• Title/Summary/Keyword: i-layer

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Enhanced Efficiency of Nanoporous-layer-covered TiO2 NanotubeArrays for Front Illuminated Dye-sensitized Solar Cells

  • Kang, Soon-Hyung;Lee, Soo-Yong;Kim, Jae-Hong;Choi, Chel-Jong;Kim, Hyunsoo;Ahn, Kwang-Soon
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.52-57
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    • 2016
  • Nanoporous-layer-covered TiO2 nanotube arrays (Type II TNTs) were fabricated by two-step electrochemical anodization. For comparison, conventional TiO2 nanotube arrays (Type I TNTs) were also prepared by one-step electrochemical anodization. Types I and II TNTs were detached by selective etching and then transferred successfully to a transparent F-doped SnO2 (FTO) substrate by a sol-gel process. Both FTO/Types I and II TNTs allowed front side illumination to exhibit incident photon-to-current efficiencies (IPCEs) in the long wavelength region of 300 to 750 nm without the absorption of light by the iodine-containing electrolyte. The Type II TNT exhibited longer electron lifetime and faster charge transfer than the Type I TNT because of its relatively fewer defect states. These beneficial effects lead to a high overall energy conversion efficiency (5.32 %) of the resulting dye-sensitized solar cell.

Secrecy Performances of Multicast Underlay Cognitive Protocols with Partial Relay Selection and without Eavesdropper's Information

  • Duy, Tran Trung;Son, Pham Ngoc
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.9 no.11
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    • pp.4623-4643
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    • 2015
  • This paper considers physical-layer security protocols in multicast cognitive radio (CR) networks. In particular, we propose dual-hop cooperative decode-and-forward (DF) and randomize-and-forward (RF) schemes using partial relay selection method to enhance secrecy performance for secondary networks. In the DF protocol, the secondary relay would use same codebook with the secondary source to forward the source's signals to the secondary destination. Hence, the secondary eavesdropper can employ either maximal-ratio combining (MRC) or selection combining (SC) to combine signals received from the source and the selected relay. In RF protocol, different codebooks are used by the source and the relay to forward the source message secretly. For each scheme, we derive exact and asymptotic closed-form expressions of secrecy outage probability (SOP), non-zero secrecy capacity probability (NzSCP) in both independent and identically distributed (i.i.d.) and independent but non-identically distributed (i.n.i.d.) networks. Moreover, we also give a unified formula in an integral form for average secrecy capacity (ASC). Finally, our derivations are then validated by Monte-Carlo simulations.

Magnetism and Magnetocrystalline Anisotropy at fcc Fe (001) Surface

  • Yun, Won-Seok;Cha, Gi-Beom;Hong, Soon-Cheol
    • Journal of Magnetics
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    • v.13 no.4
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    • pp.144-148
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    • 2008
  • The size and surface effects on the magnetism of a fcc Fe (001) surface was investigated by performing firstprinciples calculations on 3, 5, 7, and 9 monolayers fcc Fe (001) single slabs with two different two-dimensional lattice constants, ${\alpha}=3.44{\AA}$ (System I) and 3.65 ${\AA}$ (System II), using the all-electron full-potential linearized augmented plane wave method within a generalized gradient approximation. The surface layers were coupled ferromagnetically to the subsurface layer in both systems. However, the magnetism of the inner layers was quite different from each other. While all the inner layers of System II were ferromagnetically coupled in the same way as the surface layer, the inner layers of System I showed a peculiar magnetism, bilayer antiferromagnetism. The calculated spin magnetic moments per Fe atom were approximately 2.7 and 2.9 ${\mu}_B$ at the surface for Systems I and II, respectively, due to the almost occupied Fe d-state being in the majority spin state and band narrowing. The spin orientations of System I were out-of-plane regardless of its thickness, whereas the orientation of System II changed from out-of-plane to in-plane with increasing thickness.

Two-step Electroless Plated Pt Ohmic Contacts to p-type InGaAs

  • Im, Hung-Su;Wang, Kai;Kim, Geun-Woo;Chang, Ji-Ho;Koo, Bon-Heun
    • Journal of the Korean institute of surface engineering
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    • v.43 no.2
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    • pp.47-50
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    • 2010
  • This work discusses a two-step electroless plating method for preparing a Pt thin film on p-type InGaAs substrate, which is defined as Pt I and Pt II. A thin Pt catalytic layer formed in Pt I bath on the substrate at $65^{\circ}C$. In the following Pt II bath, thick Pt films then easily grew on the sensitized layer on InGaAs previously formed in the Pt I bath. The growth of Pt film is strongly influenced by the plating temperature and pH value. To study the plating time effect, the plating of Pt II bath is 5 to 40 min at $80^{\circ}C$ after using Pt I bath at 50~$65^{\circ}C$ for 5min of pH 8~13. Pt film for ohmic contact to p-type InGaAs was successfully prepared by using the two-step Pt electroless plating.

Developmental Changes of the Oocyte and Its Enveloping Layers, in Micropercops swinhonis (Pisces: Perciformes)

  • Park, Jong-Young;Richardson, Ken-C.Richardson;Kim, Ik-Soo
    • Animal cells and systems
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    • v.2 no.4
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    • pp.501-506
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    • 1998
  • In the goby Micropercops swinhonis, the development of its egg's enveloping layers could be divided into 4 stages. In the earliest developmental period, stage I, there is a simple oocyte surrounded by a layer of squamous follicular cells. Stage II corresponds to the yolk vesicle stage of vitellogenesis. Here the initial follicular layer has become bilaminar with the retention of its outer squamous cell layer and the acquisition of an inner cuboidal cell layer just over the zona radiata. The number and size of the cuboidal cells increases throughout this stage. Stage III corresponds to the yolk granule stage of true vitellogenesis. Here the cuboidal cells begin to be replaced by columnar cells. As the oocyte grows, the columnar cells increase in size. The columnar cells produce cytoplasmic neutral mucins and by the end of this stage their cytoplasm has been filled with this mucin. In stage IV a single layer of squamous cells still remained as the outer follicular layer of the oocyte. The secretory activity of the inner follicular layers' columnar cells has ceased and they had lost their cell wall integrity and ended as a series of bullet-shaped, neutral mucin deposits.

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Electrolytic Boronizing on Carbon Steels in Fused Slat of Borax and Sodium Chloride Mixture (붕사와 염화나트륨 혼합용융욕에서 탄현강의 전해붕화처리)

  • 이두환;김정기;김한삼;김수식
    • Journal of the Korean institute of surface engineering
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    • v.30 no.1
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    • pp.23-32
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    • 1997
  • The electrolytic boronizing on carbon steels in the mixture of $Na_2B_4O_7$ and NaCl was conducted at 750~$950^{\circ}C$ for 1~6 hours under 0.5A/$\textrm{cm}^2$ current density. The micorostructrure and microheredness of boronized layer was also studien. The effect of the additive such as $CaCl_2$ or NaOH on the formation of boronized layer was also investigated. The boronized layer were composed of two sublayers, i.e., FeB and $Fe_2B$ , which have tooth structure. the average layer thinknesses of the low carbon steel and SM45C boronized at $900^{\circ}C$ for 4hours were 153 and 138 $\mu\textrm{m}$, respectively. The thickness of the twosublayers was significantly increased with increasing boronizing temperature. To obtain a single $Fe_2B$ layer without FeB sublayer, the boronized materials ware homegenized at $950^{\circ}C$ for 4 hours. It was fount that the single layer with a microhardness Hv$\thickapprox$ 1120 -1250 was formed. The calculated activation energies for formation of boronized layer on the low carbon steel and SM45C were 18.7 and 12.6 Kcal/mol, respectively.

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The magnetic characteristics of Co-Cr-(Ta) films (Co-Cr-(Ta)박막의 자기특성)

  • Kim, K-H;Jang, K-U;Kim, J-H;S Nakagawa;M Naoe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.242-244
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    • 1996
  • The effects of $Co_{67}$C $r_{33}$ underlayer on the crystallographec and magnetic characteristics of the Co-Cr-Ta layer deposited on the underlayer was investigated. The diffraction intensity $I_{p(002)}$ of Co-Cr-Ta layers on the $Co_{67}$C $r_{33}$ layer was stronger than that of single layer and Co-Cr-Ta/Ti double layer. Therefore, the crystallinity of Co-Cr-Ta layer was improved by the $Co_{67}$C $r_{33}$ underlayers rather than Ti ones. However, the coercivity $H_{c}$ of Co-Cr-Ta layers deposited on $Co_{67}$C $r_{33}$ underlayer was as low as 250 Oe even at substrate temperature of 22$0^{\circ}C$. This $H_{c}$ decrease seems to be attributed to the effect of the $Co_{67}$C $r_{33}$ underlayer as well as interval time between deposition of the underlayer and the Co-Cr-Ta layer.yer.layer.yer.

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Property analysis of multi layer Organic Light Emitting Diodes using equivalent circuit models (등가 회로 모델을 이용한 다층 유기발광 소자의 특성 분석)

  • Park, Hyung-Jun;Kim, Hyun-Min;Yi, Jun-Sin;Nam, Eun-Kyoung;Jung, Dong-Geun
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.119-120
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    • 2006
  • The impedance spectroscopy is one of the effective ways to understand the electrical properties of organic light emitting diodes. The frequency-dependant properties of small molecule based OLEDs have been studied. The equivalent circuit of single-layer device is composed of contact resistance ($R_c$), bulk resistance ($R_p$) and bulk capacitance ($C_p$). The equivalent circuit of double layer device is composed of two parallel circuits connected in series, each of which is a parallel resistor and a capacitor. We have fabricated a double layer device indium-rio-oxide (ITO, anode), N,NV -diphenyl- N,NV -bis(3-methylphenyI)-1,1V -diphenyl-4,4V-diamine (TPD, hole-transporting layer), tris-(8-hydroxyquinoline) aluminum (Alq3, emitting layer), and aluminum (AI, cathode) and two single layer devices ([TO/ Alq3/ AI, ITO/TPD/AI).

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Improving printability by designing a multi-layered coating structure (I) - The effect of binder properties in the pre-coating layer on the characteristics of the top-coating layer - (다층도공층의 설계에 의한 인쇄적성 개선 (제1보) - 프리코팅층의 바인더 물성이 탑코팅층의 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Won, Jong Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.27-33
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    • 2016
  • This study was carried out in order to investigate the effect of binder properties in pre-coating layer on the characteristics of top-coating layer and print mottle of coated paper. Four different latices were used as a binder in pre-coating layer, and coating color prepared with a same formulation was applied for top-coating. The properties and print mottle of coated paper were evaluated. It was found that glass transition temperature (Tg) was the important factor to control the properties of pre- and top-coating layer. PPS roughness of coated paper was decreased and paper gloss was increased with applying binder which has lower Tg. Properties of top-coating layer were affected by the binder used in pre-coating layer. Print mottle of coated paper was improved with using binder which has lower Tg in pre-coating layer. These results indicate that final printability and properties of top-coating layer can be improved with using suitable binder in pre-coating layer.

Chimie Douce Reaction to Layered High-$T_c$ Superconducting / Super-ionic Conducting Heterostructures

  • Kim, Young-Il;Hwang, Seong-Ju;Yoo, Han-Ill;Choy, Jin-Ho
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.95-98
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    • 1998
  • We have developed new type of superconducting-superionic conducting nanohybrids, $Ag_xI_wBi_2Sr_2Ca_{n-1}Cu_nO_y$ (n=1 and 2) by applying the chimie douce reaction to the superconducting Bi-based cuprates. These nanohybrids can be achieved by the stepwise intercalation whereby the $Ag^+$ ion is thermally diffused into the pre-intercalated iodine sublattice of $IBi_2Sr_2Ca_{n-1}Cu_nO_y$. According to the X-ray diffraction analysis, the Ag-I intercalates are found to have an unique heterostructure in which the superionic conducting Ag-I layer and the superconducting $IBi_2Sr_2Ca_{n-1}Cu_nO_y$ layer are regularly interstratified with a remarkable basal increment of ~7.3$\AA$. The systematic XAS studies demonstrate that the intercalation of Ag-I accompanies the charge transfer between host and guest, giving rise to a change in hole concentration of $CuO_2$ layer and to a slight $T_c$ change. The Ag K-edge EXAFS result reveals that the intercalated Ag-I has a $\beta$-AgI-like local structure with distorted tetrahedral symmetry, suggesting a mobile environment for the intercalated $Ag^+$ ion. In fact, from ac impedance analyses, we have found that the Ag-I intercalates possess a fast ionic conductivity ($\sigma_i=10^{-1.4}\sim 10^{-2.6}\Omega^{-1}\textrm{cm}^{-1}\;at\;270^{\circ}C$ with an uniform activation energy ($\DeltaE_a=0.22\pm 0.02$ eV). More interesting finding is that these intercalates exhibit high electronic conducting as well as ionic ones ($t_i$=0.02~0.60) due to their interstratified structure consisting of superionic conducting and superconducting layers. In this respect, these new intercalates are expected to be useful as an electrode material in various electrochemical devices.

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