• Transactions of the Korean hydrogen and new energy society
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• v.29 no.6
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• pp.570-577
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• 2018

Composite pressure vessels made through filament winding are widely used in various fields. Numerous studies regarding composite pressure vessels have been conducted in the automotive industry to improve the space efficiency of trunks as well as the fuel efficiency. Compared with steel liquefied petroleum gas (LPG) vessels used in the conventional LPG vehicles, the use of type 4 composite pressure vessels has advantages in terms of reduction of the weight of vehicles. This study focused on development of type 4 composite pressure vessels that can be installed in the spare tire well. Those type 4 composite pressure vessels are designed with torispherical dome shapes instead of geodecis dome shapes because of the space limitation. To reduce deformation due to the stresses in the axial direction of the vessels, thereby securing the safety of the container, the reinforcing bar concept was applied. A structural analysis software, ABAQUS, confirmed the effect of the reinforcing bar on the axial deformation through the type 4 composite pressure vessel. As a result, the final winding angle of the composite layer was analyzed by applying $26^{\circ}/28^{\circ}/26^{\circ}/28^{\circ}/26^{\circ}/88^{\circ}$ The tensile stress was 939.2 MPa and the compressive stress was 249.3 MPa.

• Composites Research
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• v.21 no.1
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• pp.1-7
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• 2008

Composite vessels for high pressure gas storage are commonly used these days because of their competitive weight reduction ability maintaining strong mechanical properties. To supplement permeability of composite under high pressure, it is usually lined by metal, which is called a Type 3 vessel. However, it has many difficulties to design the Type 3 vessel because of its complex geometry, fabrication process variables, etc. In this study, therefore, GUI (graphic user interface) optimal design code for Type 3 vessels was developed based on semi-geodesic algorithm in which various factors of geometry and fabrication variables are considered and genetic algorithm for optimization. In addition, hydrogen vessels for 350/700 bar that can be applied to FCVs(fuel cell vehicles) were designed using this code for verification.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.150-154
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• 2004

Gas explosion characteristics of hydrogen and liquefied petroleum gas(LPG) were measured in 6L cylindrical vessel, and experiment for explosion to fire transition phenomena of the gases were carried out using the 270L vessel. Explosion characteristics were measured using the stain type pressure transducer and explosion to fire transition phenomena was analyzed with the hish-speed camera. Base on the experiment, it was found that explosion pressure was most high slightly above the stoichiometric concentration, and explosion pressure rise rate and flame propagation velocity were proportional to the combustion velocity. And we find that those kind of explosion characteristics affect the explosion-to-fire transition, in addition, explosion flame temperature, flame residence time, are important parameters in explosion-to-fire transition.

• Nuclear Engineering and Technology
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• v.23 no.2
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• pp.183-199
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• 1991

Transient response of temperature distributions in a Pressurized Water Reactor (PWR) pressurizer vessel wall for the Inadvertent Auxiliary Spray transient has been analyzed with conservatism accounted for the resulting thermal stresses in the regions of the vessel wall which are wetted by the spray water droplets. In order to determine the forced convective heat transfer coefficient at the inner boundary surface of vessel wall where the droplets impinge on and flow down, the transient temperatures of spray droplets when they reach the inner surface of the vessel wall after travelling from the spray nozzle through the pressurizer interior space occupied with the saturated steam-noncondensable hydrogen gas mixture have been predicted. The transient temperature distributions in the vessel wall have been obtained by using the finite element method, and the typical results have been provided. It has been shown that the results of thermal analysis are consistent with representation of the input transient and have plausible physical meaning.

• Transactions of the Korean hydrogen and new energy society
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• v.13 no.2
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• pp.151-158
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• 2002

The hydorgen storage alloys were produced by melting in arc melting furnace and then solution heat treated at $1,100^{\circ}C$ followed by pulverization. The chemical analysis on the samples showed that the major elements of misch metal(Mm) were La, Ce, Pr and Nd with impurity less than 1wt.%. X-ray diffraction indicated that the structure for these samples were a single phase of hexagonal with $CaCu_5$ type. Compared to the initial particle size $100{\sim}110{\mu}m$, the many fine cracks were found and particle size decreased to $14{\mu}m$ for $MmNi_{4.5}Mn_{0.5}$ after hydriding/dehydring test run. To activate the sample the vessel filled with hydrogen storage alloys was first evacuated for for at $70^{\circ}C$ and then treated for 10.5hr under hydrogen pressure of 20atm for $MmNi_{4.5}Mn_{0.5}$ alloy. The experimental data showed that the hydrogen storage alloy of $MmNi_{4.5}Mn_{0.5}$ had superior adsorption and description properties within a temperature rang of $40^{\circ}C{\sim}80^{\circ}C$ and also they had a good P-C-T curve.

• Nuclear Engineering and Technology
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• v.45 no.3
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• pp.401-414
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• 2013

HTR50S is a small modular reactor system based on HTGR. It is designed for a triad of applications to be implemented in successive stages. In the first stage, a base plant for heat and power is constructed of the fuel proven in JAEA's $950^{\circ}C$, 30MWt test reactor HTTR and a conventional steam turbine to minimize development risk. While the outlet temperature is lowered to $750^{\circ}C$ for the steam turbine, thermal power is raised to 50MWt by enabling 40% greater power density in 20% taller core than the HTTR. However the fuel temperature limit and reactor pressure vessel diameter are kept. In second stage, a new fuel that is currently under development at JAEA will allow the core outlet temperature to be raised to $900^{\circ}C$ for the purpose of demonstrating more efficient gas turbine power generation and high temperature heat supply. The third stage adds a demonstration of nuclear-heated hydrogen production by a thermochemical process. A licensing approach to coupling high temperature industrial process to nuclear reactor will be developed. The low initial risk and the high longer-term potential for performance expansion attract development of the HTR50S as a multipurpose industrial or distributed energy source.

• Journal of Platform Technology
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• v.10 no.4
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• pp.3-10
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• 2022

In this study, damage resulting from internal flaws was investigated by finite element analysis for the safety evaluation of a non-destructive testing platform for hydrogen pressure vessels. A specimen was modeled and calculated using finite element analysis to determine material properties in accordance with the parameters of the composite material in order to assess the safety of the Type 4 hydrogen pressure vessel. Through this, flaws in the hydrogen pressure vessel were modeled, and test conditions were provided in accordance with rules to look into whether there was safety. Delamination, foreign object, and vertical cracks were modeled for internal flaws, and damage was examined in accordance with failure criteria. As the delamination defect approached the interior of the hydrogen pressure tank, it became more likely to cause damage. Additionally, as the crack depth grew in the case of vertical cracks, the likelihood of crack propagation rose. On the other hand, it was anticipated that the foreign item defect would suffer more damage from the outside in. A non-destructive testing platform will be used to assess the safety of fuel cell vehicles that are already in operation in future research.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2022.11a
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• pp.158-159
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• 2022

Due to the climate crisis, various environmental regulations including greenhouse gas reduction are in effect. This is not limited to any specific industry sector, but is affecting the entire industry worldwide. For this reason, the IMO and governments of each country are announcing strategies and policies related to the shipbuilding and shipping industries. The current regulations can be partially resolved through additional facilities such as scrubbers while using existing fossil fuels, but ultimately, the emission of greenhouse gases such as CO2 from the exhaust gases generated by ships must be restricted through energy conversion. To this end, it is necessary to develop fuels that can replace traditional fuels such as oil and natural gas. Among them, hydrogen is attracting attention as a clean energy that does not emit pollutants when used as a fuel. However, hydrogen has a wide explosive range and a fast dispersion speed, so research on this is necessary. Therefore, in this paper, when hydrogen leakage occurs in the fuel preparation room of a hydrogen-powered ship, the trend was analyzed and the ventilation characteristics were investigated.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.12
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• pp.1497-1502
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• 2013

When using hydrogen gas as an ecofriendly energy sources, it is necessary to conduct a safety assessment and ensure thereliability of the hydrogen pressure vessel against hydrogen embrittlement expected in the steel materials. In this study, by applying the in-situ SP test method, the gas hydrogen embrittlement behaviors in SA372 steel, which is commonly used as a pressurized hydrogen gas storage container, were evaluated. To investigate the hydrogen embrittlement behavior, SP tests at different punch velocities were conducted for specimens with differently fabricated surfaces at atmospheric pressure and under high-pressure hydrogen gas conditions. As a result, the SA372 steel showed significant hydrogen embrittlement under pressurized hydrogen gas conditions. The effect of punch velocity on the hydrogen embrittlement appeared clearly; the lower punch velocity case indicated significant hydrogen embrittlement resulting in lower SP energy. The fractographic morphologies observed after SP test also revealed the hydrogen embrittlement behavior corresponding to the punch velocity adopted. Under this pressurized gas hydrogen test condition, the influence of specimen surface condition on the extent of hydrogen embrittlement could not be determined clearly.

• Analytical Science and Technology
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• v.26 no.6
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• pp.375-380
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• 2013

Ammonium biflouride ($NH_4HF_2$) digestion was studied for germanium analysis in rock and sediment by inductively coupled plasma mass spectrometry (ICP/MS). QLO-1 and SDO-1 are used for reference materials from USGS. Sediment, basalt and ball clay for GeoPT were chosen as real samples. The loss of germanium in open vessel digestion was well known which can be caused by easy transformation to volatile compounds. But ammonium bifluoride digestion could suppress loss of germanium in open vessel digestion. Germanium recovery was not influenced by hydrogen peroxide with ammonium bifluoride digestion. Furthermore, the new method was simple and rapid in germanium analysis by ICP/MS. MDL(method detection limit) was 0.015 ${\mu}g/g$ and germanium recovery was 106~128%.