• Title/Summary/Keyword: id reaction

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Extinction Limits of Low Strain Rate Counterflow Nonpremixed Flames in Normal Gravity (정상 중력장에서 낮은 스트레인율을 갖는 대향류 비예혼합화염의 소화한계)

  • Oh, Chang-Bo;Choi, Byung-Il;Kim, Jeong-Soo;Hamins, Anthony;Park, Jeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.9 s.240
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    • pp.997-1005
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    • 2005
  • The extinction characteristics of low strain rate normal gravity (1-g) nonpremixed methane-air flames were studied numerically and experimentally. A time-dependent axisymmetric two-dimensional (2D) model considering buoyancy effects and radiative heat transfer was developed to capture the structure and extinction limits of 1-g flames. One-dimensional (1D) computations were also conducted to provide information on 0-g flames. A 3-step global reaction mechanism was used in both the 1D and 2D computations to predict the measured extinction limit and flame temperature. A specific maximum heat release rate was introduced to quantify the local flame strength and to elucidate the extinction mechanism. Overall fractional contribution by each term in the energy equation to the heat release was evaluated to investigate the multi-dimensional structure and radiative extinction of 1-g flames. Images of flames were taken for comparison with the model calculation undergoing extinction. The two-dimensional numerical model was validated by comparing flame temperature profiles and extinction limits with experiments and ID computation results. The 2D computations yielded insight into the extinction mode and flame structure of 1-g flames. Two combustion regimes depending on the extinction mode were identified. Lateral heat loss effects and multi-dimensional flame structure were also found. At low strain rates of 1-g flame ('Regime A'), the flame is extinguished from the weak outer flame edge, which is attributed to multi-dimensional flame structure and flow field. At high strain rates, ('Regime B'), the flame extinction initiates near the flame centerline due to an increased diluent concentration in reaction zone, which is the same as the extinction mode of 1D flame. These two extinction modes could be clearly explained with the specific maximum heat release rate.

Null Allele in the D18S51 Locus Responsible for False Homozygosities and Discrepancies in Forensic STR Analysis

  • Eom, Yong-Bin
    • Biomedical Science Letters
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    • v.17 no.2
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    • pp.151-155
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    • 2011
  • Short tandem repeats (STRs) loci are the genetic markers used for forensic human identity test. With multiplex polymerase chain reaction (PCR) assays, STRs are examined and measured PCR product length relative to sequenced allelic ladders. In the repeat region and the flanking region of the commonly-used STR may have DNA sequence variation. A mismatch due to sequence variation in the DNA template may cause allele drop-out (i.e., a "null" or "silent" allele) when it falls within PCR primer binding sites. The STR markers were co-amplified in a single reaction by using commercial PowerPlex$^{(R)}$ 16 system and AmpFlSTR$^{(R)}$ Identifiler$^{(R)}$ PCR amplification kits. Separation of the PCR products and fluorescence detection were performed by ABI PRISM$^{(R)}$ 3100 Genetic Analyzer with capillary electrophoresis. The GeneMapper$^{TM}$ ID software were used for size calling and analysis of STR profiles. Here, this study described a forensic human identity test in which allelic drop-out occurred in the STR system D18S51. During the course of human identity test, two samples with a homozygous (16, 16 and 21, 21) genotype at D18S51 locus were discovered using the PowerPlex$^{(R)}$ 16 system. The loss of alleles was confirmed when the samples were amplified using AmpFlSTR$^{(R)}$ Identifiler$^{(R)}$ PCR amplification kit and resulted in a heterozygous (16, 20 and 20, 21) genotype at this locus each other. This discrepancy results suggest that appropriate measures should be taken for database comparisons and that allele should be further investigated by sequence analysis and be reported to the forensic community.

Oxygen Ring Formation Reaction of Mono-Oxo Bridged Binudear Molybdenum (Ⅴ) Complex (Ⅲ). Reaction of $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ with solvent Water in Binary Aqueous Mixtures (한개의 산소다리를 가진 몰리브덴(V) 착물의 산소고리화 반응 (제 3 보). 2 성분 혼합용매에서 용매물과 $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$의 반응)

  • Sang Oh Oh;Huee Young Seok
    • Journal of the Korean Chemical Society
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    • v.32 no.6
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    • pp.528-535
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    • 1988
  • The rates of oxygen ring formation of $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ have been investigated spectrophotometric method in binary aqueous mixtures. Temperature was $20^{\circ}C$ to $40^{\circ}C$ and pressure was varied up to 1500 bar. The observed rate constants are increased by hydrogen ion and decreased by thiocyanate. The more increasing of co-solvents dielectric constant, the more stable intermediate is formed. The observed rate constant is given by, $k_{obs}^{-1} = k^{-1} (1 + K^{-1}[H_2O]^{-1}) All activation parameters are positive values. The oxygen ring formation of [Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ is believed to be a interchange-dissociative mechanism..

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Hydrogen Production through High Temperature Steam Electrolysis System (고온 수증기 전해 수소제조)

  • Choi, Ho-Sang
    • Membrane Journal
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    • v.19 no.1
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    • pp.1-6
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    • 2009
  • Hydrogen energy id the 2nd clean energy able to be produced from the abundant resources, and the products of combustion or reaction do not spread an environmental pollution. Also, the hydrogen is the chemical media easily to transport and storage as energy source. The hydrogen production technology using by water splitting through electrolysis could be usable as a permanent renewable energy system without the environmental impact. The key technology of high temperature steam electrolysis is the development of an electrolyte rapidly to conduct an oxygen or proton ion decomposed from water. Subsequently, the important technology is to keep the joining technology of an electrolyte membrane and electrode materials to affect into the current efficiency.

Forensic STR Analysis of Mixed Chimerism after Allogeneic Bone Marrow Transplantation

  • Eom, Yong-Bin
    • Biomedical Science Letters
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    • v.16 no.3
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    • pp.193-196
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    • 2010
  • Multiplex PCR-based short tandem repeat (STR) analysis is considered as a good tool for monitoring bone marrow engraftment after sex-mismatched allogeneic transplantation and provides a sensitive and accurate assessment of the contribution of both donor and/or recipient cells in post-transplantation specimens. Forensic STR analysis and quantitative real time PCR are used to determine the proportion of donor versus recipient each contained within the total DNA. The STR markers were co-amplified in a single reaction by using commercial $PowerPlex^{(R)}$ 16 system and $AmpFISTR^{(R)}$ $Identifiler^{(R)}$ / $Yfiler^{(R)}$ PCR amplification kits. Separation of the PCR products and fluorescence detection were performed by ABI $PRIS^{(R)}$ 3100 Genetic Analyzer with capillary electrophoresis. The $GeneMapper^{TM}$ ID software were used for size calling and analysis of STR profiles. Extracted DNA was quantified by the $Quantifiler^{TM}$ Human DNA / Y Human Male DNA Quantification Kit The intent of this study was to analyze the ratio of donor versus recipient cells in the post-transplant peripheral blood, spleen, lung and kidney specimens. Specimens were taken from the traffic accident male victim who had been engrafted from bone marrow female donor. Blood and spleen specimens displayed female donor DNA profile. Kidney specimen showed male recipient DNA profile. Interestingly, lung tissue showed mixed profiles. The findings of this study indicate that the forensic STR analysis using fluorescence labeling PCR combined with capillary electrophoresis is quick and reliable enough to assess the ratio of donor versus recipient cells and to monitor the mixed chimeric patterns.

Study on high performance cathode on YSZ electrolyte for intermediate-temperature solid oxide fuel cells(IT-SOFC) (중온형 고체산화물 연료전지를 위한 YSZ 전해질에서의 고성능 공기극 연구)

  • Lee, Chang-Bo;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.368-371
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    • 2006
  • [ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

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A study on the oxidation characteristics of Polybutadiene & Polyisoprene containing various types of antioxidants by DSC (산화방지제(酸化防止劑)를 배합(配合)한 Polybutadiene과 Polyisoprene의 DSC에 의(依)한 산화특성(酸化特性) 연구(硏究))

  • Yoo, Chong-Sun;Choi, Seoi-Young;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.18 no.4
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    • pp.140-147
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    • 1983
  • The purpose of this dissertation is to increase oxidation resistance for Polybutadiene & Polyisoprene, and to investigate the energetics of inhibited oxidation of Polybutadiene & Polyisoprene stabilized with various types of antioxidants using DSC. The results of the study are as fellows: 1. In the DSC SCREEN for the onset temperature of oxidation, Polybutadiene was faster than Polyisoprene for the samples containing no antioxidant in air. 2. In the DSC evaluation for Polybutadiene, Recipe BG-4 with 2.0phr compounds of antioxidant was the best effective, and Recipe BS-4 with 2.0phr compounds of antioxidant was the worst effective, and the degrees of effect of antioxidant were exhibited in the ranking of G-1, D, BHT, and SP, roughly. 3. In the DSC evaluation for the Polyisoprene, Recipe IG-4 with 2.0phr compounds of antioxidant was the best effective, and Recipe ID-4 with 2.0phr compounds of antioxidant was the worst effective, and the degrees of effect of antioxidant were exhibited in the ranking of G-1, SP, BHT, and D roughly. 4. In the study on enthalpy which depends on exothermal reaction, the enthalpy of Polyisoprene was gloater than that of Polybutadiene. However, the problem was not solved completely, and it needs further studies.

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Insertion/Deletion Polymorphism of the Angiotensin Converting Enzyme Gene in Coronary Artery Disease in Southern Turkey

  • Acarturk, Esmeray;Attila, Gulen;Bozkurt, Abdi;Akpinar, Onur;Matyar, Selcuk;Seydaoglu, Gulsah
    • BMB Reports
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    • v.38 no.4
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    • pp.486-490
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    • 2005
  • Genetic factors are important in the pathogenesis of coronary artery disease (CAD). Angiotensin converting enzyme (ACE) gene insertion(I)/deletion(D) polymorphism is one of the genetic factor found to be related with CAD. We investigated the association between I/D polymorphism of the ACE gene and the presence of CAD. Threehundred and seven patients (187 males and 120 females, aged between 35-80, mean $54.3{\pm}9.8$ years) who underwent diagnostic coronary angiography were included in the study. ACE I/D polymorphism was detected by polymerase chain reaction. Of the 307, 176 had CAD. The most frequently observed genotype in all subjects was ID (47.9 %). However, in patients with CAD the frequency of II genotype was lower whereas DD genotype was higher compared to the controls (p < 0.05). The number of D allele carrying subjects were also higher (p < 0.05) in CAD patients. The logistic regression analysis indicated that the ACE D allele is an independent risk factor (odds ratio = 1.48, 95% CI = 1.01-2.18, p < 0.05). In conclusion, the I/D polymorphism of ACE gene (carrying D allele) is an independent risk factor for CAD in the studied Turkish population.

Studies on Characteristics of $ZnCa_2O_4$ Prepared by Glycine Nitrate Process anti S01id State Reaction for FE8 Phosphor (GNP법과 고상반응법으로 제조한 FED 형광체용 $ZnCa_2O_4$ 분말의 특성에 관한 연구)

  • Sin, Han;Park, Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.91-95
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    • 1999
  • PED용 형광체로 사용되는 ZnCa$_2$O$_4$를 Clycine Nitrate Process로 합성하여 고상 반응법으로 합성한 ZnCa$_2$O$_4$ 분말과 비교 분석하였다. 또한 Glycine Nitrate Process로 제조시 Mn의 doping 농도를 변화시키면서 각각의 조성비에 따른 발광특성을 알아보았다. TGA 측정 결과 GNP법으로 합성된 ZnCa$_2$O$_4$ 의 경우 약 40$0^{\circ}C$ 이상에서 무게감량의 변화가 없었으며, XRD 상분석 결과 연소반응 후 이미 상형성이 이루어짐을 알 수 있었다. PL측정을 결과 GNP(GIycine Nitrate Process)로 제조된 ZnCa$_2$O$_4$분말의 발광효율이 고상 반응법으로 제조된 분말보다 우수하였으며, 균일하고 비표면적이 큰 단일상임이 관찰되었고, 더 작은 에너지와 시간으로 제조할 수 있는 장점이 있었다

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Multi-Certification of Agent System Using XML (XML 전자서명을 이용한 다중인증 멀티 에이전트시스템)

  • J. Kim, Kui-Nam
    • Convergence Security Journal
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    • v.5 no.1
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    • pp.29-34
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    • 2005
  • Internet becomes absolutely necessary tools due to rapid progress of information technology. Educational correspondence about an age of information demand is focused on a learner and remote education based on information technology WBI(Web Based Instruction) is a formation that remotly educate a learner using web, possible mutual reaction between instructor and learner, submit various studying material, has a good point to overcome spatial restriction. Internal and external standardization working is accelerated and recently XML security studies are activated using XML which is next generation web standard document format. In this paper, we propose multi-Certification of agent system using XML digital signature to satisfy security requirement.

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