• Title/Summary/Keyword: hydrogen storage materials

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복합재 고압용기의 스마트 모니터링을 위한 FBG 센서의 삽입 적용성에 관한 연구 (Feasibility Study of Embedded FBG Sensors for the Smart Monitoring of High Pressure Composite Vessel)

  • 박상욱;박상오;김천곤
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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    • pp.33-36
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    • 2005
  • In this research, for the smart health monitoring of the hydrogen storage high pressure composite vessel, the feasibility study of an embedded fiber Bragg grating(FBG) sensor is carried out. To verify strain measurement in various temperature environment which is needed for the hydrogen pressure vessel, tensile test of a composite specimen with both an embedded FBG sensor and a strain gauge is made in low temperature. Before we try a real-size hydrogen storage pressure vessel, a small & cheap composite pressure vessel having the same structure is fabricated with embedded FBG sensors and tested. In the case of an aluminum liner inside the vessel, survivability of FBG sensors at the interface is lower than the other areas.

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수소센서 기술의 고찰과 최근동향 (Review and new trends of hydrogen gas sensor technologies)

  • 한상도
    • 센서학회지
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    • 제19권2호
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    • pp.67-86
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    • 2010
  • Hydrogen is emerging as clean fuel and important industrial raw materials. The hydrogen gas is not sensed by the human olfactory system, But the combustion characteristics of hydrogen is that the ignition is very easy, the propagation speed of the flame is very fast and explosion limits is a wide range of 4 %~75 %. Therefore it is extremely in danger, and the need for its leakage detection technologies is especially important in places such as a production, transportation, storage and usage. The hydrogen sensors are classified with ceramic type, semiconductor type, optical type, electrochemical type and so on. Hydrogen sensors and their technologies are reviewed in detail for materials, fabrication process, sensing characteristics, good point and faults, and production and utilization of sensors be discussed.

고압수소 저장용 Cr-Mo계 저합금강의 수소취성에 미치는 템퍼링 온도의 영향 (Effect of Tempering Temperature on Hydrogen Embrittlement of Cr-Mo Low Alloy Steels for High-pressure Gaseous Hydrogen Storage)

  • 정민섭;신희창;김상규;황병철
    • 소성∙가공
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    • 제33권3호
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    • pp.185-192
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    • 2024
  • This study examined how varying tempering temperatures affect the susceptibility of Cr-Mo low alloy steels to hydrogen embrittlement. A slow strain-rate test (SSRT) was carried out on the steels electrochemically pre-charged with hydrogen in order to examine the hydrogen embrittlement behavior. The results showed that the hydrogen embrittlement resistance of the Cr-Mo low alloy steels improved with increasing tempering temperature. Thermal desorption analysis (TDA) revealed that diffusible hydrogen content decreased with increasing tempering temperature, accompanied by a slight increase in the peak temperature. This decrease in hydrogen content was likely due to a reduction in dislocation density which served as reversible hydrogen trap sites. These findings underline the significant role of tempering temperature in enhancing the hydrogen embrittlement resistance of Cr-Mo low alloy steels.

BCC계 Ti-Cr-V 합금의 전기화학적 특성에 미치는 Mn 및 $AB_5$계 합금 첨가 효과 (Effects of the Addition of Mn and $AB_5$ Type Alloy on the Electrochemical Characteristics of Ti-Cr-V BCC Type Alloys)

  • 김종연;유정현;박충년;박찬진;최전;조성욱
    • 한국수소및신에너지학회논문집
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    • 제18권1호
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    • pp.52-59
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    • 2007
  • We investigated the effects of the addition of Mn and $AB_5$ type alloy on the electrochemical characteristics of Ti-Cr-V BCC type alloys as anode materials for Ni-MH battery. The activation behavior and discharge capacity of the BCC type alloys were significantly improved by ball-milling with the $LmNi_{4.1}Al_{0.25}Mn_{0.3}Co_{0.65}$ alloy, because the $AB_5$ type alloy acted as hydrogen path on the surface of the BCC type alloy. Among the Mn substituted alloys($Mn=0.03%{\sim}0.08%$), the $Ti_{0.32}Cr_{0.38}Mn_{0.05}V_{0.25}$ alloy ball-milled with $AB_5$ type alloy exhibited the greatest discharge capacity of $336\;mAh{\cdot}g^{-1}$. In addition, Mn substituted alloys exhibited the lower plateau pressure in P-C- T curve, the better hydrogen storage capacity and faster surface activation compared with the alloy without Mn.

부피법을 이용한 고압·극저온 수소 흡착량 측정 방식의 기본 원리 (Volumetric Hydrogen Sorbent Measurement at High Pressure and Cryogenic Condition - Basic Measurement Protocols)

  • 오현철
    • 한국수소및신에너지학회논문집
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    • 제27권4호
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    • pp.349-356
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    • 2016
  • Volumetric capacity metrics at cryogenic condition are critical for technological and commercial development. It must be calculated and reported in a uniform and consistent manner to allow comparisons among different materials. In this paper, we propose a simple and universal protocol for the determination of volumetric capacity of sorbent materials at cryogenic condition. Usually, the sample container volume containing porous sample at RT can be directly determined by a helium expansion test. At cryogenic temperatures, however, this direct helium expansion test results in inaccurate values of the sample container volume for microporous materials due to a significant helium adsorption, resulting significant errors in hydrogen uptake. For reducing this container volume error, therefore, we introduced and applied the indirect method such as 'volume correction using a non-porous material', showing a reliable cold volume correction.

IRMOF-3 의 수소 흡착 실험 및 Organic Linker 의 작용기에 따른 분자모델링 연구 (Hydrogen adsorption experiments with IRMOF-3 as a sorbent, and the molecular modeling studies on the functionalized MOFs)

  • 이은성;오유진;윤지혜;김자헌;김대진;이태범;최승훈;이준;조성준
    • 한국수소및신에너지학회논문집
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    • 제15권2호
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    • pp.108-118
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    • 2004
  • To find out rational design and synthetic strategies toward efficient hydrogen storage materials, molecular modeling and quantum mechanical studies have been carried out on the MOFs(Metal-Organic Frameworks) having various organic linkers and nanocube frameworks. The calculation results about the free volume ratio, surface area, and electron density variation of the frameworks indicated that the capacity of the hydrogen storage of MOFs was largely dependent on the specific surface area and electron localization around benzene ring rather than the free volume of MOFs. The prediction of the modeling study could be supported by the hydrogen adsorption experiments using IRMOF-1 and -3, which showed more enhanced hydrogen storage capacities of IRMOF-3 compared with the IRMOF-1's at both experimental conditions, 77K, ∠ $H_2$ 1 atm and ambient temperature, ∠ $H_2$ 35 atm.