• Korean Journal of Materials Research
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• v.19 no.5
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• pp.233-239
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• 2009

The electrocatalytic behavior of the PtCo catalyst supported on the multi-walled carbon nanotubes (MWNTs) has been evaluated and compared with commercial Pt/C catalyst in a polymer electrolyte membrane fuel cell(PEMFC). A PtCo/MWNTs electrocatalyst with a Pt:Co atomic ratio of 79:21 was synthesized and applied to a cathode of PEMFC. The structure and morphology of the synthesized PtCo/MWNTs electrocatalysts were characterized by X-ray diffraction and transmission electron microscopy. As a result of the X-ray studies, the crystal structure of a PtCo particle was determined to be a face-centered cubic(FCC) that was the same as the platinum structure. The particle size of PtCo in PtCo/MWNTs and Pt in Pt/C were 2.0 nm and 2.7 nm, respectively, which were calculated by Scherrer's formula from X-ray diffraction data. As a result we concluded that the specific surface activity of PtCo/MWNTs is superior to Pt/C's activity because of its smaller particle size. From the electrochemical impedance measurement, the membrane electrode assembly(MEA) fabricated with PtCo/MWNTs showed smaller anodic and cathodic activation losses than the MEA with Pt/C, although ohmic loss was the same as Pt/C. Finally, from the evaluation of cyclic voltammetry(CV), the unit cell using PtCo/MWNTs as the cathode electrocatalyst showed slightly higher fuel cell performance than the cell with a commercial Pt/C electrocatalyst.

• Macromolecular Research
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• v.12 no.4
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• pp.422-426
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• 2004

Solid polymer electrolytes based on poly(ethylene glycol)-polyurethane (PEG-PU) complexed with LiClO$_4$ salt have been prepared by the solvent casting method. A PEG-PU material (PEG:4,4'-diphenylmethane diisocyanate: l,4-butanediol = 1:2:1) was synthesized through a typical two-step condensation reaction. We investigated the effects of the salt concentration on the ionic conductivity ($\sigma$) and the glass transition temperature (T$_{g}$ ) of the complex electrolytes by using alternating current impedance spectroscopy, differential scanning calorimetry, and dynamic mechanical thermal analysis. The measured values of both $\sigma$ and T$_{g}$ exhibited similar tendencies in that they had maxima within the range studied, probably because of two opposite effects, i.e., the increased number of carrier ions and the decreased chain mobility (or increased T$_{g}$ ) caused by the increase in the salt concentration. The highest conductivity, on the order of 2.43 ${\times}$ 10$^{6}$ S$cm^{-1}$ /, was obtained at an [O]/[Li$^{+}$] ratio of ca. 16 (0.92 ㏖ salt per kg of matrix polymer).

• Journal of Korean Medicine for Obesity Research
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• v.4 no.1
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• pp.67-80
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• 2004

Objectives: Obesity is a growing epidemic with subsequent health consequences leading not only to reduced quality of life but also to increased medical costs. Recently nutritional balances are emphasized in the field of obesity, and especially maintaining proper equilibriums of minerals. The correlation of minerals obtained from the method of HTMA(Hair Tissue Mineral Analysis) with obese degree has not been studied in Korea yet. We studied any significant difference of mineral concentrations and components according to the obese degree. Methods: 78 subjects were analyzed who visited Garosero clinic of oriental medicine to lose their weight from June to November 2004. We used BMI(Body Mass Index), PBF(Percent Body Fat), WHR(Waist-Hip Ratio) and abdominal circumference obtained by bio-electrical impedance analysis as an obese degree. And we analyzed correlation with mineral concentrations and ratios obtained from HTMA. Results & Conclusion: 1. Na, K, Zn, Se had significant correlation with obese degree in case of nutritional minerals from HTMA. Especially, K had high significance. 2. Toxic minerals from HTMA had no significance with obese degree. 3. Rb had significant correlation with obese degree in case of additional minerals from HTMA. 4. Among important ratios from HTMA, Na/K had significant correlation with obese degree, but Ca/K had correlation except PBF, and Na/Mg had correlation except WHR. 5. Among toxic ratios from HTMA, Se/Hg had significant correlation with obese degree, but S/Hg had correlation except BMI. 6. Na, K, Zn, Rb, Na/K, Ca/K had significant differences between obesity groups classfied by BMI. Ob II group had sinificant difference from NW group in cases of K, Zn, Rb, Na/K, and Ob II group had sinificant difference from OW group in case of Ca/K.

• Bulletin of the Society of Naval Architects of Korea
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• v.14 no.1
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• pp.1-10
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• 1977

The major objects of this report are to supplement data of natural frequencies of thin elastic rectangular plates to the available data, and to give an experimental verification for natural frequencies obtained by Rayleigh-Ritz method, the generation set of which are eigenfunctions of Euler beams. For the first object the following five models, for which data only for the fundamental mode or data only for square plates are available, are adopted; (1) two opposed edges are clamped and the other two opposed edges simply supported (C-C, S-S), (2) one edge is simply supported and the other three edges clamped (C-C, C-S), (3) one edge is free and the other three edges clamped (C-C, C-F), (4) two adjacent edges are clamped and the other two adjacent edges free (C-F, C-F). For the (C-C, S-S) model the frequency equation obtained with the mode shapes assumed as of a single trigonometric series is solved. And for the other four models Rayleigh-Ritz method taking eigenfunctions of Euler beams as the generating set is applied. The numerical examples are obtained up to the fourth, the fifth or the sixth order depending on the range of the aspect ratio (0.1-10.0). The number of terms in the generating set for Rayleigh-Ritz method is fifteen for all models. For the experiment three models made of 3.2mm thickness mild steel plate for general structure use were prepared in following size; $300mm{\times}600mm,\;600mm{\times}600mm\;and\;900mm{\times}600mm$. Their boundary conditions are made to fit (C-C, C-F) condition. From the experiment mechanical impedance curves based on the frequency response method were obtained together with phase relation diagrams. The experimental data are resulted in good conformity to calculated values.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.44 no.1
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• pp.155-161
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• 2007

This paper presents the design simulation, implementation, and measurement of a miniaturized PCS / Satellite DMB dual-band stacked mompole antenna with a parasitic patch for mobile communication terminals. A stacked helix is realized by using a via hole with height of 0.4 mm and a diameter of 0.35 mm to connect upper- and lower-layer helix sections for a reduction of the dimensions of the antenna. In addition the stacked helix chip antenna is interleaved with a parasitic patch to achieve two different radiation modes. The ratio of the first frequency and the second frequency vary with the geometrical parameter of the parasitic patch. The fabricated antenna uses FR-4 substrate with a relative permittivity of 4.2. Its dimensions are $15.5{\times}7.6{\times}0.4 mm^3$. The measured impedance bandwidths (VSWR<2) are 240 and 250 MHz at the operating frequencies, respectively.

• Journal of the Korean Electrochemical Society
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• v.1 no.1
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• pp.28-32
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• 1998

The electrochemical behavior of film and charge-discharge capacity of Li-ion cell in 1 M $LiPF_6/EC:DME$ (1 : 1, by volume ratio) electrolyte solution was studied using chronopotentiometry, cyclic voltammetry, chronoamperometry, and impedance spectroscopy. The first irreversible capacity was higher than the second irrversible capacity because of solvent decomposition. Especially, passivation film that is electron insulating and ionic conducting were formed on the MPCF by solvent decomposition during the first charge. The solvated Li is co-intercalated with solvent into MPCF electrode. Part of the MPCF is expoliated during co-intercalation of solvent-Li. The MPCF ends up nonuniformly covered by a relatively thick layer of exfoliated particles embedded in a matrix of product by solvent decomposition.

• Journal of electromagnetic engineering and science
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• v.14 no.4
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• pp.393-398
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• 2014

A highly efficient dual-mode linear CMOS stacked-FET power amplifier (PA) is implemented for 3G UMTS and 4G LTE handset applications. High efficiency is achieved at a backed-off output power ($P_{out}$) below 12 dBm by employing an active-bypass amplifier, which consumes very low quiescent current and has high load-impedance. The output paths between high- and low-power modes of the PA are effectively isolated by using a bypass switch, thus no RF performance degradation occurs at high-power mode operation. The fabricated 900 MHz CMOS PA using a silicon-on-insulator (SOI) CMOS process operates with an idle current of 5.5 mA and shows power-added efficiency (PAE) of 20.5%/43.5% at $P_{out}$ = 12.4 / 28.2 dBm while maintaining an adjacent channel leakage ratio (ACLR) better than -39 dBc, using the 3GPP uplink W-CDMA signal. The PA also exhibits PAE of 35.1% and $ACLR_{E-UTRA}$ of -33 dBc at $P_{out}$ = 26.5 dBm, using the 20 MHz bandwidth 16-QAM LTE signal.

• ETRI Journal
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• v.38 no.5
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• pp.981-987
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• 2016

We present a cost-effective dual polarization quadrature phase-shift coherent receiver module using a silica planar lightwave circuit (PLC) hybrid assembly. Two polarization beam splitters and two $90^{\circ}$ optical hybrids are monolithically integrated in one silica PLC chip with an index contrast of $2%-{\Delta}$. Two four-channel spot-size converter integrated waveguide-photodetector (PD) arrays are bonded on PD carriers for transverse-electric/transverse-magnetic polarization, and butt-coupled to a polished facet of the PLC using a simple chip-to-chip bonding method. Instead of a ceramic sub-mount, a low-cost printed circuit board is applied in the module. A stepped CuW block is used to dissipate the heat generated from trans-impedance amplifiers and to vertically align RF transmission lines. The fabricated coherent receiver shows a 3-dB bandwidth of 26 GHz and a common mode rejection ratio of 16 dB at 22 GHz for a local oscillator optical input. A bit error rate of $8.3{\times}10^{-11}$ is achieved at a 112-Gbps back-to-back transmission with off-line digital signal processing.

• JSTS:Journal of Semiconductor Technology and Science
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• v.14 no.1
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• pp.109-116
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• 2014

This paper presents a high-efficiency digital class-D audio amplifier using a composite interpolation filter for portable audio devices. The proposed audio amplifier is composed of an interpolation filter, a delta-sigma modulator, and a class-D output stage. To reduce power consumption, the designed interpolation filter has an optimized composite structure that uses a direct-form symmetric and Lagrange FIR filters. Compared to the filters with homogeneous structures, the hardware cost and complexity are reduced by about half by the optimization. The coefficients of the digital delta-sigma modulator are also optimized for low power consumption. The class-D output stage has gate driver circuits to reduce shoot-through current. The implemented class-D audio amplifier exhibited a high efficiency of 87.8 % with an output power of 57 mW at a load impedance of $16{\Omega}$ and a power supply voltage of 1.8 V. An outstanding signal-to-noise ratio of 90 dB and a total harmonic distortion plus noise of 0.03 % are achieved for a single-tone input signal with a frequency of 1 kHz.

• Bulletin of the Korean Chemical Society
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• v.33 no.7
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• pp.2207-2212
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• 2012

Dimethylaluminum isopropoxide (DMAI, $(CH_3)_2AlO^iPr$) as a single precursor, which contains one aluminum and one oxygen atom, has been adopted to deposit non-stoichiometric aluminum oxide ($AlO_x$) films by low pressure metal organic chemical vapor deposition without an additional oxygen source. The atomic concentration of Al and O in the deposited $AlO_x$ film was measured to be Al:O = ~1:1.1 and any serious interfacial oxide layer between the film and Si substrate was not observed. Gaseous by-products monitored by quadruple mass spectrometry show that ${\beta}$-hydrogen elimination mechanism is mainly contributed to the $AlO_x$ CVD process of DMAI precursor. The current-voltage characteristics of the $AlO_x$ film in Au/$AlO_x$/Ir metalinsulator-metal (MIM) capacitor structure show high ON/OFF ratio larger than ${\sim}10^6$ with SET and RESET voltages of 2.7 and 0.8 V, respectively. Impedance spectra indicate that the switching and memory phenomena are based on the bulk-based origins, presumably the formation and rupture of filaments.