• Title/Summary/Keyword: hydration effect

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Effect of Pretreatment on the Dissolution of Aluminum Alloy during Hydration Process (수화과정에서 전처리가 알루미늄 합금의 용출에 미치는 효과)

  • Lee, Byoung-Gu;Lee, Hoyeon;Tak, Yongsug
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.215-219
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    • 2013
  • Aluminum alloy(3003) can be dissolved during hydration process with hot tap water. In order to increase the stability of aluminum alloy, it was pretreated with anodization and phosphoric acid before hydration process. The effect of pretreatment on the surface property changes was analyzed with X-ray Photoelectron Spectroscopy (XPS) and Inductively Coupled Plasma-Optical Emission Spectrometer (ICP-OES) and their results supported that the increase of hydroxyl group (-OH) on the surface formed during anodization and phosphorous acid treatment prevented the dissolution of aluminum alloy during hydration process at high temperature.

The Effects of the Heavy Metal Ions on the Hydration and Microstructure of the Cement Paste (중금속이온이 시멘트의 수화 및 미세구조에 미치는 영향)

  • 김창은;이승규
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.967-973
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    • 1993
  • The effect on the hydration of cement was that Cu and Pb reacted with alkali to form soluble hydrates at theinitial stage and then there followed a slow reaction forming insoluble metal hydroxides. These hydroxides were deposited on the surface of cement particles providing a barrier against further hydration. But as a slow reaction continued, the insoluble layers were eventually destroyed and the hydration reaction resumed. Thereafter, another retardation occured by restricting the polymerization of silicates, shown by FT-IR spectroscopy analysis. In the case of Cr, as its reaction with cement caused H2O, the coordinator of Cr complex, to replace or polymerize with OH-, the formation of Cr complex promoted the leakage of OH- and increased the heat of dissolution. So the total heat evolution during hydration was larger than that in the case of Pb or Cu. The retarding effect of heavy metal ions was in the order Pb>Cu>Cr.

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Effect of Hydration Heat Evolution on Autogenous Shrinkage of High Strength Concrete (초기수화발열이 고강도콘크리트의 자기수축특성에 미치는 영향)

  • 정해문;도변박지;하야도륭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.95-100
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    • 2003
  • The shrinkage of high strength/high performance concrete is very important property for the good working of a structure since it very often generates early age cracking due to thermal and autogenous shrinkage. Autogenous shrinkage occurs as a result of internal moisture depletion due to hydration and temperature-induced effects. The level of autogenous shrinkage occurring due to hydration also depends on temperature history at very early age. It is necessary that effect of temperature on autogenous shrinkage is investigated since the stress generated due to autogenous shrinkage is quantified. In this study, Effect of hydration heat evolution on autogenous shrinkage of high strength concretes with W/C=25-40% was investigated.

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Reducing effect for Hydration Heat of High-Strength Concrete according to Admixture Types and Replacement Ratios (혼화재 종류 및 대체율에 따른 고강도콘크리트의 수화열 저감 효과)

  • 유범재;김용로;최세진;김상윤;김상규;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.409-414
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    • 2001
  • The hydration of cement paste occurs when the cement is mixed with water. During the hydration, hydration heat causes the thermal stress depending on the size of concrete and the cement content. Especially in the high-strength concrete, we must give care to the concrete due to its large cement content. In this study, conduction calorimeter and concrete insulation hydration heat meter were used to investigate the hydration heat characteristics of cement and concrete. To reduce hydration heat of high-strength concrete, several types of replacement of fly-ash and blast-furnace slag powder were used in this experiment.

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An Experimental Study on the Characteristics of Hydration Heat Generation of Low Heat Concrete with Binder Types (결합재 종류에 따른 저발열 콘크리트의 수화발열 특성에 관한 실험적 연구)

  • Kim, Yong-Ro;Jung, Yang-Hee;Lee, Sang-Ho;Kim, Do-Su;Khil, Bae-Su;Han, Seung-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.417-420
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    • 2006
  • Recently, the attention is paid to the problem of thermal crack by hydration heat according to the increase of high strength and mass concrete structures. At this point, various research has been carried out for the control of hydration heat in high strength and mass concrete. As a part of the research, it was investigated application of hydration heat reduction agent (HR) for the control of thermal crack by hydration heat in this study. To investigate the application, it was selected HR which can reduce hydration heat of concrete with effect in series I and II. Also, it was investigated the characteristics of hydration heat generation of low heat concrete using HR with binder types in seriesIII.

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Hydration Heat and Strength Properties of Mass Concrete Transfer Girder (고강도 매스 콘크리트-보의 수화열 및 강도특성)

  • Kang, Yeon-Woo;Kim, Gyu-Yong;Kim, Soon-Mook;Kim, Soo-Bong;Han, Jang-Hun;Jung, Jae-Yung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.28-29
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    • 2013
  • When concrete was hardened, it should had considered a crack to make internal stress by hydration heat. For control of crack, admixture was use to change cement because hydration heat was effect to cement. High strength mass concrete had much hydration heat with high volume of cement. It was necessary to reduce hydration heat in construction method. In this study, it evaluates hydration heat, compressive strength of transfer concrete girder regard to field construction type such as separation, whole etc. Also, we test compressive strength of concrete with core and mold specimen.

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An Analysis on the Effect of Reinforced Steel Bar to the Beat of Hydration in the Concrete Structures (철근의 영향을 고려한 콘크리트 구조물의 수화열 해석)

  • 양옥빈;윤동용;민창식
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.35-40
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    • 2002
  • This paper presents a numerical study on the heat of hydration of reinforced concrete with different steel ratio. And this study intends to determine the effect of the steel on the variation of temperatures during hydration. In order to do this, the thermal analyses of the pier-foundation models were carried out using the finite element analysis program, ADINA. As the steel rate increased, the maximum temperature and the internal-external temperature difference decreased.

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Properties of Hydration and Strength of Sol-gol Derived Fine Particle in the System $CaO-P_2O_5-SiO_2$ (졸겔법에 의한 $CaO-P_2O_5-SiO_2$계 미세분말의 수화 및 강도특성)

  • 이형우;김정환
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1231-1239
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    • 1994
  • In this study, gel powder which had relatively high hydration reactivity in CaO and P2O5 rich composition of CaO-P2O5-SiO2-H2O system was prepared by sol-gel process and its hydrated specimen was manufactured. The it was investigated to appropriate calcination temperature in sol-gel process which hydrated specimen of gel powder have proven to strength and the effect of factors influenced strength in hydration process. The major product of before and after hydration reaction was hydroxyapatite, and crystalline phase of C-S-H was already formed during gelation process. After hydration reaction of pressed specimen, crystalline phase of C-S-P-H was formed. It was hydrated product of silicocarnotite (5CaO.P2O5.SiO2). Gel phases of C-S-H and C-S-P-H occured as a result of partial substitution of amorphous silica by P2O5 was formed. The strength of hydrated hardened body is developed by strong bonding and bridging between the gel phases of C-S-H or C-S-P-H and the crystalline products such as hydroxyapatite, Ca(OH)2 C-S-H and C-S-P-H. In addition, the ultrafine gel powder have an great effect on increase of hydration reaction.

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The Correlation Analysis of Fluid Intake, Skin Hydration and Skin pH of College Students (대학생의 수분섭취, 피부 수분보유도 및 피부 pH와의 관계)

  • Kim, Nam-Jo;Hong, Hae Sook
    • Journal of Korean Biological Nursing Science
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    • v.17 no.2
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    • pp.132-139
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    • 2015
  • Purpose: The purpose of this study was to verify the correlation analysis between fluid intake on skin hydration and pH of college students. Methods: The subjects were 129 female nursing students in D city. Data were collected by a self-administered questionnaire, using a skin moisture checker and skin pH meter on faces, hands, and feet. The collected data were analyzed by descriptive statistics, t-test, ANOVA, and Pearson correlation analysis, using SPSS WIN, 20. Results: The daily fluid intake was composed of 57% pure water, 21% caffeinated beverages, 22% non-caffeinated beverages. There were significant differences in average skin hydration on the three body parts according to pure water, caffeinated beverages, and non-caffeinated beverages; however, there was no significant difference measured by fluid intake. There was a significant positive correlation between fluid intake and skin hydration: between pure water and skin hydration. There was significant negative correlation between caffeinated beverages and skin hydration: between non-caffeinated beverages and skin hydration. Conclusion: The results suggest that fluid intake, pure water, caffeinated beverages, and non-caffeinated beverages have an effect on skin hydration and pH. Therefore, it is good to increase the amount of fluid intake but, it is recommended to increase the amount of intake of pure water rather than beverages to improve skin status.

Dispersion Effect of Hydration Heat in Mass Concrete Using Embedded Heat Pipe (매입형 히트파이프를 이용한 매스콘크리트 수화열 분산 효과)

  • Kim, Myung-Sik;Youm, Chi-Sun;Baek, Dong-Il
    • Journal of Ocean Engineering and Technology
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    • v.23 no.4
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    • pp.85-90
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    • 2009
  • Although most of existing hydration heat control methods show a certain degree of hydration heat control, generally, there are many problems as mentioned above. Therefore, our laboratory previously developed a hydration heat control method using an exposed heat pipe, which solves most of these problems and simultaneously displays excellent hydration heat control. Unfortunately, even this method had some problems such as the processing, transport, and assembly of heat pipes, and the surface treatment of a cut plane after pouring, and hardening concrete. Therefore, in this study, a hydration heat control method using an embedded pipe has been developed with the expectation that this method solves those problems in hydration heat control using an exposed heat pipe. As a result of the experiment, the peak temperature of ECHP and ICHP specimen about $4.5{\sim}6.5^{\circ}C$ than the OPC specimen and the probability of thermal cracked generated in ECHP and ICHP specimen decreased up to $13{\sim}20%$. Finally, it was confirmed in this study that the hydration heat control method using an embedded heat pipe is significantly more superior and cost effective than the existing method of an exposed one.