• 제목/요약/키워드: hydration property

검색결과 146건 처리시간 0.038초

Meta Kaolin 및 Silica Fume을 이용한 고성능 고강도 시멘트 모르타르 특성에 관한 연구 (Studies on the Properties of High Performance and High Strength Cement Mortar Using Meta Kaolin and Silica Fume)

  • 정민철
    • 한국세라믹학회지
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    • 제33권5호
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    • pp.519-523
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    • 1996
  • 시멘트 수화시 생성되는 수산화칼슘은 시멘트 모르타르의 강도 및 내구성을 감소시킨다. 이에 포졸란물질인 meta kaolin 및 silica fume을 이용하여 이러한 결점을 해결하고자 하였다. Meta kailin 및 silica fume의 함량변화에 대한 수산화칼슘의 감소는 Fourier의 시차열분석에 의해 규명되었고, mela kaolin 및 silica fume을 무첨가(0%)에 비하여 10% 이상 첨가시 수산화칼슘양이 큰 폭으로 감소함을 나타내었다. 이는 meta kaolin 및 silica fume의 SiO2 성분과 시멘트의 CaO와의 포졸란반응에 의한 것으로 나타났다.

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CFRD 차부벽콘크리트의 수성수축균열 제어특성에 관한 실험적 연구 (An Experimental Study on the Control Property of PlasticShrinkage Crack for CFRD Face Slab Concrere)

  • 김완영;최세진;원종필
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.118-121
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    • 2000
  • CFRD (Concrete Faced Rockfill Dam) face slab concrete has a much capability to occur crack due to drying shrinkage, hydration heat and bas compaction etc. Because of crack of concrete induce structural problem and decrease durability of concrete, it is need to reduce crack of concrete. This is an experimental study to analyze the Control Property of Plastic Shrinkage Crack for CFRD face slab concrete. For this purpose, it was investigated and analyzed the engineering properties of plain concrete and using admixtures (polypropylene fiber, fly-ash) according to test result As the result, it was found that crack width and area of concrete using admixtures less than of plain concrete.

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시멘트 재료의 수밀성에 대한 스테아르산의 영향 (Effects of Stearic Acid on the Watertightness Properties of the Cementitious Materials)

  • 라승현;강현주;송명신
    • 한국세라믹학회지
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    • 제46권4호
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    • pp.365-371
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    • 2009
  • It is well known that the properties of concrete such as the compressive strength, water permeability, water tightness and durability are affected by micro-structure in hardened cement paste. Especially, for durability of concrete, watertightness of cementitious materials is the most critical property among various properties. Recently, many types of materials as organic and/or inorganic materials are used for watertightness of concrete. In this study, The effect of Stearic Acid at $0.5\;wt%{\sim}3.0\;wt%$ adding ratios on the hydration and watertightness property of cement were investigated. And we also discussed the changing of microstructure in hardened cement paste by addition of Stearic Acid. Cement paste with Stearic Acid showed improvement of watertightness by reducing of cement total pore volume and decomposition of Stearic Acid.

저열 포틀랜드 시멘트를 사용한 초고강도 콘크리트의 특성에 관한 연구 (An Experimental Study For Basic Property of Ultra High Strength Concrete using Belite Cement)

  • 민홍준;김지만;공민호;양동일;이한석;정상진
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.457-460
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    • 2006
  • Recently ultra high strength concrete is actively being developed and studied, and this trend is explained with the following effects. Technological effects expected from the application of ultra high strength concrete include the reduction of section, the decrease of structure mass and the improvement of workability. Belite cement has properities like low heat of hydration, excellent long term strength, and durablity without admixture. so, Belite cement is suitable for mass structure which is needed high strenghth, high fluidity and heat property. The objective of this study is to examine the suitability of mixture ratio through experiment of basic physical properties and provide materials for the field application of ultra high strength concrete.

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서중환경의 단열온도상승 특성을 고려한 고강도 콘크리트의 압축강도 특성 (Compressive Strength Properties of high strength concrete considering Adiabatic temperature rise of hot weather environment)

  • 이은경;함은영;구경모;이보경;미야우치 히로유키;김규용
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 추계 학술논문 발표대회
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    • pp.56-57
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    • 2013
  • In this study, in regard to concrete considering variety of admixture content rate, we evaluated property of adiabatic temperature rise. By setting up high temperature history, we evaluated effect to compression strength property of high strength concrete by early high temperature history. As a result, early high temperature history accelerated Hydration reaction of cement and contribute early strength development but it didn't accomplish performance objective in long-term aged.

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150MPa급 초고강도 노출콘크리트의 현장적용에 관한 연구 (A Study on Field Application of 150MPa Ultra Strength Surface-Exposed Concrete)

  • 공태웅;이수형;장재환;이한백
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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    • pp.989-992
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    • 2008
  • 본 연구에서는 선일공업(주)의 축적된 기술력을 바탕으로 초고강도(150MPa급) 콘크리트를 당사 기술 연구소 신축시 노출콘크리트에 적용함으로써, 이에 대한 사례를 소개하고자 한다. 현장적용에 앞서 실내실험 및 레미콘 배치플랜트 실험(이하 B/P Test)을 통해 콘크리트의 기초물성(슬럼프플로우, 공기량, 50cm도달시간, 경시변화, 압축강도) 및 생산성을 평가하였으며, 다음으로 실구조물과 동일한 벽체두께 거푸집종류 노출콘크리트용 콘 등을 고려하여 제작한 모의부재를 대상으로 Mock-up Test를 실시하여 충진성, 표면마감성(육안관찰) 및 수화열을 평가하였다. 그 결과 슬럼프플로우, 공기량, 50cm도달시간, 경시변화 및 압축강도는 요구조건에 만족한 결과를 보였으며, 수화열 계측결과는 온도균열지수 0.78로 유해한 균열발생을 제한할 지수를 나타냈다. 현장타설시 초고강도 콘크리트의 높은 단위용적중량으로 인해 거푸집 터짐현상이 발생하였기 때문에, 재타설시에는 재발방지를 위해 거푸집을 보강하고 타설시간을 조정하였다. 또한 노출표면의 극대화를 위해 저주파(1차) 및 고주파(2차)로 2회에 걸쳐 진동다짐을 실시하였지만 표면곰보가 발생하였다. 따라서 향후 초고강도 콘크리트를 노출콘크리트에 적용할 경우, 다양한 변수조건에 대한 체계적인 시공관리계획 및 시공방법개선이 중요할 것으로 판단된다.

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환원슬래그를 사용한 모르타르의 저온에서의 초기동해 방지에 관한 기초적 실험 (A Fundamental Experiment on Preventing Frost Damage at Early Age of Mortar in Low Temperature using Reduction Slag)

  • 민태범;문영범;김형철;최현국;김재영;이한승
    • 한국건축시공학회지
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    • 제16권1호
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    • pp.1-7
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    • 2016
  • 본 연구에서는 $-5^{\circ}C$이하에서도 가열 양생이 없이 수화 반응시 수화열이 높게 발생되는 환원슬래그를 시멘트 분체와 치환사용 하여 영하의 온도에서도 콘크리트의 자체 발열로 인해 압축강도를 재령 3일 이내 5MPa를 발현시켜 초기동해를 방지시키는 것이 최종 연구의 목적이며 이에 대하여 환원슬래그의 물리적 특성 평가와 열적 특성 평가를 실시한 결과 환원슬래그는 높은 수화열을 발생시키기 때문에 저온에서도 압축강도 발현이 우수함을 알 수 있었다. 이는 환원 슬래그의 성분 중 $C_{12}A_7$$C_3A$에 의해 수화열이 높게 발생됨 저온에서도 압축강도가 발현되는 것으로 나타났다. 하지만 환원슬래그 단독 치환하였을 경우 $SO_3$함량 부족으로 급결이 발생하는 것을 알 수 있었다. 급결을 방지하기 위해서는 석고의 사용이 필수적으로 사용되어야 한다. 따라서 본 연구 결과 환원슬래그와 석고를 3성분계로 사용하였을 경우 저온에서도 재령 3일에서 5MPa 압축강도를 나타나는 것으로 보아 저온에서도 콘크리트의 초기동해를 방지할 수 있을 것으로 판단된다.

요소-수용성 유황 혼화제가 콘크리트 압축강도 및 건조수축에 미치는 영향 (Influence on Compressive Strength and Drying Shrinkage of Concrete with Urea-Water Soluble Sulfur Admixture)

  • 박재규;한상훈;홍기남;조용인
    • 한국안전학회지
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    • 제31권5호
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    • pp.74-81
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    • 2016
  • This paper presents an experimental study to ivestigate mechanical property of concretes according to addition of urea and urea-water soluble sulfur contents. Urea was added at 5~20% replacement by weight of water, and water soluble sulfur was used at 2%, 4% replacement by weight of cement. The setting times, the hydration heat, the compressive strength, and the drying shrinkage, were measured on concretes with single and binary admixtures. From the test result, it was confirmed that the hydration heat of urea-water soluble sulfur was lower than that of normal concrete by $10.1^{\circ}C$, and the drying shrinkage of urea-water soluble sulfur concrete was more excellent than normal concrete. In the case of urea of 5%, Compressive strength were improved with an increase of water soluble sulfur contents. The urea-water soluble sulfur used in this research can be used as improvement materials for drying shrinkage and compressive strength.

수밀 콘크리트용 규불화염계 무기 조성물을 첨가한 콘크리트 수밀성 및 균열저감 특성 (Watertightness and Crack Reduction Property of Concrete added Fluosilicate Salt Based Inorganic Compound for Watertight Concrete)

  • 김도수;길배수;최세진;박민용;이성연;여병철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2004년도 학술대회지
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    • pp.33-38
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    • 2004
  • This study was performed to know watertightness and reduction effect and crack occurred by hydration heat, restraint of multiplication of hydration heat, through mechanical test, strength test and crack control test using fluosilicate salt based inorganic compound made from by-product during phosphoric acid manufacturing process. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.5-2.0\%$ of adding ratio of fluosilicate salt based inorganic compound. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. Effect of crack reduction was evaluated by length, drying shrinkage as well as stress change of hardened concrete at unrestraint/restraint state and also elucidated crack pattern on the concrete surface. It is ascertained that characteristics of crack resistance and watertightness for concrete was improved by an adequate addition of fluosilicate salt based inorganic compound.

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시멘트 유동성과 물성에 미치는 영향인자에 관한 연구 (A Study of Effecting Factor in the Reology and Physical Properties of Cements)

  • 엄태선;최상흘
    • 한국세라믹학회지
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    • 제34권10호
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    • pp.1027-1036
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    • 1997
  • The reology and several physical properties of cements are studied by varying the different mineral composition and particle size distribution(PSD) of cements with closed circuit ball mill for high workability, low heat of hydration, and high strength. In this study, we found that the workability of concretes is related to the viscosity of cement, and affects to strength. Here, this workability is affected by mineral composition (C3A) and the PSD. Especially, rosin-rammer index and 44${\mu}{\textrm}{m}$ residue in the PSD of cements are affected to water demand, casting property, slump loss, strength of cements. From the above results, the conditions of cement for high workability, low heat of hydration and high strength are to use low C3A clinker, 5-10% slag addition, and to grind cement below 0.7 rosin-rammer index, above 3.5-4.5% 44 ${\mu}{\textrm}{m}$ residue, 4000$\pm$100 $\textrm{cm}^2$/g blaine. Such cements are, therefore, supurior to super low heat cement and slag-blended cement in comparing the physical properties of strength, slump, slump-flow, adiabetic temperature, etc.

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