• 한국수소및신에너지학회논문집
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• 제17권3호
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• pp.317-323
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• 2006

Electric conductive material should be homogeneously mixed with sulfur in sulfur electrode fabrication of lithium/sulfur battery, because sulfur is electric insulator. In this paper electrochemical properties of Li/S battery was studied with various compositions of sulfur electrodes. When content of sulfur changed from 40 wt.% to 80 wt.%, the 60 wt.% sulfur electrode showed the maximum capacity of 1489 mAh/g-sulfur. Electrochemical properties of Li/S battery using 60 wt.% sulfur was also investigated with various carbon contents. The discharge capacity changed as a function of carbon contents. The optimum composition was 25 wt.% carbon for 60 wt.% sulfur electrode.

• 한국수소및신에너지학회논문집
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• 제16권1호
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• pp.92-101
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• 2005

[ $Li_3AlH_6$ ] (5.6wt% theoretical hydrogen storage capacity) powders with and without Ti-containing dopants have been successfully synthesized by mechanochemical reaction near room temperatures from mixtures of LiH and $LiAlH_4$ powders. It has been observed that single phase $Li_3AlH_6$ could be obtained within 2-3 hours of milling, but the addition of reactive $TiCl_2\;or\;TiCl_3$ to the starting mixtures. caused partial decomposition of $LiAlH_4$ into LiCl and free Al with gaseous $H_2$. By addition of these reactive dopants to the as-synthesized $Li_3AlH_6$, this problem could be solved. The addition of 2 mol% $TiCl_2\;or\;TiCl_3\;to\;Li_3AlH_6$ decreased the decomposition start temperature up to 30-50$^{\circ}C$, while that of Ti or $TiH_2$ did not change the thermal decomposition behavior of $Li_3AIH_6$.

• 대한금속재료학회지
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• 제50권5호
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• pp.383-387
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• 2012

The activation of Mg-10 wt%$Fe_2O_3$ was completed after one hydriding-dehydriding cycle. Activated Mg-10 wt%$Fe_2O_3$ absorbed 5.54 wt% H for 60 min at 593 K under 12 bar $H_2$, and desorbed 1.04 wt% H for 60 min at 593 K under 1.0 bar $H_2$. The effect of the reactive grinding on the hydriding and dehydriding rates of Mg was weak. The reactive grinding of Mg with $Fe_2O_3$ is believed to increase the $H_2$-sorption rates by facilitating nucleation (by creating defects on the surface of the Mg particles and by the additive), by making cracks on the surface of Mg particles and reducing the particle size of Mg and thus by shortening the diffusion distances of hydrogen atoms. The added $Fe_2O_3$ and the $Fe_2O_3$ pulverized during mechanical grinding are considered to help the particles of magnesium become finer. Hydriding-dehydriding cycling is also considered to increase the $H_2$-sorption rates of Mg by creating defects and cracks and by reducing the particle size of Mg.

• 한국수소및신에너지학회논문집
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• 제5권2호
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• pp.73-79
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• 1994

The hydrogenation behavior of Ti-Ni powders prepared by mechanical alloying in a high energy ball mill have been investigated by P-C isotherm curves, DSC(differential scanning calorimetry), X-ray diffractometer, SEM(scanning electron microscope). Amorphous TiNi phase was formed after 10 milling hours. The hydrogen storage capacity gradually decreased as a function of mechanical alloying time. There appears the DSC endothermic peak due to hydrogen evolution of amorphous hydride phase.

• 한국수소및신에너지학회논문집
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• 제18권1호
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• pp.26-31
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• 2007

Hydrogen has a high potential to be a renewable substitute for fossil fuels, because of its high gravimetric energy density and environment friendliness. In particular, Magnesium have attracted much interest since their hydrogen capacity exceeds that of known metal hydrides. One of the approaches to improve the kinetic is addition of metal oxide. In this paper, the effect of $Fe_2O_3$ concentration on the kinetics of Mg hydrogen absorption reaction was investigated. $MgH_x-Fe_2O_3$ composites have been synthesized by hydrogen induced mechanical alloying. The powder synthesized was characterized by XRD, SEM and simultaneous TG, DSC analysis. The hydrogenation behaviors were evaluated by using a sievert's type automatic PCT apparatus. Absorption and desorption kinetics of Mg catalyzed with 5,10 mass% $Fe_2O_3$ are determined at 423, 473, 523, 573, 623K.

• 대한기계학회논문집A
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• 제36권8호
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• pp.829-833
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• 2012

대체천연가스(SNG)는 에너지 안보 차원에서 에너지 수급 안정화 방안의 하나로 많은 관심을 받고 있다. 또한 HCNG (또는 $H_2CNG$)는 배기가스 내의 유해 성분을 현저히 줄이고 열효율도 높일 수 있어서 내연기관이나 가정용 연료로 사용될 것으로 기대되고 있다. 그러나 SNG나 HCNG에 포함되어 있는 수소는 재료에 침투하여 그 재료의 역학적 특성을 크게 저하시키는 것으로 알려져 있다. 따라서 SNG나 HCNG를 안전하고 효율적으로 수송 공급하려면 이를 위해 운용되는 인프라의 안전성과 신뢰성 확보가 선결되어야 한다. 본 연구에서는 중공 시험편을 이용한 인장시험법을 통하여 CNG 저장용기용 저합금강이 나타내는 고압 수소 분위기에서의 인장 특성 변화에 대하여 조사하였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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• pp.203-206
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• 2005

The objective of study on composite cylinder for alternative fuel vehicle is to develop safe, efficient, and commercially viable, on-board fuel storage system for the fuel cell vehicle or natural gas vehicle that use highly compressed gaseous fuel such as hydrogen or natural gas. This study presents the whole procedure of development and certification of a type 3 composite cylinder of 207bar service pressure and 70 liter water capacity, which includes design/analysis, processing of filament winding, and validation through various testing and evaluation. Design methods of liner configuration and winding patterns are presented. Three dimensional, nonlinear finite element analysis techniques are used to predict burst pressure and failure mode. Design and analysis techniques are verified through burst and cycling tests. The full qualification test methods and results for validation and certification are presented.

• 한국수소및신에너지학회논문집
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• 제21권2호
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• pp.81-88
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• 2010

Hydrogen energy applications have recognized clean materials and high energy carrier. Accordingly, Hydrogen energy applies for fuel cell by Mg and Mg-based materials. Mg and Mg-based materials are lightweight and low cost materials with high hydrogen storage capacity. However, commercial applications of the Mg hydride are currently hinder by its high absorption/desorption temperature, and very slow reaction kinetics. Therefore one of the most methods to improve kinetics focused on addition transition metal oxide. Addition to transition metal oxide in $MgH_x$ powder produce $MgH_x$-metal oxide composition by mechanical alloy and it analyze XRD, EDS, TG/DSC, SEM, and PCT. This report considers kinetics by transition metal oxide rate and Hydrogen pressure. In this research, we can see behavior of hydriding/dehydriding profiles by addition catalyst (transition metal oxide). Results of PCI make a excellent showing $MgH_x$-5wt.% Sc2O3 at 623K, $MgH_x$-10wt.% $Sc_2O_3$ at 573K.

• Carbon letters
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• 제8권4호
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• pp.340-348
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• 2007

• Carbon letters
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• 제8권3호
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• pp.225-231
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• 2007