• Title/Summary/Keyword: hydrophobic resin

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In vitro study of Streptococcus mutans adhesion on composite resin coated with three surface sealants

  • Kim, Da Hye;Kwon, Tae-Yub
    • Restorative Dentistry and Endodontics
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    • v.42 no.1
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    • pp.39-47
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    • 2017
  • Objectives: Although the coating of surface sealants to dental composite resin may potentially reduce bacterial adhesion, there seems to be little information regarding this issue. This preliminary in vitro study investigated the adhesion of Streptococcus mutans (S. mutans) on the dental composite resins coated with three commercial surface sealants. Materials and Methods: Composite resin (Filtek Z250) discs (8 mm in diameter, 1 mm in thickness) were fabricated in a mold covered with a Mylar strip (control). In group PoGo, the surfaces were polished with PoGo. In groups PS, OG, and FP, the surfaces polished with PoGo were coated with the corresponding surface sealants (PermaSeal, PS; OptiGuard, OG; Fortify Plus, FP). The surfaces of the materials and S. mutans cells were characterized by various methods. S. mutans adhesion to the surfaces was quantitatively evaluated using flow cytometry (n = 9). Results: Group OG achieved the lowest water contact angle among all groups tested (p < 0.001). The cell surface of S. mutans tested showed hydrophobic characteristics. Group PoGo exhibited the greatest bacterial adhesion among all groups tested (p < 0.001). The sealant-coated groups showed statistically similar (groups PS and FP, p > 0.05) or significantly lower (group OG, p < 0.001) bacterial adhesion when compared with the control group. Conclusions: The application of the surface sealants significantly reduced S. mutans adhesion to the composite resin polished with the PoGo.

Separation and Purification of Teicoplanin by Diaion HP-20 and Conacnavalin A Chromatography (소수성 Diaion HP-20및 친화성 Concannvalin A 크로마토그래피를 이용한 Glycopeptide계 항생제 Teicoplanin의 분리 및 정제)

  • 김창진;이재찬;박해룡;박동진;김영배
    • Microbiology and Biotechnology Letters
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    • v.31 no.2
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    • pp.201-204
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    • 2003
  • Glycopeptide antibiotics, teicoplanin was purified from a mutant strain of Actinoplanes teichomyceticus ATCC31121, A. teichomyceticus MSL2211. We developed a simple procedure to separate and purify the teicoplanin from the fermentation broth. Teicoplanin was purified by two-step purification system, hydrophobic adsorption and sugar affinity chromatography in combination with HPLC analysis based on the properties of hydrophobic acyl chain and sugar moiety in teicoplanin. Teicoplanin was separated from the culture broth by Diaion HP-20 and further purified by concanavalin A affinity column chromatography. As an adsorbent resin, Diaion HP-20 in broth eliminated toxic effects on growth, reduced feedback repression of teicoplanin production, and assisted In rapid recovery of teicoplanin. The teicoplanin displayed the final yield of 80% and 95% of purity.

RESEARCH PAPERS : CHARACTERIZATION OF DISSOLVED ORGANIC MATTER IN A SHALLOW EUTROPHIC LAKE AND INFLOWING WATERS

  • Kim, Yong-Hwan;Lee, Seon-Hwa;Akio, Imai;Kazuo, Matsushige
    • Environmental Engineering Research
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    • v.7 no.2
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    • pp.93-101
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    • 2002
  • The seasonal patterns of dissolved organic matter (DOM) in Lake Kasumigaura, a shallow, eutrophic lake, and serveral DOM sources in its catchment area were investigated. DOM was fractionated using three resin adsorbents into classes: aquatic humic substances (AHS=humic acid+fulvic acid), hydrophobic neutrals (HoN), hydrophilic acids (HiA), bases (BaS) and hydrophilic neutrals (HiN). The DOM produced significantly different fraction distributions depending on the origin of sample. AHS and HiA prevailed over AHS in the lake while AHS and HiA existed at almost the same concentration levels in the rivers. AHS seems to be a more dominant component in rever water than lake water. The dominance of organic acids was also observed in the DOM sources: forest stream (FS), plowed field percolate (PFP), domestic sewage (DS) and sewage treatment plant effluent (STPE).

A Study on the Hydrophobicity Modification and Physical Properties of Tencel Regenerated Fibers for Polypropylene Resin Composites (폴리프로필렌 수지 복합을 위한 텐셀 재생섬유의 소수화 표면개질 특성 연구)

  • Yoon, Songhyun;Kim, Mikyung;Lee, Eunsoo
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.258-268
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    • 2021
  • This study conducted on the introduction of recycled cellulose fibers, which are widely used in the textile industry as eco-friendly biomass materials, into polypropylene resins, which are mainly used for interior and exterior materials such as door trims and console parts of automobiles. In general, cellulose fibers can affect mechanical properties and have a lightening effect when used as a reinforcing agent. However, since cellulose fibers have hydrophilic properties and have relatively low compatibility with industrial polymer resins, they are used in combination through fiber hydrophobic surface treatment. Therefore, through this study, the reforming reaction conditions optimized in terms of hydrophobicity and workability for cellulose fibers are studied. Furthermore, polypropylene containing surface-modified cellulose fibers was prepared to compare physical properties by fiber content and study optimized content.

Formation and Removal of Trihalomethanes based on Characterization of Hydrophobic and Hydrophilic Precursors (전구물질의 소수성 및 친수성 특성에 따른 트리할로메탄의 생성과 제거에 관한 연구)

  • Jeon, Heekyung;Kim, Junsung;Choi, Yoonchan;Choi, Haeyeon;Chung, Yong
    • Journal of Korean Society on Water Environment
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    • v.24 no.1
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    • pp.123-128
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    • 2008
  • The Dissolved Organic Carbon (DOC) existing in a water includes both hydrophobic and hydrophilic substances however, most of the discussion focuses on hydrophobic substances. The hydrophobic fraction was easily removed by absorption or coagulation more than hydrophilic fraction. Therefore, control of the hydrophilic fraction is very important in water treatment process. This study is to determine the variation of DOC, the removal efficiency of DOC, and Trihalomethane formation potential (THMFP) after each stage of water treatment process by fractionating Natural Organic Matters (NOM) into hydrophobic and hydrophilic substance. DOC from raw water was fractionated at acidic pH (pH<2) using XAD 8 resin column, into two fraction : hydrophobic substance (i.e. humic substance) adsorbed on XAD 8 and hydrophilic substance which represent the organics contained in the final effluent. THMFP was carried out according to the following set condition: Cl2/DOC=4 mg/mg, incubation at $25^{\circ}C$ in darkness, pH 7 adjust with HCl or NaOH as necessary, and 72hour-contact time. THMs analyzed in this study were chloroform, bromodichloromethane, dibromochloromethan, and bromoform. Sewage was almost evenly split between the hydrophobic (56%) and hydrophilic fraction (44%). But, Aldrich humic substance (AHS) was found to contain less hydrophilics (14%) than hydrophobics (86%). The formation of THMs may depend on the source which is characterized by the composition of organic matters such as AHS and sewage. The THMFP yield of sewage and AHS were assessed as follows. The value of the THMFP reaction yield, AHS $172.65{\mu}g/mg$, is much higher than that of sewage $41.68{\mu}g/mg$. This illustrates possible significant difference in THMFP according to the component type and the proportion of organic matter existing in water source. Apparently AHS react with chlorine to produce more THMFP than do the smaller molecules found in sewage. Water treatment process may reduce THMFP, nevertheless residual DOC (the more hydrophilic substance) has significant THMFP. Further reduction in organic halide precursors requires application of alternative treatment techniques.

Investigation of the Effect of Organoclay Additives on Mechanical Properties of PF resin and MPB-OSL using Creep Behavior Analysis and IB Test

  • Kim, Yong-Sik;Kadla, John F.
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.5
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    • pp.381-389
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    • 2011
  • The effect of organoclays on the mechanical properties of cured phenol formaldehyde resin and oriented strand lumber made from Mountain Pine Beetle killed pine strands was analyzed. Three organoclays were used: a natural montmorillonite, hydrophobic organically modified 10 A, and hydrophilic organically modified 30 B. The oriented strand lumber samples were less creep deformation as well as improved internal bonding strength by adding organoclays in the order of 10 A 2% > MMT 2% > 30 B 2% > control. Furthermore, time-temperature superposition (TTS) analysis was proved to be able to predict the long-term creep behavior of MPB-OSL samples.

Study on the characterization of dissolved organic matters by XAD resin fractionation (XAD 수지분획에 의한 용존유기물질 특성 연구)

  • Park, Jeong-Min;Heo, Seong-Nam;Im, Tae-Hyo;Shin, Chan-Ki
    • Journal of environmental and Sanitary engineering
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    • v.22 no.4
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    • pp.23-32
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    • 2007
  • Changes in the characteristics of dissolved organic matter was studied at selected stations in the Nakdong river basin using physical and chemical methods. Characteristics of dissolved organic matters were analysed and assessed. Production of disinfection byproducts were also investigated. Distribution of the organic compounds according to the Molecular weight(MW) indicate that MWs higher than 100K were highest with cattle excrement wastewater and MW between 100-10K were highest with waters from forest streams. Low MW compounds (Jess than 1K) were highest with the effluents from environmental facilities. Results of resin fractionation study show that acidic hydrophobic substances(AHS) were dominant in many stations. The values were higher in the samples from mainstreams and sidestreams where the influence of organic matter is higher than the water from environmental facilities. Hydrophilic neutral substances(HoN) such as hydrocarbon, pesticides and detergents were higher in the wastewater treatment facilities. HoN values of water from the forest streams were 4.7% indicating there is no synthetic pollutant.

The feature of Microcapsule Involving Ultraviolet Rays Absorbent

  • Ueda, Yuka;Segawa, Akihiro;Murakoshi, Noriyuki;Hayashi, Natsuko;Yoshioka, Masato
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.417-430
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    • 2003
  • A new method was developed to prepare microcapsules involving hydrophobic components. A totally new "silicone-resin-polypeptide" was used as the wall materials. The polypeptide was made by hydrolysis of collagen and silk protein and so on, and that was combined with silicone. This microcapsule was easily prepared from silicone-resin-polypeptide in water solution. The ratio of encapsulation in the microcapsule was not only high level as 90%, which had never been reached, but also the particle size could be controlled to obtain very small size (average particle size: 2${\mu}{\textrm}{m}$). Moreover, these microcapsules were resistant to high shearing forces and were stable over a long time period. This stable microcapsule was not crushed in pressure with finger spreading, so the core materials hardly touch the skin directly. Application in cosmetics by using microcapsule involving UV absorbents (2-ethylhexy1-4-methoxycinnamate (OMC) and 4-tert-butyl-4' -methoxydibenzoyl-methane (BMDBM)) was examined. It was possible to apply organic UV absorbents in water-rich formulations without any surfactant by using this microcapsule. This formulation demonstrated a good moisturizing and soft skin feel. Therefore, the microcapsule was applied to hair care products. As a result, the sunscreen hair lotion with microcapsule was able to prevent from damaging and decoloring of hair color by UV rays. As just, it was suggested that this microcapsules were be widely applied in cosmetics.cosmetics.

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A Study on Characteristics of Natural Organic Matter using XAD and FTIR in Yeongsan River System (XAD 및 FT-IR을 이용한 영산강수계 광주시 유역 자연유기물질의 분포특성 연구)

  • Lee, Dong-Jin;Chon, Kang-Min;Kim, Sang-Don;Jung, Soo-Jung;Lee, Kyung-Hee;Hwang, Tae-Hee;Lim, Byung-Jin;Cho, Jae-Weon
    • Korean Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.358-363
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    • 2011
  • This study investigated the characteristics of natural organic matter(NOM) with tXAD resin and FT-IR in the Yeongsan river system of Gwangju region. NOM fractionation by XAD 8/4 resins was used to classify hydrophobic and hydrophilic substances. FTIR was applied to classify functional groups in the structure of NOM. In the XAD investigation, most of the four site-samples were mainly hydrophilic substances. In March, hydrophobic substances were dominant in the Gwangju 1 site (GJ-1), while hydrophilic substances were dominant for the other sites. In May, samples of all four sites were hydrophilic with a vigorous activity of microorganism due to increasing temperatures. The October results were very similar with those from March. In the FT-IR investigation, most of the broad and large peaks were assigned to the aliphatic group, particularly the OH group, C-H, $C-H_2$, $C-H_3$, and C-O alcohol group. All were related to hydrophilic substances. Other peaks showed the aromatic group, particularly the C=O (Ketone) Group. As a result, there is an identification of NOM in the Yeongsan river system composing mainly of hydrophilic substances and functional groups (OH, C-H etc.) of the aliphatic compound.

Influence of Fluoro-illite on Flame Retardant Property of Epoxy Complex (에폭시 복합체의 난연 특성에 미치는 불소화 일라이트의 영향)

  • Yu, Hye-Ryeon;Jeong, Eui-Gyung;Kim, Jin-Hoon;Lee, Young-Seak
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.47-51
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    • 2011
  • In this study, illite, an environmental friendly, low cost, and high aspect ratio additive, was used to improve flame retardant property of epoxy and it was fluorinated to enhance dispersion of hydrophilic illite in hydrophobic epoxy by introducing hydrophobic functional groups. Fluorination of illite enhanced illite dispersion ill epoxy solution before curing and that in the complex after curing. These enhanced dispersions were attributed to the increased affinity of illite to hydrophobic epoxy solution induced by fluorination of illite and the increased intercalation of epoxy polymer or exfoliation of illite by epoxy curing. Hence, limited oxygen index(LOI) of fluorinated illite/epoxy complex increased by 24%, compared to that of epoxy, suggesting that the preparation of fluorinated illite/epoxy complex increased their flame retardant properties.