• The Korean Journal of Petroleum Geology
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• v.2 no.2 s.3
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• pp.83-90
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• 1994

Thermal maturation and diagenesis of the Gyeongsang Supergroup in the Euiseong area are studied by means of organic geochemical techniques and illite crystallinity. Black mudrocks of the Singdong Group contain organic matter of $0.5{\~}2{\%}$ derived from higher plants, being compared to type Ⅲ. Thermal maturity of organic matter reached dry gas generation phase. Tmax by Rock Eval pyrolysis varies between $578^{\circ}C$ and $593^{\circ}C$ regardless of stratigraphic position and localities, and vitrinite reflectance is about 2.9 and $3{\~}4{\%}Ro$ in the Jinju and the Nagdong Formations, respectively. Vitrinite reflectance measurements indicate that the maturation is mainly due to burial and partly to be affected by post-depositional intrusions. Illite crystallinity values from the Nagdong, Hasandong, Jiniu Formations and part of the Iljig Formation are plotted around the boundary between diagenesis and anchizone, indicating dry gas generation stage. However, the values are not dependent on stratigraphic position. The values from the Iljig, Hupyeongdong, Geomgog, and Sagog Formations fall into the range of anchizone, probably resulted from the post-depositional intrusions which occur locally. Both organic geochemical and illite crystallinity data indicate thermal maturation stage of dry gas generation. Diagenesis of the Gyeongsang strata is mostly controlled by burial, and partly affected by post-depositional intrusions. Paleotemperature of the Sindong Group is estimated at around $200^{\circ}C$ on the basis of illite crystallinity.

• Journal of the Mineralogical Society of Korea
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• v.4 no.1
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• pp.32-42
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• 1991

Illite 'crystallinity' and chlorite chemistry are applied to the evaluation of the thermal grade of the Jigunsan Formation. Illite 'crystallinity' value of the formation has the range fom 4.48 to 32.5 in Weaver index (W.I.) and from $0.14{{\Delta}{\circ}}\;2{\Theta}$to $0.03{{\Delta}{\circ}}\;2{\Theta}$in kubler index (K.I). Most of illite 'crystallinity' values in this formation belong to the epizone field (K.I.<$0.21{{\Delta}{\circ}}\;2{\Theta}$). The chemistry and calculated temperature of chlorites from this formation (Fe/(Fe+Mg)=0.45, Tet. Al/Octa. Al=0.84, the calculated temperature=250-270${\circ}C$) are similar to those of epizone chlorites in the literature. The results of this work show that the metamorphic grade of the Jigunsan Formation belongs to the epizone and the formation is believed to have been reached paleotemperatures of at least 300${\circ}C$.

• Journal of the Mineralogical Society of Korea
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• v.24 no.3
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• pp.165-178
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• 2011

The potential of petroleum generation was investigated by clay mineralogical changes of illite-smectite on the sedimentary basins: Tertiary Pohang basin and Cretaceouls Gyeongsang basin on land, and offshore basins east and west of Korea. Only disordered illite-smectite mixed layer minerals occur in the Pohang sediment, where petroleum generation cannot be expected due to low temperatures below $100^{\circ}C$. By contrast, the Gyeongsang basin is characterized by the occurrence of illite and high temperatures above $200^{\circ}C$ which are obtained by illite crystallinity. The high temperatures indicate that the Gyeongsang sediment ha, already passed through the oil generation stage. The change of disordered illite-smectite to R-l ordered illite-smectite is shown in the sediment of the East Sea continental shelf area at a depth of 2,500 m. Therefore, the oil generation can be expected in the sediments below the depth of 2,500 m. The sequential change of disordered illite-smectie to R=3 ordered illite-smectite through R=l ordered illite-smectite occurs in the sediments of West Sea continental shelf area with burial depth which shows the favorable condition for oil and gas generation. The temperatures of sediments measured by illite-smectite indicate that hydrocarbon potential is very low in the onland basins but high in the continental shelf areas.

• Journal of the Mineralogical Society of Korea
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• v.32 no.3
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• pp.163-172
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• 2019

A long core (RS15-LC48) was collected at a site in the continental rise between the Southern Ocean and the Ross Sea (Antarctica) during the 2015 Ross Sea Expedition. The mineralogical characteristics and the origin of clay minerals in marine sediments deposited during the Quaternary in the Ross Sea were determined by analyzing sedimentary facies, variations in grain size, sand fraction, mineralogy, clay mineral composition, illite crystallinity, and illite chemical index. Core sediments consisted mostly of sandy clay, silty clay, or ice rafted debris (IRD) and were divided into four sedimentary facies (units 1-4). The variations in grain size distribution and sand content with depth were very similar to the variations in magnetic susceptibility. Various minerals such as smectite, chlorite, illite, kaolinite, quartz, and plagioclase were detected throughout the core. The average clay mineral composition was dominated by illite (52.7 %) and smectite (27.7 %), with less abundant clay minerals of chlorite (11.0 %) and kaolinite (8.6 %). The IC and illite chemical index showed strong correlation trends with depth. The increase in illite and chlorite content during the glacial period, together with the IC and chemical index values, suggest that sediments were transported from the bedrocks of the Transantarctic Mountains. During the interglacial period, smectite may have been supplied by the surface current from Victoria Land, in the western Ross Sea. High values for IC and the illite chemical index also indicate relatively warm climate conditions during that period.

• Journal of the Mineralogical Society of Korea
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• v.25 no.3
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• pp.163-173
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• 2012

In this study, we determined the relative clay mineral composition of 51 surface sediments from SEYSM (Southeastern Yellow Sea Mud) (northern part 25, southern part 26) and 30 river sediments inflow to Yellow Sea using the semi-quantitative X-ray diffraction analyses. In addition to we analyzed illite characteristics of the same samples. The clay-mineral assemblage is composed of illite (61~75%), chlorite (14~24%), kaolinite (9~14%), and smectite (1~7%), in decreasing order. The average composition of each clay mineral is not different from northern part to southern part of SEYSM except a little higher kaolinite and lower smectite content in northern part. Smectite content generally has reverse relationship with illite content. Mineralogical characteristics of illite such as illite crystallinity index also is not different between two areas and show very narrow range (0.18~0.24 ${\Delta}^{\circ}2{\theta}$). Our results reveal that clay mineral composition and illite characteristics are nearly the same between northern and southern part of SEYSM. Characteristics of surface sediments in SEYSM is closer to Korean river sediments than Chinese Hanghe sediments, however it is necessary to investigate further study including Yangtze river sediments. This study conclude that most of surface sediments in SEYSM attribute to the supply of considerable amount of sediments from the nearby Korean rivers. The large sediment budget and high accumulation rate in the SEYSM can be explained by erosion and reworking of surface sediments in this area. Tidal and regional current system around SEYSM might contribute these erosional and depositional regimes.

• Journal of the Korean earth science society
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• v.23 no.7
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• pp.575-586
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• 2002

Authigenic minerals found in sandstones and mudrocks of the Lower Hayang Group (Cretaceous) in the central part of the Kyungsang Basin are carbonate minerals (calcite, dolomite), clay minerals (illite, chlorite, C/S, I/S and kaolinite), albite, quartz and hematite. Characteristic diagenetic mineral assemblages are as follows: albite-chlorite (including C/S)-hematite in the Chilgog Formation, albite-illite-calcite in the Silla Conglomerate, illite-chlorite-hematite in the Haman Formation and albite-chlorite-dolomite in the Panyawol Formation, respectively. Among clay minerals reflecting the physical and chemical change of the diagenetic process, illite, the dominant clay mineral, occurs in every formation in the study area. Chlorite occurs mainly in green or gray sandstones and mudrocks, or in sandstones and mudrocks of the Chilogok Formation which contains a high content of volcanic materials. Based on the mineral assemblage, diagenetic minerals are strongly related with source rocks. Judging from the illite crystallinity, diagenesis of sandstones and mudrocks in the study area reached the late diagenetic stage or low grade metamorphisim. The diagenetic process was much influenced by intrusion of the Bulguksa granite, content of organic materials, grain size, and depositional environment rather than burial depth.

• Korean Journal of Soil Science and Fertilizer
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• v.7 no.3
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• pp.127-135
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• 1974

The samples were taken from the following localities previously classified as "Akiochi" area: Yangpyung, Puchun, and Pyungtaik, all of Kyonggi-do province. Five soil profiles were described in the field, and taken to the laboratory for physical and chemical analysis and mineralogical analysis by X-ray diffraction. The predominant clay minerals consist mainly of illite, vermiculite, chlorites and intergrade with vermiculite, and kaolinite. Illite or mica was found present in all samples and in all horizons. This was identified by the 9.83 to $10{\AA}$ (0.01) and $3.32{\AA}$ (003) basal reflections, Interhorizontal variations in mineral content and crystallinity are illustrated in their respective Xray diffractogram. Comparing the peak intensity, of the $14{\AA}$, $10{\AA}$ and $7{\AA}$ indicated the degree of weathering from the surface to the lower horizons. In general, the weathering of illite on the surface produced less pronounced $10{\AA}$ and $14{\AA}$ peak as compared to the lower horizons. The same may be said with kaolinite. On K-saturation, the $14{\AA}$ peak broadening on the low angle side was observed. This is interpreted to be due to chlorization. Heat treament from $100^{\circ}C$, $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$, and $800^{\circ}C$. caused significant changes in the different diffractograms. Heating caused collasped of the $14{\AA}$ to $10{\AA}$ and the appearance of scattered peaks between $10-14{\AA}$. This is interpreted to the presence of vermiculite chlorite intergradient. The complete collapse of the $14{\AA}$ at $800^{\circ}C$ to $10{\AA}$ with increased intensity was attributed to the preservce of vermiculite. The principal difference among the clay minerals in each horizon is the concomitant increase and decrease in intensity with depth of the $14{\AA}$, $10{\AA}$ and $7{\AA}$ diffraction spacings. Apparently the weathering of illite ($10{\AA}$) is resulting in the formation of vermiculite ($14{\AA}$) and the interstratified material being an intermediate stage and the beginning of the formation of vermiculite. Some broadening- in the 17 to $18{\AA}$ was observed in Puchun-1 Pyungtaik-1 and Pyungtaik-2 specially so in the lower horizon in the Ca or Mg-saturated sample. Heated treatment tend to shift this peak to $14{\AA}$ indicating the presence of regular layering of the interstratified complex. The high amount of extractable aluminum and iron coupled with low exchange capacity indicate that iron and aluminum plays an important role in the weathering of these soils and is responsible to the low exchange capacity, high acidity and high phosphate absorptive capacity. The results presented substantiated the weathering sequence of Jackson in that mica ${\rightarrow}$ vermiculite ${\rightarrow}$ chloritezed vermiculite ${\rightarrow}$ kaolinite.

• Journal of the Mineralogical Society of Korea
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• v.1 no.1
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• pp.48-62
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• 1988

The high aluminous meta-claystones are thinly bedded to metasedimentary rocks which belong to Chununsan Formation. Major high aluminous minerals in the ores ae andalusite, kaolinite and pyrophyllite. The other significant constituents are sericite, chloritoid and carbonaceous material, etc. Ores can be classified into 4 types according to mineral compositions; andalusite- kolinite-sericite, andalusite-kaolinite-chloritoid, kaolinite-sericite-pyrophyllite, and kaolinite-chloritoid-sericite ore. The formation of ore minerals are resulted from sedimentary, diagenetic, metamorphic and hydrothermal processes. Andalusite are formed by low-grade metamorphism under the conditions of $400~500^{\circ}C$ and below 4kb, from the view-point of mineral stability field, illite-mica crystallinity and graphitization degree of the carbonaceous material. Andalusites are partly altered to kaolinite, forming major mineral phase in the ores.

• Economic and Environmental Geology
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• v.32 no.3
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• pp.293-306
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• 1999

The lower Permian jungseong Formation, Taebaegsan basin (Baegunsan Syncline), represents a coal-bearing siliciclastic succession which was later modified by the Songrim or Dabo orogeny. Sandstone perography and clay mineralogy were studied to understand the thermal history of the Jangseong Formation during basin evolution. Petrographic study indicates the Jangseong sandstones are composed of quartz, feldspar, lithic fragments (metamorphic and sedimetary), and varying proportions of matrix and cement. The dominance of quartz(<97%) over feldspar (<1%) and lithic fragments (<2%) classifies most Jangseong sandstones as quartz arenotes or quartzwackes, but lithic graywackes and sublithic arenite locally occur. The diagentic features of these sandstones include mechanical compaction, cemenation by quartz and clay minerals indentified in the Jangseong Formation by X-ray diffraction analysis are late-stage clay pore-filling. Clay minerals isdentified in the Jangseong Formation by X-ray diffaction analysis are illite, kaolinte, and pyrophyllite with a minor amount of chlorite and micas. The illite, kaolinite, and pyrophyllite appear to be largely autjigenic based on their well-crystallinity forms. There authigenic clay minerals form clay minerals form clay coats/rims and late-stage pore-filling cements, Illitecrystallinity shows that the Jangseong formation has been in late-diagenetic zone to early-epizone, which ranges in temperature from $200^{\circ}C$ to $300^{\circ}C$. In assition, kaolinite-pyrophyllite transition suggests that paleotemperature of the formation has reached at least $265^{\circ}C$. Such temperatureis likely to be consistent with homogenixation temperatures of fluid inclusions in quartz veins in the formation. Thus, the Jangseong Formation has been subjected to paleotemperature of about $265^{\circ}C$. The major heat source responsible for paleotemperature may be hydrothermal solutions. The passage of hydrothermal solutions was probably assisted by fractures created during the basin-modifying tectonism of the taebaegsan basin.

• Journal of the Mineralogical Society of Korea
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• v.21 no.4
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• pp.397-413
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• 2008

In Gaya area, the Boseong kaolin deposits exhibit locally unusual occurrences such as downward enrichment of kaoin minerals, characteristic hydrothermal alterations (illite and stilbite), and phase relations among kaolin minerals in addition to the extensive weathering of anorthositic country rocks. This indicates that the kaolin deposits seem to be genetically formed as a mixed hydrothermal and residual model. The kaolin ores can be divided into five types on the basis of differences in occurrence, mineral composition and characters. These consist of two types of high-grade ores ranging above 80% in grade and low-grade ores as low as less than 80% including feldspar residuals or the peculiar impurity phase of illite-vermiculite-stilbite. Halloysite and kaolinite are mostly coexisted in the Boseong kaolin, and these kaolin minerals exhibit diverse appearances in crystallinity and morphology. Such a diversity in mineral phase and crystallinity seems to be originated from the complexity in genesis. In addition to these diverse characters of the kaolin, its applied-mineralogical characteristics such as chemical composition, thermal properties, whiteness, viscosity, and etc. made it disadvantageous in terms of ore quality.