• Title/Summary/Keyword: hydrogen generation

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Experiment study on hydrogen-rich gas generation using non-thermal plasma (저온 플라즈마를 이용한 과 수소가스 발생에 관한 실험적 연구)

  • Wang, Hui;Wei, Wei;Zheng, MengLei;Chae, Jae-Ou;Yu, Guang-Xun
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2918-2922
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    • 2007
  • This is a report of a feasibility study on the reduction of harmful substances such as particulate matters and nitric oxides emitted from diesel engines by using a plasma reforming system that can generate hydrogen-rich gas. In this paper, an exhaust reduction mechanism of the non-thermal plasma reaction was investigated to perform its efficiency and characteristics on producing hydrogen-rich gas. Firstly, we explain briefly the chemistry of hydrocarbon reforming. The experimental system is showed in the second part. Finally, we demonstrate the feasibility of producing hydrogen using non-thermal plasma. The experimental results are focused on the influence of the different operating parameters (air ratio, inlet flow rates, voltage) on the reformer efficiency and the composition of the produced gas.

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Preliminary Structural Sizing of the Co-axial Double-tube Type Primary Hot Gas Duct for the Nuclear Hydrogen Reactor (수소생산용 원자로에서 동심축 이중관형 1차 고온가스덕트의 예비 구조정산)

  • Song, Kee-nam;Kim, Y-W
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.4 no.2
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    • pp.1-6
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    • 2008
  • Very High Temperature Gas Cooled Reactor (VHTR) has been selected as a high energy heat source for nuclear hydrogen generation. The VHTR can produce hydrogen from heat and water by using a thermo-chemical process or from heat, water, and natural gas by steam reformer technology. A co-axial double-tube primary hot gas duct (HGD) is a key component connecting the reactor pressure vessel and the intermediate heat exchanger (IHX) for the VHTR. In this study, a preliminary design analysis for the primary HGD of the nuclear hydrogen system was carried out. These preliminary design activities include a determination of the size, a strength evaluation and an appropriate material selection. The determination of the size was undertaken based on various engineering concepts, such as a constant flow velocity model, a constant flow rate model, a constant hydraulic head model, and finally a heat balanced model.

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Hydrogen Sensor and Neuromorphic Applications Using Correlated Materials (강상관계 소재를 이용한 수소 센서 및 수소 뉴로모픽 소자)

  • Oh, Chadol;Son, Junwoo
    • Ceramist
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    • v.22 no.1
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    • pp.17-26
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    • 2019
  • The metal-to-insulator transition (MIT) with external stimuli is one of the main issues in correlated oxides. The physical properties are extremely sensitive to band filling, because the MIT is attributed to the strong correlation between electrons in narrow d-band. Since hydrogen is the smallest and lightest element, it is not only likely to doped reversibly in oxides, but also acts as a dopant to provide electrons. The correlated oxides showing MIT are structurally expanded after hydrogenation, and their electrical properties are drastically changed. Researches on this phenomenon have been actively carried out to date. They are of great scientific importance, and the use of this material is very diverse, including the development of next-generation hydrogen sensor, or hydrogen-based neuromorphic devices.

Combustion Instability Modeling in a Hydrogen-Natural Gas Mixed Fuel Gas Turbine Combustor using a 3-Dimensional Finite Element Method Approach (3차원 유한요소해석 기법을 사용한 수소-천연가스 혼소 가스터빈 연소기에서의 연소불안정 해석)

  • Hong, Sumin;Kim, Daesik
    • Journal of ILASS-Korea
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    • v.27 no.1
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    • pp.36-41
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    • 2022
  • In this study, the combustion instability characteristics according to the change in the hydrogen ratio in the fuel in the single nozzle system of the hydrogen-natural gas mixed gas turbine for power generation was analyzed using a three-dimensional finite element analysis-based Helmholtz solver. This combustor shows the instability characteristics in which mode transition occurs from a mode having a low amplitude near 70 Hz to a mode having a high amplitude of 250 Hz or higher as the hydrogen fraction in the fuel increases. The current modeling results are found to reasonably predict the main characteristics of the change in measured instability frequency and growth rate with the change in fuel composition.

Antigenotoxicity and Action Mechanism of Quercetin and its Glycosides against Oxidative DNA Damage (Oxidative DNA 손상에 대한 Quercetin 및 그 배당체들의 유전독성억제효과와 작용기전)

  • 김수희;허문영
    • Environmental Mutagens and Carcinogens
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    • v.19 no.2
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    • pp.116-121
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    • 1999
  • Quercetin and its glycosides showed a strong free radical scavenging effect to DPPH radical generation. However, there were not big differences between quercetin aglycone and glycosides under experimental condition of this study. On the other hand, quercetin had pro-oxidant effect in bleomycin-dependent DNA assay. Quercetin aglycone and its glycosides, quercitrin inhibited $H_2$$O_2$- induced DNA damage in CHL cells. They also have an anticlastogenicity toward DNA breakage agent by radical generation like bleomycin. These results indicate that quercetin aglycone and its glycosides are capable of protecting the free radical generation induced by reactive oxygen species like $H_2$$O_2$. The mechanism of inhibition in hydrogen peroxide-induced genotoxicity may be due to their free radical scavenging properties. Therefore, quercetin aglycone and its glycosides may be useful chemopreventive agents by protecting of free radical generation which are involved in carcinogenesis and aging. However, quercetin and its glycosides must also carefully examined for pro-oxidant properties before being proposed for use in vivo.

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Numerical Study on High Temperature CO-Shift Reactor in IGFC (고온수소 전환 반응기에 관한 수치해석적 연구)

  • SEO, DONG-KYUN;LEE, JIN-HYANG;CHI, JUN-HWA;HONG, JIN-PYO;OH, SUK-IN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.4
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    • pp.324-330
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    • 2018
  • In this study a numerical study was conducted to show flow, temperature and gas distributions in a high temperature CO shift reactor which was designed specially for energy saving and then evaluated with the related experiment. Mole fractions of syngas at the end of the catalyst bed were predicted with various assumed pre-exponential factors, were compared with the corresponding experimental results and $10^8$ was finally selected as the value. With the selection, a base case was examined. It was calculated that the inlet duct attached asymmetrically to the CO shift reactor affects on the distribution of the upward momentum (+z directional). In addition, CO conversion ratio is achieved up to 90% in the catalyst bed and especially it reached up to 70% at the initial part of catalyst bed.

PEMFC Based Cogeneration System Using Heat Pump (히트펌프를 이용한 PEMFC 기반 열병합 발전 시스템)

  • BUI, TUANANH;KIM, YOUNG SANG;LEE, DONG KEUN;AHN, KOOK YOUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.324-330
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    • 2021
  • In recent years, polymer electrolyte membrane fuel cell (PEMFC) based cogeneration system has received more and more attention from energy researchers because beside electricity, the system also meets the residential thermal demand. However, the low-quality heat exited from PEMFC should be increased temperature before direct use or storage. This study proposes a method to utilize the heat exhausted from a 10 kW PEMFC by coupling a heat pump. Two different configuration using heat pump and a reference layout with heater are analyzed in term of thermal and total efficiency. The system coefficient of performance (COP) increases from 0.87 in layout with heaters to 1.26 and 1.29 in configuration with heat pump and cascade heat pump, respectively. Lastly, based on system performance result, another study in economics point of view is proposed.