• 제목/요약/키워드: impurity effect

검색결과 266건 처리시간 0.031초

Evaluation of Effects of Impurities in Nuclear Fuel and Assembly Hardware on Radiation Source Term and Shielding

  • Taekyung Lee;Dongjin Lee;Kwangsoon Choi;Hyeongjoon Yun
    • 방사성폐기물학회지
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    • 제21권2호
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    • pp.193-204
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    • 2023
  • To ensure radiological safety margin in the transport and storage of spent nuclear fuel, it is crucial to perform source term and shielding analyses in advance from the perspective of conservation. When performing source term analysis on UO2 fuel, which is mostly used in commercial nuclear power plants, uranium and oxygen are basically considered to be the initial materials of the new fuel. However, the presence of impurities in the fuel and structural materials of the fuel assembly may influence the source term and shielding analyses. The impurities could be radioactive materials or the stable materials that are activated by irradiation during reactor power operation. As measuring the impurity concentration levels in the fuel and structural materials can be challenging, publicly available information on impurity concentration levels is used as a reference in this evaluation. To assess the effect of impurities, the results of the source term and shielding analyses were compared depending on whether the assumed impurity concentration is considered. For the shielding analysis, generic cask design data developed by KEPCO-E&C was utilized.

Halo 구조의 MOSFET에서 이동도 감소 현상 (The Behavior of the Mobility Degradation in Pocket Implanted MOSFETS)

  • 이병헌;이기영
    • 대한전자공학회논문지SD
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    • 제42권4호
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    • pp.1-8
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    • 2005
  • 소오스와 드레인 근처에 포켓이온이 주입된 halo구조의 MOSFET에서 전송자의 이동도 감소는 포켓이온주입의 조건에 따라 이온화된 불순물의 증가에 따른 쿨롱(Coulomb) 산란율의 증가에 의한 이동도의 감소량보다 큰 이동도의 감소가 관측될 수 있다. 게이트 바이어스에 대한 이동도의 특성변화도 기존의 일차적인 쿨롱산란의 증가효과에 의한 해석과 비교하여 상이한 결과가 나타날 수 있음이 실험적으로 확인되고 있다. 본 연구에서는 포켓이온 주입에 의하여 쿨롱산란원이 되는 유효불순물 농도의 증가에 따른 일차적인 이동도의 감소효과를 벗어난 이동도 특성을 분석하여 이동도의 감소현상을 일반적으로 설명할 수 있는 개선된 해석적 모델을 제시하였다. 해석적인 결과를 도출하기 위하여 일차원 영역구분의 근사방법을 적용한 결과, 포켓이온 주입에 의하여 포논산란율 및 표면산란율(surface roughness scattering rate)의 증가도 이동도감소에 기여함이 보여 졌다. 채널의 전송자분포가 드레인 전류에 영향을 미치게 되므로 포켓이온에 의해 유발된 전송자분포의 효과를 분석하여 유효이동도가 추가적으로 감소함을 확인하였다.

Systematic Analysis for the Effects of Atmospheric Pollutants in Cathode Feed on the Performance of Proton Exchange Membrane Fuel Cells

  • Yoon, Young-Gon;Choi, Insoo;Lee, Chang-Ha;Han, Jonghee;Kim, Hyoung-Juhn;Cho, EunAe;Yoo, Sung Jong;Nam, Suk Woo;Lim, Tae-Hoon;Yoon, Jong Jin;Park, Sehkyu;Jang, Jong Hyun
    • Bulletin of the Korean Chemical Society
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    • 제35권12호
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    • pp.3475-3481
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    • 2014
  • This paper describes how primary contaminants in ambient air affect the performance of the cathode in fuel cell electric vehicle applications. The effect of four atmospheric pollutants ($SO_2$, $NH_3$, $NO_2$, and CO) on cathode performance was investigated by air impurity injection and recovery test under load. Electrochemical analysis via polarization and electrochemical impedance spectroscopy was performed for various concentrations of contaminants during the impurity test in order to determine the origins of performance decay. The variation in cell voltage derived empirically in this study and data reported in the literature were normalized and juxtaposed to elucidate the relationship between impurity concentration and performance. Mechanisms of cathode degradation by air impurities were discussed in light of the findings.

7XXX계 단조재의 피로 및 파괴인성에 미치는 제조공정의 영향 (Effect of Fabrication Processes on the Fatigue and Fracture Toughness of 7XXX Series Aluminum Forgings)

  • 이오연;임재규;송기홍;손영일;은일상;신돈수
    • 열처리공학회지
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    • 제9권3호
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    • pp.161-168
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    • 1996
  • The purpose of this study is to investigate the effect of impurity level and fabrication processes on the strength, fracture toughness and fatigue resistance of 7075, 7050 and 7175 high strength aluminum forgings. It has been verified that plane strain fracture toughness and fatigue characteristics of a specially processed 7175S-T74 alloy is superior to a conventionally processed 7075-T6/T73, 7050-T74 and 7175-T74 alloys. These beneficial effects primarily arise from two view points, i.e., the effect of reducing the impurity level of iron and silicon has significantly diminished the size and volume fraction of second phase particles such as $Al_7Cu_2Fe$ and $Mg_2Si$. Futher reduction of the amount of nonequilibrium second phase particles has been observed by applying a special fabrication process.

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고전압 리튬이차전지를 위한 LiNi0.5Mn1.5O4 양극용 전해질로써 상온 이온성 액체 전해질의 불순물 효과에 관한 연구 (The Influence of Impurities in Room Temperature Ionic Liquid Electrolyte for Lithium Ion Batteries Containing High Potential Cathode)

  • 김지용;;임태은;문준영
    • 전기화학회지
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    • 제18권2호
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    • pp.51-57
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    • 2015
  • 상온 이온성 액체인 propylmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PMPyr-TFSI)를 리튬이차전지 전해질 용매로 사용 시 PMPyr-TFSI 내 수분 및 브롬 불순물이 전지의 성능에 미치는 영향을 연구하였다. 고전압 양극 물질인 $LiNi_{0.5}Mn_{1.5}O_4$ 스피넬 구조 양극을 이용한 반쪽 전지의 전해질로 PMPyr-TFSI를 사용 하는데 있어, PMPyr-TFSI의 수분 함유량을 각각 12, 77, 1060 ppm으로 제어하고 전압 곡선 개형 및 쿨롱 효율 거동 추적을 통해 PMPyr-TFSI 수분량이 전지 성능에 부정적인 영향을 미치는 것을 구체적으로 확인하였다. 또한, PMPyr-TFSI 전해질 내의 브롬 이온 불순물 양 제어를 통하여, 전지 내에서 브롬 이온 불순물과 관련한 전기화학 부반응을 찾아 내었다. 이들 할로겐 불순물에 의한 초기 전지 쿨롱 효율저하는 눈에 띠었으나, 수명 저하에는 큰 변화가 없음을 확인하였다.

금속 불순물 오염에 따른 실리콘 기판 및 태양전지 특성의존성 분석 (Effect of metal impurity contamination on silicon wafer and solar cell properties)

  • 백상훈;이정철;조준식;왕진석;송진수
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.167-167
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    • 2009
  • 결정질실리콘 태양전지를 제조함에 있어 실리콘 기판 내의 금속 불순물들은 소자제작 시에 성능 저하의 원인으로 작용한다. 따라서 본 연구에서는 실리콘 기판에 Cr, Cu, Ni 불순물을 강제 오염시킨 후 태양전지를 제작하여 각각의 불순물에 대한 특성을 조사 하였다. p-type 실리콘 기판을 오염시키기 위해 일정 시간동안 표준용액에 담근 후 질소 분위기에서 열처리 하여 불순물을 확산시켰다. 이후 상용 공정을 이용하여 태양전지를 제작하고 기판내 금속불순물 농도에 따른 태양전지의 동작특성을 분석하였다.

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$MnO_2$가 첨가된 PZT-PSN압전세라믹의 압전 및 전기적특성 분석 (Ihe Electrical and Piezoelectric Characteristics of PZT-PSN ceramics added $MnO_2$)

  • 김성곤;김철수;박정호;이상렬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.161-164
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    • 2001
  • In this paper, we investigated the dielectric and piezoelectric properties of Pb(Sb, Nb)O$_3$-Pb(Zr, Ti)O$_3$ ceramic(PSN) for piezoelectric transformer and actuator etc. Effect of MnO$_2$ addition on the PSN ceramic was investigated. Anisotropic properties of electromechanical coupling factor and piezoelectric properties proved to be varied with amount of MnO$_2$ impurity and sintering temperature. The electromechanical coupling factor k$_{p}$ of 0.38 and the mechanical quality factor Q$_{m}$ of 1944 were obtained from the specimen with 0.4 wt% MnO$_2$ sintered at 115$0^{\circ}C$ addition. Experimental results indicated that the PSN ceramic with MnO$_2$ impurity can be effectively used for piezoelectric transformer and actuator.tor.

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7XXX계 알루미늄합금 단조재의 파괴인성 개선 (Improvement of Fracture Toughness in 7XXX Series Aluminum Alloy Forings)

  • 송기홍;이오연
    • 열처리공학회지
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    • 제11권3호
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    • pp.200-206
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    • 1998
  • The aim of this study is to investigate the effect of impurity level and fabrication processes on the strength, impact and fracture toughness of 7075, 7050 and 7175 aluminum alloy forgings. A specially processed 7175S-T74 aluminum forgings was superior to a conventionally processed 7075-T73, 7050-T74 and 7175-T74 aluminum forgings in both strength and toughness. The reduction of impurity level of iron and silicon has significantly diminished the size and volume fraction of second phase particles such as $Al_7Cu_2Fe$ and $Mg_2Si$. A further reduction of the amount of second phase particles has been observed by applying a special fabrication process. This phenomena result from the application of intermediate soaking at higher temperature and more sufficiant hot working temperature than that of a conventional processing.

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The Effects of Impurities in Silicon Nitride Substrate on Tribological Behavior between Diamond Film and Silicon Nitride Ball

  • Lim, Dae-Soon;Kim, Jong-Hoon
    • Tribology and Lubricants
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    • 제11권5호
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    • pp.20-25
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    • 1995
  • Diamond films were prepared by a hot filament vapor deposition onto polycrystal silicon nitride substrates. Different kinds of silicon nitride containing CaO and $Fe_{2}O_{3}$ were manufactured to investigate the impurity effect of substrate on the morphology of diamond films and their wear behaviors. Nucleation rates and morphologies of diamond films deposited on various kinds of silicon nitride were compared. The highest nucleation rate was observed in a substrate containing 1% of CaO. Wear tests were performed with a silicon nitride ball on the disk geometry to investigate the tribological behavior of diamond film against silicon nitride. This study demonstrated that different morphologies of diamond film due to substrate impurities produced different wear behavior against silicon nitride.

변압기유의 불순물에 따른 유동대전 영향 (The Effect on the Streaming Electrification of Insulating Oils with Impurity)

  • 이용우;이광석;송병기;김왕곤;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.329-333
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    • 1996
  • In this Paper, the streaming electrification of transformer oils generated at the interface of transformer oils and the AC breakdown with impurity is studied. The electrification current is measured by the electrometer connected the faraday cage. And a oil velocity is maintained equally. In case of the AC breakdown test, the temperature are 30[$^{\circ}C$], 50[$^{\circ}C$], 80[$^{\circ}C$] and 90[$^{\circ}C$], repetitively. As a result of breakdown experiment, the dielectric breakdown strength is decreased in low temperature region and is increased in high temperature region according to increase of contained sodium. In case of streaming electrification experiment, the streaming current is more increased with the specimen contained sodium than the original specimen.

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