• 제목/요약/키워드: impedance ratio

검색결과 569건 처리시간 0.026초

20, 40 wt% Pt/C 촉매를 사용한 MEA제조에서 나피온의 최적비 (Optimum Ratio between Nafion and 20, 40 wt% Pt/C Catalysts for MEAs)

  • 정주해;정동원;김준범
    • 전기화학회지
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    • 제14권1호
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    • pp.50-55
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    • 2011
  • Pt/C 촉매 (20, 40 wt% Pt/C)를 사용하여 고분자 전해질 연료전지의 MEA를 제조하고 각각의 촉매에서 최적의 나피온 이오노머 함량을 알아보았다. 나피온 함량에 따른 MEA의 전기화학적인 성능변화는 단위전지 성능평가, electrochemical impedance spectroscopy (EIS), cyclic voltammetry(CV)을 통해서 분석하였다. 나피온의 함량에 따라 전지의 활성화 분극, 옴 저항, 물질전달 저항 등의 변화가 나타났다. 이는 전극의 촉매층 내에서 발생되는 전기/이온 전도도 사이의 'trade-off'와 물질전달(물 배출과 반응가스 확산)에 의한 것이며, 대부분 활성화 분극과 물질전달 저항의 변화로 나타났다. 20 wt% Pt/C와 40 wt% Pt/C 촉매에서 최적의 나피온 함량은 각각 35 wt%와 20 wt%로 나타났다. 이는 Pt 중량비에 따른 Pt 입자간의 거리 및 촉매의 비표면적의 차이 때문에 나타난 결과이며 서로 다른 나피온 함량에서 최적의 삼상계면이 형성되는 것으로 판단된다.

변형된 급전 구조를 가지는 소형 직사각형 스파이럴 안테나 (Compact Rectangular Spiral Antenna Employing Modified Feeding Network)

  • 이동현;김태수;전중창
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2006년도 춘계종합학술대회
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    • pp.595-598
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    • 2006
  • 본 논문에서는 그라운드 평면을 가지는 소형 직사각형 스파이럴 안테나를 제안하였다. 제안된 안테나는 일반적인 스파이럴 안테나의 급전 방식인 중앙에서 급전하지 않고, 스파이럴이 끝나는 가장 자리에서 급전되는 변형된 급전 구조를 가진다. 이와 함께 급전 위치에 $'{\sqsupset}'$자 모양의 매칭회로를 추가하였다. 이 매칭회로는 공간의 제약을 받지 않고 쉽게 입력 임피던스를 매칭 할 수 있도록 한다. 안테나의 원형 편파 특성을 결정하는 파라미터를 설명하고, 제안한 안테나의 설계 방법을 제시하였다. 9.5GHz에서 동작하는 안테나를 설계하였으며, 제안한 안테나의 크기는 $0.6\lambda_g\times0.6\lambda_g$로 소형이다. 시뮬레이션 한 안테나의 입력 임피던스 대역폭$(S11\leq-10)$과 AR 대역폭$(AR\leq-3)$은 각각 8.12%, 4.62%으로 간단한 구조에 비해 특성이 매우 우수하다.

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염료감응형 태양전지의 효율향상에 관한 연구 (A Study on the Efficiency Improvement of Dye Sensitized Solar Cell)

  • 김희제;석영국;김민철
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2009년도 공동학술대회
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    • pp.467-470
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    • 2009
  • 외부적으로 직렬 및 병렬로 접속된 50개의 DSSC로써 새로운 8 V DC 전원을 만들었다. 한 개의 DSSC는 $5.2{\times}2.6$ cm(유효면적 8 $cm^2$) 약 4.2%의 효율을 보이며, 전기화학적 임피던스 분석법 및 I-V 곡선으로 특성이 분석되었다. 또한 펄스형 Nd:YAG 레이저 빔을 활용하여 투명 도전층을 식각함으로써, 최종효율 약 45%를 달성하였다.

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Mg와 Zn의 복합치환에 따른 LiMn2-yMyO4 정극 활물질의 결정 구조 및 전기화학적 특성 (Crystal Structure and Electrochemical Properties of LiMn2-yMyO4 Cathode Material by Complex Substitution of Mg and Zn)

  • 정인성;정해덕;구할본
    • 한국전기전자재료학회논문지
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    • 제15권4호
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    • pp.361-366
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    • 2002
  • Spinel $LiMn_{2-y}M_yO_4$ and $LiMn_{2-y}M_yO_4$ (M=Mg, Zn) powders were synthesized by solid-state method at $800^{\circ}C$ for 37h. Crystal structure and electrochemical properties were analyzed by X-ray diffraction, charge-discharge test, cyclic voltammetry and ac impedance to $LiMn_{2-y}M_yO_4$. All cathode material showed spinel structure in X-ray diffraction. Ununiform distortion which calculated by (111) face and (222) face was almost constant in spite of the change of the kind and the substituting ratio of the metal cation in $LiMn_{2-y}M_yO_4$ (M=Mg, Zn). $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$ cell substituted $Mg^{+2}$ and $Zn^{+2}$ showed excellent discharge capacities than other cells, which it presented about 120mAh/g at the 1st cycle and about 73mAh/g at the 250th cycle, respectively. AC impedance of $LiMn_{2-y}M_yO_4/Li$ cells showed the similar resistance of about 65~110$\Omega$ before cycling.

Discriminant Analysis of Marketed Liquor by a Multi-channel Taste Evaluation System

  • Kim, Nam-Soo
    • Food Science and Biotechnology
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    • 제14권4호
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    • pp.554-557
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    • 2005
  • As a device for taste sensation, an 8-channel taste evaluation system was prepared and applied for discriminant analysis of marketed liquor. The biomimetic polymer membranes for the system were prepared through a casting procedure by employing polyvinyl chloride, bis (2-ethylhexyl)sebacate as plasticizer and electroactive materials such as valinomycin in the ratio of 33:66:1, and were separately attached over the sensitive area of ion-selective electrodes to construct the corresponding taste sensor array. The sensor array in conjunction with a double junction reference electrode was connected to a high-input impedance amplifier and the amplified sensor signals were interfaced to a personal computer via an A/D converter. When the signal data from the sensor array for 3 groups of marketed liquor like Maesilju, Soju and beer were analyzed by principal component analysis after normalization, it was observed that the 1st, 2nd and 3rd principal component were responsible for most of the total data variance, and the analyzed liquor samples were discriminated well in 2 dimensional principal component planes composed of the 1st-2nd and the 1st-3rd principal component.

등가선형해석을 이용한 지반증폭 영향 요소 연구 (A Parametric Study on Site Amplification using Equivalent Linear Analysis)

  • 김동수
    • 한국지진공학회:학술대회논문집
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    • 한국지진공학회 2000년도 추계 학술발표회 논문집 Proceedings of EESK Conference-Fall 2000
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    • pp.98-107
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    • 2000
  • Free-field ground motion during earthquake is significantly affected by the local site conditions and it is essential for the seismic design to perform the ground response analysis In this study, ground response analyses based on the equivalent linear method were carried out to evaluate the effects of various ground conditions on the site amplification. Four major factors including the depth of the site(very soft and dense soil), the impedance ratio between soil layer and bed rock, linear analysis versus equivalent linear analysis, and the location of soft soil layer were deeply discussed. Based on the analysis results, the importance of various local site conditions on the site amplification was emphasized.

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Preparation and Electrochemical Properties of LiFePO4-PSS Composite Cathode for Lithium-ion Batteries

  • Nguyen, Hiep Van;Jin, En Mei;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • 제13권4호
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    • pp.177-180
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    • 2012
  • In this study, we prepared $LiFePO_4$- poly (sodium 4-styrenesulfonate) (PSS) composite by the hydrothermal method and ball-milling process. Different wt% PSS were added to $LiFePO_4$. The cathode electrodes were made from mixtures of $LiFePO_4$-PSS: SP-270: PVDF in a weighting ratio of 70%: 25%: 5%. $LiFePO_4$-PSS powders were characterized by X-ray diffraction (XRD), and scanning electron microscopy (SEM). The electrochemical properties of $LiFePO_4$-PSS/Li batteries were analyzed by cyclic voltammetry, charge/discharge tests, and AC impedance spectroscopy. A Li/$LiFePO_4$-PSS battery with 4.75 wt% PSS shows the best electrochemical properties, with a discharge capacity of 128 mAh/g.

2개 센서를 이용한 부분방전 위치추정 기법 연구 (A Study on the Partial Discharge Location Method using 2 Sensors)

  • 김정태;김동욱
    • 전기학회논문지
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    • 제61권2호
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    • pp.251-256
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    • 2012
  • This study deals with the location of partial discharges(PDs) for power cables and GIS using 2 PD sensors and long coaxial signal cables. Throughout the experiments by use of simulated PD pulses and corona discharges in the power cable system, it is found out that the impedance matching between the coaxial signal cable and the measuring equipment should be done for good S/N ratio and the on-site measurement using more than 100m-long coaxial signal cable is possible. In addition, new PD location algorithm with the polarities of PD pulses and the arrival time difference between two pulses was proposed and was proved through the partial discharge experiments for the cable joint defect and artificial void defect.

A Cost-Effective 40-Gb/s ROSA Module Employing Compact TO-CAN Package

  • Kang, Sae-Kyoung;Lee, Joon Ki;Huh, Joon Young;Lee, Jyung Chan;Kim, Kwangjoon;Lee, Jonghyun
    • ETRI Journal
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    • 제35권1호
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    • pp.1-6
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    • 2013
  • In this paper, we present an implemented serial 40-Gb/s receiver optical subassembly (ROSA) module by employing a proposed TO-CAN package and flexible printed circuit board (FPCB). The TO-CAN package employs an L-shaped metal support to provide a straight line signal path between the TO-CAN package and the FPCB. In addition, the FPCB incorporates a signal line with an open stub to alleviate signal distortion owing to an impedance mismatch generated from the soldering pad attached to the main circuit board. The receiver sensitivity of the ROSA module measures below -9 dBm for 40 Gb/s at an extinction ratio of 7 dB and a bit error rate of $10^{-12}$.

전대역 TV 전파수신 안테나의 개발연구 (Study on a combined televisin Receiving Antenna)

  • 박정기;이두수
    • 대한전자공학회논문지
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    • 제11권4호
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    • pp.9-16
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    • 1974
  • The low channels with frequency range of 54~88MHz and the high channels with frequency range if 174~216 MHz are in use for TV broadcasting in Korea. Since the ratio of the highest frequency to the lowest frequency is 4 to 1, only a logarithmic periodic antenna cou1d cover such an wide frequency range. But, this log-periodic antenna should be big in size. Studies have been done on an antenna of small size with reasonable gain which combines through a channel filter a LPD antenna if low channel with boom length of 2m and a LPD antenna of high channel with boom length of 1.8m. The whole antenna is connected to feeder line through a talun. Experiment shows that the gain of low and high channels is 7 dB and 9 dB respectively, which are lower than theoretical values br nomore than ldB. The difference seemed to come from slight impedance mismatches between antennas and feeder lines, loss in the filter and measurement errors.

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