• Title/Summary/Keyword: hydrophilic fractions

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Characteristics of Organic Matters in the Suyeong River During Rainfall Event (강우 시 수영강 유역 내 유기물질의 특성)

  • Kim, Suhyun;Kim, Jungsun;Kang, Limseok
    • Journal of Korean Society on Water Environment
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    • v.34 no.5
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    • pp.487-493
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    • 2018
  • Urban stormwater runoff is the one of the most extensive causes of deterioration of water quality in streams in urban areas. Especially, in the Suyeong River watershed, non-point sources from urban-residential areas are the most common cause of water pollution. Also, it has been ascertained that BOD and COD as indexes of organic matter, have limitation on management of Suyeong River's water quality. In this study, changes of organic matter properties of Suyeong River from inflow of non-point source during rainfall were investigated. Fractions of organic matters were analyzed using water samples collected at two sites (Suyeong River and Oncheon Stream) during a rain event. Variations of dissolved organic carbon (DOC) concentration by rainfall were similar to flow rate change in the river. Distribution of organic matter fraction according to change of rain duration revealed that while hydrophilic component increased at initial rainfall, the hydrophobic component was similar to change in dissolved organic carbon (DOC) concentration. Also, the relative proportion of hydrophilic components in organic matter in river water increased, due to rainfall. Results of biodegradation of organic matters revealed that decomposition rate of organic matters during rainfall was higher than that of during a non-rainfall event.

Variation of Natural Organic Matter Characteristics through Water Treatment Processes (정수공정별 천연유기물질의 특성 변화)

  • Hwang, Jeong-Eun;Kang, Lim-Seok;Kim, Seung-Hyun;Yoon, Cho-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.7
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    • pp.1253-1261
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    • 2000
  • Natural organic matter (NOM) which occurs ubiquitously in both surface and ground waters, consists of both humic (i.e., humic and fulvic acids) and nonhumic components. NOM in general as well as certain constituents are problematic in water treatment. From a regulatory perspective, concerns focus upon the role of NOM constituents as disinfection byproduct (DBP) precursors. The fractionation of NOM through water treatment processes can provide insight into treatment process selection and applicability. Problematic NOM fractions can be targeted for removal or transformation. Significant source-related differences in NOM were observed among various source waters. This study found that bulk Dissolved Organic Carbon (DOC) concentration was hardly removed by oxidation process. Oxidation transformed high Molecular Weight (MW) hydrophobic fraction into low MW hydrophilic fraction. Ozone reduced s-pecific Ultraviolet Absorbance (SUVA) value more than chlorine. High MW hydrophobic fraction was effectively removed by coagulation process. About 50% of Trihalomethane Formation Potential (THMFP) was removed by coagulation process.

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Effect of the Extruded Ginseng on Antioxidant Activity (압출 성형 인삼의 항산화 활성 증강 효과)

  • Kim, Sung-Hwan
    • Journal of the East Asian Society of Dietary Life
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    • v.17 no.3
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    • pp.402-408
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    • 2007
  • This study was conducted in order to evaluate the antioxidant activity of extruded ginseng in different extracted fractions. Each of the fractions obtained from extruded ginseng and ginseng (control) were extracted with 80% ethanol, and then the lipophilic components were removed with ether while the hydrophilic components were separated with water-saturated butanol. Each of the 80% ethanol/butanol/water layers were collected and evaporated to acquire samples for tests of saponin content and antioxidant activity. The antioxidant activity of extruded ginseng fractions and ginseng fractions were determined via the oxygen radical absorbance capacity (ORAC) assay. Overall, the extruded ginseng samples harbored saponin contents of 2.2 (Rg1), 2.3 (Re), 1.2 (Rc), 1.3 (Rb2), and 2.2 (Rd) times that measured in the ginseng prior to extrusion. Antioxidant capacity was also higher, not only in the 80% ethanol/butanol which harbor a significant quantity of saponin, but also in the water fractions, which harbor relatively low quantities of saponin as compared to the control samples. All three of the fractions extracted from extruded ginseng evidence significantly higher antioxidant capacity than the controls (0.05

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Characteristics of Dissolved Organic Matter(DOM) Based on Molecular Weight Fractions and Fluorescence Properties in the Downstream Nakdong River (낙동강 하류 수역에서 분자량 크기 및 형광특성을 고려한 용존유기물질 특성)

  • Ji, Hwaseong;Kim, Mihee;Lee, Youjung;Son, Heejong
    • Journal of Korean Society on Water Environment
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    • v.36 no.3
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    • pp.194-205
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    • 2020
  • The characteristics and behavior of dissolved organic matter (DOM) were determined by analyzing the molecular weight fractions and fluorescence properties of water samples in the downstream Nakdong River. Biogeochemical water quality parameters and fluorescent dissolved organic matter (FDOM) were analyzed at five sampling points in the downstream area of the Nakdong River January-August 2019. The molecular weight fractions of the DOM were separated by the Liquid Chromatography-Organic Carbon Detection (LC-OCD). The DOM predominantly comprised humic substances, followed by the building blocks, low molecular weight neutrals and biopolymers. The hydrophobic (aromatic) and hydrophilic properties were shown as coexisting, as most of the SUVA254nm values were under four. The FDOM was characterized as humic-like (FDOMH) with allochthonous origin and protein-like (FDOMP) with autochthonous origin; the FDOMH with autochthonous origin was also identified. The FDOMH relies on the aromaticity of the allochthonous organic matter and increases during summer. The FDOMH and FDOMP, which depend on the biodegradable dissolved organic matter from phytoplankton, were highly fluorescent in winter. The allochthonous organic matter was the dominant factor contributing to the behavior of the DOM, externally introduced to the river by rainfall. The FDOM only minimally contributed to the behavior of the DOM. It can be explained as the seasonal characteristics of the DOM, varied by the source of the organic matter.

Changes in Dissolved Organic Matter Composition in the Namhan River during a Heavy Rain Event (집중 강우시 남한강 내 용존 유기물의 성상 변화)

  • Oh, Seijin;Woo, Sungho;Hur, Jin;Jung, Myung-Sook;Shin, Hyun-Sang
    • Journal of Korean Society on Water Environment
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    • v.25 no.5
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    • pp.697-703
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    • 2009
  • In this study, changes in the composition of dissolved organic carbon (DOC) were investigated using water samples collected at a downstream site of the Namhan River near the Lake Paldang ($N37^{\circ}24^{\prime}05.33^{{\prime}{\prime}}E127^{\circ}32^{\prime}25.01^{{\prime}{\prime}}$) during a heavy rain event from July 23 to July 28, 2008. The DOC concentrations varied from 1.68 to 3.18 mg/L with the maxium value at a peak of the river water level. Each DOC sample was fractionated into three compositions including hydrophilic (Hi), hydrophobic acid (HoA) and hydrophobic neutral (HoN) fractions. The results showed that HoA was most abundant fractions, constituting 47.2~56.5% of DOC. Refractory dissolved organic carbon (R-DOC) contents were also determined by measuring the DOC concentration after 28-day dark incubation of the samples. R-DOC content was in the range from 83 to 99% of DOC and it was significantly correlated with HoA contents (r = 0.91, p<0.005), while it did not exhibit such a good correlation with the fractions of Hi and HoN (p>0.02). Our results suggest that the HoA, which is associated with humic substances, may be a major composition of refractory organic matters in rivers during storm events.

Potential of Benthic Diatoms Achnanthes longipes, Amphora coffeaeformisand Navicula sp. (Bacillariophyceae) as Antioxidant Sources

  • Lee, Seung-Hong;Karawita, Rohan;Affan, Abu;Lee, Joon-Baek;Lee, Ki-Wan;Lee, Bae-Jin;Kim, Dong-Woo;Jeon, You-Jin
    • ALGAE
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    • v.24 no.1
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    • pp.47-55
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    • 2009
  • Recently, interest in plant-derived food additives has developed natural antioxidants, in order to alternate syn-thetic antioxidants with several disadvantages. In the present study, different organic fractions from solvent parti-tions of 80% methanol extract from Jeju benthic diatoms, Achnanthes longipes, Navicula sp. and Amphora coffeaeformis was assessed for their potential antioxidant effects. Among the solvent fractions tested, n-hexane (80.4%) and 80% methanol extract (76.6%) from A. longipes, chloroform (63.2%) from Navicula sp. and n-hexane (67.4%) from A. cof-feaeformis were effective in DPPH free radical scavenging. Fractions of chloroform (53.4%) and n-hexane (53.1%) from A. longipes exhibited higher activities on $H_2O_2$ scavengin. Fraction of n-Hexane from A. longipes exhibited the highest hydroxyl radical scavenging activity and NO. scavenging activity (56.5% and 75.6%, respectively). Aqueous residue from A. coffeaeformis (75.6%) showed the highest metal chelating effect. chloroform and ethyl acetate frac-tion of all the diatoms exhibited significant antioxidant activities in lipid peroxidation inhibitory activity. In particu-lar, both chloroform and the ethyl ecetate fraction from A. longipes and A. coffeaeformis exhibited lipid peroxidation inhibitory activity significantly higher than that of $\alpha$- tocopherol. These data suggest that the Jeju benthic diatoms tested are rich in hydrophilic and hydrophobic antioxidative compounds with different antioxidative properties that can be applied in food industry.

A Rapid Separation of an Edible Panaxadiol and Panaxatriol in Ginseng Saponins by Benzene Ethylene Resin Adsorption (벤젠 에틸렌 수지 흡착에 의한 인삼의 Panaxadiol과 Panaxatriol의 신속한 분리)

  • Kim, Cheon-Seok;Jeong, Seung-Il;Lee, Yong-Gu
    • Journal of Ginseng Research
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    • v.22 no.3
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    • pp.211-215
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    • 1998
  • A rapid separation of an edible panaxadiol (PD) and panaxatriol (PT) in ginseng saponins has been investigated by benzene ethylene resin adsorption method. Briefly, powdered red ginseng was extracted with water. The obtained ginseng extract were dissolved in suitable volume of distilled water, and adsorbed on the benzene ethylene resin with 200 folds water of the resin weight. Sugars and hydrophilic character compounds not absorbed were washed with water, and eliminated by 10-fold water of the resin weight. An edible panaxadiol and panaxatriol can be perfectly separated from ginseng saponins with the fractions below 40% aqueous ethanol and over 45% as an fluent.

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Deer Antler Extract Selectively Suppresses Hyphal Growth in Dimorphic Fungus, Candida albicans

  • Park, Hyun-Sook;Jeon, Gil-Ja;Choi, Won-Ja
    • Journal of Microbiology and Biotechnology
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    • v.8 no.3
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    • pp.291-294
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    • 1998
  • Transfer of Candida albicans grown in Sabouraud medium to the RPMI medium induces the transition from a nonpathogenic yeast form to a pathogenic hyphal form. This transition was severely inhibited in a dose-dependent manner when deer antler extract was added to the RPMI medium in a nontoxic range (up to $500{\mu}g$). In that range, deer antler extract inhibited the hyphal transition and cell growth, whereas no effect was observed on the yeast growth. When hydrophobic or hydrophilic fractions were prepared by detergent-solubilization of deer antler extract, the hydrophobic fraction showed a large degree of inhibition of the hyphal growth in Candida albicans. Neither fraction affected the growth in the yeast form. The pattern of chitin localization in the culture of the yeast form grown in RPMI in the presence of deer antler extract was confirmed by calcofluor staining and this exhibited strongly the suppression of hyphal transition.

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Wetting Behavior and Evaporation Characteristics of Nanofluid Droplets on Glass Surfaces (나노유체 액적의 젖음거동 및 증발 특성)

  • Shin, Dong-Hwan;Lee, Seong-Hyuk
    • Journal of ILASS-Korea
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    • v.17 no.1
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    • pp.9-13
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    • 2012
  • This study investigates experimentally evaporation characteristics of nanofluid droplets containing 50 nm alumina($Al_2O_3$) particles and the wettability changes on a hydrophilic glass surfaces. From the captured digital images by using a CMOS camera and a magnifying lens, we examined the effect of particle concentration on droplet evaporation rate which can be indirectly deduced from the measured droplet volumes varying with time. In particular, with the use of a digital image analysis technique, the present study measured droplet perimeters and the contact angles to study the wetting dynamics during evaporating process. In addition, we compared the measured total evaporation time with theoretically estimated values. It was found that as the volume fractions of nanofluid increased, the total evaporation time and the initial contact angles decreased, while the droplet perimeters increased.

Suppressive Effects of Coumarins on Pumpkin Seedling Growth and Glutathione S-Transferase Activity

  • Hossain, Md. Daud;Li, Jing;Guo, Shirong;Fujita, Masayuki
    • Journal of Crop Science and Biotechnology
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    • v.11 no.3
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    • pp.187-192
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    • 2008
  • The effects of some coumarins(coumarin, 7-hydroxycoumarin, scopoletin and esculetin) were investigated on pumpkin(Cucurbita maxima Duch.) seedlings and on pumpkin glutathione S-transferases(GSTs). Coumarin and esculetin suppressed the growth of seedlings, especially the elongation of roots as well as hypocotyls. Among the compounds tested, only esculetin inhibited the activity of a particular pumpkin GST by 50%, CmGSTU3 toward 1-chloro-2, 4- dinitrobenzene(CDNB) and at a concentration of 22 ${\mu}M$. Both ethylacetae(EtOAc) and water fractions in pumpkin seedlings and different organs of one-month-old pumpkin plants contained esculetin or similar hydrophobic fluorescent substances as well as hydrophilic substances, which showed different degrees of inhibitory effects on CmGSTU3 activity.

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