engineering
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• v.8 no.1
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• pp.76-83
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• 1997

Blends of thermotropic liquid crystalline polymer(TLCP) with poly(ethylene terephthalate) (PET) were prepared by the coprecipitation from a common solvent. The blends were processed through a capillary die at $287^{\circ}C$ to produce a monofilament. Morphology and mechanical, thermal properties of blends and composites were examined by differential scanning calorimetry(DSC), tensile test, optical microscopy and scanning electron microscopy. Crystallization kinetics of the blends were investigated by the isothermal DSC method. The Avrami analyses were applied to obtain the information on the crystal growth geometry and factors controlling the rate of crystallization. In the blends, liquid crystalline phase did not reveal any significant macrophase separation and thermal degradation at the processing temperature. From scanning electron micrographs of cryogenic fracture surfaces of extruded fibers, the TLCP domains were found to be more or less finely dispersed with $0.1{\mu}m$ to $0.2{\mu}m$ in size. Interfacial adhesion between the TLCP and matrix polymer was excellent. Tensile strength and modulus of TLCP/PET in-situ fiber composites were enhanced with increasing draw ratio and LCP content.

• Magazine of the Korean Society of Agricultural Engineers
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• v.40 no.5
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• pp.68-79
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• 1998

In the years, the concern about high-strength concrete which is new material has been heightened as a result of active research and development. Recently, as the building structure has been being bigger, higher, longer and more specialized, the demand of material with high-strength concrete for building has been increasing. The demand of high -strength concrete is expected to increase with expansion of usage about the complex concrete structures such as bridge structure as well as nuclear plants, underground structures, hydraulic structures and arctic area sturctures. In this research, silica-fume was used as an admixture in order to get a high-strength concrete. Water/binder ration was limited no more than 18 percent and the amount of unit cement was increased. In this study, a number of trial in concrete mix was carried out to get optimal mix design, and the target slump with $10{\pm}2cm$ was set for in-situ construction. High-strength concrete with cylinder strength of 1,200kgf/$cm^2$ in the 28-days was produced and tested. The static test was carried out to measure the ultimate load, the initial load of flexural and diagonal cracking, crack patterns, fracture modes. The load versus strain and load versus deflection relations were obtained form the static test. The test results were compared with the shear strengths predicted by the equations of ACI code 318-89 and orther researchers. Based on the test results, shear strength equation of reinforced concrete beam using high strength concrete was proposed. Form an evaluation of the results of this experimental investigation, it was concluded that shear strength after diagonal tention cracking diminished with the increase in compressive strength for beams.

• The Journal of Engineering Geology
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• v.12 no.2
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• pp.189-202
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• 2002

In this study we carried out the in situ test in order to explore the grouting effects of fracture zone on mechanical properties and permeability in tunnel. After consolidation grouting the rock mass averaged 2.30 in the modulus of deformation and 2.49 in the modulus of elasticity. The results obtained through this study are as follows. (1) With advance of the injection steps, the total cement take shows uniformity of the rock mass. (2) After consolidation grouting the improvement of permeability can be identified by reduction of Lugeon values. (3) Grouting injection can improve deformability and strength of rock mass. (4) More mechanical improvement appears for more deformable rock mass before grouting injection.

• Korean Journal of Metals and Materials
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• v.50 no.10
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• pp.775-783
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• 2012

The effect of thermal annealing on the in-situ growth characteristics of intermetallics (IMCs) and the mechanical strength of Cu pillar/Sn-3.5Ag microbumps are systematically investigated. The $Cu_6Sn_5$ phase formed at the Cu/solder interface right after bonding and grew with increased annealing time, while the $Cu_3Sn$ phase formed at the $Cu/Cu_6Sn_5$ interface and grew with increased annealing time. IMC growth followed a linear relationship with the square root of the annealing time due to a diffusion-controlled mechanism. The shear strength measured by the die shear test monotonically increased with annealing time. It then changed the slope with further annealing, which correlated with the change in fracture modes from ductile to brittle at a critical transition time. This is ascribed not only to the increasing thickness of brittle IMCs but also to the decreasing thickness of the solder, as there exists a critical annealing time for a fracture mode transition in our thin solder-capped Cu pillar microbump structures.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.03a
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• pp.237-244
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• 2002

Televiewer is a logging tool capable of scanning the borehole wall. The tool uses a rotating acoustic beam generator that acts as both a transmitter and receiver. The beams are sent toward the wall. The amplitude of a returning signal from the wall has nearly a linear relationship with the reflection coefficient R of the borehole wall, when the wall is smooth. As R depends only on rock impedance for fixed water impedance, the amplitude is directly associated with mass density and seismic velocity of rock. Meanwhile, the amplitude can be further reduced by wall roughness that may be caused by drilling procedures, differences in rock hardness, because the rough surface can easily scatter the acoustic energy and sometimes the hole becomes elongated in all directions according to the degree of weathering. In this sense, the amplitude is related to the hardness of rocks. For convenience of analysis, the measured amplitude image(2-D data(azimuth ${\times}$ depth)) is converted, with an appropriate algorithm, to the 1-D data(depth), where the amplitude image values along a predetermined fracture signature(sinusoid) are summed up and averaged. The resulting values are subsequently scaled simply by a scalar factor that is possibly consistent with a known strength. This scaled Televiewer reflectivity is named, as a matter of convenience,“Televiewer rock strength”. This paper shows, based on abundant representative case studies from about 8 years of Televiewer surveys, that Televiewer rock strength might be regarded, on a continuous basis with depth, as a quitely robust indicator of rock classification and in most cases as an approximate uniaxial strength that is comparable to the rebound value from Schmidt hammer test.

• Korean Journal of Materials Research
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• v.19 no.1
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• pp.1-6
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• 2009

In this study, the stress-strain response and the cracking behaviors of ITO film on a PET substrate are investigated. The cracking behaviors of ITO thin films deposited on a thermoplastic semi-crystalline polymer developed for flexible display applications was investigated by means of tensile experiments equipped with an electrical measurement apparatus and an in-situ optical microscope. Electrical resistance increased gradually in the elastic-to-plastic transition region of the stress strain curves and cracks formed. Numerous cracks were found in this region, and the increase of the resistance was linked to the cracking of ITO thin films. Upon loading, the initial cracks perpendicular to the tensile axis were observed at about 1% of the total strain. They propagated to the entire sample width as the strain increased. The spacing between the horizontal cracks is thought to be determined by the fracture strength and the thickness of the ITO film as well as by the interfacial strength between the ITO and PET. The effect of the strain rate on the cracking behavior was also investigated. The crack density increased as the strain increased. The spacing between the horizontal cracks (perpendicular to the stress axis) increased as the strain rate decreased. The increase of the crack density as the strain rate decreased can be attributed to the higher fraction of the plastic strain to the total strain at a given total strain. The higher critical strain for the onset of the increase in the resistance and the crack initiation of the ITO/PET with a thinner ITO film (300 ohms/sq.) suggests a higher strength of the thinner ITO film.

• Journal of the Korea Concrete Institute
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• v.23 no.2
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• pp.235-244
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• 2011

Failures of segmental bridges have been attributed to the inadequate joint connection techniques, which led to corrosion of the post-tensioned tendons connecting the segmental joints. The principal objective of this study is to evaluate the performances of the in-situ cast joint and epoxy applied shear key joints as a function of shear and ultimate strengths. Furthermore, shear behavior and strength of shear key joints in ultra high performance precasted concrete segmental bridges are experimentally evaluated to understand its shear failure behavior. The test parameters of shear key shape and type, load-displacement relations, cracking behavior, concrete strength, and fracture modes are considered in the study. Also, several parameters which influence the mechanical behavior of the shear key joint are analyzed. Based on the study results, the optimal shear key shape and joint type are proposed for the joint design and analysis guidelines.

• Journal of the Microelectronics and Packaging Society
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• v.15 no.1
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• pp.33-37
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• 2008

A noticeable amount of Kirkendall voids formed at the Sn-3.5Ag solder joint with electroplated Cu, and that became even more significant when an additive was added to Cu electroplating bath. With SPS, a large amount of voids formed at the $Cu/Cu_3Sn$ interface of the solder joint during thermal aging at $150^{\circ}C$. The in-situ AES analysis of fractured joints revealed S segregation on the void surface. Only Cu, Sn, and S peaks were detected at the fractured $Cu/Cu_3Sn$ interfaces, and the S peak decreased rapidly with AES depth profiling. The segregation of S at the $Cu/Cu_3Sn$ interface lowered interface energy and thereby reduced the free energy barrier for the Kirkendall void nucleation. The drop impact test revealed that the electrodeposited Cu film with SPS degraded drastically with aging time. Fracture occurred at the $Cu/Cu_3Sn$ interface where a lot of voids existed. Therefore, voids occupied at the $Cu/Cu_3Sn$ interface are shown to seriously degrade drop reliability of solder joints.

• Journal of the Korean Geotechnical Society
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• v.25 no.10
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• pp.17-30
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• 2009

Underground construction such as tunneling can induce damages on the surrounding rock mass, due to the stress concentration of in situ stresses and excessive energy input during construction sequence, such as blasting. The developed damage on the rock mass can have substantial influence on the mechanical and hydraulic behaviors of the rock masses around a tunnel. In this study, investigation on the generation of damage around an opening in a jointed rock model under biaxial compression condition was conducted. The joint dip angles employed are 30, 45, and 60 degrees to the horizontal, and the synthetic rock mass was made using early strength cement and water. From the biaxial compression test, initiation and propagation of tensile cracks at norm to the joint angle were found. The propagated tensile cracks eventually developed rock blocks, which were dislodged from the rock mass. Furthermore, the propagation process of the tensile cracks varies with joint angle: lower joint angle model shows more stable and progressive tensile crack propagation. The development of the tensile crack can be explained under the hypothesis that the rock segment encompassed by the joint set is subjected to the developing moment, which can be induced by the geometric irregularity around the opening in the rock model. The experiment results were simulated by using discrete element method PFC 2D. From the simulation, as has been observed from the test, a rock mass with lower joint angle produces wider damage region and rock block by tensile cracks. In addition, a rock model with lower joint angle shows progressive tensile cracks generation around the opening from the investigation of the interacted tensile cracks.

• The Journal of Engineering Geology
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• v.25 no.3
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• pp.357-368
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• 2015

Brittle failure of Mesozoic granite in the Daejeon region is predicted using empirical analysis and numerical modeling techniques. The input parameters selected for these techniques were based on the results of laboratory tests, including damage-controlled tests. Rock masses that were considered to be strong during laboratory testing were assigned to "group A" and those considered to be extremely strong were assigned to "group B". The properties of each group were then used in the analyses. In-situ stress measurements, or the ratio of horizontal to vertical stress (k), were also necessary for the analyses, but no such measurements have been made in the study area. Therefore, k values of 1, 2, and 3 were assumed. In the case of k=1, empirical analysis and numerical modeling show no indication of brittle failure from the surface to1000 m depth. When k=2, brittle failure of the rock mass occurs at depths below 800 m. For k=3, brittle failure occurs at depths below 600 m. Although both the Cohesion Weakening Friction Strengthening (CWFS) and Mohr-Coulomb models were used to predict brittle failure, only the CWFS model performed well in simulating the range and depth of the brittle failure zone.