• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.11
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• pp.1246-1251
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• 2004

This paper is investigated about the effect of carrier gas type and the humidity for generating hydrogen gas. The vibration of the water surface is more powerful with increasing applied voltage. In this experimental reactor which is made of multi-needle and plate, the maximum acquired hydrogen production rate is about 3500 ppm. In the experimental result of generating hydrogen gas by non-thermal plasma reactor, the rate of generating hydrogen gas is different with what kind of carrier gas is. We used two types of carrier gas, such as $N_2$ and He. $N_2$ as carrier gas is more efficient to generate hydrogen gas than He because $N_2$ is reacted with $O_2$, which is made from water dissociation. In comparison with water droplet by humidifier and without water droplet by humidifier, the generation of hydrogen gas is decreased in case of water droplet by humidifier. That is the result that the energy for water dissociation is reduced on water surface because a part of plasma energy is absorbed at the small water molecular produced from humidifier.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.3
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• pp.226-232
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• 2013

A compact hydrogen generation device of fuel cell system using chemical hydride storage technique was designed to fit the propulsion device requirement of a small unmanned aerial vehicle(SUAV). For high efficient, compact, and lightweight hydrogen generation control device, the Co-B catalyst hydrogen conversion rate by $NaBH_4$ aqueous solution flux is measured so that the proper amount of Co-B catalyst for maximum hydrogen generation of 100W stack was proposed. A compact hydrogen generation device is controlled by pump's on/off using its own internal pressure and consumes fuel in high efficiency through a dead-end type fuel cell. The fuel cell system has stable operation for a planed flight profile. The system operates up to maximum 7 hours and at least 4 hours for tough flight profiles.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.296-298
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• 2005

Hydrogen generation by the hydrolysis of aqueous sodium borohydride $(NaBH_4)$ solutions was studied using IRA-400 anion resin dispersed Pt. Ru catalysts and Lithium Cobalt oxide $(LiCoO_2)$ supported Pt, Ru and PtRu catalysts. The performance of the $LiCoO_2$ supported catalysts is better than the ion exchange resin dispersed catalysts. There is a marked concentration dependence on the performance of the $LiCoO_2$ supported catalysts and the hydrogen generation rate goes down if the borohydride concentration is increased beyond $10\%$. The efficiency of PtRu- $LiCoO_2$ is almost double that of either Ru-$LiCoO_2$ or Pt-$LiCoO_2$ for $NaBH_4$ concentrations up to $10\%$.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2379-2383
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• 2018

We report a facile one-pot aqueous-phase synthesis of PdAu bimetallic nanoparticles with different Pd/Au ratio. The synthesis was conducted by co-reduction of Pd and Au precursor using ascorbic acid as a reducing agent and in the presence of polyallylamine hydrochloride (PAH). By high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectrometry (EDS) analyses, we found that the synthesized nanoparticles had an onion-like core/shell/shell/shell structure with Au-rich core, Pd-rich shell, Au-rich shell, and Pd shell, respectively. We also investigated the catalytic performance of the synthesized PdAu nanoparticles toward hydrogen peroxide generation reaction.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.4
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• pp.351-362
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• 2020

Recently, renewable power is rapidly increasing globally due to extensive effort to mitigate climate change and conventional power generation industry faces new challenges. The gas turbine technology has potentials to expand its role in future power generation based on the intrinsic characteristics such as fuel diversity and fast load following ability. Hydrogen is one of the most promising fuel in terms of reducing emissions and storing variable renewable energy and replacing hydrocarbon fuel with hydrogen has become very popular. Therefore, this paper presents the core technologies to combust hydrogen added fuel efficiently in gas turbines and the analysis of domestic and international R&D trends.

• Journal of the Korean Solar Energy Society
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• v.37 no.2
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• pp.13-22
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• 2017

Two-step water splitting thermochemical cycle with $CeO_2/ZrO_2$ foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of $CeO_2/ZrO_2$ foam device depending on heat recovery of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of $CeO_2/ZrO_2$ and $NiFe_2O_4/ZrO_2$ foam devices was compared. Resultantly, the quantity of hydrogen generation increased by 52.02% when the carrier gas of Thermal-Reduction step is preheated to $200^{\circ}C$ and, when the $N_2/steam$ is preheated to $200^{\circ}C$ in the Water-Decomposition step, the quantity of hydrogen generation increased by 35.85%. Therefore, it is important to retrieve the heat from the highly heated gases discharged from each of the reaction spaces in order to increase the reaction temperature of each of the stages and thereby increasing the quantity of hydrogen generated through this.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.6
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• pp.485-489
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• 2019

Hydrogen is known to be a clean fuel which does not generate a green house gas during the combustion. However, about 8 kg of carbon dioxide is generated during the course of producing 1 kg of hydrogen through reforming, water gas shift reaction and pressure swing adsorption in order to obtain a high purity hydrogen over 99.999% by volume. In this work, carbon dioxide generation is estimated according to four kinds of natural gas compositions supplied by Korea Gas Corporation and regarding natural gas as pure methane. For the simulation of the modeling, PRO/II with PROVISION V10.2 at AVEVA was utilized and Peng-Robinson equation of state with Twu's alpha function was selected.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.215-219
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• 2004

This paper is investigated about the effect of carrier gas and humidity for generating hydrogen gas. In the experimental result of generating hydrogen gas by non-thermal plasma reactor, the rate of generating hydrogen gas is different with what kind of carrier gas is. We used two types of carrier gas, such as $N_2$ and He. $N_2$ as carrier gas is more efficient to generate hydrogen gas than He because $N_2$ is reacted with $O_2$, which is made from water dissociation. In comparison with no humidity and humidity 45[%], the generation of hydrogen gas is decreased with increasing the humidity. That is the result that the energy for water dissociation is reduced on water surface because a part of plasma energy is absorbed at the small particle produced from humidifier.

• Transactions of the KSME C: Technology and Education
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• v.3 no.4
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• pp.299-305
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• 2015

Nuclear hydrogen production technology is being developed for the future energy supply system. The sulfur-iodine thermo-chemical hydrogen production process directly splits water by using of the heat generated from very high temperature gas-cooled reactor, a typical Generation IV nuclear system. Nuclear hydrogen key technologies are composed of VHTR simulation technology at elevated temperature, computational tools, TRISO fuel, and sulfur iodine hydrogen production technology. Key technology for nuclear hydrogen production system were developed and demonstrated in a laboratory scale test facility. Technical challenges for the commercial hydrogen production system were discussed.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.4
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• pp.346-353
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• 2010

Hydrogen fueled vehicle was evaluated as one of the next-generation technology that will be able to solve the global warming, depletion of fossil fuel and etc. The practical use of hydrogen fueled vehicle, nevertheless, is being delayed more than expected schedule due to various causes. In order to promote the dissemination of hydrogen fueled vehicle, development status and obstacle factors of practical use for hydrogen fueled vehicles were reviewed and the strategy plans for dissemination promotion were proposed. Hydrogen fueled vehicles are included the hydrogen fuel cell, neat and enriched hydrogen fueled engines. The technicalness, economy, safety, cognizance, system, support and etc were considered in the strategy plans.